CN109693073A - A kind of production method of clad steel plate - Google Patents
A kind of production method of clad steel plate Download PDFInfo
- Publication number
- CN109693073A CN109693073A CN201710983255.8A CN201710983255A CN109693073A CN 109693073 A CN109693073 A CN 109693073A CN 201710983255 A CN201710983255 A CN 201710983255A CN 109693073 A CN109693073 A CN 109693073A
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- clad
- milling
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- steel plate
- production
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
- B23P15/00—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
Abstract
The present invention provides a kind of production methods of clad steel plate, production method: milling processing is carried out to a surface of clad sheet steel and Substrate sheet respectively, opposite be stacked together after preheated to 150 DEG C~200 DEG C in milling face is directly welded the surrounding of contact surface, φ 5~30mm hole is stayed at solder up, using assembly of the present invention welding without being vacuum-treated, production cost is low, simple production process, production efficiency and high reliablity.
Description
Technical field
The invention belongs to field of material processing more particularly to a kind of clad steel plate and its production methods.
Background technique
The main method of production nickel-base alloy composite plate has explosion method and rolling at present, for composite pipe aspect, machine
Also comparing for tool composite algorithm application is more.The nickel-base alloy composite plate produced using explosion method, specification are very restricted,
It is difficult to meet user's requirement, due to the operation operation of big ability milling train, the nickel-base alloy composite plate of explosion method preparation is only certain
Special dimension is used, and has had already appeared the trend being eliminated.Mechanical composite algorithm is that nickel-based alloy pipe and pipeline steel tube is direct
It is nested together, has no be fixedly connected between the two, application field is extremely limited.In recent years, more and more scholars are directed to and roll
Preparation method prepares the compound plate technique of nickel-base alloy and is studied.
Highly corrosive oil gas field generallys use corrosion resistant alloy even nickel-base alloy during mining operations and oil-gas transportation
Pipeline.Significant raising is not only caused in terms of economic cost, while great limitation is also received on overall performance.It is general
Lead in anti-corrosion tubing and is used as part against corrosion and only accounts for that one third or so is even lower, and rest part is both used as structural support, if
All using corrosion resistant alloy production, it will cause the significant wastages of resource.No matter from economic aspect or aspect of performance, corrosion resistant alloy
The research and development application of multiple tube becomes one of the effective way to solve the above problems.Welding sandwich rolling process is to prepare bimetallic to answer
Condensation material is most economical, efficient manufacturing method, especially produces the composite plate of big specification, and product size precision is high, raw
It produces that high-efficient and significant change will not occur for chemical component between cladding and parent metal, its performance is influenced smaller.It uses herein
Vacuum electron beam welding assembly+hot rolling technique is prepared for a kind of nickel-base alloy composite plate, and process complexity is low, high production efficiency,
Especially suitable for industrial mass production.
Patent " a kind of heat-resistant wearable clad steel plate and its manufacturing method " (application number: 201310287560.5) discloses one
Kind has excellent heat-resisting and wear-resisting property clad steel plate, and performance is uniform, complete in specifications, has a wide range of application, but its refractory layer contains
There are Cr26-28%, Ni11-15%, wearing layer contains C0.2-0.4%, Cr1.6-1.8%, Mo0.18-0.25%, it may have one
Fixed corrosion resistance, but more far short of what is expected than nickel alloy, and its carbon equivalent is higher is not easy to weld.
" a kind of for producing the production method of steel nickel nickel-base alloy composite blank " (publication number: CN104801562A) is introduced
A kind of preparation method for the composite blank preparing nickel-base alloy composite plate for rolling, wherein the phosphorus content of carbon steel layer exists
0.01-0.10%, high production efficiency, adaptation capacity of equipment is strong, and it is compound steel nickel/nickel-base alloy can be further made by the blank
Plate.But be applicable in carbon steel phosphorus content it is lower, be unable to satisfy at present to intensity increasingly higher demands.
