CN109679701A - A kind of clean fuel for vehicle additive and preparation method thereof - Google Patents

A kind of clean fuel for vehicle additive and preparation method thereof Download PDF

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Publication number
CN109679701A
CN109679701A CN201910095661.XA CN201910095661A CN109679701A CN 109679701 A CN109679701 A CN 109679701A CN 201910095661 A CN201910095661 A CN 201910095661A CN 109679701 A CN109679701 A CN 109679701A
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parts
clean fuel
vehicle additive
vehicle
clean
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张西强
王金栋
马畅
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Hebei Gold Jingda New Energy Polytron Technologies Inc
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Hebei Gold Jingda New Energy Polytron Technologies Inc
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/1802Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/232Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
    • C10L1/233Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/232Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
    • C10L1/233Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
    • C10L1/2335Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles morpholino, and derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)

Abstract

The invention discloses a kind of clean fuel for vehicle additives, belong to fuel technology field, solve the problems, such as that a large amount of tail gas discharging pollutant can be generated in gasoline combustion process;Including below according to the raw material of parts by weight: etherificate hydrocarbon 100-150 parts, 2-5 parts of N-methylmorpholine, 1-3 parts of zinc acetate, 0.5-2 parts of comburant, 0.5-2 parts of ring amine, 2,3-4 parts of -4 cresols of 4- di-t-butyl, 2-4 parts of phenylpropyl triazole, 6-10 parts of anti-knock agent, 1-2 parts of castor oil, 10-15 parts of dimethoxym ethane, 35-45 parts of isobutanol, clean fuel for vehicle additive prepared by the present invention is with composite alcohol, ethers, hydro carbons etc. for main component, through catalytic modification, fuse, obtain a kind of more economical, effective and clean clean fuel for vehicle additive.

