CN109679274A - A kind of water-permeable colored pitch and its production technology - Google Patents

A kind of water-permeable colored pitch and its production technology Download PDF

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Publication number
CN109679274A
CN109679274A CN201811611856.7A CN201811611856A CN109679274A CN 109679274 A CN109679274 A CN 109679274A CN 201811611856 A CN201811611856 A CN 201811611856A CN 109679274 A CN109679274 A CN 109679274A
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China
Prior art keywords
water
parts
permeable colored
colored pitch
petropols
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CN201811611856.7A
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Chinese (zh)
Inventor
田林乐
赵俊
吕华生
郝水平
吉永海
邹进忠
涂娟
万路
李煜城
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GUANGXI GUOCHUANG ROAD MATERIALS Co Ltd
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GUANGXI GUOCHUANG ROAD MATERIALS Co Ltd
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Priority to CN201811611856.7A priority Critical patent/CN109679274A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C08L57/02Copolymers of mineral oil hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention belongs to Expressway Pavement Material technical fields, and in particular to a kind of water-permeable colored pitch is made of raw material from the following weight: 40-55 parts of Petropols, 30-55 parts of furfural extract oil, 4-12 parts of SBS modifier, 0.2-3 parts of Fischer-Tropsch wax.The present invention also provides the production technologies of water-permeable colored pitch.Water-permeable colored pitch of the invention, it is low that it produces required temperature compared with the prior art, it is energy saving, and high speed shear is not needed during the preparation process, without additionally adding equipment, production cost and process, and obtained water-permeable colored pitch excellent combination property are reduced, extraordinary color asphalt technical requirements in " urban road colour asphalt pavement technical regulation " CJJ/T218-2014 are met.

Description

A kind of water-permeable colored pitch and its production technology
Technical field
The invention belongs to Expressway Pavement Material technical fields, and in particular to a kind of water-permeable colored pitch and its production technology.
Background technique
With the development of economy with the continuous improvement of scientific and technological level, people have the coordination performance of road and environment Understanding more profound also has higher requirement the comfort and functionality of road.Colorful Asphalt Pavement is as a kind of novel Paving technology, exactly meet these requirements, cause the extensive concern of people.Color asphalt concrete is used in the road It is laid with road surface, mainly there are two big functions: 1. beautifying city, road improvement environment, Urban style effect is shown, is applied particularly to Avenue, square, scenic spot, park and tourist sight road etc.;2. inducing wagon flow, change traffic administration intuitively, specifically answers Increase the traffic capacity and traffic peace of road with the section and lane for distinguishing different function to improve the recognition effect of driver Entirely.
Currently, Colorful Asphalt Pavement making is mainly divided to two classes: the first kind is spray coating method, and the method is convenient for construction, low cost It is honest and clean but not durable;Another kind of to mix chromatic bitumen mixture spreading method for heat, the color persistence of the method is longer.Heat mixes colored drip Blueness is by early stage asphalt decoloration preparation till now using main materials systems such as resinous material, base oil, high molecular polymers It is standby.Production cost and technology difficulty all reduce very much, and technology is more mature, and present heat mixes the ductility of color asphalt, high temperature Stability, low-temperature cracking-resistance and durability are more preferable.
China sponge city pilot is carried out in succession, and color asphalt drainage pavement is also more and more prominent in sponge urban construction Out, however, this is also to the cementitious matter of color asphalt drainage pavement, more stringent requirements are proposed: the 1. viscosity and softening of color asphalt Point is very high, to meet the structural strength of macroporosity drainage pavement, to resist traffic load and external environment active force;② Cementitious matter will also have enough anti-aging and anti-water damage property.
In the prior art, usually addition SBS modifier improves the performance of color asphalt into color asphalt, but When preparing color asphalt, addition SBS modifier usually requires high speed shear, not only increases preparation section in this way, it is also necessary to It increases manufacturing facilities more.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of water-permeable colored pitches, needed for production compared with the prior art Temperature is low, energy saving, and does not need high speed shear during the preparation process, without additional addition equipment, reduce production cost and Process, and obtained water-permeable colored pitch excellent combination property meet " urban road colour asphalt pavement technology rule Journey " extraordinary color asphalt technical requirements in CJJ/T218-2014.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of water-permeable colored pitch, is made of raw material from the following weight: 40-55 parts of Petropols, furfural extract oil 30- 55 parts, 4-12 parts of SBS modifier, 0.2-3 parts of Fischer-Tropsch wax.
