CN109666258A - A kind of low smell is low to distribute ABS alloy material and preparation method thereof - Google Patents
A kind of low smell is low to distribute ABS alloy material and preparation method thereof Download PDFInfo
- Publication number
- CN109666258A CN109666258A CN201811612112.7A CN201811612112A CN109666258A CN 109666258 A CN109666258 A CN 109666258A CN 201811612112 A CN201811612112 A CN 201811612112A CN 109666258 A CN109666258 A CN 109666258A
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- Prior art keywords
- low
- alloy material
- abs alloy
- abs
- smell
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
ABS alloy material and preparation method thereof is distributed the invention discloses a kind of low smell is low, which is mainly made of 70~90 parts of ABS, 10~20 parts of high glue powder, 0.1~2 part of antioxidant, 0.1~2 part of light stabilizer, 0.5~2 part of adsorbent.It is reasonably matched using being there is the present invention to pass through, it is preferred that going out high glue powder, antioxidant and its type and dosage for being suitble to improve ABS plastic mechanical toughness performance, a small amount of adsorbent is added in ABS plastic, there is better improvement to ABS alloy material smell, adsorbent by after being blended with major ingredient and one superhigh speed of auxiliary agent through extrusion, it is squeezed out from double screw extruder and passes through vacuum and largely detach small molecule, reduce plastics smell, obtain the low smell ABS alloy material of high comprehensive performance.
Description
Technical field
ABS alloy material and preparation method thereof more particularly to a kind of low smell are distributed the present invention relates to a kind of low smell is low
It is low to distribute ABS alloy material, belong to engineering plastics technical field.
Background technique
Engineering plastics are cheap and with excellent heat resistance and processing easy to form etc. because it is wide with raw material sources
Feature, and be widely used in the products such as automobile interior exterior decorations, household electrical appliances, PC, become plastics variety with the fastest developing speed
One of.Recently as the continuous development of continuous improvement of people's living standards and science and technology, people to ABS plastic and its
The health of product and the requirement of the feature of environmental protection are also higher and higher, particularly with certain ABS plastic often frequently contacted with human body
Product, such as some household electrical appliance, daily necessities and automotive upholstery, these components are during using and storing, certain
Temperature under the conditions of, product be easy to produce smell and breed largely to human health generate smell has been unable to meet people not
The disconnected health environment-friendly demand improved.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of low smell it is low distribute ABS alloy material and
Preparation method, this method mainly include that a kind of adsorbent is added in ABS major ingredient to be total to by double screw extruder or injection molding machine
Mixed extrusion is prepared.It is crowded from double screw extruder or injection molding machine that there is adsorbent the carrier of preferable compatibility to be added in major ingredient
When out, pass through the small molecule object of double vacuum drawns generation of extruder.
For up to foregoing invention purpose, the present invention is achieved through the following technical solutions:
A kind of low smell is low to distribute ABS alloy material, is prepared according to parts by weight by following ingredients:
ABS:70~90 part；
High glue powder: 10~20 parts；
Antioxidant: 0.1~2 part；
Light stabilizer: 0.1~2 part；
0.5~2 part of adsorbent.
Further, the ABS is that acrylonitrile-butadiene-phenylethylene material refers at 220 DEG C, material under the conditions of 10Kg
ABS material of the flowing velocity of material in 5~30g/10min.
The high glue powder is styrene, acrylonitrile-butadiene rubber.
The adsorbent is the agent of AS carrier adsorption.
The auxiliary agent is antioxidant DSTP (the double octadecyls of thio-2 acid), antioxidant 1010 (four (β-3,5-two
4-hydroxy phenyl of tert-butyl -) pentaerythritol resin), (three (2,4-di-tert-butyl-phenyl) phosphite esters, light are steady for irgasfos 168
Determine agent V703,5589,531, the double stearoylketene amine (EBS) of vinyl are one such or several mixtures.
The low preparation method for distributing ABS alloy material of above-mentioned low smell, its step are as follows:
(3) each raw material is weighed in parts by weight；
(4) raw material is added in high speed mixer after mixing by step (1) together, is then added to twin-screw extrusion
In machine, ABS alloy material is prepared into through double screw extruder melting, extrusion, cooling, pelletizing.