Description

A kind of clean fuel for vehicle additive and preparation method thereof
Technical field
The present invention relates to fuel technology field, specifically a kind of clean fuel for vehicle additive and preparation method thereof.
Background technique
With the growth of the size of population, the contradiction in terms of energy resource supply and energy-consuming between air environmental pollution is suitable Prominent, problem of environmental pollution has become an important factor for influencing Chinese society development and the people's livelihood, and atmosphere pollution is common one kind Environmental pollution, in the influence factor of atmosphere pollution, air pollution caused by vehicle exhaust account for the 50% of air pollution total amount with On, but the production activity of modern society and life in, automobile is indispensable, thus using low emission clean energy resource with Part or all of vapour, diesel product are substituted, is of great significance for the angle of protection environment;Currently, substitute energy source for petroleum The research work of aspect is concentrated mainly in the development and utilization of dimethyl ether fuel, LPG, LNG, Aalcohols fuel.
Gasoline is a kind of volatile, inflammable mixture of light hydrocarbons, the direct steaming gasoline group that gasoline is obtained by petroleum refining Point, the different gasoline components such as catalytically cracked gasoline component, catalytic reforming gasoline component after refining with antiknock component through adjusting Be made, the boiling range of petroleum is 30 DEG C -220 DEG C, and main component is C5-C12 aliphatic hydrocarbon and cycloalkane and a certain amount of fragrance Hydrocarbon, with the development of society, petrol engine performance constantly improves and Law on Environmental Protection Laws & Regulations are increasingly strict, to gasoline matter The requirement of amount is higher and higher.
But a large amount of tail gas discharging pollutant can be generated in gasoline combustion process, in order to improve quality of gasoline, improve The service performance of gasoline needs to be added the additive of different function in the oil, and the type of gasoline additive has very much, such as anti- Detonator, anti-freezing agent, antiwear additive, antismoke agent, combustion adjuvant, detergent-dispersant additive, the function that different gasoline additives rises also not phase Together.They can make the combustion-supporting ingredient in gasoline additive improve burning mixture gas in-cylinder combustion flame propagation velocity, Shorten combustion duration, improves cycle efficieny, reduce the fuel consumption of engine, while reducing the surface tension of fuel oil, make to fire Oil is easier to be atomized, and forms uniform gaseous mixture, to keep burning more complete, exhaust emission is reduced, therefore, it is proposed that one Kind clean fuel for vehicle additive and preparation method thereof.
Summary of the invention
The purpose of the present invention is to provide a kind of clean fuel for vehicle additives and preparation method thereof, to solve above-mentioned background The problem of being proposed in technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of clean fuel for vehicle additive, including below according to the raw material of parts by weight: etherificate hydrocarbon 100-150 parts, N- methyl 2-5 parts of quinoline, 1-3 parts of zinc acetate, 0.5-2 parts of comburant, 0.5-2 parts of ring amine, 3-4 parts of -4 cresols of 2,4- di-t-butyl, benzene Third 2-4 parts of triazole, 6-10 parts of anti-knock agent, 1-2 parts of castor oil, 10-15 parts of dimethoxym ethane, 35-45 parts of isobutanol.
As a further solution of the present invention: including below according to the raw material of parts by weight: etherificate 120 parts of hydrocarbon, N- methyl 3 parts of quinoline, 2 parts of zinc acetate, 1 part of comburant, 1 part of ring amine, 3.5 parts of -4 cresols of 2,4- di-t-butyl, 3 parts of phenylpropyl triazole, 8 parts of anti-knock agent, 1.5 parts of castor oil, 12 parts of dimethoxym ethane, 40 parts of isobutanol.
As further scheme of the invention: anti-knock agent is the tert-butyl alcohol.
As further scheme of the invention: comburant is uns-dimethylhydrazine.
The preparation method of the clean fuel for vehicle additive, steps are as follows:
S1, quantitative methanol is weighed, then methanol progress oxidative polycondensation reacts to obtain oligomeric methanol, carries out rectifying to oligomeric methanol Separation obtains etherificate hydrocarbon;
S2, etherificate hydrocarbon, N-methylmorpholine, zinc acetate, comburant, ring amine merging are weighed, obtains mixed component A;
S3, -4 cresols of 2,4- di-t-butyl, phenylpropyl triazole, anti-knock agent, castor oil, dimethoxym ethane, isobutanol merging are weighed, obtained Mixed component B;
S4, it after merging mixed component A and mixed component B, is stirred 30 minutes, obtains clean fuel for vehicle additive;
S5, swelling character test is carried out to clean fuel for vehicle additive, clean fuel for vehicle additive is added to 100m1 circle The rubber weighed is put into the flask of bottom simultaneously;
S6, thermostat are warming up to 55 DEG C in advance, keep constant temperature, are put into round-bottomed flask and connect condenser pipe reflux;
S7, rubber is taken out after reaction 24 hours, be placed in air within stopping 30 seconds, use electronics after surface liquid volatilization is clean Balance weighing, and record, then carry out pure gasoline comparative test.
Compared with prior art, the beneficial effects of the present invention are: clean fuel for vehicle additive prepared by the present invention is with multiple Conjunction alcohols, ethers, hydro carbons etc. are main component, through catalytic modification, are fused, and a kind of more economical, effective and clean vehicle is obtained With clean fuel additive, which provides a kind of path of crude oil substitution, it is both the energy, can be with Part substitution oil product;It is that vapour, the modifying agent of diesel quality and green oxygenation agent, contained oxygen atom can be such that gasoline fills again Divided combustion is effectively reduced the motor vehicle exhaust emission total amount of pollutant, decreases by 50% or more, can greatly alleviate vehicle exhaust pair The pollution of atmosphere.
Specific embodiment
