CN109652600A - A kind of ox leather processing - Google Patents

A kind of ox leather processing Download PDF

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Publication number
CN109652600A
CN109652600A CN201910065333.5A CN201910065333A CN109652600A CN 109652600 A CN109652600 A CN 109652600A CN 201910065333 A CN201910065333 A CN 201910065333A CN 109652600 A CN109652600 A CN 109652600A
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CN
China
Prior art keywords
leather
parts
carbon nanotube
emulsifier
hand feeling
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Granted
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CN201910065333.5A
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Chinese (zh)
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CN109652600B (en
Inventor
张朝佩
周滋润
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Wenzhou Huiquan Industry And Trade Co Ltd
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Wenzhou Huiquan Industry And Trade Co Ltd
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Classifications

    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B1/00Manufacture of leather; Machines or devices therefor
    • C14B1/26Leather tensioning or stretching frames; Stretching-machines; Setting-out boards; Pasting boards
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B1/00Manufacture of leather; Machines or devices therefor
    • C14B1/30Pressing or rolling leather
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B1/00Manufacture of leather; Machines or devices therefor
    • C14B1/40Softening or making skins or leather supple, e.g. by staking, boarding, or crippling machines, by dry mills
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B1/00Manufacture of leather; Machines or devices therefor
    • C14B1/58Drying
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B17/00Details of apparatus or machines for manufacturing or treating skins, hides, leather, or furs
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather

Abstract

The invention discloses a kind of ox leather processing, used hand feeling agent includes following parts by weight of component in the treatment process: 8-11 parts of silicone emulsion;130-150 parts of paraffin;50-70 parts of fatty acid;14-18 parts of emulsifier;1-3 parts of carbon nanotube.The invention has the following advantages: adding carbon nanotube in hand feeling agent, after carbon nanotube is uniformly distributed, slight convex is formed in ox leather surface, so that light generates certain diffusing reflection in ox leather surface, with photoextinction, simultaneously because the elongated tubular characteristic of carbon nanotube, so that the texture of ox leather surface is more naturally beautiful.Furthermore, the both ends of carbon nanotube also have suction-operated, ox-hide leather usually requires periodically to be nursed with care agent to guarantee its brightness and feel, and carbon nanotube can then adsorb a certain amount of care agent, and the continuous slow release during loss of care agent, so that care agent is constantly supplemented, with extend ox leather surface oil film there are the times, to extend the service life of ox-hide leather.