The area the I~X processing temperature of the double screw extruder is followed successively by 165 DEG C, and 200 DEG C, 215 DEG C, 215 DEG C, 220
DEG C, 220 DEG C, 225 DEG C, 225 DEG C, 230 DEG C, 235 DEG C.Driving screw revolving speed is 250~400r/min, sink temperature 23 DEG C~50
℃。
Compared with prior art, the present invention with following technical advantage: the present invention, which uses, has the addition of low smell ABS major ingredient
Adsorbent and antioxidant, ultraviolet-resistant aid etc., and using twin-screw extrusion equipment by vacuum drawn small molecule object, it is prepared
ABS alloy material have the characteristics that low smell it is low distribute, good mechanical performance.
Specific embodiment
Comparative example 1
In contrast, preferably to embody with embodiment 2,3,4,5, a kind of low smell of the present invention is low to distribute ABS alloy material
And preparation method thereof the mechanical performances such as corresponding stretchings, impact strength, corresponding comparative example 1 is using routine ABS alloy side at present
Method directly adds the ratio of parts by weight same as Example 1, main including implementation steps in detail below:
It in parts by weight, is 90 parts of 8391ABS material of 25g/10min by step (1) flowing velocity, high glue powder powder 5
Part, 0.5 part of antioxidant, other auxiliary agents: double 1.9 parts of amine of the stearoylketenes of vinyl, which are added to together in high speed mixer, to be uniformly mixed
Afterwards, it is then added in double screw extruder, is prepared into ABS alloy material through double screw extruder melting, extrusion, cooling, pelletizing.
The area the I~X processing temperature of the double screw extruder is followed successively by 165 DEG C, and 190 DEG C, 210 DEG C, 215 DEG C, 225
DEG C, 230 DEG C, 235 DEG C, 235 DEG C, 240 DEG C, 235 DEG C.Driving screw revolving speed be 350r/min, 40 DEG C of sink temperature.
Embodiment 2
For in contrast, preferably embodied with embodiment 11 a kind of low smell of the invention it is low distribute ABS alloy material and its
The mechanical performances such as preparation method stretches accordingly, impact strength, corresponding comparative example 1 is using conventional ABS alloy method at present, directly
The ratio for adding parts by weight same as Example 1 is connect, main including implementation steps in detail below:
In parts by weight, by 90 parts of 8391ABS material that step (1) flowing velocity is 25g/10min, 5 parts of high glue powder powder,
It 0.5 part of antioxidant, 0.5 part of adsorbent, in high speed mixer after mixing, is then added in double screw extruder, through double spiral shells
The melting of bar extruder, extrusion, cooling, pelletizing are prepared into anti-ABS alloy material.
The area the I~X processing temperature of the double screw extruder is followed successively by 165 DEG C, and 190 DEG C, 210 DEG C, 215 DEG C, 225
DEG C, 230 DEG C, 235 DEG C, 235 DEG C, 240 DEG C, 235 DEG C.Driving screw revolving speed be 350r/min, 40 DEG C of sink temperature
Embodiment 3
For in contrast, preferably embodied with embodiment 11 a kind of low smell of the invention it is low distribute ABS alloy material and its
The mechanical performances such as preparation method stretches accordingly, impact strength, corresponding comparative example 1 is using conventional ABS alloy method at present, directly
The ratio for adding parts by weight same as Example 1 is connect, main including implementation steps in detail below:
In parts by weight, by 90 parts of 8391ABS material that step (1) flowing velocity is 25g/10min, 5 parts of high glue powder powder,
It 0.5 part of antioxidant, 1 part of adsorbent, in high speed mixer after mixing, is then added in double screw extruder, through twin-screw
Extruder melting, extrusion, cooling, pelletizing are prepared into ABS alloy material.
The area the I~X processing temperature of the double screw extruder is followed successively by 165 DEG C, and 190 DEG C, 210 DEG C, 215 DEG C, 225
DEG C, 230 DEG C, 235 DEG C, 235 DEG C, 240 DEG C, 235 DEG C.Driving screw revolving speed be 350r/min, 40 DEG C of sink temperature
Embodiment 4
For in contrast, preferably embodied with embodiment 11 a kind of low smell of the invention it is low distribute ABS alloy material and its
The mechanical performances such as preparation method stretches accordingly, impact strength, corresponding comparative example 1 is using conventional ABS alloy method at present, directly
The ratio for adding parts by weight same as Example 1 is connect, main including implementation steps in detail below:
In parts by weight, by 90 parts of 8391ABS material that step (1) flowing velocity is 25g/10min, 5 parts of high glue powder powder,
It 0.5 part of antioxidant, 1.5 parts of adsorbent, in high speed mixer after mixing, is then added in double screw extruder, through double spiral shells
The melting of bar extruder, extrusion, cooling, pelletizing are prepared into ABS alloy material.
