CN109628846B - 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and production method thereof - Google Patents

1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and production method thereof Download PDF

Info

Publication number
CN109628846B
CN109628846B CN201811563499.1A CN201811563499A CN109628846B CN 109628846 B CN109628846 B CN 109628846B CN 201811563499 A CN201811563499 A CN 201811563499A CN 109628846 B CN109628846 B CN 109628846B
Authority
CN
China
Prior art keywords
rolling
equal
temperature
rolled steel
heat preservation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201811563499.1A
Other languages
Chinese (zh)
Other versions
CN109628846A (en
Inventor
冯晓勇
张洪波
杜明山
王云阁
邝霜
杜雁冰
耿志宇
李梦龙
刘丽萍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tangshan Iron and Steel Group Co Ltd
HBIS Co Ltd Tangshan Branch
Original Assignee
Tangshan Iron and Steel Group Co Ltd
HBIS Co Ltd Tangshan Branch
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tangshan Iron and Steel Group Co Ltd, HBIS Co Ltd Tangshan Branch filed Critical Tangshan Iron and Steel Group Co Ltd
Priority to CN201811563499.1A priority Critical patent/CN109628846B/en
Publication of CN109628846A publication Critical patent/CN109628846A/en
Application granted granted Critical
Publication of CN109628846B publication Critical patent/CN109628846B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273Final recrystallisation annealing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

The invention discloses a 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and a production method thereof, wherein the steel plate comprises the following chemical components in percentage by mass: c: 0.2-0.3%, Mn: 1.3-2.0%, S is less than or equal to 0.005%, P is less than or equal to 0.02%, Si: 0.2-0.3%, Als is less than or equal to 0.08%, Nb: 0.01-0.03%, Ti: 0.04-0.08%, B: 0.001-0.004%, Mo: 0.2-0.3%, Cr: 0.05-0.10%, V: 0.01-0.02% of Fe and other inevitable impurities as the rest; the production method comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling and straightening. The cold-rolled steel plate has excellent mechanical properties, the yield strength is more than or equal to 850MPa, the tensile strength is more than or equal to 1300MPa, the elongation is more than or equal to 7 percent, and the cold-forming property is good.