Preferably, water-permeable colored pitch of the present invention, is made of raw material from the following weight: 50 parts of Petropols, 45 parts of furfural extract oil, 8 parts of SBS modifier, 1.6 parts of Fischer-Tropsch wax.
Preferably, Petropols of the present invention are C9 Petropols, molecular weight 1000-6000, softening point 100- 130℃。
Preferably, SBS modifier of the present invention is type SBS or star-shaped sbs, or the mixture for the two.
Preferably, Fischer-Tropsch wax model SX105 of the present invention.
The present invention also provides the production technologies of water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 155-160 DEG C, SBS modifier stirring is added development 0.5-1 hours, is mixed Expect a;
2) Petropols are added in above-mentioned mixture a, 145-155 DEG C of temperature control, stirring development 1.5-2 hours obtains Mixture b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 145-155 DEG C of temperature control, stirring development 0.5-1 hours to get saturating Water color asphalt finished product.
Preferably, in the method for the present invention, in the step 1), 158 DEG C are warming up to.
Preferably, in the method for the present invention, in the step 2), 150 DEG C of temperature control.
Preferably, in the method for the present invention, in the step 3), 148 DEG C of temperature control.
In production application, color according to actual needs, be added toner and water-permeable colored pitch of the invention at Product mix and stir.
Water-permeable colored pitch of the invention is developed with extraordinary color asphalt technical standard.
Compared with prior art, the beneficial effects of the present invention are:
1, the water-permeable colored asphalt production of present invention gained addition species used are few, and when adding SBS modifier, are not required to High speed shear is wanted, without additional addition equipment, reduces production cost and process, overall simplified production technology.
2, the present invention, which adds a small amount of Fischer-Tropsch wax SX105, can be improved stability of the SBS modifier in system, reduce saturating The kinematic viscosity that 135 DEG C of water color asphalt;Meanwhile the wearability of water-permeable colored pitch, prolonging service life of pavement can be improved.
3, the water-permeable colored pitch excellent combination property that the present invention obtains meets " urban road color asphalt concrete road Surface technology regulation " extraordinary color asphalt technical requirements in CJJ/T218-2014.
Specific embodiment
The invention will be further described with reference to embodiments, but the invention is not limited to these embodiments.
Embodiment 1
A kind of water-permeable colored pitch, is made of raw material from the following weight: 50 parts of Petropols, 45 parts of furfural extract oil, 8 parts of SBS modifier, 1.6 parts of the Fischer-Tropsch wax of model SX105, the Petropols be C9 Petropols, molecular weight 5000, Softening point is 120 DEG C, and the SBS modifier is that type SBS and star-shaped sbs are mixed by the weight ratio of 1:1.
The production technology of the water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 158 DEG C, SBS modifier stirring is added development 0.8 hour, obtains mixture a;
2) Petropols are added in above-mentioned mixture a, 150 DEG C of temperature control, stirring development 1.8 hours obtains mixture b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 148 DEG C of temperature control, stirring development 0.5 hour to get water-permeable colored Pitch finished product.
Embodiment 2
A kind of water-permeable colored pitch, is made of raw material from the following weight: 40 parts of Petropols, 55 parts of furfural extract oil, 4 parts of type SBS modifying agent, 0.2 part of the Fischer-Tropsch wax of model SX105, the Petropols are C9 Petropols, and molecular weight is 6000, softening point is 100 DEG C.
The production technology of the water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 160 DEG C, SBS modifier stirring is added development 0.5 hour, obtains mixture a;
2) Petropols are added in above-mentioned mixture a, 155 DEG C of temperature control, stirring development 2 hours obtains mixture b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 155 DEG C of temperature control, stirring development 0.5 hour to get water-permeable colored Pitch finished product.
Embodiment 3
A kind of water-permeable colored pitch, is made of raw material from the following weight: 55 parts of Petropols, 30 parts of furfural extract oil, 12 parts of star-shaped sbs modifying agent, 3 parts of the Fischer-Tropsch wax of model SX105, the Petropols are C9 Petropols, and molecular weight is 1000, softening point is 130 DEG C.
The production technology of the water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 155 DEG C, SBS modifier stirring is added development 1 hour, obtains mixture a;
2) Petropols are added in above-mentioned mixture a, 145 DEG C of temperature control, stirring development 1.5 hours obtains mixture b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 145 DEG C of temperature control, stirring development 0.8 hour to get water-permeable colored Pitch finished product.
