CN109651956A - A kind of waterproof material and preparation method thereof - Google Patents
A kind of waterproof material and preparation method thereof Download PDFInfo
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- CN109651956A CN109651956A CN201811398369.7A CN201811398369A CN109651956A CN 109651956 A CN109651956 A CN 109651956A CN 201811398369 A CN201811398369 A CN 201811398369A CN 109651956 A CN109651956 A CN 109651956A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
- C08K2003/3036—Sulfides of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of waterproof materials and preparation method thereof, its raw material is as follows by weight: 30-50 parts of pitch, 5-8 parts of antioxidant, 1-5 parts of defoaming agent, 2-5 parts of antimildew disinfectant, 20-40 parts of binder, 3-5 parts of stabilizer, 10-20 parts of core-shell structure polymerized emulsion, 20-40 parts of curing agent, 15-20 parts of flexibility agent；Preparation method: S1, preparation, S2, stirring, S3, drying, S4, storage.The present invention makes raw material be not in agglomerate during stirring by adding lubricant, convenient for stirring, by adding binder, make raw material that graininess, the adhesion of reinforcing material will not be presented during stirring, the present invention is capable of the toughness and intensity of reinforcing material, the also heat-resisting quantity of reinforcing material, it is suitble to large-scale production, present invention process is simple and convenient to operate, and is easy to industrialization promotion.
Description
Technical field
The invention belongs to waterproof material technical fields, more specifically more particularly to a kind of waterproof material.Meanwhile this hair
A kind of bright preparation method for further relating to waterproof material.
Background technique
Currently, waterproof material mostly uses water-soluble waterproof material, but water-soluble waterproof material cannot grasp water well
Dosage, excessive and very few, the viscosity that will lead to waterproof material is feeding-up and excessively dilute, feeding-up and excessively dilute can all lead to waterproof material
Adhesiveness be deteriorated, will affect the using effect of waterproof material, and existing water-soluble waterproof material is unable to high temperature resistant and tough
Property it is poor, be not easy to smear, so, we invent it is a kind of raising toughness, wearability and viscosity waterproof material, it is above-mentioned to solve
Problem.
Summary of the invention
The purpose of the present invention is to provide a kind of waterproof materials and preparation method thereof, to solve to propose in above-mentioned background technique
The problem of.
To achieve the above object, the invention provides the following technical scheme:
A kind of waterproof material, raw material are as follows by weight: 30-50 parts of pitch, 5-8 parts of antioxidant, and 1-5 parts of defoaming agent,
2-5 parts of antimildew disinfectant, 20-40 parts of binder, 3-5 parts of stabilizer, 10-20 parts of core-shell structure polymerized emulsion, curing agent 20-40
Part, 15-20 parts of flexibility agent.
Preferably, the binder selects one of polyvinyl alcohol, carboxymethyl cellulose, epoxy resin, butyl rubber
Or it is a variety of.
Preferably, the curing agent selects one of four ammonia of triethylene, m-xylene diamine, diamino cyclohexane or more
Kind.
Preferably, the stabilizer selects lanolin fatty acid, sodium hydroxide, calcium chloride, white vitriol, calcium zinc inorganic salts, thick
One of lanolin fatty acid is a variety of.
Preferably, one of the flexibility agent selected fatty acid diglycollic amide, polyethers, polyphenylene oxide ketone or a variety of.
The present invention also provides a kind of preparation methods of waterproof material, include the following steps:
S1, preparation: according to punishment amount, raw material being poured into agitator tank, every when a kind of raw material is added, and to add some profits
Lubrication prescription and adhesive, while water to be added into agitator tank, next step operation can be carried out；
S2, stirring: after raw material and water pour agitator tank into, can be stirred, while stirring, according to being viscosity,
Suitable addition water will prevent raw material from agglomerating during stirring, if agglomeration, is smashed to pieces, meanwhile, in stirring
In the process, every 3-5min, lubricant is added into agitator tank, convenient for stirring；
S3, drying: the material after stirring directly uses, if selling, by the good material of stirring, device has in bucket
It is dried with dedicated drying case in the manufacturer of condition, and the temperature setting of baking box is at 10-20 DEG C, if not having, then by material
Material places drying, and shady and cool place dries, and the sun can't be allowed directly to be exposed to the sun, right every 5-10 minutes when drying
It is observed.