Description

A kind of ox leather processing
Technical field
The present invention relates to leather and fur products fields, more specifically, it relates to a kind of ox leather processing.
Background technique
Ox-hide leather goods are very universal in life and liked by people because of its good texture and appearance.
The Chinese patent that notification number is CN105925736B discloses a kind of full grain and receives the covering with paint of pa leather finish composition Scytoblastema formed full grain Na Papi Coating technology, the Coating technology the following steps are included:
1) scytoblastema falls soft: the disability scytoblastema picked out is put into and falls soft rotary drum, fall it is 1.5-2.5 hours soft, then from rotary drum In take out;
2) toggling: treated that scytoblastema is face-up placed on toggling machine by step 1), it is desirable that whole scytoblastema is taut flat, There cannot be a wrinkle, folder is removed after 1.5-2.5 hours toggling time away from 10-15 centimetres;
3) mend wound: by the scytoblastema of step 2) treated scytoblastema be placed on upward it is smooth scrape on lending somebody a hand, benefit will be scraped with scraper It starches whole equably to scratch in scytoblastema, stands 2-5 hours;
4) polish: the speed for adjusting polishing machine is 75-85 code/hour, and the interval between felt and roller is 1.5-2.5mm, By the front polishing of step 3) treated scytoblastema, dust is removed;
5) erupt alveolar layer: by hand spray gun by foaming slurry even application in the front by step 4) treated scytoblastema, Drying;
6) foam: upright embossing machine card is bodkin card, in the front embossing foaming through step 5) treated scytoblastema, Drying;
7) it is secondary fall it is soft: will by step 6) treated that putting into for scytoblastema falls soft rotary drum, fall it is 0.8-1.2 hours soft, from It is taken out in rotary drum, dedusting;
8) shake soft: the soft machine lattice number of adjustment vibration and speed will be by the face-up soft by shaking of the scytoblastema after step 7) hot light Machine vibration is soft;
9) spray cation: by hand spray gun by cation slurry even application by the front of step 8) treated scytoblastema, Equably the primary cation of spraying is starched again after drying, drying;
10) press fine needle line: adjusting upright embossing machine card is fine needle line, to the front by step 9) treated scytoblastema Embossing;
11) hot light: by the conveyer belt by being placed on natural lustre finishing machine on the front of step 10) treated scytoblastema upward On, entirely pass through natural lustre finishing machine hot light;
12) spray plane is starched: starch adhesive liquid is equably sprayed on the front by step 11) treated scytoblastema by spray gun by hand On, a starch adhesive is sprayed after drying again, then dry, spray third time, drying;
13) spray bright layer: light slurry is equably sprayed on by step 12) treated scytoblastema just by spray gun by hand On face, drying;
14) secondary hot light: will being face-up placed on the conveyer belt of natural lustre finishing machine by step 13) treated scytoblastema, It is smooth to pass through natural lustre finishing machine hot light;
15) spray feel slurry: feel slurry is equably sprayed on by step 14) treated scytoblastema just by spray gun by hand On face, drying, finally obtained full grain receives pa.
Wherein, bright slurry is made of following components in parts by weight: 80-120 parts of water, 80-120 parts of water-based gloss oil, and hand Agent 5-15 parts of sense;Feel slurry is made of following components in parts by weight: 150-250 parts of water, 2-8 parts of hand feeling agent, and nonionic hand Agent 15-25 parts of sense.
Hand feeling agent has the function of to add lustre to, is smooth, improving leather hand feeling, enhancing kishke feel etc., bright in above-mentioned leather and fur products It is added to hand feeling agent and nonionic hand feeling agent in slurry and feel slurry, includes also furthermore water-based gloss oil in bright slurry, so that leather table Face will excessively smooth light lose naturalness, have much room for improvement.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of ox leather processing, acquisition Ox-hide leather goods shiny appearance is natural.
To achieve the above object, the present invention provides the following technical scheme that
A kind of ox leather processing, it is characterised in that: include the following steps,
Step 1, cation slurry is sprayed on grain side of leather, equably sprays primary cation after drying again by spray cation Slurry, drying;
Step 2, leather to be scalded, grain side of leather is put on the belt upward and is flattened using roll-in, the temperature of roller is 130 DEG C, Pressure is 20-30kg;
Step 3, it falls soft, leather is put into and is fallen in soft rotary drum, soft 30h is fallen;
Step 4, leather is placed on to stretch tight on toggling machine and put down by toggling;
Step 5, grain side of leather is put on the belt upward and is flattened using roll-in by secondary boiling hot leather, and the temperature of roller is 130 DEG C, pressure 10-20kg;
