CN109679674A - A kind of needle-shape coke raw material pretreating process - Google Patents

A kind of needle-shape coke raw material pretreating process Download PDF

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CN109679674A
CN109679674A CN201910030795.3A CN201910030795A CN109679674A CN 109679674 A CN109679674 A CN 109679674A CN 201910030795 A CN201910030795 A CN 201910030795A CN 109679674 A CN109679674 A CN 109679674A
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solvent
tower
raw material
tank
pump
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李刚
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B55/00Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The invention discloses a kind of needle-shape coke raw material pretreating process, it include: slurry oil (1), raw material surge tank (2), high pressure solvent tank (3), extraction tower (4), supercritical recovery tower (5), vacuum pump line (6), deasphalted oil stripper (7), vacuum pump line (8), asphaltene stripper (9), solvent tank (10), carburet hydrogen (11), fresh solvent (12), desolvation agent (13), acid water (14), fresh water (15), raw material pumps (16), high-pressure solvent pump (17), move back oily line (18), diesel cycle line (19), rich aromatic naphtha (20), pitch (21), sewage pump (22), solvent (23) and static mixer (24), catalytic slurry is used to produce needle coke product for raw material, catalytic slurry first uses supercritical extract, it is enriched with it Middle aromatic component, then hydrogenated purification again, removes the impurity such as S, N therein, most produces needle coke through needle coke coking plant afterwards.