Description

1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and production method thereof
Technical Field
The invention belongs to the technical field of metallurgy, and particularly relates to a 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and a production method thereof.
Background
In recent years, in order to meet the requirements of weight reduction, energy saving, environmental protection and safety of automobiles, the development and research of high-strength automobile steel have been one of the key subjects in the field of steel material research. Compared with the second generation and third generation advanced high-strength automobile steel, the dual-phase steel is a typical representative of the first generation advanced high-strength automobile steel due to the characteristics of low production cost, low yield ratio, high elongation, obvious work hardening, easiness in stamping, good plasticity, good toughness matching and the like, and occupies the greatest proportion in the automobile high-strength steel.
The microstructure of the dual-phase steel automobile plate product consists of ferrite and martensite, the martensite structure is dispersed and distributed on a ferrite matrix in an island shape, and the strength and the proportion of the martensite phase determine the strength grade of the dual-phase steel. At present, the research on high-strength dual-phase steel is mostly focused on the DP1180 strength level and below, and with the progress of the steel industry and the automobile body manufacturing technology, advanced high-strength steel with the strength of 1300MPa or above is increasingly applied to the automobile body manufacturing.
Disclosure of Invention
The invention aims to solve the technical problem of providing a 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and a production method thereof. The steel plate produced by the invention has good plasticity and toughness matching, good forming performance, low manufacturing cost, simple process and high performance stability, and can bring considerable economic benefit.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: the 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for the automobile comprises the following chemical components in percentage by mass: c: 0.2-0.3%, Mn: 1.3-2.0%, S is less than or equal to 0.005%, P is less than or equal to 0.02%, Si: 0.2-0.3%, Als is less than or equal to 0.08%, Nb: 0.01-0.03%, Ti: 0.04-0.08%, B: 0.001-0.004%, Mo: 0.2-0.3%, Cr: 0.05-0.10%, V: 0.01-0.02%, and the balance of Fe and other inevitable impurities.
The thickness of the steel plate is 0.8-2.0 mm; the microstructure consists of ferrite and martensite, and the martensite is dispersed and distributed on the ferrite matrix in an island shape.
The yield strength of the steel plate is more than or equal to 850MPa, the tensile strength is more than or equal to 1300MPa, and the elongation A80 is more than or equal to 7%.
The invention also provides a production method of the 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for the automobile, which comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling and straightening; in the hot rolling process, the heating temperature of a plate blank is more than or equal to 1200 ℃, the rough rolling is carried out for 3-7 times, the thickness of an intermediate blank after the rough rolling is 28-40 mm, the inlet temperature of the finish rolling is 1020-1100 ℃, the final rolling temperature is 820-900 ℃, and the coiling temperature is 550-650 ℃.
The steelmaking process comprises molten iron desulphurization and slagging, converter smelting, L F furnace refining and RH vacuum treatment.
According to the continuous casting process, the surface and internal quality of the slab is controlled in the casting process, and microcracks and secondary cracks on the surface of the slab are prevented.
In the acid rolling process, cold rolling is carried out after acid pickling, and the cold rolling reduction rate is more than or equal to 45 percent.
In the continuous annealing process, the heat preservation temperature of the soaking section is 760-840 ℃, and the heat preservation time is 60-225 s; the heat preservation temperature of the overaging section is 250-320 ℃, and the heat preservation time of the overaging section is 300-1225 s.
The leveling, pulling and straightening process has the leveling elongation of 0.1-0.4%.
The invention relates to a 1300MPa grade ultrahigh strength cold-rolled steel sheet for automobiles, which is subject to GB/T228.1-2010 standard reference.
Adopt the produced beneficial effect of above-mentioned technical scheme to lie in: 1. the invention adopts C, Mn and Mo elements to improve the hardenability of steel and ensure the strength of strip steel; meanwhile, Nb, V and Ti are adopted for micro-alloying, and the yield strength and toughness are improved by utilizing the fine grain strengthening effect; the ultra-high strength steel has the advantages that the ultra-high strength steel can be realized, the better elongation is kept, the reduction of the elongation caused by too much Nb element is avoided, and the ultra-high strength steel has the characteristics of excellent comprehensive performance, low cost and the like. 2. The method of the invention controls the processes of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling and straightening and withdrawal, produces the automobile ultrahigh strength cold rolled steel plate with good plasticity and toughness matching, and has the characteristics of low cost, stable production process, excellent and stable finished product performance. 3. The ultrahigh-strength cold-rolled steel sheet for the automobile, which is obtained by the method, has excellent mechanical properties, the yield strength of more than or equal to 850MPa, the tensile strength of more than or equal to 1300MPa and the elongation of more than or equal to 7 percent, and has good cold-forming property.
