CN109679376A - A kind of ambient self-crosslinking fluorescent macromolecule dyestuff and its application - Google Patents
A kind of ambient self-crosslinking fluorescent macromolecule dyestuff and its application Download PDFInfo
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- CN109679376A CN109679376A CN201910024373.5A CN201910024373A CN109679376A CN 109679376 A CN109679376 A CN 109679376A CN 201910024373 A CN201910024373 A CN 201910024373A CN 109679376 A CN109679376 A CN 109679376A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
- C09B69/109—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds containing other specific dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of ambient self-crosslinking fluorescent macromolecule dyestuff and its applications, are related to cosmetic technical field.Ambient self-crosslinking fluorescent macromolecule dye is prepared from the following raw materials by percentage to the quality: 20-80 parts of acrylate mixture, 0.1-5 parts of fluorescent dye monomer, 1-10 parts of Diacetone Acrylamide, 1-10 parts of adipic dihydrazide, 0.1-1 parts of anion emulsifier, 0.1-0.3 parts of nonionic emulsifier, 0.1-1 parts of water soluble starter；Application of the ambient self-crosslinking fluorescent macromolecule dyestuff in cosmetics；It is applied particularly in hair jelly and mousse preparation.Fluorescent macromolecule dyestuff prepared by the present invention is water-base polyurethane material, and safety and environmental protection is nontoxic, and glossiness is high, and filming performance is excellent；Good to the adhesive force of hair applied to hair jelly obtained in cosmetics and mousse, easy cleaning moderate at film hardness will not damage hair.
Description
Technical field
The invention belongs to cosmetic technical fields, more particularly to a kind of ambient self-crosslinking fluorescent macromolecule dyestuff and are somebody's turn to do
Application of the macromolecular dyestuff in cosmetics.
Background technique
Hairspray (hair gel, mousse, hair gel cream, hair jelly etc.) is designed as reaching protection hair and fixed effect
's.In aesthetic procedure, setting agent needs easy cleaning, and aesthetics is critically important to consumer after the drying, especially gloss, feel
And arrangement property.As the demand of performance and effect is constantly promoted, functional and diversity starts to develop, various colored hairs
It glue and comes into being by spraying, makes hair jelly or hair gel band colored or fluorescence can also be more other than it can protect hair quality
Add colorful, it is more beautiful.But traditional dyestuff or fluorescent molecule, such as oxadiazoles and its derivative species, triazole and its derivative
Species, rhodamine and its derivative species, coumarin derivatives etc., due in structure there are conjugate planes structure, between molecule
With stronger intermolecular force, generated intramolecule electron transition dipole moment phenomenon causes to be in aggregation shape when it
Occurs Fluorescence-quenching when state.
Self-crosslinking is copolymerized colored homopolymer resin in hair jelly, hair gel, mousse, when extending frizzly recovery
Between, when combing hair, will not change curling and wave-like, after hair fixing, will not make curly headed through rainwater or adhesional wetting of taking a shower
It disappears.The access of fluorescent chemicals will not generate fluorescent quenching effect because of fluorescence intensity problem.Because fluorescent molecule is fixed on
On polymer segment, so that the internal molecular motion of fluorescent molecule is limited, absorbed UV energy mainly passes through fluorescence radiation side
Formula release, so that preparing paint solidification coating with intense fluorescence effect.