Technical solution of the present invention is described in more detail With reference to embodiment, it is clear that described Embodiment be only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ability Domain those of ordinary skill every other embodiment obtained without making creative work, belongs to guarantor of the present invention The range of shield.
Embodiment 1
A kind of clean fuel for vehicle additive, including below according to the raw material of parts by weight: etherificate 150 parts of hydrocarbon, N-methylmorpholine 5 Part, 3 parts of zinc acetate, 2 parts of comburant, 2 parts of ring amine, 4 parts of -4 cresols of 2,4- di-t-butyl, 4 parts of phenylpropyl triazole, anti-knock agent 10 parts, 2 parts of castor oil, 15 parts of dimethoxym ethane, 45 parts of isobutanol.
Anti-knock agent is the tert-butyl alcohol.
Comburant is uns-dimethylhydrazine.
In the present embodiment, the preparation method of the clean fuel for vehicle additive, steps are as follows:
S1, quantitative methanol is weighed, then methanol progress oxidative polycondensation reacts to obtain oligomeric methanol, carries out rectifying to oligomeric methanol Separation obtains etherificate hydrocarbon;
S2, etherificate hydrocarbon, N-methylmorpholine, zinc acetate, comburant, ring amine merging are weighed, obtains mixed component A;
S3, -4 cresols of 2,4- di-t-butyl, phenylpropyl triazole, anti-knock agent, castor oil, dimethoxym ethane, isobutanol merging are weighed, obtained Mixed component B;
S4, it after merging mixed component A and mixed component B, is stirred 30 minutes, obtains clean fuel for vehicle additive;
S5, swelling character test is carried out to clean fuel for vehicle additive, clean fuel for vehicle additive is added to 100m1 circle The rubber weighed is put into the flask of bottom simultaneously;
S6, thermostat are warming up to 55 DEG C in advance, keep constant temperature, are put into round-bottomed flask and connect condenser pipe reflux;
S7, rubber is taken out after reaction 24 hours, is placed in air and stops 28 seconds, use electronic balance after surface liquid volatilization is clean Weighing, and record, then carry out pure gasoline comparative test.
Embodiment 2
A kind of clean fuel for vehicle additive, including below according to the raw material of parts by weight: etherificate 100 parts of hydrocarbon, N-methylmorpholine 2 Part, 0.5 part of comburant, 0.5 part of ring amine, 3 parts of -4 cresols of 2,4- di-t-butyl, 2 parts of phenylpropyl triazole, resists 1 part of zinc acetate 6 parts of detonator, 1 part of castor oil, 10 parts of dimethoxym ethane, 35 parts of isobutanol.
Anti-knock agent is the tert-butyl alcohol.
Comburant is uns-dimethylhydrazine.
In the present embodiment, the preparation method of the clean fuel for vehicle additive, steps are as follows:
S1, quantitative methanol is weighed, then methanol progress oxidative polycondensation reacts to obtain oligomeric methanol, carries out rectifying to oligomeric methanol Separation obtains etherificate hydrocarbon;
S2, etherificate hydrocarbon, N-methylmorpholine, zinc acetate, comburant, ring amine merging are weighed, obtains mixed component A;
S3, -4 cresols of 2,4- di-t-butyl, phenylpropyl triazole, anti-knock agent, castor oil, dimethoxym ethane, isobutanol merging are weighed, obtained Mixed component B;
S4, it after merging mixed component A and mixed component B, is stirred 30 minutes, obtains clean fuel for vehicle additive;
S5, swelling character test is carried out to clean fuel for vehicle additive, clean fuel for vehicle additive is added to 100m1 circle The rubber weighed is put into the flask of bottom simultaneously;
S6, thermostat are warming up to 55 DEG C in advance, keep constant temperature, are put into round-bottomed flask and connect condenser pipe reflux;
S7, rubber is taken out after reaction 24 hours, is placed in air and stops 25 seconds, use electronic balance after surface liquid volatilization is clean Weighing, and record, then carry out pure gasoline comparative test.
Embodiment 3
A kind of clean fuel for vehicle additive, including below according to the raw material of parts by weight: etherificate 120 parts of hydrocarbon, N-methylmorpholine 3 Part, 2 parts of zinc acetate, 1 part of comburant, 1 part of ring amine, 3.5 parts of -4 cresols of 2,4- di-t-butyl, 3 parts of phenylpropyl triazole, antiknock 8 parts of agent, 1.5 parts of castor oil, 12 parts of dimethoxym ethane, 40 parts of isobutanol.
Anti-knock agent is the tert-butyl alcohol.
Comburant is uns-dimethylhydrazine.
In the present embodiment, the preparation method of the clean fuel for vehicle additive, steps are as follows:
S1, quantitative methanol is weighed, then methanol progress oxidative polycondensation reacts to obtain oligomeric methanol, carries out rectifying to oligomeric methanol Separation obtains etherificate hydrocarbon;
S2, etherificate hydrocarbon, N-methylmorpholine, zinc acetate, comburant, ring amine merging are weighed, obtains mixed component A;
S3, -4 cresols of 2,4- di-t-butyl, phenylpropyl triazole, anti-knock agent, castor oil, dimethoxym ethane, isobutanol merging are weighed, obtained Mixed component B;
S4, it after merging mixed component A and mixed component B, is stirred 30 minutes, obtains clean fuel for vehicle additive;
S5, swelling character test is carried out to clean fuel for vehicle additive, clean fuel for vehicle additive is added to 100m1 circle The rubber weighed is put into the flask of bottom simultaneously;
S6, thermostat are warming up to 55 DEG C in advance, keep constant temperature, are put into round-bottomed flask and connect condenser pipe reflux;
S7, rubber is taken out after reaction 24 hours, is placed in air and stops 21 seconds, use electronic balance after surface liquid volatilization is clean Weighing, and record, then carry out pure gasoline comparative test.
Clean fuel for vehicle additive prepared by the present invention with composite alcohol, ethers, hydro carbons etc. for main component, through being catalyzed It is modified, fused, obtain a kind of more economical, effective and clean clean fuel for vehicle additive, clean fuel for vehicle addition Agent provides a kind of path of crude oil substitution, it is both the energy, can partially substitute oil product;It is vapour, diesel quality again Modifying agent and green oxygenation agent, contained oxygen atom can make gasoline full combustion, it is total that motor vehicle exhaust emission pollutant are effectively reduced Amount, decreases by 50% or more, can greatly alleviate pollution of the vehicle exhaust to atmosphere.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (8)