Drawings
FIG. 1 is a metallographic structure diagram of an ultra-high strength cold rolled steel sheet for an automobile according to example 1;
FIG. 2 is a drawing graph of an ultra-high strength cold rolled steel sheet for automobiles according to example 1.
Detailed Description
The invention is described in further detail below with reference to the figures and specific examples.
Example 1
The thickness of the 1300MPa grade ultrahigh strength cold rolled steel plate for automobiles in the embodiment is 0.8mm, and the chemical composition and the mass percentage content thereof are shown in Table 1.
The production method of the 1300 MPa-grade ultrahigh-strength cold-rolled steel sheet for the automobile comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling, pulling and straightening, and comprises the following specific processing steps:
(1) the steel making process comprises molten iron desulphurization and slagging off, converter smelting, L F furnace refining and RH vacuum treatment;
(2) and (3) continuous casting process: controlling the surface and internal quality of the slab in the casting process;
(3) a hot rolling procedure: the heating temperature of the plate blank is 1250 ℃; rough rolling for 5 times, wherein the thickness of the intermediate blank after rough rolling is 34 mm; the inlet temperature of finish rolling is 1050 ℃, the finish rolling temperature is 820 ℃ and the coiling temperature is 580 ℃;
(4) acid rolling process: cold rolling is carried out after acid cleaning, and the cold rolling reduction rate is 45%;
(5) a continuous annealing process: the heat preservation temperature of the soaking section is 820 ℃, and the heat preservation time is 100 s; the heat preservation temperature of the overaging section is 250 ℃, and the heat preservation time of the overaging section is 1000 s;
(6) leveling, pulling and straightening: the flat elongation was 0.20%.
The performance indexes of the 1300MPa grade ultrahigh-strength cold-rolled steel sheet for automobiles in the embodiment are shown in Table 2; the microstructure consists of ferrite and martensite, and the martensite is dispersed and distributed on the ferrite matrix in an island shape.
The metallographic structure of the 1300MPa grade ultrahigh strength cold-rolled steel sheet for automobiles obtained in the embodiment is shown in figure 1; the tensile curve of the ultra-high strength cold rolled steel sheet is shown in FIG. 2. (the metallographic structure of the ultra-high strength cold rolled steel sheet for automobiles of examples 2 to 8 is similar to that of FIG. 1 and thus omitted; the tensile strength of the ultra-high strength cold rolled steel sheet for automobiles of examples 2 to 8 is similar to that of FIG. 2 and thus omitted.)
Example 2
The thickness of the 1300MPa grade ultrahigh strength cold rolled steel plate for automobiles in the embodiment is 1.0mm, and the chemical component composition and the mass percentage content are shown in Table 1.
The production method of the 1300 MPa-grade ultrahigh-strength cold-rolled steel sheet for the automobile comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling, pulling and straightening, and comprises the following specific processing steps:
(1) the steel making process comprises molten iron desulphurization and slagging off, converter smelting, L F furnace refining and RH vacuum treatment;
(2) and (3) continuous casting process: controlling the surface and internal quality of the slab in the casting process;
(3) a hot rolling procedure: the heating temperature of the plate blank is 1220 ℃; rough rolling for 5 times, wherein the thickness of the intermediate blank after rough rolling is 38 mm; the inlet temperature of finish rolling is 1060 ℃, the finish rolling temperature is 835 ℃, and the coiling temperature is 550 ℃;
(4) acid rolling process: cold rolling is carried out after acid cleaning, and the cold rolling reduction rate is 55 percent;
(5) a continuous annealing process: the heat preservation temperature of the soaking section is 760 ℃, and the heat preservation time is 225 s; the heat preservation temperature of the overaging section is 295 ℃, and the heat preservation time of the overaging section is 300 s;
(6) leveling, pulling and straightening: the flat elongation was 0.40%.
The performance indexes of the 1300MPa grade ultrahigh-strength cold-rolled steel sheet for automobiles in the embodiment are shown in Table 2; the microstructure consists of ferrite and martensite, and the martensite is dispersed and distributed on the ferrite matrix in an island shape.
Example 3
The thickness of the 1300MPa grade ultrahigh strength cold rolled steel plate for automobiles in the embodiment is 2.0mm, and the chemical component composition and the mass percentage content are shown in Table 1.
The production method of the 1300 MPa-grade ultrahigh-strength cold-rolled steel sheet for the automobile comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling, pulling and straightening, and comprises the following specific processing steps:
(1) the steel making process comprises molten iron desulphurization and slagging off, converter smelting, L F furnace refining and RH vacuum treatment;