Summary of the invention
The purpose of the present invention is to provide a kind of ambient self-crosslinking fluorescent macromolecule dyestuff and its application, the fluorescence of preparation is big
Molecular dye is water-base polyurethane material, and safety and environmental protection is nontoxic, and glossiness is high, and filming performance is excellent；Applied to cosmetics
In be made hair jelly and mousse it is good to the adhesive force of hair, easy cleaning moderate at film hardness will not damage hair.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions:
The present invention be a kind of ambient self-crosslinking fluorescent macromolecule dyestuff, the macromolecular dyestuff by percentage to the quality by with
Lower raw material is made:
20-80 parts of acrylate mixture, 0.1-5 parts of fluorescent dye monomer, 1-10 parts of Diacetone Acrylamide, adipic acid
Two 1-10 parts of hydrazides, 0.1-1 parts of anion emulsifier, 0.1-0.3 parts of nonionic emulsifier, 0.1-1 parts of water soluble starter；
The preparation method of macromolecular dyestuff includes:
Step 1 measures above-mentioned each raw material for standby by formula；
Deionized water dispersion is added in Diacetone Acrylamide and fluorescent dye monomer by step 2,60 DEG C is warming up to, with 400
The revolving speed stirring turned, reacts 2 hours；
Step 3 continues that anion emulsifier and initiator is added to the reaction mixture of step 2, is heated to 80 DEG C,
Reaction 30 minutes；
Step 4 continues for acrylic acid mixture to be added to the water, at room temperature with 1600 revs/min of speed, high speed dispersion 30
Minute pre-emulsification is carried out, in the system before pre-emulsification monomer is slowly added into, is warming up to 85 DEG C, mixing speed control exists
500 revs/min, one-step method is reacted 2 hours, and system is cooled to room temperature；
Step 5 is eventually adding nonionic emulsifier, then adjusting pH value with AMP-95 is 10, and two acyl of adipic acid is then added
Hydrazine dissolution, is stirred 1 hour, is uniformly mixed, and the ambient self-crosslinking fluorescent macromolecule dyestuff is obtained.
Further, the acrylate mixture is methyl methacrylate, in the misery different ester of propylene, methacrylic acid
It is one or more.
Further, the water soluble starter is ammonium persulfate or potassium peroxydisulfate.
Further, the fluorescent dye monomer is selected from one or several kinds of combinations of following structural formula DYE1-DYE4:
R in structure above DYE1-DYE4 is-OH and/or-NH2.
A kind of application of ambient self-crosslinking fluorescent macromolecule dyestuff in cosmetics.
Ambient self-crosslinking macromolecular dyestuff is prepared applied to hair jelly；The hair jelly includes that ambient self-crosslinking is big in parts by weight
15-25 parts of molecular dye, 30-80 parts and essence 0.3-0.8 parts of ethyl alcohol；
Wherein, the weight ratio of the essence and ethyl alcohol is 0.5-1:100；
Wherein, the hair jelly is using ambient self-crosslinking macromolecular dyestuff as setting agent.
Further, the specific preparation method that the macromolecular dyestuff is applied to hair jelly preparation includes: by fluorescent macromolecule
Dyestuff and ethyl alcohol are added in stirring container, and at room temperature and normal pressure then stirring is added essence, is further continued for stirring 30 to dissolving
Minute.
Ambient self-crosslinking macromolecular dyestuff is prepared applied to mousse；The mousse includes room temperature selfing by weight percentage
The United Nations General Assembly molecular dye 10-20%, triethanolamine 0.5-1.5%, surfactant 1-2%, preservative 0.05-0.1%, essence
0.1-0.8% and excess water；
The mousse is using ambient self-crosslinking macromolecular dyestuff as setting agent.
Further, the specific preparation method that the macromolecular dyestuff is applied to mousse preparation includes: to add water to stir
It mixes in container, it is then living in room temperature, normal pressure addition ambient self-crosslinking fluorescent macromolecule dyestuff, triethanolamine, surface under stiring
Property agent, essence and preservative, stir 3 hours.
Further, the surfactant is polyether-modified dimethyl silicone polymer, laureth -9, nonyl phenol gather
At least one of ether -10, rilanit special, laureth sodium sulphate, lauryl glucoside.
The invention has the following advantages:
1, the ambient self-crosslinking fluorescent macromolecule dyestuff that invention obtains is water-base polyurethane material, safety collar
It protects, nontoxic, glossiness is high, and filming performance is excellent.
2, the Diacetone Acrylamide in the present invention is integrated in macromolecular by free radical, in film forming, is total to
Poly- Diacetone Acrylamide group can carry out self-crosslinking reaction with adipic dihydrazide, real when latex particle being promoted to form a film
Existing crosslinking net form.It can make the enhanced strength of fluorescence.It is not in be quenched.
3, the present invention in fluorescent dye monomer is integrated in macromolecular by covalent bond, can solve small molecule dyes or
The migration and permeability problems of pigment.
4, hair jelly and mousse prepared by the present invention, good to the adhesive force of hair, easy cleaning moderate at film hardness will not damage
Evil hair.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Specific embodiment
The fluorescent macromolecule dyestuff and hair jelly and mousse are described further below by embodiment.Each reality below
It applies the reagent used in example and meets cosmetics requirement.