Invent " explosion welding methods of nickel-based alloy composite steel plates " (publication number: CN101559527A) " use explosion method
The nickel-base alloy composite plate of preparation, have it is enough effectively that nickel-base alloy plate and general steel plate is compound, thus guarantee clad steel plate
Under the premise of having the advantages that nickel-base alloy is all, have the intensity of needs, to save the usage amount of expensive metal.But
It is that the composite plate that explosive welding produces forms serious noise pollution to surrounding enviroment in the process, has been gradually backed out the arena of history.
By the above immediate prior art it is found that the production method of clad steel plate has following deficiency at present:
1, it needs to vacuumize after welding or weld under vacuum conditions, production efficiency is low;
2, composite plate substrate strength performance is lower, can not adapt to big intensity requirement;
3, explosion technology generates serious noise pollution, is unfavorable for environmental protection.
Summary of the invention
It is an object of the invention to overcome the above problem and insufficient and provide a kind of simple production process, production efficiency and can
By property height;The production method of the clad steel plate of compound interface excellent in mechanical performance.
The object of the present invention is achieved like this:
A kind of production method of clad steel plate, including Substrate sheet and clad sheet steel milling, stack, preheat, welding, plus
Heat, rolling, cooling carry out milling processing to a surface of clad sheet steel and Substrate sheet respectively, and milling face is stacked relatively
150 DEG C~200 DEG C are preheating to after together, to remove the steam of contact surface, reduce atmospheric density and oxygen content in gap,
The surrounding of contact surface is welded again, stays φ 5~30mm hole at solder up, then with aluminum strip by holes blocking, it can be to prevent
Only contact surface aoxidizes in 660 DEG C or less heating processes.And 660 DEG C or more leads melt, and internal high-pressure gas is excluded, it can be to prevent
Only burst in steel plate bulge and the operation of rolling;This method vacuumizes, greatly without welding in a vacuum chamber without in postwelding
Working efficiency is increased, equipment investment and occupied area are reduced.
Further, milling surface roughness Ra is not more than 10um after clad sheet steel and Substrate sheet milling;Cladding when rolling
Steel plate is under, and upper, slab heating temperature is controlled at 1230 DEG C~1280 DEG C Substrate sheet;Slab start rolling temperature is controlled 1200
DEG C~1250 DEG C;Percentage pass reduction is more than or equal to 25%;It rolls rear and water-spraying control is carried out to the plied timber of downside, open cold temperature
At 900 DEG C~950 DEG C, for cooling velocity in 15 DEG C/s~25 DEG C/s, red temperature is the excellent mechanics of base at 550 DEG C~600 DEG C
The guarantee of performance.
The two of technical solution provided by the invention are to provide pipeline made from a kind of production method using clad steel plate to use
The ingredient of nickel alloy clad steel plate, the nickel alloy clad steel plate substrate is as follows by weight percentage: C:0.03%~
0.0.6%, Si:0.20%~0.25%, Mn:1.10%~1.50%, P≤0.020%, S≤0.005%, Nb:0.03%~
0.05%, Ti:0.04%~0.06%, V:0.03%~0.05%, remaining is Fe and inevitable impurity;The nickel alloy
The ingredient of clad layer of steel clad plate is as follows by weight percentage: C:0.008%~0.02%, Si:0.15%~0.25%, Mn:
0.40%~0.60%, Mo:2.5%~3.5%, P≤0.020%, S≤0.015%%, Ni:40%~45%, Cr:20%
~22%, Ti:0.8%~1.0%, Cu:1.8%~2.8%, Als:0.005~0.045%, remaining is for Fe and unavoidably
Impurity.
It is as follows that ingredient designs reason:
C: be influence steel plate structure property key element, amplitude of variation is very big, carbon content difference can get hardness and
The Different matching relationship of toughness, and the generally the least expensive most direct element of steel hardness is improved, but high carbon alloy hardness Gao Erren
Property it is insufficient, be also unfavorable for the welding of structural member, low-carbon alloy toughness is higher and lower hardness, present invention determine that most suitable cladding
Steel plate carbon content 0.008%~0.02%, Substrate sheet carbon content 0.03%~0.06%.