1. a kind of clean fuel for vehicle additive, which is characterized in that including below according to the raw material of parts by weight: etherificate hydrocarbon 100- 150 parts, 2-5 parts of N-methylmorpholine, 1-3 parts of zinc acetate, 0.5-2 parts of comburant, 0.5-2 parts of ring amine, 2,4- di-t-butyl- 4 3-4 parts of cresols, 2-4 parts of phenylpropyl triazole, 6-10 parts of anti-knock agent, 1-2 parts of castor oil, 10-15 parts of dimethoxym ethane, isobutanol 35-45 Part.
2. clean fuel for vehicle additive according to claim 1, which is characterized in that including below according to the original of parts by weight Material: etherificate 120 parts of hydrocarbon, 3 parts of N-methylmorpholine, 2 parts of zinc acetate, 1 part of comburant, 1 part of ring amine, -4 first of 2,4- di-t-butyl 3.5 parts of phenol, 3 parts of phenylpropyl triazole, 8 parts of anti-knock agent, 1.5 parts of castor oil, 12 parts of dimethoxym ethane, 40 parts of isobutanol.
3. clean fuel for vehicle additive according to claim 1, which is characterized in that anti-knock agent is the tert-butyl alcohol.
4. clean fuel for vehicle additive according to claim 1, which is characterized in that comburant is uns-dimethylhydrazine.
5. a kind of preparation method of the clean fuel for vehicle additive as described in claim 1-4 is any, which is characterized in that step It is as follows:
S1, quantitative methanol is weighed, then methanol progress oxidative polycondensation reacts to obtain oligomeric methanol, carries out rectifying to oligomeric methanol Separation obtains etherificate hydrocarbon;
S2, etherificate hydrocarbon, N-methylmorpholine, zinc acetate, comburant, ring amine merging are weighed, obtains mixed component A;
S3, -4 cresols of 2,4- di-t-butyl, phenylpropyl triazole, anti-knock agent, castor oil, dimethoxym ethane, isobutanol merging are weighed, obtained Mixed component B;
S4, it after merging mixed component A and mixed component B, is stirred, obtains clean fuel for vehicle additive;
S5, swelling character test is carried out to clean fuel for vehicle additive, clean fuel for vehicle additive is added to 100m1 circle The rubber weighed is put into the flask of bottom simultaneously;
S6, thermostat heat up in advance, keep constant temperature, are put into round-bottomed flask and connect condenser pipe reflux;
S7, rubber is taken out after reaction, be placed in air within stopping 30 seconds, use electronics day after surface liquid volatilization is clean Flat weighing, and record, then carry out pure gasoline comparative test.
6. the preparation method of clean fuel for vehicle additive according to claim 5, which is characterized in that in step S4, stir The time for mixing mixing is 30 minutes.
7. the preparation method of clean fuel for vehicle additive according to claim 5, which is characterized in that permanent in step S6 Warm slot is warming up to 55 DEG C.
8. the preparation method of clean fuel for vehicle additive according to claim 5, which is characterized in that in step S7, instead It is 24 hours between seasonable.
CN201910095661.XA 2019-01-31 2019-01-31 A kind of clean fuel for vehicle additive and preparation method thereof Pending CN109679701A (en)