S4, storage: the raw material after drying, be cut into it is blocky put into bucket, be also fabricated to powdered, put into packaging bag, so
After place it in dry, ventilation, shady and cool place can save a very long time.
Preferably, after S3 drying, some materials is first taken out and are tested, small room, coats waterproof material between selecting one,
It is primary every observation in 5-6 hour into room plus water after 24 hours, it observes either with or without leakage, the case where either with or without ponding, such as
The step of fruit occurs, then material is poured into agitator tank, repeats S2-S3.
Preferably, lubricant selects one of magnesium stearate, superfine silica gel powder, talcum powder, sodium stearyl fumarate in S2
Or it is a variety of.
Compared with prior art, make raw material in stirring the beneficial effects of the present invention are: the present invention is by adding lubricant
In the process be not in agglomerate, make raw material that particle will not be presented during stirring by adding binder convenient for stirring
Shape, the adhesion of reinforcing material, the present invention are capable of the toughness and intensity of reinforcing material, go back the heat-resisting quantity of reinforcing material, may be used also
Material is damaged to prevent from expanding with heat and contract with cold, is suitble to large-scale production, present invention process is simple and convenient to operate, and is easy to industrialization promotion.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Case one
A kind of waterproof material, raw material are as follows by weight: 30 parts of pitch, 5 parts of antioxidant, and 1 part of defoaming agent, antimycotic antiseptic
2 parts of agent, 20 parts of binder, 3 parts of stabilizer, 10 parts of core-shell structure polymerized emulsion, 20 parts of curing agent, 15 parts of flexibility agent.
Specifically, the binder selects one of polyvinyl alcohol, carboxymethyl cellulose, epoxy resin, butyl rubber
Or it is a variety of.
Specifically, the curing agent selects one of four ammonia of triethylene, m-xylene diamine, diamino cyclohexane or more
Kind.
Specifically, the stabilizer selects lanolin fatty acid, sodium hydroxide, calcium chloride, white vitriol, calcium zinc inorganic salts, thick
One of lanolin fatty acid is a variety of.
Specifically, one of the flexibility agent selected fatty acid diglycollic amide, polyethers, polyphenylene oxide ketone or a variety of.
The present invention also provides a kind of preparation methods of waterproof material, include the following steps:
S1, preparation: according to punishment amount, raw material being poured into agitator tank, every when a kind of raw material is added, and to add some profits
Lubrication prescription and adhesive, while water to be added into agitator tank, next step operation can be carried out；
S2, stirring: after raw material and water pour agitator tank into, can be stirred, while stirring, according to being viscosity,
Suitable addition water will prevent raw material from agglomerating during stirring, if agglomeration, is smashed to pieces, meanwhile, in stirring
In the process, every 3-5min, lubricant is added into agitator tank, convenient for stirring；
S3, drying: the material after stirring directly uses, if selling, by the good material of stirring, device has in bucket
It is dried with dedicated drying case in the manufacturer of condition, and the temperature setting of baking box if not having, then puts material at 10 DEG C
Drying is set, shady and cool place is dried, and the sun can't be allowed directly to be exposed to the sun, and when drying, to be seen every 5 minutes to it
It examines.
S4, storage: the raw material after drying, be cut into it is blocky put into bucket, be also fabricated to powdered, put into packaging bag, so
After place it in dry, ventilation, shady and cool place can save a very long time.
Specifically, first to take out some materials after S3 drying and test, small room, coats waterproof material between selecting one,
Primary every observation in 5 hours into room plus water after 24 hours, observation is either with or without leakage, the case where either with or without ponding, if
The step of appearance, then material is poured into agitator tank, repeats S2-S3.
Specifically, lubricant selects one of magnesium stearate, superfine silica gel powder, talcum powder, sodium stearyl fumarate in S2
Or it is a variety of.
Case two
A kind of waterproof material, raw material are as follows by weight: 40 parts of pitch, 6 parts of antioxidant, and 3 parts of defoaming agent, antimycotic antiseptic
4 parts of agent, 30 parts of binder, 4 parts of stabilizer, 15 parts of core-shell structure polymerized emulsion, 30 parts of curing agent, 17 parts of flexibility agent.
Specifically, the binder selects one of polyvinyl alcohol, carboxymethyl cellulose, epoxy resin, butyl rubber
Or it is a variety of.