Description

A kind of needle-shape coke raw material pretreating process
Technical field
The present invention relates to a kind of processes of oil refining field needle-shape coke raw material preparation, refer in particular to oil system needle The process of preparing of shape coke raw material.
Background technique
Needle coke is a kind of quality material in the carbon materials greatly developed the 1970s, and appearance is silver gray, has The porosu solid of metallic luster, surface have lubrication to feel in apparent elongated needle-shaped or fibrous texture trend, internal holes it is big and It is few, it is slightly ob-round, because its appearance has an apparent needle-shaped or fibrous texture structure, therefore referred to as needle coke (Needle Coke), needle coke is with low thermal coefficient of expansion, low-porosity, low-sulfur, low ash point, low-metal content, high conductivity and Yi Shimo The series of advantages such as change.The graphite product made of needle coke has high density, high intensity, high-purity, high-crystallinity, highly conductive The features such as thermal conductivity, low thermal coefficient of expansion, low fever's corrosion, mainly for the production of electric furnace steel making high power, ultrahigh power graphite Electrode production is used as high-energy neutron decelerating material in atomic pile, is also used in rocketry, wherein in metallurgical industry Dosage is maximum.In metallurgical industry, when the ultra high power made of needle coke (UHP) graphite electrode can shorten electric furnace steel making smelting Between 50~70%, power consumption can reduce by 30%, can improve efficiency significantly, reduce power consumption and raw materials consumption, reduce ring Border pollution.Needle coke can be divided into petroleum needle coke and coal-based needle coke according to the difference of raw material.Due to the production of needle coke Raw material and process conditions difference, performance is also not quite similar, but purposes is essentially identical.The main performance index of needle coke has very close Degree, thermal expansion coefficient, ash content, sulfur content, nitrogen content, intensity, size distribution, resistivity and inoxidizability etc..It sees on the whole, The quality of petroleum needle coke is better than coal-based needle coke, and price is also higher than coal-based needle coke by 10% or so.Needle coke in the world Production technology is mainly monopolized by a few countries such as the U.S., Britain, Japan, Germany, in terms of Chinese steel industry development prospect, therefrom State sees in big specification ultra high power graphite electrode production field strength at present, increases needle coke production technology and develops dynamics, makes excellent The production domesticization of matter needle coke, not only can change China and produces big specification ultra high power graphite electrode status under one's control, and It can also promote the development of China's steel and iron industry, a kind of prepare the one of high-quality needle-shape coke raw material in consideration of it, provided by the invention Kind processing technology routine.
Summary of the invention
Purpose provided by the invention is to provide a kind of a kind of processing technology routine for preparing high-quality needle-shape coke raw material, packet Include: slurry oil (1), high pressure solvent tank (3), extraction tower (4), supercritical recovery tower (5), vacuum pump line (6), takes off raw material surge tank (2) Coal tar stripper (7), asphaltene stripper (9), solvent tank (10), carburet hydrogen (11), fresh solvent (12), moves back at vacuum pump line (8) Solvent (13), fresh water (15), raw material pump (16), high-pressure solvent pump (17), moves back oily line (18), diesel cycle at acid water (14) Line (19), rich aromatic naphtha (20), pitch (21), sewage pump (22), solvent (23) and static mixer (24), using catalytic slurry Needle coke product is produced for raw material, catalytic slurry first uses supercritical extract, enrichment wherein aromatic component, then hydrogenated essence again System, removes the impurity such as S, N therein, most produces needle coke, technical process through needle coke coking plant afterwards are as follows:
1. by tank field Lai catalytic slurry enter raw material surge tank (1) through Liquid level adjusting valve, raw material by raw material pump (16) extract out after Enter static mixer (24) after feedstock oil goes into operation heater heating;
It goes into operation heater 2. solvent in high pressure solvent tank (3) is forced into after 1-6MPa extraction by high-pressure solvent pump (17) through solvent Enter static mixer (24) after heating, enters in extraction tower (4) after being sufficiently mixed in static mixer (24) with slurry oil (1) Portion, another way solvent (23) enter extraction tower (4) lower section and are further extracted oil therein;
3. most of aromatic naphtha phase hydro carbons is dissolved in solvent (23) in slurry oil (1), the lesser light phase of density is formed, and it is most of Colloid, asphalitine do not dissolve in then solvent (23), formed the biggish heavy phase of density, weight two-phase in extraction tower respectively upwards, to Lower flowing, heavy phase are finally settled down to extraction tower (4) bottom during decline, form light, weight two-phase in this way, and light phase is rich aromatic hydrocarbons Oil solution, heavy phase are cold primer-oil;
4. overflowing the rich aromatic naphtha liquid phase containing a large amount of solvents at the top of from extraction tower (4), supercritical recovery is entered after heated heating Tower (5);
5. entering asphaltene stripper (9) after the cold primer-oil come out from extraction tower (4) bottom is heated, solvent is from asphaltene stripper (9) top outflow, cold primer-oil are sent after the extraction cooling of asphaltene stripper (9) bottom to tank field;
6. in supercritical recovery tower (5), since the solubility of the rich aromatic naphtha of the raising of temperature in a solvent reduces, rich aromatic naphtha It is separated with solvent, solvent enters high pressure solvent tank (17) after outflow cooling at the top of supercritical recovery tower (5);