Si: silicon is the essential elements of deoxidation in steel making, has the function of certain solution strengthening.Also it can inhibit first kind Temper brittleness
Property, improve the temper resistance of martensite, improve tempering temperature, obtains preferable performance, the content model of clad sheet steel silicon of the present invention
It encloses for 0.15%~0.25%, Substrate sheet silicone content 0.20%~0.25%.
Mn: manganese is the essential element for improving intensity and toughness, can significantly improve the element of steel hardenability, cost is very low
It is honest and clean, it is main adding elements, but the excessively high ductility reduction that can make steel of Mn, clad sheet steel manganese content of the invention are limited to
0.40%~0.60%, Substrate sheet manganese content 1.10%~1.50%.
Mo is the effective element for improving hardness of steel and harden ability, but the price of Mo is higher, clad sheet steel Mo control of the present invention
System is 2.50%~3.5%.
Cr can expand ferrite area, improve quench hardening, corrosion proof advantage, therefore Cr is added in clad sheet steel of the present invention and contains
Amount is 20%-22%.
Ni: nickel does not influence welding heat affected zone hardenability and toughness, the intensity of base material can be made to improve, and make low temperature
Toughness and corrosion resistance greatly improve, therefore the content of clad sheet steel Ni is controlled in 40-45% in the present invention.
The Ni content and Cr content of the range make steel have excellent corrosion resistance, can be adapted for most tight at present
Severe corrosive environment.
Micro Nb, V, Ti can effectively refine crystal grain, improve the obdurability of steel, therefore in Substrate sheet of the present invention
Nb0.03%-0.05%, Ti0.04%-0.06%, V0.03%-0.05%.
Al: aluminium is deoxidant element, can be used as AlN formation element, effectively refines crystal grain, in order to reach good deoxidation
The range of effect clad sheet steel Al content of the invention is Al0.005%~0.045%.
Squama, sulphur be harmful element, clad sheet steel P≤0.020% of the present invention, S≤0.015%, Substrate sheet P≤
0.020%, S≤0.005%.
It finally obtains composite surface shear strength and is greater than 500Mpa, base -40 more than or equal to 480Mpa, composite plate yield strength
DEG C impact be more than or equal to 100J clad steel plate.
Effect of the invention is that: the welding of clad steel plate assembly is without being vacuum-treated, and production cost is low, production technology is simple
Single, production efficiency and high reliablity;Compound interface excellent in mechanical performance.
Specific embodiment
Below by embodiment, the present invention is further illustrated.
A kind of production method of clad steel plate, including blank surface milling, stack assembly, preheating, welding, reheat, roll
System, cooling.It is characterized by: Substrate sheet and clad sheet steel pass through in advance after after milling, milling face is stacked together relatively
Heat directly welds the surrounding of contact surface to 150 DEG C~200 DEG C, φ 5~30mm hole is stayed at solder up, then use aluminum strip
By holes blocking.
Milling surface roughness Ra is not more than 10um after clad sheet steel and Substrate sheet milling;Clad sheet steel is under when rolling,
Upper, slab heating temperature is controlled at 1230 DEG C~1280 DEG C Substrate sheet;Slab start rolling temperature is controlled 1200 DEG C~1250
℃;Percentage pass reduction is more than or equal to 25%;It rolls rear and water-spraying control is carried out to the plied timber of downside, open cold temperature at 900 DEG C
~950 DEG C, cooling velocity is in 15 DEG C/s~25 DEG C/s, and red temperature is at 550 DEG C~600 DEG C.
Pipeline produced by the invention is shown in Table 1 with nickel alloy clad steel plate ingredient.Production flow line nickel alloy of the present invention is compound
The main technologic parameters of steel plate are shown in Table 2.Production flow line of the present invention is shown in Table 3 with the performance of nickel alloy clad steel plate;Present invention production
Composite plate ingredient with wearability is shown in Table 4, present invention production, and there are the composite plate main technologic parameters of wearability and performance to see
Table 5;The present invention produces the bridge that the bridge composite plate ingredient with corrosion resistance is shown in Table 6, present invention production has corrosion resistance
Composite plate main technologic parameters are shown in Table 7, and there is the bridge composite plate performance of corrosion resistance to be shown in Table 8 for present invention production.
