CN109650849A - A kind of flame retardant type wall brick and its production method - Google Patents

A kind of flame retardant type wall brick and its production method Download PDF

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Publication number
CN109650849A
CN109650849A CN201910148680.4A CN201910148680A CN109650849A CN 109650849 A CN109650849 A CN 109650849A CN 201910148680 A CN201910148680 A CN 201910148680A CN 109650849 A CN109650849 A CN 109650849A
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parts
flame retardant
wall brick
type wall
retardant type
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孙日东
史镜成
孙杰
周建康
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Yangzhou Fu Ming New Material Co Ltd
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Yangzhou Fu Ming New Material Co Ltd
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Priority to CN201910148680.4A priority Critical patent/CN109650849A/en
Publication of CN109650849A publication Critical patent/CN109650849A/en
Priority to PCT/CN2019/124610 priority patent/WO2020173174A1/en
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B33/00Clay-wares
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/52Constituents or additives characterised by their shapes
    • C04B2235/5208Fibers
    • C04B2235/5216Inorganic
    • C04B2235/524Non-oxidic, e.g. borides, carbides, silicides or nitrides
    • C04B2235/5248Carbon, e.g. graphite
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    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Abstract

The invention discloses a kind of flame retardant type wall brick, the flame retardant type wall brick includes the raw material being equipped with according to following number: 10-15 parts of flyash, 10-15 parts of feldspar, 5-10 parts of perlite, 10-15 parts of laterite, 10-15 parts of glass fibre, 4-9 parts of nano zine oxide, 8-15 parts of nano silica, 6-12 parts of bamboo charcoal powder, 5-10 parts of steel slag, 5-15 parts of glass dregs, 3-7 parts of acrylic acid series elastic resin, 1-3 parts of grinding aid, 3-5 parts of fire retardant, 1.5-3 parts of antioxidant, 1.5-2.5 parts of heat stabilizer and water.The invention also discloses a kind of production methods of flame retardant type wall brick.The present invention improves anti-flammability, and environmental protection.