7. rich aromatic naphtha is from supercritical recovery tower (5) bottom, extraction enters deasphalted oil stripper (7), in deasphalted oil stripper (7) in, since pressure declines, rich aromatic naphtha and solvent (23) are further separated, and solvent (23) is stripped from deasphalted oil Outflow at the top of tower (7), cooling after being mixed with the solvent flowed out at the top of deasphalted oil stripper (7) to enter solvent tank (10), Fu Fang Hydrocarbon ils is sent after cooling from the extraction of deasphalted oil stripper (7) bottom to tank field;
8. solvent (23) is mixed into high pressure solvent tank (3) through solvent pump (24) and supercritical recovery tower (5) top solvent recovery line, It is recycled;
9. sewage pumps out workshop through sewage pump (22).
The vacuum pump line (6) is from extraction tower (4) tower top, supercritical recovery tower (5) tower top, deasphalted oil stripper (7) Tower top and the extraction of asphaltene stripper (9) tower top, enter solvent tank (10) after collecting, the recycling design in the solvent tank (10) Extraction tower (4) are returned after solvent pump (23) extraction.
Gaseous hydrocarbon (11) in the solvent tank (10) is by the outer discharger of solvent tank (10) overhead line, with stylish Fresh solvent (12) enters solvent tank (10) by overhead line.
The pump discharge of the solvent pump (23) returns to high-pressure solvent pump (17) by moving back oily line, the solvent pump (23) Another outlet by diesel cycle line (19) return extraction tower (4) feeding line.
Detailed description of the invention
Fig. 1 is process flow chart of the invention.
In appended drawing reference figure, 1 slurry oil, 2 raw material surge tanks, 3 high pressure solvent tanks, 4 extraction towers, 5 supercritical recovery towers, 6 are taken out Ceases to be busy, 7 deasphalted oil strippers, 8 vacuum pump lines, 9 asphaltene strippers, 10 solvent tanks, 11 carburet hydrogens, 12 fresh solvents, 13 desolvations Agent, 14 acid waters, 15 fresh waters, 16 raw materials pump, 17 high-pressure solvent pumps, 18 move back oily line, 19 diesel cycle lines, 20 rich aromatic naphtha, 21 pitches, 22 sewage pumps, 23 solvents, 24 static mixers
Specific embodiment
Below by a kind of preparation side of specific embodiment orderly mesophase needle coke that present invention be described in more detail Method, those skilled in the art is after having read this specific embodiment, it is to be understood that and implement technical solutions according to the invention, Excellent effect described in it can also be embodied by specific embodiment.
Embodiment
This method is similar to the true boiling point distillation of crude oil, using the dissolubility property of lighter hydrocarbons solvent in the supercritical state, Dare matter oil by all kinds of and efficiently separate.The advantage is that: separation temperature is low (< 250 DEG C), extracting rate is high, can obtain more A narrow fraction, and its separation principle is similar to the solvent extraction of industry, and result of study has practical value, and this method can have Effect ground separation catalytic slurry.
1. by tank field Lai catalytic slurry enter raw material surge tank (1) through Liquid level adjusting valve, raw material by raw material pump (16) take out Enter static mixer (24) after feedstock oil goes into operation heater heating after out;
It goes into operation heater 2. solvent in high pressure solvent tank (3) is forced into after 1-6MPa extraction by high-pressure solvent pump (17) through solvent Enter static mixer (24) after heating, enters in extraction tower (4) after being sufficiently mixed in static mixer (24) with slurry oil (1) Portion, another way solvent (23) enter extraction tower (4) lower section and are further extracted oil therein;
3. most of aromatic naphtha phase hydro carbons is dissolved in solvent (23) in slurry oil (1), the lesser light phase of density is formed, and it is most of Colloid, asphalitine do not dissolve in then solvent (23), formed the biggish heavy phase of density, weight two-phase in extraction tower respectively upwards, to Lower flowing, heavy phase are finally settled down to extraction tower (4) bottom during decline, form light, weight two-phase in this way, and light phase is rich aromatic hydrocarbons Oil solution, heavy phase are cold primer-oil;
4. overflowing the rich aromatic naphtha liquid phase containing a large amount of solvents at the top of from extraction tower (4), supercritical recovery is entered after heated heating Tower (5);
5. entering asphaltene stripper (9) after the cold primer-oil come out from extraction tower (4) bottom is heated, solvent is from asphaltene stripper (9) top outflow, cold primer-oil are sent after the extraction cooling of asphaltene stripper (9) bottom to tank field;
6. in supercritical recovery tower (5), since the solubility of the rich aromatic naphtha of the raising of temperature in a solvent reduces, rich aromatic naphtha It is separated with solvent, solvent enters high pressure solvent tank (17) after outflow cooling at the top of supercritical recovery tower (5);
7. rich aromatic naphtha is from supercritical recovery tower (5) bottom, extraction enters deasphalted oil stripper (7), in deasphalted oil stripper (7) in, since pressure declines, rich aromatic naphtha and solvent (23) are further separated, and solvent (23) is stripped from deasphalted oil Outflow at the top of tower (7), cooling after being mixed with the solvent flowed out at the top of deasphalted oil stripper (7) to enter solvent tank (10), Fu Fang Hydrocarbon ils is sent after cooling from the extraction of deasphalted oil stripper (7) bottom to tank field;
8. solvent (23) is mixed into high pressure solvent tank (3) through solvent pump (24) and supercritical recovery tower (5) top solvent recovery line, It is recycled;
9. sewage pumps out workshop through sewage pump (22).
The vacuum pump line (6) is from extraction tower (4) tower top, supercritical recovery tower (5) tower top, deasphalted oil stripper (7) Tower top and the extraction of asphaltene stripper (9) tower top, enter solvent tank (10) after collecting, the recycling design in the solvent tank (10) Extraction tower (4) are returned after solvent pump (23) extraction.
Gaseous hydrocarbon (11) in the solvent tank (10) is by the outer discharger of solvent tank (10) overhead line, with stylish Fresh solvent (12) enters solvent tank (10) by overhead line.
The pump discharge of the solvent pump (23) returns to high-pressure solvent pump (17) by moving back oily line, the solvent pump (23) Another outlet by diesel cycle line (19) return extraction tower (4) feeding line.