The area the I~X processing temperature of the double screw extruder is followed successively by 165 DEG C, and 190 DEG C, 210 DEG C, 215 DEG C, 225
DEG C, 230 DEG C, 235 DEG C, 235 DEG C, 240 DEG C, 235 DEG C.Driving screw revolving speed be 350r/min, 40 DEG C of sink temperature
Embodiment 5
For in contrast, preferably embodied with embodiment 11 a kind of low smell of the invention it is low distribute ABS alloy material and its
The mechanical performances such as preparation method stretches accordingly, impact strength, corresponding comparative example 1 is using conventional ABS alloy method at present, directly
The ratio for adding parts by weight same as Example 1 is connect, main including implementation steps in detail below:
In parts by weight, by 90 parts of 8391ABS material that step (1) flowing velocity is 25g/10min, 5 parts of high glue powder powder,
It 0.5 part of antioxidant, 2 parts of adsorbent, in high speed mixer after mixing, is then added in double screw extruder, through twin-screw
Extruder melting, extrusion, cooling, pelletizing are prepared into ABS alloy material.
The area the I~X processing temperature of the double screw extruder is followed successively by 165 DEG C, and 190 DEG C, 210 DEG C, 215 DEG C, 225
DEG C, 230 DEG C, 235 DEG C, 235 DEG C, 240 DEG C, 235 DEG C.Driving screw revolving speed be 350r/min, 40 DEG C of sink temperature
It is tested using Volkswagen's interior trim smell PV3900 standard, tests grade and test condition is as follows:
| Score | Assessment |
| 1 | It can not recognize |
| 2 | It can recognize, noiseless factor |
| 3 | It can clearly debate, noiseless factor |
| 4 | There is disturbing factor |
| 5 | There is severe jamming factor |
| 6 | It can't bear to endure |
| Serial number | Test rating | The method of inspection | Unit | Test condition |
| 1 | Smell | PV3900 | Grade | 80℃*2h |
2 Examples 1 to 4 of the table and its low smell of comparative example is low distributes ABS alloy material material smell test data
Embodiment 2~5 is to distribute ABS alloy material and its preparation side according to a kind of low smell of the invention patent is low in table 2
The low test result for distributing ABS alloy material of low smell of method part representative embodiment preparation.As can be drawn from Table 2 with
Draw a conclusion:
(1) distributing ABS alloy material and preparation method thereof since a kind of low smell of the present invention is low is by adding AS carrier
Adsorbent and its main body A BS material and various auxiliary agents high speed is blended after it is by double screw extruder and effective by pair vacuum
The smell for reducing material.
(2) smell can be effectively reduced after adding 2 parts using the agent of AS carrier adsorption due to the present invention, can be simultaneously reached
3.5 grades of requirements of public odor standards PV3900.
Claims (7)
1. a kind of low smell is low to distribute ABS alloy material, it is characterised in that: be prepared according to parts by weight by following ingredients:
ABS:70~90 part；
High glue powder: 10~20 parts；
Antioxidant: 0.1~2 part；
Light stabilizer: 0.1~2 part；
0.5~2 part of adsorbent.
2. a kind of low smell according to claim 1 is low to distribute ABS alloy material, it is characterised in that: the ABS is third
Alkene is fine-and butadiene-styrene material refers at 220 DEG C, ABS of the flowing velocity of material in 5~30g/10min under the conditions of 10Kg
Material.
3. a kind of low smell according to claim 1 is low to distribute ABS alloy material, it is characterised in that: the high glue powder
For styrene, acrylonitrile-butadiene rubber.
4. a kind of low smell according to claim 1 is low to distribute ABS alloy material, it is characterised in that: described is described
Adsorbent is the agent of AS carrier adsorption.