Description

A kind of flame retardant type wall brick and its production method
Technical field
The present invention relates to a kind of technical field of wall brick, especially a kind of flame retardant type wall brick and its production method.
Background technique
Wall brick is suitable for the places such as kitchen, parlor, toilet, plays the work of protection and decoration as a kind of construction material With, but current wall brick is easily broken off, it is therefore desirable to improve since fire-type is not strong after pre- high temperature.
Summary of the invention
A kind of flame retardant type wall brick and its production are provided the purpose of the present invention is to solve above-mentioned the deficiencies in the prior art Method.
To achieve the goals above, the present invention designed by a kind of flame retardant type wall brick, the flame retardant type wall brick include according to The raw material that following number is equipped with: 10-15 parts of flyash, 10-15 parts of feldspar, 5-10 parts of perlite, 10-15 parts of laterite, glass fibers Tie up 10-15 parts, 4-9 parts of nano zine oxide, 8-15 parts of nano silica, 6-12 parts of bamboo charcoal powder, 5-10 parts of steel slag, glass dregs 5- 15 parts, 3-7 parts of acrylic acid series elastic resin, 1-3 parts of grinding aid, 3-5 parts of fire retardant, 1 .5-3 parts of antioxidant, heat stabilizer 1 .5-2 .5 parts and water.
Further, the flame retardant type wall brick further includes 5-10 parts of antibacterial agent.
Further, the flame retardant type wall brick further includes 5-10 parts of anti-blushing agent.
Further, the flame retardant type wall brick further includes 3-9 parts of smectite powder.
Further, the raw material including being equipped with according to following number: 12 parts of flyash, 12 parts of feldspar, 8 parts of perlite, laterite 12 parts, 12 parts of glass fibre, 8 parts of nano zine oxide, 12 parts of nano silica, 11 parts of bamboo charcoal powder, 8 parts of steel slag, glass dregs 8 Part, 5 parts of acrylic acid series elastic resin, 2 parts of grinding aid, 4 parts of fire retardant, 2 parts of antioxidant, 2 parts of heat stabilizer and water.
Further, the smectite powder is 5 parts.
Further, the fire retardant is ammonium polyphosphate, phosphoric acid narrows base urea, phosphate, melamine phosphate, melamine One of pyrophosphate or a variety of combinations.
Further, the heat stabilizer is the combination of 2 ethyl hexanoic acid salt, Ding Xinji ZDDP and N- phenyl-α-naphthylamine.
The invention also discloses a kind of production methods of flame retardant type wall brick, specifically includes the following steps:
1) flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag are subjected to primary filter;
2) then by filtered flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag and nano oxidized Zinc, nano silica, bamboo charcoal powder, acrylic acid series elastic resin, grinding aid, fire retardant, antioxidant, heat stabilizer and water mixing And it grinds and slurry is made, and the ratio of the water is adjusted in real time in grinding, ultimately becomes relatively sticky slurry;
3) painting oil processing is carried out to mold, then slurry is sent into the mold of oiling and carries out platen composition embryo material;
4) it after embryo material being carried out the pre-heat treatment cooling, calcined, cooled down and constitute flame retardant type wall brick after being demoulded processing;
Wherein, the calcination temperature is to be warming up to 500-700 degrees Celsius from 20-30 degrees Celsius with 7-9 centigrade per minute Primary calcining 1.5 hours is carried out, then proceedes to be warming up to 1300-1400 degrees Celsius of lower secondary clacining, calcination time is that 0.5-1 is small When.
Further, it is additionally added antibacterial agent in step 2.
A kind of flame retardant type wall brick and its production method that the present invention obtains, all raw materials environmental protection that the present invention uses, can return It receives, finally reduces production cost, it is environmentally protective, while flame retardant type being provided.
Specific embodiment
Innovation and creation are described further below with reference to embodiment.
Embodiment 1:
A kind of flame retardant type wall brick provided in this embodiment, the flame retardant type wall brick include the raw material being equipped with according to following number: powder 10-15 parts of coal ash, 10-15 parts of feldspar, 5-10 parts of perlite, 10-15 parts of laterite, 10-15 parts of glass fibre, nano zine oxide 4- 9 parts, 8-15 parts of nano silica, 6-12 parts of bamboo charcoal powder, 5-10 parts of steel slag, 5-15 parts of glass dregs, acrylic acid series elastic resin 3-7 parts, 1-3 parts of grinding aid, 3-5 parts of fire retardant, 1 .5-3 parts of antioxidant .5 parts of 1 .5-2 of heat stabilizer and water.
Further, the flame retardant type wall brick further includes 5-10 parts of anti-blushing agent.5 parts of the anti-blushing agent.
Further, the raw material including being equipped with according to following number: 12 parts of flyash, 12 parts of feldspar, 8 parts of perlite, laterite 12 parts, 12 parts of glass fibre, 8 parts of nano zine oxide, 12 parts of nano silica, 11 parts of bamboo charcoal powder, 8 parts of steel slag, glass dregs 8 Part, 5 parts of acrylic acid series elastic resin, 2 parts of grinding aid, 4 parts of fire retardant, 2 parts of antioxidant, 2 parts of heat stabilizer and water.
Further, the smectite powder is 5 parts.
Further, the fire retardant is ammonium polyphosphate, phosphoric acid narrows base urea, phosphate, melamine phosphate, melamine One of pyrophosphate or a variety of combinations.
Further, the heat stabilizer is the combination of 2 ethyl hexanoic acid salt, Ding Xinji ZDDP and N- phenyl-α-naphthylamine.
The present embodiment also discloses a kind of production method of flame retardant type wall brick, specifically includes the following steps:
1) flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag are subjected to primary filter;