(2) and (3) continuous casting process: controlling the surface and internal quality of the slab in the casting process;
(3) a hot rolling procedure: the heating temperature of the plate blank is 1200 ℃; rough rolling for 3 times, wherein the thickness of the intermediate blank after rough rolling is 40 mm; the inlet temperature of finish rolling is 1100 ℃, the finish rolling temperature is 900 ℃, and the coiling temperature is 620 ℃;
(4) acid rolling process: cold rolling is carried out after acid cleaning, and the cold rolling reduction rate is 45%;
(5) a continuous annealing process: the heat preservation temperature of the soaking section is 800 ℃, and the heat preservation time is 150 s; the heat preservation temperature of the overaging section is 280 ℃, and the heat preservation time of the overaging section is 600 s;
(6) leveling, pulling and straightening: the flat elongation was 0.20%.
The performance indexes of the 1300MPa grade ultrahigh-strength cold-rolled steel sheet for automobiles in the embodiment are shown in Table 2; the microstructure consists of ferrite and martensite, and the martensite is dispersed and distributed on the ferrite matrix in an island shape.
Example 4
The thickness of the 1300MPa grade ultrahigh strength cold rolled steel plate for automobiles in the embodiment is 1.5mm, and the chemical component composition and the mass percentage content are shown in Table 1.
The production method of the 1300 MPa-grade ultrahigh-strength cold-rolled steel sheet for the automobile comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling, pulling and straightening, and comprises the following specific processing steps:
(1) the steel making process comprises molten iron desulphurization and slagging off, converter smelting, L F furnace refining and RH vacuum treatment;
(2) and (3) continuous casting process: controlling the surface and internal quality of the slab in the casting process;
(3) a hot rolling procedure: the heating temperature of the plate blank is 1245 ℃; rough rolling for 5 times, wherein the thickness of the intermediate blank after rough rolling is 34 mm; the inlet temperature of finish rolling is 1040 ℃, the finish rolling temperature is 845 ℃, and the coiling temperature is 650 ℃;
(4) acid rolling process: cold rolling is carried out after acid cleaning, and the cold rolling reduction rate is 50%;
(5) a continuous annealing process: the heat preservation temperature of the soaking section is 780 ℃ and the heat preservation time is 180 s; the heat preservation temperature of the overaging section is 270 ℃, and the heat preservation time of the overaging section is 500 s;
(6) leveling, pulling and straightening: the flat elongation was 0.15%.
The performance indexes of the 1300MPa grade ultrahigh-strength cold-rolled steel sheet for automobiles in the embodiment are shown in Table 2; the microstructure consists of ferrite and martensite, and the martensite is dispersed and distributed on the ferrite matrix in an island shape.
Example 5
The thickness of the 1300MPa grade ultrahigh strength cold rolled steel plate for automobiles in the embodiment is 1.2mm, and the chemical component composition and the mass percentage content are shown in Table 1.
The production method of the 1300 MPa-grade ultrahigh-strength cold-rolled steel sheet for the automobile comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling, pulling and straightening, and comprises the following specific processing steps:
(1) the steel making process comprises molten iron desulphurization and slagging off, converter smelting, L F furnace refining and RH vacuum treatment;
(2) and (3) continuous casting process: controlling the surface and internal quality of the slab in the casting process;
(3) a hot rolling procedure: the heating temperature of the plate blank is 1265 ℃; rough rolling for 5 times, wherein the thickness of the intermediate blank after rough rolling is 32 mm; the inlet temperature of finish rolling is 1055 ℃, the finish rolling temperature is 880 ℃, and the coiling temperature is 600 ℃;
(4) acid rolling process: cold rolling is carried out after acid cleaning, and the cold rolling reduction rate is 60 percent;
(5) a continuous annealing process: the heat preservation temperature of the soaking section is 840 ℃, and the heat preservation time is 60 s; the heat preservation temperature of the overaging section is 320 ℃, and the heat preservation time of the overaging section is 900 s;
(6) leveling, pulling and straightening: the flat elongation was 0.40%.
The performance indexes of the 1300MPa grade ultrahigh-strength cold-rolled steel sheet for automobiles in the embodiment are shown in Table 2; the microstructure consists of ferrite and martensite, and the martensite is dispersed and distributed on the ferrite matrix in an island shape.
Example 6
The thickness of the 1300MPa grade ultrahigh strength cold rolled steel plate for automobiles in the embodiment is 1.3mm, and the chemical component composition and the mass percentage content are shown in Table 1.
The production method of the 1300 MPa-grade ultrahigh-strength cold-rolled steel sheet for the automobile comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling, pulling and straightening, and comprises the following specific processing steps:
(1) the steel making process comprises molten iron desulphurization and slagging off, converter smelting, L F furnace refining and RH vacuum treatment;