The pipeline produced by the invention of table 1 nickel alloy clad steel plate ingredient (wt%)
Note: surplus is Fe and inevitable trace impurity
The main technologic parameters of 2 pipeline produced by the invention nickel alloy clad steel plate of table
The performance of 3 pipeline produced by the invention nickel alloy clad steel plate of table
4 present invention production of table has the composite plate ingredient (wt%) of wearability
Note: surplus is Fe and inevitable trace impurity
5 present invention production of table has the composite plate main technologic parameters and performance of wearability
6 present invention production of table has the bridge composite plate ingredient (wt%) of corrosion resistance
Note: surplus is Fe and inevitable trace impurity
7 present invention production of table has the bridge composite plate main technologic parameters of corrosion resistance
8 present invention production of table has the bridge composite plate performance of corrosion resistance
In order to state the present invention, explanation appropriately and is being sufficiently carried out to the present invention by embodiment among the above, it is above
Embodiment is merely to illustrate the present invention, and not limitation of the present invention, those of ordinary skill in related technical field, not
In the case where being detached from the spirit and scope of the present invention, it can also make a variety of changes and modification, made any modification are equally replaced
It changes, improve, should all be included in the protection scope of the present invention, scope of patent protection of the invention should be limited by claim
It is fixed.
Claims (2)
1. a kind of production method of clad steel plate, including Substrate sheet and the milling of clad sheet steel surface, stack assembly, preheating, weldering
It connects, heat, roll, cool down, it is characterised in that: milling processing is carried out to a surface of clad sheet steel and Substrate sheet respectively,
Opposite be stacked together after preheated to 150 DEG C~200 DEG C in milling face is directly welded the surrounding of contact surface, welding envelope
φ 5~30mm hole is stayed at mouthful, then with aluminum strip by holes blocking.
2. a kind of a kind of production method of clad steel plate described in claim 1, it is characterised in that: clad sheet steel and Substrate sheet
Milling surface roughness Ra is not more than 10um after milling;Clad sheet steel is under when rolling, and Substrate sheet is in upper, slab heating temperature
1230 DEG C~1280 DEG C;1200 DEG C~1250 DEG C of slab start rolling temperature;Percentage pass reduction >=25%;It rolls rear only to the cladding of downside
Metal carries out water-spraying control, opens cold temperature at 900 DEG C~950 DEG C, cooling velocity exists in 15 DEG C/s~25 DEG C/s, red temperature
550 DEG C~600 DEG C.
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CN201710983255.8A CN109693073A (en) | 2017-10-20 | 2017-10-20 | A kind of production method of clad steel plate |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110480280A (en) * | 2019-09-06 | 2019-11-22 | 鞍钢股份有限公司 | A kind of method of the vacuum composite welding production ultra-thin carbon equivalent high steel plate of wide cut |
CN110539140A (en) * | 2019-09-06 | 2019-12-06 | 鞍钢股份有限公司 | Production method of super-thick steel plate for pre-hardened plastic mold |
CN113843284A (en) * | 2021-08-30 | 2021-12-28 | 湖南华菱湘潭钢铁有限公司 | Production method of low-yield-ratio 316L + Q500qE stainless steel composite plate |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110480280A (en) * | 2019-09-06 | 2019-11-22 | 鞍钢股份有限公司 | A kind of method of the vacuum composite welding production ultra-thin carbon equivalent high steel plate of wide cut |
CN110539140A (en) * | 2019-09-06 | 2019-12-06 | 鞍钢股份有限公司 | Production method of super-thick steel plate for pre-hardened plastic mold |
CN113843284A (en) * | 2021-08-30 | 2021-12-28 | 湖南华菱湘潭钢铁有限公司 | Production method of low-yield-ratio 316L + Q500qE stainless steel composite plate |
CN113843284B (en) * | 2021-08-30 | 2024-04-05 | 湖南华菱湘潭钢铁有限公司 | Production method of low yield ratio type 316L+Q500qE stainless steel composite plate |
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