Specifically, the curing agent selects one of four ammonia of triethylene, m-xylene diamine, diamino cyclohexane or more
Kind.
Specifically, the stabilizer selects lanolin fatty acid, sodium hydroxide, calcium chloride, white vitriol, calcium zinc inorganic salts, thick
One of lanolin fatty acid is a variety of.
Specifically, one of the flexibility agent selected fatty acid diglycollic amide, polyethers, polyphenylene oxide ketone or a variety of.
The present invention also provides a kind of preparation methods of waterproof material, include the following steps:
S1, preparation: according to punishment amount, raw material being poured into agitator tank, every when a kind of raw material is added, and to add some profits
Lubrication prescription and adhesive, while water to be added into agitator tank, next step operation can be carried out；
S2, stirring: after raw material and water pour agitator tank into, can be stirred, while stirring, according to being viscosity,
Suitable addition water will prevent raw material from agglomerating during stirring, if agglomeration, is smashed to pieces, meanwhile, in stirring
In the process, every 3-5min, lubricant is added into agitator tank, convenient for stirring；
S3, drying: the material after stirring directly uses, if selling, by the good material of stirring, device has in bucket
It is dried with dedicated drying case in the manufacturer of condition, and the temperature setting of baking box if not having, then puts material at 15 DEG C
Drying is set, shady and cool place is dried, and the sun can't be allowed directly to be exposed to the sun, and when drying, to be seen every 8 minutes to it
It examines.
S4, storage: the raw material after drying, be cut into it is blocky put into bucket, be also fabricated to powdered, put into packaging bag, so
After place it in dry, ventilation, shady and cool place can save a very long time.
Specifically, first to take out some materials after S3 drying and test, small room, coats waterproof material between selecting one,
Primary every observation in 5 hours into room plus water after 24 hours, observation is either with or without leakage, the case where either with or without ponding, if
The step of appearance, then material is poured into agitator tank, repeats S2-S3.
Specifically, lubricant selects one of magnesium stearate, superfine silica gel powder, talcum powder, sodium stearyl fumarate in S2
Or it is a variety of.
Case three
A kind of waterproof material, raw material are as follows by weight: 50 parts of pitch, 8 parts of antioxidant, and 5 parts of defoaming agent, antimycotic antiseptic
5 parts of agent, 40 parts of binder, 5 parts of stabilizer, 20 parts of core-shell structure polymerized emulsion, 40 parts of curing agent, 20 parts of flexibility agent.
Specifically, the binder selects one of polyvinyl alcohol, carboxymethyl cellulose, epoxy resin, butyl rubber
Or it is a variety of.
Specifically, the curing agent selects one of four ammonia of triethylene, m-xylene diamine, diamino cyclohexane or more
Kind.
Specifically, the stabilizer selects lanolin fatty acid, sodium hydroxide, calcium chloride, white vitriol, calcium zinc inorganic salts, thick
One of lanolin fatty acid is a variety of.
Specifically, one of the flexibility agent selected fatty acid diglycollic amide, polyethers, polyphenylene oxide ketone or a variety of.
The present invention also provides a kind of preparation methods of waterproof material, include the following steps:
S1, preparation: according to punishment amount, raw material being poured into agitator tank, every when a kind of raw material is added, and to add some profits
Lubrication prescription and adhesive, while water to be added into agitator tank, next step operation can be carried out；
S2, stirring: after raw material and water pour agitator tank into, can be stirred, while stirring, according to being viscosity,
Suitable addition water will prevent raw material from agglomerating during stirring, if agglomeration, is smashed to pieces, meanwhile, in stirring
In the process, every 3-5min, lubricant is added into agitator tank, convenient for stirring；
S3, drying: the material after stirring directly uses, if selling, by the good material of stirring, device has in bucket
It is dried with dedicated drying case in the manufacturer of condition, and the temperature setting of baking box if not having, then puts material at 20 DEG C
Drying is set, shady and cool place is dried, and the sun can't be allowed directly to be exposed to the sun, and when drying, to be carried out every 10 minutes to it
Observation.
S4, storage: the raw material after drying, be cut into it is blocky put into bucket, be also fabricated to powdered, put into packaging bag, so
After place it in dry, ventilation, shady and cool place can save a very long time.
