CN109663413A - A kind of preparation method of high-temperature-resistant filtering material heat resisting film-coating - Google Patents

A kind of preparation method of high-temperature-resistant filtering material heat resisting film-coating Download PDF

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Publication number
CN109663413A
CN109663413A CN201910153962.3A CN201910153962A CN109663413A CN 109663413 A CN109663413 A CN 109663413A CN 201910153962 A CN201910153962 A CN 201910153962A CN 109663413 A CN109663413 A CN 109663413A
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China
Prior art keywords
temperature
filtrate
overlay film
nomex
preparation
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Pending
Application number
CN201910153962.3A
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Chinese (zh)
Inventor
罗洪杰
张鸿帅
姜昊
何其乐
王昭田
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Fushun Tian Cheng Environmental Protection Technology Co Ltd
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Fushun Tian Cheng Environmental Protection Technology Co Ltd
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Priority to CN201910153962.3A priority Critical patent/CN109663413A/en
Publication of CN109663413A publication Critical patent/CN109663413A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing

Abstract

The invention belongs to fiber surface modification fields, and in particular to a kind of preparation method of the heat resisting film-coating of high-temperature-resistant filtering material.By polytetrafluoroethylene (PTFE), silane coupling agent, polyacrylate, nanometer silicate polymer, crosslinking agent and water, 11:1.5:5:12:5:65.5 is mixed by mass percentage, hybrid inorganic-organic overlay film liquid is obtained by stirring and ultrasonic disperse, then filtrate is impregnated in peritoneal fluid impregnated, pressure rolling, sizing, press polish post-processing, form overlay film on the fiber of filtrate.The present invention makes basalt fibre Nomex coated with film after 320 DEG C of high-temperature process, and strength retention promotes 20% or more, has been obviously improved the temperature tolerance of filtrate.The acid resistance of the silicates fiber such as basalt fibre and glass fibre effectively is enhanced, strength retention compared to the filtering material of non-overlay film improves 20% after the HCl solution corrosion of 2mol/L by present invention basalt fibre filtering material coated with film.