Embodiment 4
A kind of water-permeable colored pitch, is made of raw material from the following weight: 50 parts of Petropols, 45 parts of furfural extract oil, 8 parts of SBS modifier, 0.2 part of the Fischer-Tropsch wax of model SX105, the Petropols be C9 Petropols, molecular weight 5000, Softening point is 120 DEG C, and the SBS modifier is that type SBS and star-shaped sbs are mixed by the weight ratio of 1:1.
The production technology of the water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 158 DEG C, SBS modifier stirring is added development 0.8 hour, obtains mixture a;
2) Petropols are added in above-mentioned mixture a, 150 DEG C of temperature control, stirring development 1.8 hours obtains mixture b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 148 DEG C of temperature control, stirring development 0.5 hour to get water-permeable colored Pitch finished product.
Embodiment 5
A kind of water-permeable colored pitch, is made of raw material from the following weight: 50 parts of Petropols, 45 parts of furfural extract oil, 8 parts of SBS modifier, 3 parts of the Fischer-Tropsch wax of model SX105, the Petropols are C9 Petropols, and molecular weight 5000 is soft Changing point is 120 DEG C, and the SBS modifier is that type SBS and star-shaped sbs are mixed by the weight ratio of 1:1.
The production technology of the water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 158 DEG C, SBS modifier stirring is added development 0.8 hour, obtains mixture a;
2) Petropols are added in above-mentioned mixture a, 150 DEG C of temperature control, stirring development 1.8 hours obtains mixture b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 148 DEG C of temperature control, stirring development 0.5 hour to get water-permeable colored Pitch finished product.
Embodiment 6
A kind of water-permeable colored pitch, is made of raw material from the following weight: 50 parts of Petropols, 45 parts of furfural extract oil, 4 parts of SBS modifier, 0.2 part of the Fischer-Tropsch wax of model SX105, the Petropols be C9 Petropols, molecular weight 5000, Softening point is 120 DEG C, and the SBS modifier is that type SBS and star-shaped sbs are mixed by the weight ratio of 1:1.
The production technology of the water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 158 DEG C, SBS modifier stirring is added development 0.8 hour, obtains mixture a;
2) Petropols are added in above-mentioned mixture a, 150 DEG C of temperature control, stirring development 1.8 hours obtains mixture b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 148 DEG C of temperature control, stirring development 0.5 hour to get water-permeable colored Pitch finished product.
Embodiment 7
A kind of water-permeable colored pitch, is made of raw material from the following weight: 50 parts of Petropols, 45 parts of furfural extract oil, 12 parts of SBS modifier, 0.2 part of the Fischer-Tropsch wax of model SX105, the Petropols be C9 Petropols, molecular weight 5000, Softening point is 120 DEG C, and the SBS modifier is that type SBS and star-shaped sbs are mixed by the weight ratio of 1:1.
The production technology of the water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 158 DEG C, SBS modifier stirring is added development 0.8 hour, obtains mixture a;
2) Petropols are added in above-mentioned mixture a, 150 DEG C of temperature control, stirring development 1.8 hours obtains mixture b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 148 DEG C of temperature control, stirring development 0.5 hour to get water-permeable colored Pitch finished product.
Comparative example 1
Unlike the first embodiment: 0.1 part of Fischer-Tropsch wax.Remaining is the same as embodiment 1.
Comparative example 2
Unlike the first embodiment: 3.2 parts of Fischer-Tropsch wax.Remaining is the same as embodiment 1.
Comparative example 3
Unlike the first embodiment: 1 part of SBS modifier.Remaining is the same as embodiment 1.
Comparative example 4
Unlike the first embodiment: 13 parts of SBS modifier.Remaining is the same as embodiment 1.
Comparative example 5
Unlike the first embodiment: changing the Fischer-Tropsch wax of model SX105 into paraffin.Remaining is the same as embodiment 1.
Comparative example 6
Unlike the first embodiment: changing the Fischer-Tropsch wax of model SX105 into polyethylene wax.Remaining is the same as embodiment 1.
Comparative example 7
Unlike the first embodiment: changing SBS modifier into SBR modifying agent.Remaining is the same as embodiment 1.