Embodiment 1: ambient self-crosslinking fluorescent macromolecule dyestuff is prepared
50g water is taken, Diacetone Acrylamide and fluorescent dye monomer (DYE1) are added thereto dispersion, are warming up to 60 DEG C,
It is stirred with 400 turns of revolving speed, reacts 2 hours, then, take anion emulsifier 0.5g and 0.5g initiator to be added thereto, add
Heat is warming up to 80 DEG C, reacts 30 minutes, 40g acrylic acid mixture is added to the water, at room temperature with 1600 revs/min of speed,
30 minutes progress pre-emulsifications of high speed dispersion in the system before being slowly added into pre-emulsification monomer, are warming up to 85 DEG C, stirring speed
At 500 revs/min, one-step method is reacted 2 hours for degree control, and system is cooled to room temperature, nonionic emulsifier is added, then use AMP-95
Adjusting pH value is 10, and adipic dihydrazide dissolution is then added, stirs 1 hour, is uniformly mixed, obtains 1# ambient self-crosslinking fluorescence
Macromolecular dyestuff.
Embodiment 2
Fluorescent dye monomer (DYE1) in above-described embodiment 1 is replaced with into fluorescent dye monomer (DYE2), fluorescent dye
Monomer (DYE3) respectively obtains 2# ambient self-crosslinking fluorescent macromolecule dyestuff, the selfing of 3# room temperature after fluorescent dye monomer (DYE4)
Join fluorescent macromolecule dyestuff and 4# ambient self-crosslinking fluorescent macromolecule dyestuff.
The structural formula of above-mentioned fluorescent dye monomer (DYE1)-(DYE4) is respectively as follows:
Hair jelly application and preparation embodiment:
Application Example 1:
Alcohol 80g, 1# ambient self-crosslinking fluorescent macromolecule dyestuff 20g is taken to be added in beaker after stirring and dissolving at room temperature
Essence 0.8g is added, is stirred for obtaining 1# hair jelly in 30 minutes；
It is normal that above-mentioned 1# ambient self-crosslinking fluorescent macromolecule dyestuff is replaced with into 2# ambient self-crosslinking fluorescent macromolecule dyestuff, 3#
Warm self-crosslinking fluorescent macromolecule dyestuff and 4# ambient self-crosslinking fluorescent macromolecule dyestuff respectively obtain 2# hair jelly, 3# hair jelly and 4# hair
Glue.
Comparative example 1
Fetch water 80g at room temperature, and acrylic resin 20g is added in beaker addition essence 1g after stirring and dissolving, is stirred for 30
Minute obtains 5# hair jelly.
Comparative example 2:
Fetch water 80g at room temperature, acrylic resin 18g, and mill base 2g is added in beaker addition essence 1g after stirring and dissolving,
It is stirred for obtaining 6# hair jelly in 30 minutes.
Mousse application and preparation embodiment:
Application Example 2
Pure water 85g is added in beaker, then under stiring in 1g triethanolamine is added in room temperature, normal pressure, 1g polyethers changes
Property dimethyl silicone polymer, 1g laureth sodium sulphate, 0.4g essence, 0.05g methylchloroisothiazandnone, 1# room temperature selfing
Join fluorescent macromolecule dyestuff 11.55g, stirring obtained 1# mousse after 3 hours.
It is normal that above-mentioned 1# ambient self-crosslinking fluorescent macromolecule dyestuff is replaced with into 2# ambient self-crosslinking fluorescent macromolecule dyestuff, 3#
Warm self-crosslinking fluorescent macromolecule dyestuff and 4# ambient self-crosslinking fluorescent macromolecule dyestuff respectively obtain 2# mousse, 3# mousse and 4# and rub
Silk.
Comparative example 3
Pure water 85g is added in beaker, then under stiring in 1g triethanolamine is added in room temperature, normal pressure, 1g polyethers changes
Property dimethyl silicone polymer, 1g laureth sodium sulphate, 0.4g essence, 0.05g methylchloroisothiazandnone, 11.55g sizing
Agent, stirring obtained 5# mousse after 3 hours.