Claims (4)

1. a kind of needle-shape coke raw material pretreating process, comprising: slurry oil (1), raw material surge tank (2), high pressure solvent tank (3), extracting It is tower (4), supercritical recovery tower (5), vacuum pump line (6), deasphalted oil stripper (7), vacuum pump line (8), asphaltene stripper (9), molten Agent tank (10), carburet hydrogen (11), fresh solvent (12), desolvation agent (13), acid water (14), fresh water (15), raw material pump (16), High-pressure solvent pump (17) moves back oily line (18), is diesel cycle line (19), rich aromatic naphtha (20), pitch (21), sewage pump (22), molten Agent (23) and static mixer (24) use catalytic slurry to produce needle coke product for raw material, and catalytic slurry first uses overcritical Extraction is enriched with wherein aromatic component, and then hydrogenated purification again, removes the impurity such as S, N therein, most fills afterwards through needle coke coking Set production needle coke, technical process are as follows:
1. by tank field Lai catalytic slurry enter raw material surge tank (1) through Liquid level adjusting valve, raw material by raw material pump (16) extract out after Enter static mixer (24) after feedstock oil goes into operation heater heating;
It goes into operation heater 2. solvent in high pressure solvent tank (3) is forced into after 1-6MPa extraction by high-pressure solvent pump (17) through solvent Enter static mixer (24) after heating, enters in extraction tower (4) after being sufficiently mixed in static mixer (24) with slurry oil (1) Portion, another way solvent (23) enter extraction tower (4) lower section and are further extracted oil therein;
3. most of aromatic naphtha phase hydro carbons is dissolved in solvent (23) in slurry oil (1), the lesser light phase of density is formed, and it is most of Colloid, asphalitine do not dissolve in then solvent (23), formed the biggish heavy phase of density, weight two-phase in extraction tower respectively upwards, to Lower flowing, heavy phase are finally settled down to extraction tower (4) bottom during decline, form light, weight two-phase in this way, and light phase is rich aromatic hydrocarbons Oil solution, heavy phase are cold primer-oil;
4. overflowing the rich aromatic naphtha liquid phase containing a large amount of solvents at the top of from extraction tower (4), supercritical recovery is entered after heated heating Tower (5);
5. entering asphaltene stripper (9) after the cold primer-oil come out from extraction tower (4) bottom is heated, solvent is from asphaltene stripper (9) top outflow, cold primer-oil are sent after the extraction cooling of asphaltene stripper (9) bottom to tank field;
6. in supercritical recovery tower (5), since the solubility of the rich aromatic naphtha of the raising of temperature in a solvent reduces, rich aromatic naphtha It is separated with solvent, solvent enters high pressure solvent tank (17) after outflow cooling at the top of supercritical recovery tower (5);
7. rich aromatic naphtha is from supercritical recovery tower (5) bottom, extraction enters deasphalted oil stripper (7), in deasphalted oil stripper (7) in, since pressure declines, rich aromatic naphtha and solvent (23) are further separated, and solvent (23) is stripped from deasphalted oil Outflow at the top of tower (7), cooling after being mixed with the solvent flowed out at the top of deasphalted oil stripper (7) to enter solvent tank (10), Fu Fang Hydrocarbon ils is sent after cooling from the extraction of deasphalted oil stripper (7) bottom to tank field;
8. solvent (23) is mixed into high pressure solvent tank (3) through solvent pump (24) and supercritical recovery tower (5) top solvent recovery line, It is recycled;
9. sewage pumps out workshop through sewage pump (22).
2. a kind of needle-shape coke raw material pretreating process according to claim 1, it is characterised in that: the vacuum pump line (6) From extraction tower (4) tower top, supercritical recovery tower (5) tower top, deasphalted oil stripper (7) tower top and asphaltene stripper (9) tower top Extraction enters solvent tank (10) after collecting, and the recycling design in the solvent tank (10) returns after solvent pump (23) extraction Pumpback stripper (4).
3. a kind of needle-shape coke raw material pretreating process according to claim 1, it is characterised in that: the solvent tank (10) In gaseous hydrocarbon (11) by the outer discharger of solvent tank (10) overhead line, while fresh solvent (12) by overhead line into Enter solvent tank (10).
4. a kind of needle-shape coke raw material pretreating process according to claim 1, it is characterised in that: the solvent pump (23) Pump discharge return to high-pressure solvent pump (17) by moving back oily line, another outlet of the solvent pump (23) passes through diesel cycle Line (19) returns to extraction tower (4) feeding line.
CN201910030795.3A 2019-01-07 2019-01-14 A kind of needle-shape coke raw material pretreating process Pending CN109679674A (en)

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Publication number Priority date Publication date Assignee Title
CN110511785A (en) * 2019-09-20 2019-11-29 黄河三角洲京博化工研究院有限公司 A method of needle-shape coke raw material oil is prepared using slurry oil
CN111961498A (en) * 2020-08-13 2020-11-20 山东益大新材料股份有限公司 Multiphase step heavy oil separation process and application of product thereof

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CN110511785A (en) * 2019-09-20 2019-11-29 黄河三角洲京博化工研究院有限公司 A method of needle-shape coke raw material oil is prepared using slurry oil
CN111961498A (en) * 2020-08-13 2020-11-20 山东益大新材料股份有限公司 Multiphase step heavy oil separation process and application of product thereof

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Application publication date: 20190426