Comparative example 8
A kind of water-permeable colored pitch, is made of raw material from the following weight: 50 parts of Petropols, 45 parts of furfural extract oil, 8 parts of SBS modifier, 1.6 parts of the Fischer-Tropsch wax of model SX105, the Petropols be C9 Petropols, molecular weight 5000, Softening point is 120 DEG C, and the SBS modifier is that type SBS and star-shaped sbs are mixed by the weight ratio of 1:1.
The production technology of the water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 158 DEG C, SBS modifier stirring is added development 0.8 hour, obtains mixture a;
2) Petropols, Fischer-Tropsch wax are added in above-mentioned mixture a, 150 DEG C of temperature control, stirring development 2.3 hours to get Water-permeable colored pitch finished product.
Comparative example 9
A kind of water-permeable colored pitch, is made of raw material from the following weight: 50 parts of Petropols, 45 parts of furfural extract oil, 8 parts of SBS modifier, 1.6 parts of the Fischer-Tropsch wax of model SX105, the Petropols be C9 Petropols, molecular weight 5000, Softening point is 120 DEG C, and the SBS modifier is that type SBS and star-shaped sbs are mixed by the weight ratio of 1:1.
The production technology of the water-permeable colored pitch, including following preparation step:
1) furfural extract oil is warming up to 158 DEG C, SBS modifier stirring is added development 0.8 hour, obtains mixture a;
2) Fischer-Tropsch wax is added in above-mentioned mixture a, 150 DEG C of temperature control, stirring development 1.8 hours obtains mixture b;
3) Petropols are added in above-mentioned mixture b, 148 DEG C of temperature control, stirring development 0.5 hour to get permeable coloured silk Color pitch finished product.
Comparative example 10
A kind of water-permeable colored pitch, is made of raw material from the following weight: 50 parts of Petropols, 45 parts of furfural extract oil, 8 parts of SBS modifier, 1.6 parts of the Fischer-Tropsch wax of model SX105, the Petropols be C9 Petropols, molecular weight 5000, Softening point is 120 DEG C, and the SBS modifier is that type SBS and star-shaped sbs are mixed by the weight ratio of 1:1.
The production technology of the water-permeable colored pitch, including following preparation step:
1) Petropols are warming up to 158 DEG C, SBS modifier stirring are added development 0.8 hour, obtain mixture a;
2) furfural extract oil is entered into above-mentioned mixture a, 150 DEG C of temperature control, stirring development 1.8 hours obtains mixture b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 148 DEG C of temperature control, stirring development 0.5 hour to get water-permeable colored Pitch finished product.
Test example: different compositions, content and the different production technologies of the water-permeable colored pitch of the present invention are to its performance It influences
The technology of the present invention standard is using " urban road colour asphalt pavement technical regulation " CJJ/T218-2014 Middle special type color asphalt technical requirements, specific requirement and test method are shown in Table 1, the different compositions of the water-permeable colored pitch of the present invention, The influence of content and different production technologies to its performance is shown in Table 2- table 5.
The extraordinary color asphalt technical standard of table 1 and test method
The different Fischer-Tropsch wax contents of table 2 influence the performance of the water-permeable colored pitch of the present invention
From table 2 it can be seen that obtained water-permeable colored asphalt performance is excellent when Fischer-Tropsch wax content is 0.2-3 parts at that time, it is full Extraordinary color asphalt technical requirements in foot " urban road colour asphalt pavement technical regulation " CJJ/T218-2014, but It is when Fischer-Tropsch wax content less than 0.2 part or when being greater than 3 parts, extraordinary colour is not achieved in obtained water-permeable colored pitch partial properties Bitumen technology requirement, can not meet production requirement.
The different SBS modifier contents of table 3 influence the performance of the water-permeable colored pitch of the present invention
From table 3 it can be seen that different SBS modifier contents will affect the performance of water-permeable colored pitch, work as SBS modifier When content is 4-12 parts, obtained water-permeable colored asphalt performance is excellent, meets " urban road colour asphalt pavement technology Regulation " extraordinary color asphalt technical requirements in CJJ/T218-2014, but when SBS modifier content less than 4 parts or is greater than 12 When part, extraordinary color asphalt technical requirements are not achieved in obtained water-permeable colored pitch partial properties, can not meet production requirement.