Comparative example 4
Pure water 85g is added in beaker, then under stiring in 1g triethanolamine is added in room temperature, normal pressure, 1g polyethers changes
Property dimethyl silicone polymer, 1g laureth sodium sulphate, 0.4g essence, 0.05g methylchloroisothiazandnone, 10g setting agent,
1g mill base, stirring obtained 6# mousse after 3 hours.
Method of evaluating performance is as follows:
1) curl retention measures
It is 30cm in long L, the hair jelly or mousse of the above-mentioned preparation of 0.6g is smeared on the topknot of weight 3g, is so post-rolled on long 9cm, it is interior
Diameter is to be fixed with hair clip on the curling iron of 1cm and be placed in 50 DEG C of baking oven drying.Topknot is removed after drying, measures the initial of topknot
Crimped length L1.Then topknot is hung in 30 DEG C, in the climatic chamber of 90%RH, the final lengths L2 of topknot is measured after 8h.
Curl retention=[(L-L2)/(L-L1)] × 100%
L is hair lengths 30cm in formula；L1 is curly hair initial length/cm；L2 is curly hair final lengths/cm.
A: curl retention is greater than 70%
B: curl retention is between 40-70%
C: curl retention is between 20-40%
2) white bits
Long 30cm, the hair jelly or mousse for applying the above-mentioned preparation of 0.6g on the topknot of 3g are weighed, topknot is done at tabular, at 50 DEG C
Middle drying；Then tabular topknot being placed on 25 DEG C, in the climatic chamber of 60%RH, placement is combed several times with comb afterwards for 24 hours,
With the white bits quantity to fall off on 20 times of entity microscope observing hairs.
A: without white bits or there are the white bits of minimal amount
B: there are white bits
C: there are a large amount of white bits
3) exudative test
It takes topknot to apply the hair jelly or mousse product of above-mentioned preparation, dries in 50 DEG C, then topknot soaks in a tepid bath,
Observe the color change of water.
A: there is no color
B: there is a little color
C: there is number of colors
1 hair jelly Evaluation results of table
2 mousse Evaluation results of table
| Project | 1# mousse | 2# mousse | 3# mousse | 4# mousse | 5# mousse | 6# mousse |
| Curl retention | A | A | A | A | C | B |
| White bits | A | A | A | A | C | B |
| Color exudation | A | A | A | A | / | C |
As can be seen that the hair that the ambient self-crosslinking fluorescent macromolecule dyestuff prepared through the invention is prepared from upper table 1 and 2
Glue and mousse shaping performance are good and rich in color, can satisfy customer demand, hair jelly and the experience of mousse performance in comparative example
Difference, and will appear serious bleeding after mill base is added.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means
Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention
In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example.
Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close
Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment
All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification,
It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention
Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only
It is limited by claims and its full scope and equivalent.
Claims (10)
1. a kind of ambient self-crosslinking fluorescent macromolecule dyestuff, it is characterised in that: the macromolecular dyestuff by percentage to the quality by
Following raw material is made:
20-80 parts of acrylate mixture, 0.1-5 parts of fluorescent dye monomer, 1-10 parts of Diacetone Acrylamide, two acyl of adipic acid
1-10 parts of hydrazine, 0.1-1 parts of anion emulsifier, 0.1-0.3 parts of nonionic emulsifier, 0.1-1 parts of water soluble starter；
The preparation method of macromolecular dyestuff includes:
Step 1 measures above-mentioned each raw material for standby by formula；
Deionized water dispersion is added in Diacetone Acrylamide and fluorescent dye monomer by step 2,60 DEG C is warming up to, with 400 turns
Revolving speed stirring, reacts 2 hours；
Step 3 continues that anion emulsifier and initiator is added to the reaction mixture of step 2, is heated to 80 DEG C, reaction
30 minutes；
Step 4 continues for acrylic acid mixture to be added to the water, at room temperature with 1600 revs/min of speed, high speed dispersion 30 minutes
Carry out pre-emulsification, in the system before pre-emulsification monomer is slowly added into, be warming up to 85 DEG C, mixing speed control 500 turns/
Point, one-step method is reacted 2 hours, and system is cooled to room temperature；
Step 5 is eventually adding nonionic emulsifier, then adjusting pH value with AMP-95 is 10, and it is molten that adipic dihydrazide is then added
Solution stirs 1 hour, is uniformly mixed, and obtains the ambient self-crosslinking fluorescent macromolecule dyestuff.