2) then by filtered flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag and nano oxidized Zinc, nano silica, bamboo charcoal powder, acrylic acid series elastic resin, grinding aid, fire retardant, antioxidant, anti-blushing agent, heat stabilizer It mixes and grinds with water and slurry is made, and the ratio of the water is adjusted in real time in grinding, ultimately becomes relatively sticky Slurry;
3) painting oil processing is carried out to mold, then slurry is sent into the mold of oiling and carries out platen composition embryo material;
4) it after embryo material being carried out the pre-heat treatment cooling, calcined, cooled down and constitute flame retardant type wall brick after being demoulded processing;
Wherein, the calcination temperature be from 20-30 degrees Celsius with 8 centigrade per minutes be warming up to 500-700 degrees Celsius into The primary calcining of row 1.5 hours then proceedes to be warming up to 1350 degrees Celsius of lower secondary clacinings, and calcination time is 0.8 hour.
All raw materials environmental protection that the present embodiment uses, can be recycled, finally reduce production cost, environmentally protective, mention simultaneously For flame retardant type.
Calcination temperature is to be warming up to 520 degrees Celsius of progress just with 8 centigrade per minutes from 21 degrees Celsius in the present embodiment Grade calcining 1.5 hours then proceedes to be warming up to 1350 degrees Celsius of lower secondary clacinings, and calcination time is 0.8 hour.
Embodiment 2:
A kind of flame retardant type wall brick provided in this embodiment, the flame retardant type wall brick include the raw material being equipped with according to following number: powder 13 parts of coal ash, 13 parts of feldspar, 8 parts of perlite, 13 parts of laterite, 13 parts of glass fibre, 7 parts of nano zine oxide, nano silica 13 parts, it is 10 parts of bamboo charcoal powder, 8 parts of steel slag, 11 parts of glass dregs, 5 parts of acrylic acid series elastic resin, 2 parts of grinding aid, 4 parts of fire retardant, anti- 2 parts of oxygen agent, 1 .8 parts of heat stabilizer and water.
Further, the flame retardant type wall brick further includes 5-10 parts of anti-blushing agent.
Further, 5 parts of the anti-blushing agent.
Further, the fire retardant is ammonium polyphosphate, phosphoric acid narrows base urea.
Further, the heat stabilizer is the combination of 2 ethyl hexanoic acid salt, Ding Xinji ZDDP and N- phenyl-α-naphthylamine.
The present embodiment also discloses a kind of production method of flame retardant type wall brick, specifically includes the following steps:
1) flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag are subjected to primary filter;
2) then by filtered flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag and nano oxidized Zinc, nano silica, bamboo charcoal powder, acrylic acid series elastic resin, grinding aid, fire retardant, antioxidant, heat stabilizer and water mixing And it grinds and slurry is made, and the ratio of the water is adjusted in real time in grinding, ultimately becomes relatively sticky slurry;
3) painting oil processing is carried out to mold, then slurry is sent into the mold of oiling and carries out platen composition embryo material;
4) it after embryo material being carried out the pre-heat treatment cooling, calcined, cooled down and constitute flame retardant type wall brick after being demoulded processing;
Wherein, the calcination temperature is to be forged from 22 degrees Celsius with the 500 degrees Celsius of progress primary that are warming up to of 7 centigrade per minutes It burns 1.5 hours, then proceedes to be warming up to 1300 degrees Celsius of lower secondary clacinings, calcination time is 0.5 hour.
Embodiment 3:
A kind of flame retardant type wall brick provided in this embodiment, the flame retardant type wall brick include the raw material being equipped with according to following number: powder 13 parts of coal ash, 13 parts of feldspar, 7 parts of perlite, 12 parts of laterite, 12 parts of glass fibre, 7 parts of nano zine oxide, nano silica 14 parts, it is 11 parts of bamboo charcoal powder, 8 parts of steel slag, 14 parts of glass dregs, 5 parts of acrylic acid series elastic resin, 2 parts of grinding aid, 4 parts of fire retardant, anti- 2.5 parts of oxygen agent, 2 parts of heat stabilizer and water.
Further, the flame retardant type wall brick further includes 5-10 parts of anti-blushing agent.7 parts of the anti-blushing agent.
Further, the fire retardant is ammonium polyphosphate, phosphoric acid narrows base urea, phosphate, melamine phosphate, melamine Pyrophosphate.
Further, the heat stabilizer is the combination of 2 ethyl hexanoic acid salt, Ding Xinji ZDDP and N- phenyl-α-naphthylamine.
The present embodiment also discloses a kind of production method of flame retardant type wall brick, specifically includes the following steps:
1) flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag are subjected to primary filter;
2) then by filtered flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag and nano oxidized Zinc, nano silica, bamboo charcoal powder, acrylic acid series elastic resin, grinding aid, fire retardant, antioxidant, heat stabilizer, anti-blushing agent It mixes and grinds with water and slurry is made, and the ratio of the water is adjusted in real time in grinding, ultimately becomes relatively sticky Slurry;
3) painting oil processing is carried out to mold, then slurry is sent into the mold of oiling and carries out platen composition embryo material;
4) it after embryo material being carried out the pre-heat treatment cooling, calcined, cooled down and constitute flame retardant type wall brick after being demoulded processing;
Wherein, the calcination temperature is to be warming up to 590 degrees Celsius of progress primary from 26 degrees Celsius with 7.9 centigrade per minutes Calcining 1.5 hours then proceedes to be warming up to 1360 degrees Celsius of lower secondary clacinings, and calcination time is 0.7 hour.
Embodiment 4:
A kind of flame retardant type wall brick provided in this embodiment, the flame retardant type wall brick include the raw material being equipped with according to following number: powder 10-15 parts of coal ash, 10-15 parts of feldspar, 5-10 parts of perlite, 10-15 parts of laterite, 10-15 parts of glass fibre, nano zine oxide 4- 9 parts, 8-15 parts of nano silica, 6-12 parts of bamboo charcoal powder, 5-10 parts of steel slag, 5-15 parts of glass dregs, acrylic acid series elastic resin 3-7 parts, 1-3 parts of grinding aid, 3-5 parts of fire retardant, 1 .5-3 parts of antioxidant .5 parts of 1 .5-2 of heat stabilizer and water.
Further, the flame retardant type wall brick further includes 5-10 parts of antibacterial agent.
Further, the flame retardant type wall brick further includes 5-10 parts of anti-blushing agent.
Further, the flame retardant type wall brick further includes 3-9 parts of smectite powder.
Further, the fire retardant is melamine phosphate, melamine pyrophosphate.
Further, the heat stabilizer is the combination of 2 ethyl hexanoic acid salt, Ding Xinji ZDDP and N- phenyl-α-naphthylamine.
The present embodiment also discloses a kind of production method of flame retardant type wall brick, specifically includes the following steps:
1) flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag are subjected to primary filter;
2) then by filtered flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag and nano oxidized Zinc, nano silica, bamboo charcoal powder, acrylic acid series elastic resin, grinding aid, fire retardant, antioxidant, heat stabilizer and water mixing And it grinds and slurry is made, and the ratio of the water is adjusted in real time in grinding, ultimately becomes relatively sticky slurry;
3) painting oil processing is carried out to mold, then slurry is sent into the mold of oiling and carries out platen composition embryo material;
4) it after embryo material being carried out the pre-heat treatment cooling, calcined, cooled down and constitute flame retardant type wall brick after being demoulded processing;
Wherein, the calcination temperature is to be forged from 28 degrees Celsius with the 600 degrees Celsius of progress primary that are warming up to of 8 centigrade per minutes It burns 1.5 hours, then proceedes to be warming up to 1390 degrees Celsius of lower secondary clacinings, calcination time is 0.8 hour.
Further, it is additionally added 8 parts of the antibacterial agent, 8 parts of anti-blushing agent, 7 parts of smectite powder in step 2.
Embodiment 5:
A kind of flame retardant type wall brick provided in this embodiment, the flame retardant type wall brick include the raw material being equipped with according to following number: powder 15 parts of coal ash, 15 parts of feldspar, 10 parts of perlite, 15 parts of laterite, 15 parts of glass fibre, 9 parts of nano zine oxide, nano silica 15 parts, 12 parts of bamboo charcoal powder, 10 parts of steel slag, 15 parts of glass dregs, 7 parts of acrylic acid series elastic resin, 3 parts of grinding aid, 5 parts of fire retardant, 3 parts of antioxidant, 2 .5 parts of heat stabilizer and water.
Further, the flame retardant type wall brick further includes 5-10 parts of antibacterial agent.
Further, the flame retardant type wall brick further includes 5-10 parts of anti-blushing agent.
Further, the flame retardant type wall brick further includes 3-9 parts of smectite powder.Antibacterial agent 10 described in the present embodiment Part, 10 parts of anti-blushing agent, 9 parts of smectite powder.
Further, the fire retardant is ammonium polyphosphate, phosphoric acid narrows base urea, phosphate, melamine phosphate, melamine One of pyrophosphate or a variety of combinations.
Further, the heat stabilizer is the combination of 2 ethyl hexanoic acid salt, Ding Xinji ZDDP and N- phenyl-α-naphthylamine.
The present embodiment also discloses a kind of production method of flame retardant type wall brick, specifically includes the following steps:
1) flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag are subjected to primary filter;
2) then by filtered flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag and nano oxidized Zinc, nano silica, bamboo charcoal powder, acrylic acid series elastic resin, grinding aid, fire retardant, antioxidant, heat stabilizer and water mixing And it grinds and slurry is made, and the ratio of the water is adjusted in real time in grinding, ultimately becomes relatively sticky slurry;
3) painting oil processing is carried out to mold, then slurry is sent into the mold of oiling and carries out platen composition embryo material;
4) it after embryo material being carried out the pre-heat treatment cooling, calcined, cooled down and constitute flame retardant type wall brick after being demoulded processing;
Wherein, the calcination temperature is to be forged from 30 degrees Celsius with the 700 degrees Celsius of progress primary that are warming up to of 9 centigrade per minutes It burns 1.5 hours, then proceedes to be warming up to 1400 degrees Celsius of lower secondary clacinings, calcination time is 1 hour.
Further, it is additionally added antibacterial agent, anti-blushing agent and smectite powder in step 2.
The common wall brick of flame retardant type wall brick made from embodiment 1-5 and the prior art is tested for the property, final result It is as follows, it is shown in Table 1:
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention, for those skilled in the art For member, it is clear that invention is not limited to the details of the above exemplary embodiments, and without departing substantially from spirit of the invention or substantially In the case where feature, the present invention can be realized in other specific forms.Therefore, in all respects, should all will implement Example regards exemplary as, and is non-limiting, and the scope of the present invention is by appended claims rather than above description limits It is fixed, it is intended that including all changes that fall within the meaning and scope of the equivalent elements of the claims in the present invention.To the greatest extent The embodiment of the present invention has been shown and described in pipe, for the ordinary skill in the art, it is possible to understand that is not taking off A variety of change, modification, replacement and modification, this hair can be carried out to these embodiments in the case where from the principle and spirit of the invention Bright range is defined by the appended claims and the equivalents thereof.