4 different material of table substitution influences the performance of the water-permeable colored pitch of the present invention
From table 4, it can be seen that when substituting Fischer-Tropsch wax with the paraffin and polyethylene wax with Fischer-Tropsch wax with similar functions, Or with SBR modifying agent replacement SBS modifier form new formula when, the identical impact of performance can not be obtained, obtain To water-permeable colored pitch partial properties extraordinary color asphalt technical requirements are not achieved, production requirement can not be met, illustrate this Invent the Fischer-Tropsch wax used and SBS modifier has irreplaceability in formula.
5 various processes of table influence the performance of the water-permeable colored pitch of the present invention
As can be seen from Table 5, in the production technology of water-permeable colored pitch, in order to reduce the equipment investment of high speed shear, Production process is reduced, in production technology of the invention, the temperature control development step of three phases can not lack a step therein, Otherwise, extraordinary color asphalt technical requirements are not achieved in the water-permeable colored pitch partial properties being prepared, and can not meet production Demand, meanwhile, in production technology, the addition sequence of raw material can not change, if changed, what is be prepared is water-permeable colored Extraordinary color asphalt technical requirements are not achieved in pitch partial properties, can not meet production requirement.

Claims (9)

1. a kind of water-permeable colored pitch, which is characterized in that be made of raw material from the following weight: 40-55 parts of Petropols, furfural 30-55 parts of oil of extraction, 4-12 parts of SBS modifier, 0.2-3 parts of Fischer-Tropsch wax.
2. water-permeable colored pitch according to claim 1, which is characterized in that be made of raw material from the following weight: petroleum 50 parts of resin, 45 parts of furfural extract oil, 8 parts of SBS modifier, 1.6 parts of Fischer-Tropsch wax.
3. water-permeable colored pitch according to claim 1 or 2, it is characterised in that: the Petropols are C9 Petropols, Molecular weight is 1000-6000, and softening point is 100-130 DEG C.
4. water-permeable colored pitch according to claim 1 or 2, it is characterised in that: the SBS modifier be type SBS or Star-shaped sbs, or the mixture for the two.
5. water-permeable colored pitch according to claim 1 or 2, it is characterised in that: the Fischer-Tropsch wax model SX105.
6. the production technology of water-permeable colored pitch according to claim 1 or 2, which is characterized in that walked including following preparation It is rapid:
1) furfural extract oil is warming up to 155-160 DEG C, SBS modifier stirring is added development 0.5-1 hours, obtains mixture a;
2) Petropols are added in above-mentioned mixture a, 145-155 DEG C of temperature control, stirring development 1.5-2 hours is mixed Expect b;
3) Fischer-Tropsch wax is added in above-mentioned mixture b, 145-155 DEG C of temperature control, stirring development 0.5-1 hours to get permeable coloured silk Color pitch finished product.
7. the production technology of water-permeable colored pitch according to claim 6, it is characterised in that: in the step 1), heating To 158 DEG C.
8. the production technology of water-permeable colored pitch according to claim 6, it is characterised in that: in the step 2), temperature control 150℃。
9. the production technology of water-permeable colored pitch according to claim 6, it is characterised in that: in the step 3), temperature control 148℃。
CN201811611856.7A 2018-12-27 2018-12-27 A kind of water-permeable colored pitch and its production technology Pending CN109679274A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114517019A (en) * 2022-02-18 2022-05-20 雨中情防水技术集团股份有限公司 Asphalt coating material, low-water-absorptivity asphalt waterproof roll and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017088892A1 (en) * 2015-11-24 2017-06-01 Inbicon A/S Bitumen compositions comprising lignin
CN107353829A (en) * 2017-07-03 2017-11-17 唐山东方雨虹防水技术有限责任公司 A kind of rubber asphalt waterproof coating and preparation method thereof
CN108395707A (en) * 2017-02-07 2018-08-14 中国石油化工股份有限公司 A kind of patching material of Colorful Asphalt Pavement and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017088892A1 (en) * 2015-11-24 2017-06-01 Inbicon A/S Bitumen compositions comprising lignin
CN108395707A (en) * 2017-02-07 2018-08-14 中国石油化工股份有限公司 A kind of patching material of Colorful Asphalt Pavement and preparation method thereof
CN107353829A (en) * 2017-07-03 2017-11-17 唐山东方雨虹防水技术有限责任公司 A kind of rubber asphalt waterproof coating and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114517019A (en) * 2022-02-18 2022-05-20 雨中情防水技术集团股份有限公司 Asphalt coating material, low-water-absorptivity asphalt waterproof roll and preparation method thereof

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Application publication date: 20190426