5. a kind of low smell according to claim 1 is low to distribute ABS alloy material, it is characterised in that: the auxiliary agent is
Antioxidant DSTP (the double octadecyls of thio-2 acid), antioxidant 1010 (four (3,5-di-t-butyl-4 β-- hydroxy phenyl)
Pentaerythritol resin), irgasfos 168 (three (2,4-di-tert-butyl-phenyl) phosphite esters, light stabilizer V703,5589,531, second
The double stearoylketene amine (EBS) of alkenyl are one such or several mixtures.
The low preparation method for distributing ABS alloy material of low smell described in 6. claim 1-5 is one of any, it is characterised in that: its
Steps are as follows:
(1) each raw material is weighed in parts by weight；
(2) raw material is added in high speed mixer after mixing by step (1) together, is then added to double screw extruder
In, ABS alloy material is prepared into through double screw extruder melting, extrusion, cooling, pelletizing.
7. the low preparation method for distributing ABS alloy material of low smell according to claim 6, it is characterised in that: described
The area the I~X processing temperature of double screw extruder is followed successively by 165 DEG C, and 200 DEG C, 215 DEG C, 215 DEG C, 220 DEG C, 220 DEG C, 225 DEG C,
225 DEG C, 230 DEG C, 235 DEG C；Driving screw revolving speed be 250~400r/min, 23 DEG C~50 DEG C of sink temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811612112.7A CN109666258A (en) | 2018-12-27 | 2018-12-27 | A kind of low smell is low to distribute ABS alloy material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811612112.7A CN109666258A (en) | 2018-12-27 | 2018-12-27 | A kind of low smell is low to distribute ABS alloy material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109666258A true CN109666258A (en) | 2019-04-23 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811612112.7A Pending CN109666258A (en) | 2018-12-27 | 2018-12-27 | A kind of low smell is low to distribute ABS alloy material and preparation method thereof |
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| Country | Link |
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| CN (1) | CN109666258A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114369332A (en) * | 2021-12-29 | 2022-04-19 | 上海普利特复合材料股份有限公司 | Composite metal oxide modified low-emission ABS material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699469A (en) * | 2005-06-15 | 2005-11-23 | 上海普利特复合材料有限公司 | Low-odour acrylonitrile-butadiene-styrene copolymer complex |
| CN1730542A (en) * | 2005-07-29 | 2006-02-08 | 上海普利特复合材料有限公司 | Little odor acrylonitrile-butadiene-styrene ternary copolymerized resin material and its preparation method |
-
2018
- 2018-12-27 CN CN201811612112.7A patent/CN109666258A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699469A (en) * | 2005-06-15 | 2005-11-23 | 上海普利特复合材料有限公司 | Low-odour acrylonitrile-butadiene-styrene copolymer complex |
| CN1730542A (en) * | 2005-07-29 | 2006-02-08 | 上海普利特复合材料有限公司 | Little odor acrylonitrile-butadiene-styrene ternary copolymerized resin material and its preparation method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114369332A (en) * | 2021-12-29 | 2022-04-19 | 上海普利特复合材料股份有限公司 | Composite metal oxide modified low-emission ABS material and preparation method thereof |
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| PB01 | Publication | ||
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Effective date of registration: 20200616 Address after: 402560 Longyun road 18, Pu Lu Industrial Park, Tongliang District, Chongqing. Applicant after: CHONGQNG PULITE NEW MATERIAL Co.,Ltd. Applicant after: SAIC VOLKSWAGEN AUTOMOTIVE Co.,Ltd. Applicant after: Shanghai Pret Composites Co.,Ltd. Applicant after: ZHEJIANG PRET NEW MATERIALS Co.,Ltd. Applicant after: SHANGHAI PRET NEW CHEMICAL MATERIAL Co.,Ltd. Applicant after: SHANGHAI PRET MATERIAL TECHNOLOGY Co.,Ltd. Address before: 402560 No.18 Longyun Road, Pulu Industrial Park, Tongliang County, Chongqing (cancelled) Applicant before: CHONGQNG PULITE NEW MATERIAL Co.,Ltd. Applicant before: Shanghai Pret Composites Co.,Ltd. Applicant before: ZHEJIANG PRET NEW MATERIALS Co.,Ltd. Applicant before: SHANGHAI PRET NEW CHEMICAL MATERIAL Co.,Ltd. Applicant before: SHANGHAI PRET MATERIAL TECHNOLOGY Co.,Ltd. |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190423 |