Description

A kind of preparation method of high-temperature-resistant filtering material heat resisting film-coating
Technical field
The invention belongs to fiber surface modification fields, and in particular to a kind of preparation of high-temperature-resistant filtering material heat resisting film-coating Method.
Background technique
In recent years, requirement of the people to fine environment is increasingly urgent to, therefore country has also put into effect more stringent environment mark Standard, everything is formed by pressure and greatly all falls in production enterprise.Carbon black, cement, waste incineration etc. Industry requires to undertake great number cost for the processing of high-temperature flue gas.Since existing filtering material maximum operating temperature only has 200 DEG C or so, therefore enterprise first must first carry out cooling processing in high-temperature smoke filtering, this just improves the cost of production.Especially with For the common SCR denitration process of dust treatment, due to the durothermic deficiency of filtering material, cause enterprise must be to sacrifice denitration Catalyst service life is that cost just can guarantee good catalytic denitration efficiency.Develop mistake of the operating temperature at 300 DEG C or more Filter material material is the only way for solving problem above.Although can expire by the high-performance fiber of new generation of representative of basalt fibre The demand of 300 DEG C of foot or more high temperature filtration, but existing filtering material overlay film is pure organic matter, it is difficult to it bears such high Temperature.
The heat resisting film-coating of filtrate requires on the basis of meeting basic processing performance and strainability, has higher resistance to Warm nature.Although pure inoranic membrane is although corrosion-resistant, solvent resistant, high temperature resistant, since it is not only hard but also crisp thus not easy to be processed. Therefore existing practicable scheme be inorganic constituents to be added in existing overlay film organic system, meet basic filtering and While processing performance, reach better heat resistance.
Patent of invention CN101270546A discloses a kind of functional topical finishing method of high temperature flue gas filter material.This method is By nanometer grade powder material and polytetrafluoroethyldispersion dispersion, silicone oil emulsion, fluorinated acrylate emulsion, it is mixed in a certain ratio, It is sufficiently stirred, is uniformly mixed it.A certain amount of water is added, overlay film lotion is configured to.Finally by fiberglass needled mat Or the filtering material of chemical fibre Nomex is impregnated and is handled in overlay film lotion, and high-temperature flue gas filtration material is made.
What patent of invention CN101624777A disclosed that aftertreatment of high-temperature flue gas filtration material uses silica containing covers Film liquid.Specifically to containing polytetrafluoroethyldispersion dispersion, this methyl-silicone oil, polyacrylate aqueous solution in nanometer or micro- is added The silica of meter level, the overlay film liquid of system.Filtering material is immersed in overlay film liquid, by pressure rolling, drying and thermal finalization, is being filtered Material surface forms the overlay film containing silica.
Patent of invention CN203208798U discloses a kind of High-intensity low-stretchability polysulfonamide high-temperature-resmembrane membrane filter material.Wherein, it is The heat resistance and filter efficiency for improving product, have used the water containing polytetrafluoroethylene (PTFE), polyacrylate, silicone oil and coupling agent Solution carries out coating processing to PSA fiber Nomex.
Patent of invention CN101745277A discloses a kind of thermostable special dedusting bag coated with film.The product is by glass fibers Wei Bu is made, and has one layer to be made of special resin, organic copper silicon, polyimide, polytetrafluoroethylene (PTFE) and graphite in private bag inner wall Overlay film.
The heat resisting film-coating method of above-mentioned high-temperature smoke filtering material is all that inorganic component is added into organic overlay film medicament To improve the heat resistance of product.The oxytolerant of dispersibility and associativity and inorganic constituents of the inorganic constituents in organic principle Change, corrosion-resistance properties are lacking, to affect the performance of overlay film entirety.The present invention is in view of the above problems, select silicic acid poly- Object is closed as inorganic constituents, makes heat resisting film-coating that there is better performance.
Summary of the invention
The purpose of the present invention is to provide a kind of high temperature resistant, resistance to strong acid corrosion, the high-temperature smoke filtrate overlay film material of resistance to oxidation The preparation method of material, by a certain percentage with polytetrafluoroethylene (PTFE), polyacrylate, coupling agent and crosslinking agent by nanometer silicate polymer Mixing, is added a certain amount of water, obtains hybrid inorganic-organic overlay film liquid by stirring and ultrasonic disperse, filtrate is impregnated in abdomen It is post-processed in film liquid, forms overlay film on the fiber of filtrate.
Specific technical solution is that a kind of preparation method of the heat resisting film-coating of high-temperature-resistant filtering material comprises the following steps that
Step 1: the preparation of overlay film liquid
Polytetrafluoroethylene (PTFE), silane coupling agent, polyacrylate, nanometer silicate polymer, crosslinking agent and water are pressed into quality hundred Divide to be placed in mixing container than 11:1.5:5:12:5:65.5 and mix, magnetic agitation under normal temperature and pressure, re-ultrasonic dispersion keeps it mixed It closes uniformly, overlay film liquid is made;