(2) and (3) continuous casting process: controlling the surface and internal quality of the slab in the casting process;
(3) a hot rolling procedure: the heating temperature of the plate blank is 1290 ℃; carrying out rough rolling for 7 times, wherein the thickness of the intermediate blank after rough rolling is 28 mm; the inlet temperature of finish rolling is 1020 ℃, the finish rolling temperature is 840 ℃, and the coiling temperature is 560 ℃;
(4) acid rolling process: cold rolling is carried out after acid cleaning, and the cold rolling reduction rate is 65 percent;
(5) a continuous annealing process: the heat preservation temperature of the soaking section is 790 ℃, and the heat preservation time is 170 s; the heat preservation temperature of the overaging section is 300 ℃, and the heat preservation time of the overaging section is 1225 s;
(6) leveling, pulling and straightening: the flat elongation was 0.25%.
The performance indexes of the 1300MPa grade ultrahigh-strength cold-rolled steel sheet for automobiles in the embodiment are shown in Table 2; the microstructure consists of ferrite and martensite, and the martensite is dispersed and distributed on the ferrite matrix in an island shape.
Example 7
The thickness of the 1300MPa grade ultrahigh strength cold rolled steel plate for automobiles in the embodiment is 1.8mm, and the chemical component composition and the mass percentage content are shown in Table 1.
The production method of the 1300 MPa-grade ultrahigh-strength cold-rolled steel sheet for the automobile comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling, pulling and straightening, and comprises the following specific processing steps:
(1) the steel making process comprises molten iron desulphurization and slagging off, converter smelting, L F furnace refining and RH vacuum treatment;
(2) and (3) continuous casting process: controlling the surface and internal quality of the slab in the casting process;
(3) a hot rolling procedure: the heating temperature of the plate blank is 1237 ℃; rough rolling for 3 times, wherein the thickness of the intermediate blank after rough rolling is 30 mm; the inlet temperature of finish rolling is 1072 ℃, the finish rolling temperature is 868 ℃, and the coiling temperature is 635 ℃;
(4) acid rolling process: cold rolling is carried out after acid cleaning, and the cold rolling reduction rate is 48 percent;
(5) a continuous annealing process: the heat preservation temperature of the soaking section is 772 ℃, and the heat preservation time is 85 s; the heat preservation temperature of the overaging section is 261 ℃, and the heat preservation time of the overaging section is 724 s;
(6) leveling, pulling and straightening: the flat elongation was 0.10%.
The performance indexes of the 1300MPa grade ultrahigh-strength cold-rolled steel sheet for automobiles in the embodiment are shown in Table 2; the microstructure consists of ferrite and martensite, and the martensite is dispersed and distributed on the ferrite matrix in an island shape.
Example 8
The thickness of the 1300MPa grade ultrahigh strength cold rolled steel plate for automobiles in the embodiment is 1.4mm, and the chemical component composition and the mass percentage content are shown in Table 1.
The production method of the 1300 MPa-grade ultrahigh-strength cold-rolled steel sheet for the automobile comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling, pulling and straightening, and comprises the following specific processing steps:
(1) the steel making process comprises molten iron desulphurization and slagging off, converter smelting, L F furnace refining and RH vacuum treatment;
(2) and (3) continuous casting process: controlling the surface and internal quality of the slab in the casting process;
(3) a hot rolling procedure: the heating temperature of the plate blank is 1278 ℃; carrying out rough rolling for 7 times, wherein the thickness of the intermediate blank after rough rolling is 36 mm; the inlet temperature of finish rolling is 1086 ℃, the finish rolling temperature is 859 ℃, and the coiling temperature is 572 ℃;
(4) acid rolling process: cold rolling is carried out after acid cleaning, and the cold rolling reduction rate is 57%;
(5) a continuous annealing process: the heat preservation temperature of the soaking section is 815 ℃, and the heat preservation time is 125 s; the heat preservation temperature of the overaging section is 312 ℃, and the heat preservation time of the overaging section is 1138 s;
(6) leveling, pulling and straightening: the flat elongation was 0.32%.
The performance indexes of the 1300MPa grade ultrahigh-strength cold-rolled steel sheet for automobiles in the embodiment are shown in Table 2; the microstructure consists of ferrite and martensite, and the martensite is dispersed and distributed on the ferrite matrix in an island shape.
TABLE 1 chemical composition of ultra high strength cold rolled steel sheet for automobile and examples 1 to 8
Mass percentage content (%)
Figure DEST_PATH_IMAGE002
The balance of the ingredients in table 1 is Fe and other unavoidable impurities.
TABLE 2 Performance index of ultra-high strength cold rolled steel sheet for automobiles of examples 1 to 8
Figure DEST_PATH_IMAGE004
Although the present invention has been described in detail with reference to the above embodiments, it should be understood by those skilled in the art that: modifications and equivalents may be made thereto without departing from the spirit and scope of the invention and it is intended to cover in the claims the invention as defined in the appended claims.