Step 6, spray plane is starched, and starch adhesive liquid is equably sprayed on to the front of leather, sprays a starch adhesive after drying again, then dry It is dry, spray third time, drying;
Step 7, light is sprayed, bright slurry is equably sprayed on to the front of leather, drying;
Step 8, leather is scalded three times, grain side of leather is put on the belt upward and is flattened using roll-in, and the temperature of roller is 135 DEG C, pressure 30-40kg;
Step 9, secondary to fall soft, leather is put into and is fallen in soft rotary drum, soft 60min is fallen;
Step 10, vacuum pattern absorbing carries out vacuum pattern absorbing 60s to leather with vacuum tattoo machine, and temperature is 80 DEG C.
Step 11, hand feeling agent is sprayed, by hand feeling agent even application in the front of leather, drying;
Step 12, grain side of leather is put on the belt upward and is flattened using roll-in by four boiling hot leather, and the temperature of roller is 130 DEG C, pressure 10-20kg;
According to parts by weight, the hand feeling agent includes following components:
By using above-mentioned technical proposal, carbon nanotube is added in hand feeling agent, after carbon nanotube is uniformly distributed, in ox Leather surface forms slight convex, so that light generates certain diffusing reflection in ox leather surface, with photoextinction, while by In the elongated tubular characteristic of carbon nanotube, so that the texture of ox leather surface is more naturally beautiful.
In addition, the both ends of carbon nanotube also have suction-operated, ox-hide leather usually requires periodically to be nursed with care agent to protect Its brightness and feel are demonstrate,proved, and carbon nanotube can then adsorb a certain amount of care agent, and during the loss of care agent not Disconnected slow release so that care agent is constantly supplemented, with extend ox leather surface oil film there are the times, to extend The service life of ox-hide leather.
Further, according to parts by weight, the hand feeling agent includes following components:
Further, according to parts by weight, the hand feeling agent includes 25-26 parts of microwax.
By using above-mentioned technical proposal, although paraffin and microwax are extract from petroleum, paraffin Be it is brittle, fracture is easy to after stress and is even crushed, and the hardness of microwax is small, and flexibility is fine, and stress is easily deformed, no Easy fragmentation.And microwax can be used as the modifying agent of paraffin, to paraffin in add microwax after, the plasticity of paraffin can be improved, So that there is physically better performance after hand feeling agent film forming.
Further, according to parts by weight, the emulsifier uses paregal O.
By using above-mentioned technical proposal, paregal O is that one kind is non-ionic by surfactant, and main component is polyoxy Ethylene fatty alcohol ether has good emulsification, so that hand feeling agent forms a uniform system.
Further, according to parts by weight, the hand feeling agent includes 24-25 parts of caryophyllus oil.
By using above-mentioned technical proposal, the main component of caryophyllus oil is eugenol, carypohyllene, Acetyl eugenol, first Base amyl ketone etc. has osmosis in the application of hand feeling agent, so that leather still has well after surface layer is worn Feel, adsorbed care agent can be discharged into the leather surface after abrasion in this outside carbon nanotube, and carry out timely Nursing.
Further, the emulsifier includes emulsifier TX-4, and the mass ratio of the emulsifier TX-4 and paregal O is 1: 1。
By using above-mentioned technical proposal, single emulsifier is bad to organosilicon emulsifying effectiveness, is easy to appear oil slick Situation, and after emulsifier TX-4 and paregal O are mutually compound, good emulsion stability obtained by emulsification
Further, hand feeling agent preparation method the following steps are included:
Step 1, by paraffin and microwax heating melting;
Step 2, fatty acid is added, mixes and melts with wax, until transparence;
Step 3, emulsifier TX-4 is added, paregal O and silicone emulsion are emulsified, 70-80 DEG C of emulsifying temperature, when emulsification Between be 25-35min, mixing speed 500-600r/min;
Step 4, caryophyllus oil and carbon nanotube are added under stiring, continues to stir 5-10min, warm water dilutes and continues to stir It mixes 20-30min and takes out finished product.
In conclusion the invention has the following advantages:
1. adding carbon nanotube in hand feeling agent, after carbon nanotube is uniformly distributed, formed in ox leather surface slight convex It rises, so that light generates certain diffusing reflection in ox leather surface, there is photoextinction, simultaneously because the elongated tubular of carbon nanotube Characteristic, so that the texture of ox leather surface is more naturally beautiful;
2. the both ends of carbon nanotube also have suction-operated, ox-hide leather usually requires periodically to be nursed with care agent to guarantee it Brightness and feel, and carbon nanotube can then adsorb a certain amount of care agent, and constantly slow during the loss of care agent On The Drug Release so that care agent is constantly supplemented, with extend ox leather surface oil film there are the times, to extend ox-hide The service life of leather;