Step 2: dipping
Using Nomex filtrate as overlay film matrix, Nomex filtrate is impregnated in the overlay film liquid made from step 1;
Step 3: pressure rolling
Nomex filtrate after dipping is subjected to pressure rolling at room temperature, pressure rolling pressure is 0.3~0.6Mpa, and pressure rolling speed is 6m/min;
Step 4: sizing
Nomex filtrate after pressure rolling carries out hot-air seasoning sizing by framing shaping machine, and setting temperature is 160~240 DEG C, setting time 2min;
Step 5: press polish
Nomex filtrate after sizing carries out smooth roll hot pressing by calender, and temperature is 230~260 DEG C, speed 15m/ Min, finally, overlay film are formed in Nomex filter material surface.
The silane coupling agent used in step 1 is A151 silane coupling agent;Crosslinking agent is the friendship of end-block type isocyanates Join agent.
The Nomex filtrate is basalt fibre Nomex filtrate or fiberglass needled mat filtrate.
The beneficial effects of the present invention are:
1. the present invention is applied to the coating processing of basalt fibre Nomex, basalt fibre Nomex coated with film is made to exist 320 DEG C, after the high-temperature process of 90min, strength retention improves 20% or more.It has been obviously improved the temperature tolerance of filtrate.
2. of the invention effectively enhance the acid resistance of the silicates fiber such as basalt fibre and glass fibre.With basalt For fiber filter material, by present invention basalt fibre filtering material coated with film after the HCl solution corrosion of 2mol/L Strength retention improves 20% compared to the basalt fibre filtering material of non-overlay film.To preferably adapt to high-temperature smoke Filter sour gas environment common in environment.
3. keeping coated filter material surface smooth due to the presence of polytetrafluoroethylene (PTFE) and nanometer materials, there is non-sticky property, be easy to Deashing.
4. present invention process is simple, easy to implement, silicate polymer advantage of lower cost effectively reduces cost.
5. heat resisting film-coating filtrate can substantially reduce the cost of industrial waste gas processing, there is objective economic value.
Specific embodiment
Embodiment 1
Used overlay film matrix are as follows: basalt fibre Nomex filtrate.
1, the preparation of overlay film liquid
Formula for raw stock:
Ingredient Mass percent
Polytetrafluoroethylene (PTFE) 11
Silane coupling agent 1.5
Polyacrylate 5
Nanometer silicate polymer 12
Crosslinking agent 5
Water 65.5
Preparation method:
Above-mentioned polytetrafluoroethylene (PTFE), silane coupling agent, polyacrylate, nanometer silicate polymer, crosslinking agent and water are set In in mixing container, magnetic agitation 15min under normal temperature and pressure, re-ultrasonic dispersion 10min are uniformly mixed it, and overlay film liquid is made.
The silane coupling agent used is A151 silane coupling agent.Crosslinking agent is end-block type isocyanate crosslinking.
2, it impregnates
Using Nomex filtrate as overlay film matrix, Nomex filtrate is impregnated in the overlay film liquid made from step 1;
3, pressure rolling
Nomex filtrate after dipping is subjected to pressure rolling at room temperature, pressure rolling pressure is 0.6Mpa, and pressure rolling speed is 6m/ min;
4, it is formed
Nomex filtrate after pressure rolling carries out hot-air seasoning sizing by framing shaping machine, and setting temperature is 160 DEG C, ventilation Drying time is 2min;
5, press polish
Nomex filtrate after sizing carries out smooth roll hot pressing by calender, and temperature is 230 DEG C, 15min ventilation solidification, most Eventually, overlay film is formed in Nomex filter material surface.
After 320 DEG C, the high-temperature process of 90min, basalt fibre Nomex strength retention coated with film is 72.4%, And the basalt fibre Nomex strength retention of non-overlay film is 50% or so, strength retention improves 20% or more, significantly Improve the temperature tolerance of basalt fibre Nomex filtrate.
It being handled 3 hours in the HCl of 2mol/L, basalt fibre Nomex strength retention coated with film is 89%, and The basalt fibre Nomex strength retention of non-overlay film is 65%~70%, effectively enhances basalt fibre Nomex filtrate Acid resistance.
Embodiment 2
Used overlay film matrix are as follows: fiberglass needled mat filtrate.
1, the preparation of overlay film liquid
Formula for raw stock:
Preparation method:
Above-mentioned polytetrafluoroethylene (PTFE), silane coupling agent, polyacrylate, nanometer silicate polymer, crosslinking agent and water are set In in mixing container, magnetic agitation 15min under normal temperature and pressure, re-ultrasonic dispersion 10min are uniformly mixed it, and overlay film liquid is made.
The silane coupling agent used is A151 silane coupling agent.Crosslinking agent is end-block type isocyanate crosslinking.
2, it impregnates
Using Nomex filtrate as overlay film matrix, Nomex filtrate is impregnated in the overlay film liquid made from step 1.
3, pressure rolling
Nomex filtrate after dipping is subjected to pressure rolling at room temperature, pressure rolling pressure is 0.6Mpa, and pressure rolling speed is 6m/ min。
4, it is formed
Nomex filtrate after pressure rolling carries out hot-air seasoning sizing by framing shaping machine, and setting temperature is 160 DEG C, ventilation Drying time is 2min.
5, press polish
Nomex filtrate after sizing carries out smooth roll hot pressing by calender, and temperature is 230 DEG C, 15min ventilation solidification, most Eventually, overlay film is formed in Nomex filter material surface.