Claims (10)

1. a kind of flame retardant type wall brick, which is characterized in that the flame retardant type wall brick includes the raw material being equipped with according to following number: fine coal 10-15 parts grey, 10-15 parts of feldspar, 5-10 parts of perlite, 10-15 parts of laterite, 10-15 parts of glass fibre, nano zine oxide 4-9 Part, 8-15 parts of nano silica, 6-12 parts of bamboo charcoal powder, 5-10 parts of steel slag, 5-15 parts of glass dregs, acrylic acid series elastic resin 3- 7 parts, 1-3 parts of grinding aid, 3-5 parts of fire retardant, 1 .5-3 parts of antioxidant .5 parts of 1 .5-2 of heat stabilizer and water.
2. a kind of flame retardant type wall brick according to claim 1, which is characterized in that the flame retardant type wall brick further includes antibacterial agent 5-10 parts.
3. a kind of flame retardant type wall brick according to claim 1 or 2, which is characterized in that the flame retardant type wall brick further includes preventing Damp agent 5-10 parts.
4. a kind of flame retardant type wall brick according to claim 1 or 2, which is characterized in that the flame retardant type wall brick further includes changing 3-9 parts of montmorillonite powder of property.
5. a kind of flame retardant type wall brick according to claim 1 or 2, which is characterized in that including what is be equipped with according to following number Raw material: 12 parts of flyash, 12 parts of feldspar, 8 parts of perlite, 12 parts of laterite, 12 parts of glass fibre, 8 part, nanometer two of nano zine oxide 12 parts of silica, 11 parts of bamboo charcoal powder, 8 parts of steel slag, 8 parts of glass dregs, 5 parts of acrylic acid series elastic resin, 2 parts of grinding aid, fire retardant 4 Part, 2 parts of antioxidant, 2 parts of heat stabilizer and water.
6. a kind of flame retardant type wall brick according to claim 3, which is characterized in that the smectite powder is 5 parts.
7. a kind of flame retardant type wall brick according to claim 1 or 2, which is characterized in that the fire retardant is ammonium polyphosphate, phosphorus Acid narrows one of base urea, phosphate, melamine phosphate, melamine pyrophosphate or a variety of combinations.
8. a kind of flame retardant type wall brick according to claim 1 or 2, which is characterized in that the heat stabilizer is 2- ethyl hexyl The combination of hydrochlorate, Ding Xinji ZDDP and N- phenyl-α-naphthylamine.
9. a kind of production method of flame retardant type wall brick, it is characterised in that specifically includes the following steps:
Flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag are subjected to primary filter;
Then by filtered flyash, feldspar, perlite, laterite, glass fibre, glass dregs and steel slag and nano oxidized Zinc, nano silica, bamboo charcoal powder, acrylic acid series elastic resin, grinding aid, fire retardant, antioxidant, heat stabilizer and water mixing And it grinds and slurry is made, and the ratio of the water is adjusted in real time in grinding, ultimately becomes relatively sticky slurry;
Painting oil processing is carried out to mold, then slurry is sent into the mold of oiling and carries out platen composition embryo material;
After embryo material is carried out the pre-heat treatment cooling, is calcined, cooled down and constitute flame retardant type wall brick after being demoulded processing;
Wherein, the calcination temperature is to be warming up to 500-700 degrees Celsius from 20-30 degrees Celsius with 7-9 centigrade per minute Primary calcining 1.5 hours is carried out, then proceedes to be warming up to 1300-1400 degrees Celsius of lower secondary clacining, calcination time is that 0.5-1 is small When.
10. a kind of production method of flame retardant type wall brick according to claim 9, it is characterised in that: be additionally added in step 2 Antibacterial agent.
CN201910148680.4A 2019-02-28 2019-02-28 A kind of flame retardant type wall brick and its production method Pending CN109650849A (en)