Specifically, first to take out some materials after S3 drying and test, small room, coats waterproof material between selecting one,
Primary every observation in 6 hours into room plus water after 24 hours, observation is either with or without leakage, the case where either with or without ponding, if
The step of appearance, then material is poured into agitator tank, repeats S2-S3.
Specifically, lubricant selects one of magnesium stearate, superfine silica gel powder, talcum powder, sodium stearyl fumarate in S2
Or it is a variety of.
The present invention makes raw material be not in agglomerate during stirring by adding lubricant, convenient for stirring, by adding
Add binder, raw material made not to be presented graininess during stirring, the adhesion of reinforcing material, by high density ethylene and
Flexibility agent, the effective influence for reducing foreign objects to this material influence using effect, the present invention be capable of reinforcing material toughness and
Intensity goes back the heat-resisting quantity of reinforcing material, is suitble to large-scale production, and present invention process is simple and convenient to operate, and is easy to industrialization and pushes away
Extensively,
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of waterproof material, which is characterized in that its raw material is as follows by weight: 30-50 parts of pitch, 5-8 parts of antioxidant, defoaming
1-5 parts of agent, 2-5 parts of antimildew disinfectant, 20-40 parts of binder, 3-5 parts of stabilizer, 10-20 parts of core-shell structure polymerized emulsion, Gu
20-40 parts of agent, 15-20 parts of flexibility agent.
2. a kind of waterproof material according to claim 1, it is characterised in that: the binder selects polyvinyl alcohol, carboxylic first
One of base cellulose, epoxy resin, butyl rubber are a variety of.
3. a kind of waterproof material according to claim 1, it is characterised in that: the curing agent select four ammonia of triethylene,
One of benzene dimethylamine, diamino cyclohexane are a variety of.
4. a kind of waterproof material according to claim 1, it is characterised in that: the stabilizer selects lanolin fatty acid, hydroxide
One of sodium, calcium chloride, white vitriol, calcium zinc inorganic salts, common and braid wool acid are a variety of.
5. a kind of waterproof material according to claim 1, it is characterised in that: the flexibility agent selected fatty acid diethanol acyl
One of amine, polyethers, polyphenylene oxide ketone are a variety of.
6. a kind of preparation method of waterproof material described in claim 1, which comprises the steps of:
S1, preparation: according to punishment amount, raw material being poured into agitator tank, every when a kind of raw material is added, and to add some bondings
Agent, while water to be added into agitator tank, next step operation can be carried out；
S2, stirring: after raw material and water pour agitator tank into, can be stirred, while stirring, according to viscosity is, in right amount
Addition water to prevent raw material from agglomerating during stirring, if agglomeration, smashed to pieces, meanwhile, in the process of stirring
In, every 3-5min, lubricant is added into agitator tank, convenient for stirring；
S3, drying: the material after stirring directly uses, if selling, by the good material of stirring, device is had ready conditions in bucket
Manufacturer it is dried with dedicated drying case, the temperature setting of baking box is at 10-20 DEG C, if not having, then puts material
Set drying, shady and cool place is dried, the sun can't be allowed directly to be exposed to the sun, when drying, every 5-10 minutes, to its into
Row observation.
S4, storage: the raw material after drying, be cut into it is blocky put into bucket, be also fabricated to powdered, put into packaging bag, then will
It is placed on dry, ventilation, and shady and cool place can save a very long time.
7. a kind of preparation method of waterproof material according to claim 6, it is characterised in that: after S3 drying, first to take out
Some materials are tested, and waterproof material is coated in small room between selecting one, and after 24 hours, water is added into room, small every 5-6
When observation it is primary, observation is either with or without leakage, the case where either with or without ponding, if there is then material is poured into agitator tank, is repeated
The step of S2-S3.
8. a kind of preparation method of waterproof material according to claim 6, it is characterised in that: lubricant is selected stearic in S2
One of sour magnesium, superfine silica gel powder, talcum powder, sodium stearyl fumarate are a variety of.
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| CN201811398369.7A CN109651956A (en) | 2018-11-22 | 2018-11-22 | A kind of waterproof material and preparation method thereof |
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| CN201811398369.7A CN109651956A (en) | 2018-11-22 | 2018-11-22 | A kind of waterproof material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112321201A (en) * | 2020-11-25 | 2021-02-05 | 宁波东兴沥青制品有限公司 | High-density asphalt concrete and preparation method thereof |
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