Claims (4)

1. a kind of preparation method of the heat resisting film-coating of high-temperature-resistant filtering material, which is characterized in that comprise the following steps that
Step 1: the preparation of overlay film liquid
By mass percentage by polytetrafluoroethylene (PTFE), silane coupling agent, polyacrylate, nanometer silicate polymer, crosslinking agent and water 11:1.5:5:12:5:65.5 is placed in mixing in mixing container, magnetic agitation under normal temperature and pressure, and re-ultrasonic dispersion keeps its mixing equal It is even, overlay film liquid is made;
Step 2: dipping
Using Nomex filtrate as overlay film matrix, Nomex filtrate is impregnated in the overlay film liquid made from step 1;
Step 3: pressure rolling
Nomex filtrate after dipping is subjected to pressure rolling at room temperature, pressure rolling pressure is 0.3~0.6Mpa, and pressure rolling speed is 6m/ min;
Step 4: sizing
Nomex filtrate after pressure rolling carries out hot-air seasoning sizing by framing shaping machine, and setting temperature is 160~240 DEG C, leads to Wind drying time is 2min;
Step 5: press polish
Nomex filtrate after sizing carries out smooth roll hot pressing by calender, and temperature is 230~260 DEG C, speed 15m/min, Finally, overlay film is formed in Nomex filter material surface.
2. preparation method according to claim 1, which is characterized in that the silane coupling agent used in step 1 is A151 silicon Alkane coupling agent;Crosslinking agent is end-block type isocyanate crosslinking.
3. preparation method according to claim 1 or 2, which is characterized in that the Nomex filtrate is basalt fibre needle Pierce lacing felt filter material or fiberglass needled mat filtrate.
4. using the heat resisting film-coating for the high-temperature-resistant filtering material that claims 1 or 2 or 3 the methods are prepared.
CN201910153962.3A 2019-03-01 2019-03-01 A kind of preparation method of high-temperature-resistant filtering material heat resisting film-coating Pending CN109663413A (en)

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CN110055699A (en) * 2019-05-13 2019-07-26 江苏菲斯特滤料有限公司 A kind of final finishing device of filtering material
CN112625383A (en) * 2020-12-12 2021-04-09 安徽新辰光学新材料有限公司 Anti-yellowing LED lamp film and preparation method thereof
CN115748262A (en) * 2022-08-27 2023-03-07 安徽省绩溪华林环保科技股份有限公司 Surface coating process for prolonging service life of glass fiber
CN116173621A (en) * 2023-02-16 2023-05-30 江苏奥凯环境技术有限公司 Aramid fiber filter material for ultralow emission and production process thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055699A (en) * 2019-05-13 2019-07-26 江苏菲斯特滤料有限公司 A kind of final finishing device of filtering material
CN112625383A (en) * 2020-12-12 2021-04-09 安徽新辰光学新材料有限公司 Anti-yellowing LED lamp film and preparation method thereof
CN115748262A (en) * 2022-08-27 2023-03-07 安徽省绩溪华林环保科技股份有限公司 Surface coating process for prolonging service life of glass fiber
CN116173621A (en) * 2023-02-16 2023-05-30 江苏奥凯环境技术有限公司 Aramid fiber filter material for ultralow emission and production process thereof
CN116173621B (en) * 2023-02-16 2023-09-29 江苏奥凯环境技术有限公司 Aramid fiber filter material for ultralow emission and production process thereof

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Application publication date: 20190423