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WO2020173174A1 (en) * 2019-02-28 2020-09-03 扬州富铭新材料有限公司 Flame retardant wall tile and production method therefor

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CN106431197A (en) * 2016-09-07 2017-02-22 安徽金生金世电子科技有限公司 Thermal insulation wall brick and preparation method thereof
KR101799914B1 (en) * 2017-06-05 2017-11-22 주식회사 비젼세라믹 Multi fuctional eco brick
CN108948575A (en) * 2018-06-14 2018-12-07 合肥尚强电气科技有限公司 Environment-friendly floor material and preparation method thereof

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CN109851324A (en) * 2019-02-27 2019-06-07 扬州扬铭新材料有限公司 A kind of anti-corrosion type wall brick and its production method
CN109650849A (en) * 2019-02-28 2019-04-19 扬州富铭新材料有限公司 A kind of flame retardant type wall brick and its production method

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CN106431197A (en) * 2016-09-07 2017-02-22 安徽金生金世电子科技有限公司 Thermal insulation wall brick and preparation method thereof
KR101799914B1 (en) * 2017-06-05 2017-11-22 주식회사 비젼세라믹 Multi fuctional eco brick
CN108948575A (en) * 2018-06-14 2018-12-07 合肥尚强电气科技有限公司 Environment-friendly floor material and preparation method thereof

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WO2020173174A1 (en) * 2019-02-28 2020-09-03 扬州富铭新材料有限公司 Flame retardant wall tile and production method therefor

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Application publication date: 20190419