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CN103965973A (en) * 2013-01-29 2014-08-06 张永钢 Engine oxygen-rich fuel
CN104178231A (en) * 2014-09-18 2014-12-03 陕西宝姜新能源技术研发有限公司 High-flash-point alcohol ether diesel oil
CN104593105A (en) * 2015-01-22 2015-05-06 杨长江 High-cleanness gasoline additive and preparation method thereof
CN105385475A (en) * 2015-11-04 2016-03-09 鹤壁宝发能源科技股份有限公司 Dimethyl-ether-mixed internal combustion engine fuel
CN105567351A (en) * 2016-01-12 2016-05-11 吴阳 Additive of gasoline and diesel for vehicles, ships and power machines and preparation method of additive
CN105885970A (en) * 2016-06-29 2016-08-24 山东辰信新能源有限公司 Vehicle fuel and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974355A (en) * 2010-10-18 2011-02-16 贾崇新 Biological alcohol ether fuel
CN102559297A (en) * 2012-02-07 2012-07-11 容启团 Composite gasoline and diesel oil with high energy-saving environmental protection used for vehicles
CN102634384A (en) * 2012-04-17 2012-08-15 罗浩南 Novel vehicle alcohols environment-friendly fuel
CN102660337A (en) * 2012-05-10 2012-09-12 河南煤业化工集团研究院有限责任公司 Method for preparing novel clean synthetic diesel oil
CN103965973A (en) * 2013-01-29 2014-08-06 张永钢 Engine oxygen-rich fuel
CN104178231A (en) * 2014-09-18 2014-12-03 陕西宝姜新能源技术研发有限公司 High-flash-point alcohol ether diesel oil
CN104593105A (en) * 2015-01-22 2015-05-06 杨长江 High-cleanness gasoline additive and preparation method thereof
CN105385475A (en) * 2015-11-04 2016-03-09 鹤壁宝发能源科技股份有限公司 Dimethyl-ether-mixed internal combustion engine fuel
CN105567351A (en) * 2016-01-12 2016-05-11 吴阳 Additive of gasoline and diesel for vehicles, ships and power machines and preparation method of additive
CN105885970A (en) * 2016-06-29 2016-08-24 山东辰信新能源有限公司 Vehicle fuel and preparation method thereof

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Application publication date: 20190426