Claims (5)

1. The 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for the automobile is characterized by comprising the following chemical components in percentage by mass: c: 0.21 to 0.3%, Mn: 1.3-2.0%, S is less than or equal to 0.005%, P is less than or equal to 0.02%, Si: 0.2-0.3%, Als is less than or equal to 0.08%, Nb: 0.01-0.03%, Ti: 0.04-0.08%, B: 0.001-0.004%, Mo: 0.22-0.3%, Cr: 0.05-0.10%, V: 0.01-0.02% of Fe and other inevitable impurities as the balance, wherein the yield strength of the steel plate is more than or equal to 850MPa, the tensile strength is more than or equal to 1300MPa, and the elongation A80 is more than or equal to 7%; the ultra-high strength cold rolled steel sheet is produced by the following method: comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling and straightening; in the hot rolling process, the heating temperature of a plate blank is more than or equal to 1200 ℃, the rough rolling is carried out for 3-7 times, the thickness of an intermediate blank after the rough rolling is 28-40 mm, the inlet temperature of the finish rolling is 1020-1100 ℃, the final rolling temperature is 820-900 ℃, and the coiling temperature is 550-650 ℃; in the continuous annealing process, the heat preservation temperature of the soaking section is 760-840 ℃, and the heat preservation time is 60-225 s; the heat preservation temperature of the overaging section is 250-320 ℃, and the heat preservation time of the overaging section is 300-1225 s.
2. The ultra-high strength cold rolled steel sheet for 1300MPa grade automobile according to claim 1, wherein the thickness of the steel sheet is 0.8-2.0 mm, and the microstructure is composed of ferrite and martensite.
3. The production method of the ultra-high strength cold rolled steel sheet for 1300MPa automobile according to claim 1 or 2, wherein the production method comprises the working procedures of steel making, continuous casting, hot rolling, acid rolling, continuous annealing and leveling and straightening; in the hot rolling process, the heating temperature of a plate blank is more than or equal to 1200 ℃, the rough rolling is carried out for 3-7 times, the thickness of an intermediate blank after the rough rolling is 28-40 mm, the inlet temperature of the finish rolling is 1020-1100 ℃, the final rolling temperature is 820-900 ℃, and the coiling temperature is 550-650 ℃; in the continuous annealing process, the heat preservation temperature of the soaking section is 760-840 ℃, and the heat preservation time is 60-225 s; the heat preservation temperature of the overaging section is 250-320 ℃, and the heat preservation time of the overaging section is 300-1225 s.
4. The method for producing the ultra-high strength cold rolled steel sheet for 1300MPa automobile according to claim 3, wherein the acid rolling step is performed after acid pickling, and the cold rolling reduction is not less than 45%.
5. The method for producing the ultra-high strength cold rolled steel sheet for 1300MPa automotive vehicle as claimed in claim 3 or 4, wherein the flattening and straightening process has a flattening elongation of 0.1-0.4%.
CN201811563499.1A 2018-12-20 2018-12-20 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and production method thereof Active CN109628846B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811563499.1A CN109628846B (en) 2018-12-20 2018-12-20 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and production method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811563499.1A CN109628846B (en) 2018-12-20 2018-12-20 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and production method thereof