Although 3. paraffin and microwax are extract from petroleum, paraffin be it is brittle, hold very much after stress Easy fracture even crushes, and the hardness of microwax is small, and flexibility is fine, and stress is easily deformed, not easily broken.And microwax can be with As the modifying agent of paraffin, to paraffin in add microwax after, the plasticity of paraffin can be improved so that hand feeling agent film forming after With physically better performance;
4. the main component of caryophyllus oil is eugenol, carypohyllene, Acetyl eugenol, methyl amyl ketone etc., in hand feeling agent Application in there is osmosis so that leather still has good feel after surface layer is worn, this outside carbon received Adsorbed care agent can be discharged into the leather surface after abrasion in mitron, and be nursed in time.
Detailed description of the invention
Fig. 1 is the flow chart of hand feeling agent preparation method in the present invention.
Specific embodiment
Below in conjunction with attached drawing 1 and embodiment, invention is further described in detail.
Embodiment
Embodiment 1
A kind of ox leather processing, comprising the following steps:
Step 1, cation slurry is sprayed on grain side of leather, equably sprays primary cation after drying again by spray cation Slurry, drying;
Step 2, leather to be scalded, grain side of leather is put on the belt upward and is flattened using roll-in, the temperature of roller is 130 DEG C, Pressure is 20-30kg;
Step 3, it falls soft, leather is put into and is fallen in soft rotary drum, soft 30h is fallen;
Step 4, leather is placed on to stretch tight on toggling machine and put down by toggling;
Step 5, grain side of leather is put on the belt upward and is flattened using roll-in by secondary boiling hot leather, and the temperature of roller is 130 DEG C, pressure 10-20kg;
Step 6, spray plane is starched, and starch adhesive liquid is equably sprayed on to the front of leather, sprays a starch adhesive after drying again, then dry It is dry, spray third time, drying;
Step 7, light is sprayed, bright slurry is equably sprayed on to the front of leather, drying;
Step 8, leather is scalded three times, grain side of leather is put on the belt upward and is flattened using roll-in, and the temperature of roller is 135 DEG C, pressure 30-40kg;
Step 9, secondary to fall soft, leather is put into and is fallen in soft rotary drum, soft 60min is fallen;
Step 10, vacuum pattern absorbing carries out vacuum pattern absorbing 60s to leather with vacuum tattoo machine, and temperature is 80 DEG C.
Step 11, hand feeling agent is sprayed, by hand feeling agent even application in the front of leather, drying;
Step 12, grain side of leather is put on the belt upward and is flattened using roll-in by four boiling hot leather, and the temperature of roller is 130 DEG C, pressure 10-20kg.
Wherein, according to parts by weight, hand feeling agent raw material components are as shown in table 1.
The preparation method of the hand feeling agent the following steps are included:
Step 1, by paraffin and microwax heating melting;
Step 2, fatty acid is added, mixes and melts with wax, until transparence;
Step 3, emulsifier TX-4 is added, paregal O and silicone emulsion are emulsified, 70-80 DEG C of emulsifying temperature, when emulsification Between be 25-35min, mixing speed 500-600r/min;
Step 4, caryophyllus oil and carbon nanotube are added under stiring, continues to stir 5-10min, warm water dilutes and continues to stir It mixes 20-30min and takes out finished product.
Embodiment 2
The difference from embodiment 1 is that according to parts by weight, hand feeling agent raw material components are as shown in table 1.
Embodiment 3
The difference from embodiment 1 is that according to parts by weight, hand feeling agent raw material components are as shown in table 1.
Embodiment 4
Difference with embodiment 3 is that according to parts by weight, hand feeling agent raw material components are as shown in table 1.
Embodiment 5
The difference from embodiment 1 is that according to parts by weight, hand feeling agent raw material components are as shown in table 1.
Embodiment 6
Difference with embodiment 5 is that according to parts by weight, hand feeling agent raw material components are as shown in table 1.
Comparative example
Comparative example 1
The difference from embodiment 1 is that according to parts by weight, hand feeling agent raw material components are as shown in table 1.
Comparative example 2
Difference with comparative example 1 is that according to parts by weight, hand feeling agent raw material components are as shown in table 1.
Performance detection test
The feel and luster effect of finished product ox-hide leather are evaluated by several experienced master workers, take overall merit.
Table 1, hand feeling agent component list
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this All by the protection of Patent Law in the scope of the claims of invention.

Claims (7)

1. a kind of ox leather processing, it is characterised in that: include the following steps,
Step 1, cation slurry is sprayed on grain side of leather by spray cation, is equably sprayed primary cation slurry after drying again, is dried It is dry;
Step 2, leather is scalded, grain side of leather is put on the belt upward and is flattened using roll-in, the temperature of roller is 130 DEG C, pressure For 20-30kg;
Step 3, it falls soft, leather is put into and is fallen in soft rotary drum, soft 30h is fallen;
Step 4, leather is placed on to stretch tight on toggling machine and put down by toggling;
Step 5, grain side of leather is put on the belt upward and is flattened using roll-in by secondary boiling hot leather, and the temperature of roller is 130 DEG C, Pressure is 10-20kg;
Step 6, spray plane is starched, and starch adhesive liquid is equably sprayed on to the front of leather, sprays a starch adhesive after drying again, then dry, and is sprayed For the third time, it dries;
Step 7, light is sprayed, bright slurry is equably sprayed on to the front of leather, drying;
Step 8, leather to be scalded three times, and grain side of leather is put on the belt upward and is flattened using roll-in, the temperature of roller is 135 DEG C, Pressure is 30-40kg;
Step 9, secondary to fall soft, leather is put into and is fallen in soft rotary drum, soft 60min is fallen;
Step 10, vacuum pattern absorbing carries out vacuum pattern absorbing 60s to leather with vacuum tattoo machine, and temperature is 80 DEG C;
Step 11, hand feeling agent is sprayed, by hand feeling agent even application in the front of leather, drying;
Step 12, grain side of leather is put on the belt upward and is flattened using roll-in by four boiling hot leather, and the temperature of roller is 130 DEG C, Pressure is 10-20kg;
According to parts by weight, the hand feeling agent includes following components:
8-11 parts of silicone emulsion;
130-150 parts of paraffin;
50-70 parts of fatty acid;
14-18 parts of emulsifier;
1-3 parts of carbon nanotube.
2. a kind of ox leather processing according to claim 1, it is characterised in that: according to parts by weight, the feel Agent includes following components:
9-10 parts of silicone emulsion;
135-145 parts of paraffin;
55-65 parts of fatty acid;
15-17 parts of emulsifier;
1-2 parts of carbon nanotube.
3. a kind of ox leather processing according to claim 2, it is characterised in that: according to parts by weight, the feel Agent includes 25-26 parts of microwax.
4. a kind of ox leather processing according to claim 2, it is characterised in that: the emulsifier includes paregal O.
5. a kind of ox leather processing according to claim 2, it is characterised in that: according to parts by weight, the feel Agent includes 24-25 parts of caryophyllus oil.
6. a kind of ox leather processing according to claim 2, it is characterised in that: the emulsifier includes emulsifier The mass ratio of TX-4, the emulsifier TX-4 and paregal O is 1:1.
7. a kind of ox leather processing according to claim 2, it is characterised in that: the preparation method of hand feeling agent include with Lower step,
Step 1, by paraffin and microwax heating melting;
Step 2, fatty acid is added, mixes and melts with wax, until transparence;
Step 3, emulsifier TX-4, paregal O and silicone emulsion is added to be emulsified, 70-80 DEG C of emulsifying temperature, emulsification times are 25-35min, mixing speed 500-600r/min;
Step 4, caryophyllus oil and carbon nanotube are added under stiring, continues to stir 5-10min, warm water dilutes and continues to stir 20-30min takes out finished product.
CN201910065333.5A 2019-01-23 2019-01-23 Cow leather treatment process Active CN109652600B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910065333.5A CN109652600B (en) 2019-01-23 2019-01-23 Cow leather treatment process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910065333.5A CN109652600B (en) 2019-01-23 2019-01-23 Cow leather treatment process

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CN109652600A true CN109652600A (en) 2019-04-19
CN109652600B CN109652600B (en) 2020-10-20

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105316437A (en) * 2014-06-25 2016-02-10 宜宾市浩宇皮业有限责任公司 Production process of environment-friendly cattle hide mattress
CN105860839A (en) * 2016-04-22 2016-08-17 广州市惠景皮革有限公司 Nappa leather coating composition and coating technology thereof
CN107881269A (en) * 2017-11-30 2018-04-06 兴业皮革科技股份有限公司 A kind of production method of water proof fire retardant upper leather
CN108453026A (en) * 2018-03-14 2018-08-28 四川大学 A kind of preparation method of hydrolysis foaming cow split leather
CN108951186A (en) * 2018-08-16 2018-12-07 陕西科技大学 A kind of manufacturing method of full aqueous ultrafine fiber synthetic leather

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105316437A (en) * 2014-06-25 2016-02-10 宜宾市浩宇皮业有限责任公司 Production process of environment-friendly cattle hide mattress
CN105860839A (en) * 2016-04-22 2016-08-17 广州市惠景皮革有限公司 Nappa leather coating composition and coating technology thereof
CN107881269A (en) * 2017-11-30 2018-04-06 兴业皮革科技股份有限公司 A kind of production method of water proof fire retardant upper leather
CN108453026A (en) * 2018-03-14 2018-08-28 四川大学 A kind of preparation method of hydrolysis foaming cow split leather
CN108951186A (en) * 2018-08-16 2018-12-07 陕西科技大学 A kind of manufacturing method of full aqueous ultrafine fiber synthetic leather

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