2. a kind of ambient self-crosslinking fluorescent macromolecule dyestuff according to claim 1, which is characterized in that the acrylate
Mixture is one of methyl methacrylate, the misery different ester of propylene, methacrylic acid or a variety of.
3. a kind of ambient self-crosslinking fluorescent macromolecule dyestuff according to claim 1, which is characterized in that the water solubility is drawn
Sending out agent is ammonium persulfate or potassium peroxydisulfate.
4. a kind of ambient self-crosslinking fluorescent macromolecule dyestuff according to claim 1, which is characterized in that the fluorescent dye
Monomer is selected from one or several kinds of combinations of following structural formula DYE1-DYE4
R in structure above DYE1-DYE4 is-OH and/or-NH2。
5. a kind of application of any one ambient self-crosslinking fluorescent macromolecule dyestuff of claim 1-4 in cosmetics.
6. application according to claim 5, which is characterized in that the ambient self-crosslinking macromolecular dyestuff is applied to hair jelly system
It is standby；The hair jelly includes 15-25 parts of ambient self-crosslinking macromolecular dyestuff in parts by weight, 30-80 parts of ethyl alcohol and essence 0.3-0.8
Part；
Wherein, the weight ratio of the essence and ethyl alcohol is 0.5-1:100；
Wherein, the hair jelly is using ambient self-crosslinking macromolecular dyestuff as setting agent.
7. application according to claim 6, which is characterized in that the macromolecular dyestuff is applied to the specific system of hair jelly preparation
Preparation Method includes: that fluorescent macromolecule dyestuff and ethyl alcohol are added in stirring container, and stirring is to dissolving at room temperature and normal pressure, so
After essence is added, be further continued for stirring 30 minutes.
8. application according to claim 5, which is characterized in that the ambient self-crosslinking macromolecular dyestuff is applied to mousse system
It is standby；The mousse includes ambient self-crosslinking macromolecular dyestuff 10-20%, triethanolamine 0.5-1.5%, table by weight percentage
Face activating agent 1-2%, preservative 0.05-0.1%, essence 0.1-0.8% and excess water；
The mousse is using ambient self-crosslinking macromolecular dyestuff as setting agent.
9. application according to claim 8, which is characterized in that the macromolecular dyestuff is applied to the specific system of mousse preparation
Preparation Method includes: to add water in stirring container, and ambient self-crosslinking fluorescence then is added in room temperature, normal pressure under stiring and divides greatly
Sub- dyestuff, triethanolamine, surfactant, essence and preservative stir 3 hours.
10. application according to claim 8 or claim 9, which is characterized in that the surfactant is polyether-modified poly dimethyl
Siloxanes, laureth -9, nonyl phenol polyethers -10, rilanit special, laureth sodium sulphate, in lauryl glucoside
At least one.
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|---|---|---|---|
| CN201910024373.5A CN109679376A (en) | 2019-01-10 | 2019-01-10 | A kind of ambient self-crosslinking fluorescent macromolecule dyestuff and its application |
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| CN201910024373.5A CN109679376A (en) | 2019-01-10 | 2019-01-10 | A kind of ambient self-crosslinking fluorescent macromolecule dyestuff and its application |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110655603A (en) * | 2019-08-28 | 2020-01-07 | 齐鲁工业大学 | Synthetic method of fluorescent polyacrylate based on anhydride naphthalene |
| CN111961301A (en) * | 2020-07-22 | 2020-11-20 | 江苏华彩化学科技有限公司 | Safe and environment-friendly boron-free ultra-light clay and preparation method thereof |
-
2019
- 2019-01-10 CN CN201910024373.5A patent/CN109679376A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110655603A (en) * | 2019-08-28 | 2020-01-07 | 齐鲁工业大学 | Synthetic method of fluorescent polyacrylate based on anhydride naphthalene |
| CN110655603B (en) * | 2019-08-28 | 2021-09-24 | 齐鲁工业大学 | Synthetic method of fluorescent polyacrylate based on anhydride naphthalene |
| CN111961301A (en) * | 2020-07-22 | 2020-11-20 | 江苏华彩化学科技有限公司 | Safe and environment-friendly boron-free ultra-light clay and preparation method thereof |
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Application publication date: 20190426 |
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| WW01 | Invention patent application withdrawn after publication |