Publications (2)

Publication Number Publication Date
CN109628846A CN109628846A (en) 2019-04-16
CN109628846B true CN109628846B (en) 2020-08-04

Family

ID=66075890

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811563499.1A Active CN109628846B (en) 2018-12-20 2018-12-20 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and production method thereof

Country Status (1)

Country Link
CN (1) CN109628846B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110129670B (en) * 2019-04-25 2020-12-15 首钢集团有限公司 1300 MPa-grade high-strength high-plasticity steel for hot stamping and preparation method thereof
CN113737087B (en) 2020-05-27 2022-07-19 宝山钢铁股份有限公司 Ultrahigh-strength dual-phase steel and manufacturing method thereof
CN111519109B (en) * 2020-06-09 2021-06-15 首钢集团有限公司 Ultrahigh-strength martensitic steel and preparation method and application thereof
CN111979470A (en) * 2020-08-05 2020-11-24 鞍钢股份有限公司 Production method of ultrahigh-strength cold-rolled martensite steel plate with good bending property
CN112048681B (en) * 2020-09-07 2021-11-16 鞍钢股份有限公司 980 MPa-grade high-formability cold-rolled DH steel and preparation method thereof
CN112795837B (en) * 2020-11-20 2022-07-12 唐山钢铁集团有限责任公司 1300Mpa high-toughness cold-formed steel plate and production method thereof
CN112795849B (en) * 2020-11-20 2022-07-12 唐山钢铁集团有限责任公司 1300Mpa high-toughness hot-dip galvanized steel plate and production method thereof
CN112981252A (en) * 2021-02-06 2021-06-18 邯郸钢铁集团有限责任公司 1500 MPa-grade steel plate for automobile and production method thereof
CN113136528A (en) * 2021-04-23 2021-07-20 唐山全丰薄板有限公司 1500 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and manufacturing method thereof
CN113308649B (en) * 2021-05-14 2022-10-18 唐山钢铁集团有限责任公司 Low-yield-ratio 1000 MPa-grade cold-rolled dual-phase strip steel and production method thereof
CN117305724A (en) * 2022-06-22 2023-12-29 宝山钢铁股份有限公司 High-elongation high-reaming-performance cold-rolled steel plate with more than 1300MPa and manufacturing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101768695A (en) * 2010-01-21 2010-07-07 北京科技大学 Ti microalloyed ultra-fine grained cold rolling dual-phase steel of 1,000MPa level and preparation method thereof
CN105132817A (en) * 2015-09-30 2015-12-09 唐山钢铁集团有限责任公司 1200MPa-grade cold-rolled annealed dual-phase steel and production method thereof
CN106834941A (en) * 2017-01-20 2017-06-13 唐山钢铁集团有限责任公司 A kind of hot press-formed steel and its production method
CN107513669A (en) * 2017-07-20 2017-12-26 首钢集团有限公司 A kind of high-strength cold rolling square and rectangular pipe steel and its manufacture method
CN108642379A (en) * 2018-05-15 2018-10-12 首钢集团有限公司 A kind of tensile strength 1200MPa grades of cold-rolled biphase steels and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5347739B2 (en) * 2009-06-11 2013-11-20 新日鐵住金株式会社 Method for producing precipitation-strengthened double-phase cold-rolled steel sheet
JP5374479B2 (en) * 2010-11-19 2013-12-25 株式会社神戸製鋼所 Manufacturing method of high strength cold-rolled steel sheet with small strength variation
KR101382908B1 (en) * 2014-03-05 2014-04-08 주식회사 포스코 Thin steel sheet having ultra high strength and manufacturing method of the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101768695A (en) * 2010-01-21 2010-07-07 北京科技大学 Ti microalloyed ultra-fine grained cold rolling dual-phase steel of 1,000MPa level and preparation method thereof
CN105132817A (en) * 2015-09-30 2015-12-09 唐山钢铁集团有限责任公司 1200MPa-grade cold-rolled annealed dual-phase steel and production method thereof
CN106834941A (en) * 2017-01-20 2017-06-13 唐山钢铁集团有限责任公司 A kind of hot press-formed steel and its production method
CN107513669A (en) * 2017-07-20 2017-12-26 首钢集团有限公司 A kind of high-strength cold rolling square and rectangular pipe steel and its manufacture method
CN108642379A (en) * 2018-05-15 2018-10-12 首钢集团有限公司 A kind of tensile strength 1200MPa grades of cold-rolled biphase steels and preparation method thereof

Also Published As

Publication number Publication date
CN109628846A (en) 2019-04-16

Similar Documents

Publication Publication Date Title
CN109628846B (en) 1300 MPa-grade ultrahigh-strength cold-rolled steel plate for automobiles and production method thereof
CN103805838B (en) High formability super strength cold-roll steel sheet and manufacture method thereof
CN106319368B (en) A kind of economical thin carrier bar and its manufacture method
EP3260569A1 (en) Steel plate used for hot stamping forming, forming process of hot stamping and hot-stamped component
CN109695006A (en) A kind of corrosion-resistant carrier bar steel and its manufacturing method
CN102912219A (en) High-strength plastic accumulation TRIP (Transformation-Induced Plasticity) steel plate and preparation method thereof
CN104498821B (en) Medium-manganese high-strength steel for automobiles and production method thereof
CN108728751B (en) IF isotropic steel for improving stamping forming and manufacturing method thereof
CN101348883A (en) Niobium and titanium composite added ultra-low carbon baking hardening steel plate and manufacturing method thereof
CN1978689A (en) Low-carbon hot-rolled deep-drawing steel sheet
CN103305762A (en) Cold-rolled dual-phase sheet steel with 400MPa-level tensile strength and preparation method thereof
CN110592348A (en) Ultra-low carbon cold rolled steel performance grading control method
CN111534739A (en) 980 MPa-grade high-formability cold-rolled phase-change induced plasticity steel and preparation method thereof
CN111020367A (en) Cold-rolled high-strength light steel and preparation method thereof
CN110714165B (en) Cold-rolled sheet for 320 MPa-level household appliance panel and production method thereof
CN113151649B (en) Production method of low-temperature annealing cold-rolled steel plate and cold-rolled steel plate
CN109136759A (en) Spoke 1300MPa grades of hot forming steel of think gauge and preparation method
CN111534760B (en) Hot-rolled hot-formed steel and preparation method thereof
CN111411295B (en) Multiphase steel member and preparation method and application thereof
CN109722604B (en) Tin plate for two-piece spray can and manufacturing method thereof
CN107829026B (en) thin-specification 980 MPa-grade dual-phase steel and processing method thereof
CN110273106A (en) A kind of 260MPa grades of cold-rolling continuous annealing glassed steel and its production method
CN109972058A (en) A kind of air-cooled reinforcing steel of automobile cold-rolled low-alloy high-strength and preparation method
CN115478203A (en) Method for producing hot-rolled thin strip steel based on thin strip casting and rolling and ultrahigh-strength part
CN110055466B (en) Preparation method of hot-rolled high-strength medium manganese steel with strength-elongation product of more than 30GPa%

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant