CN109628009A - The cold mounting basement membrane of the super low noise of crystal - Google Patents

The cold mounting basement membrane of the super low noise of crystal Download PDF

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Publication number
CN109628009A
CN109628009A CN201811651765.6A CN201811651765A CN109628009A CN 109628009 A CN109628009 A CN 109628009A CN 201811651765 A CN201811651765 A CN 201811651765A CN 109628009 A CN109628009 A CN 109628009A
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layer
dosage
low noise
basement membrane
information level
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蔡岩胜
蔡扬龙
刘桂华
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Hubei Moral Prestige Packaging Science And Technology Ltd
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Hubei Moral Prestige Packaging Science And Technology Ltd
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Priority to CN201811651765.6A priority Critical patent/CN109628009A/en
Publication of CN109628009A publication Critical patent/CN109628009A/en
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/62Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225Polymers of esters of acrylic or methacrylic acid
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    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
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    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
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    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
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    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
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    • C09J7/00Adhesives in the form of films or foils
    • C09J7/50Adhesives in the form of films or foils characterised by a primer layer between the carrier and the adhesive
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
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    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
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    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
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    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
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    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/10Presence of inorganic materials
    • C09J2400/16Metal
    • C09J2400/163Metal in the substrate
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    • C09J2423/00Presence of polyolefin
    • C09J2423/10Presence of homo or copolymers of propene
    • C09J2423/106Presence of homo or copolymers of propene in the substrate
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2429/00Presence of polyvinyl alcohol
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    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00Presence of polyurethane

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  • Life Sciences & Earth Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention belongs to technical field of membrane, and in particular to a kind of cold mounting basement membrane.The cold mounting basement membrane of the super low noise of crystal, it is characterized by: being made of substratum transparent, aluminium layer, molding Information Level, coating layer, antireflection layer and bidirectional stretching polypropylene film, substratum transparent, aluminium layer, molding Information Level, coating layer, antireflection layer, bidirectional stretching polypropylene film are successively combined into one;The dosage of substratum transparent is 4g/m2, the dosage of aluminium layer is 2-3g/m2, the dosage of coating layer is 3.5-4g/m2, the dosage of antireflection layer is 2-3g/m2, the dosage of the bidirectional stretching polypropylene film is 10-12g/m2;The molding Information Level are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 microns, form molding Information Level.The film has the characteristics that transparent good, low noise.

Description

The cold mounting basement membrane of the super low noise of crystal
Technical field
The invention belongs to technical field of membrane, and in particular to a kind of cold mounting basement membrane.
Background technique
The transparency of existing cold mounting basement membrane is poor.
Summary of the invention
The purpose of the present invention is to provide a kind of cold mounting basement membrane of the super low noise of crystal, which has the characteristics that the transparency is good.
To achieve the goals above, the technical solution used in the present invention is: the cold mounting basement membrane of the super low noise of crystal, feature It is: is made of substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5 and bidirectional stretching polypropylene film 6, Substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5, bidirectional stretching polypropylene film 6 are successively combined into one Body;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 2-3g/m2, the dosage of coating layer 4 is 3.5-4g/m2, antireflection layer 5 dosage is 2-3g/m2, the dosage of the bidirectional stretching polypropylene film 6 is 10-12g/m2
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro- Rice forms molding Information Level.
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 84- 87%, neopelex 2-4%, curing agent 4-6%, polyurethane 2-4%, polyvinyl alcohol 5-8%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 55-58%, silane Coupling agent 2-5%, organic solvent 40-43%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is toluene di-isocyanate(TDI) or methyl diphenylene diisocyanate.
The silane coupling agent is KH550, KH570;The organic solvent is ethyl alcohol or isopropanol.
The preparation of the cold mounting basement membrane of the super low noise of above-mentioned crystal, it includes the following steps:
1) material of one layer of antireflection layer is coated in the upper surface of bidirectional stretching polypropylene film 6, drying obtains antireflection layer 5;? The upper surface of antireflection layer 5 is coated with one layer of gloss oil, forms coating layer 4;
2) metal laser holography version is directly born against on coating layer 4, fringe depths are 3~4 microns, form molding Information Level 3;
3) using equipment of aluminizing, aluminium wire is heated to 1500 DEG C or so melting evaporations, and the condensation that distils, on the information layer 3 One layer of aluminium layer is uniformly steamed, aluminium layer 2 is formed;
4) in the material of the upper surface of aluminium layer 2 coating layer of transparent glue-line, rubberised layer 1 is formed.
The beneficial effects of the present invention are: using substratum transparent and antireflection layer, which has the characteristics that the transparency is good.Due to Polyurethane is used in substratum transparent, which also has the characteristics that low noise (absorbing sound and lowering noise effect is good).
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention.
In figure: 1- substratum transparent, 2- aluminium layer, 3- are molded Information Level, 4- coating layer, 5- antireflection layer, 6- biaxial stretching polypropylene Alkene film.
Specific embodiment
For a better understanding of the present invention, below with reference to the embodiment content that the present invention is furture elucidated, but it is of the invention Content is not limited solely to the following examples.
In following embodiments, the molding Information Level 3 are as follows: control molding temperature (170-190 DEG C), molding pressure (15- 20kg/cm2), using the thermoplastic deformation behavior of coating layer, metal laser holography version, which is directly born against on coating layer, (makes metal laser Candy strip in holographic version is transferred on coating layer, forms molding Information Level).
In following embodiments, the preparation of the cold mounting basement membrane of the super low noise of the crystal, it includes the following steps:
1) material of one layer of antireflection layer is coated in the upper surface of bidirectional stretching polypropylene film 6, drying obtains antireflection layer 5;? The upper surface of antireflection layer 5 is coated with one layer of gloss oil, forms coating layer 4;
2) metal laser holography version is directly born against on coating layer 4, fringe depths are 3~4 microns, form molding Information Level 3;
3) using equipment of aluminizing, aluminium wire is heated to 1500 DEG C or so melting evaporations, and the condensation that distils, on the information layer 3 One layer of aluminium layer is uniformly steamed, aluminium layer 2 is formed;
4) in the material of the upper surface of aluminium layer 2 coating layer of transparent glue-line, rubberised layer 1 is formed.
Embodiment 1:
As shown in Figure 1, the cold mounting basement membrane of the super low noise of crystal, by substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, Antireflection layer 5 and bidirectional stretching polypropylene film 6 form, substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5, Bidirectional stretching polypropylene film 6 is successively combined into one;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 2g/m2, apply The dosage of layer of cloth 4 is 3.5g/m2, the dosage of antireflection layer 5 is 2g/m2, the dosage of the bidirectional stretching polypropylene film 6 is 10g/m2
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro- Rice forms molding Information Level;
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 84%, Neopelex 2%, curing agent 4%, polyurethane 2%, polyvinyl alcohol 8%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 55%, and silane is even Join agent 5%, organic solvent 40%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is toluene di-isocyanate(TDI).
The silane coupling agent is KH550;The organic solvent is ethyl alcohol.
By transparent experiment, the film transparency is good.It is tested by noise, the film absorbing sound and lowering noise effect is good.
Embodiment 2:
As shown in Figure 1, the cold mounting basement membrane of the super low noise of crystal, by substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, Antireflection layer 5 and bidirectional stretching polypropylene film 6 form, substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5, Bidirectional stretching polypropylene film 6 is successively combined into one;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 2.5g/m2, The dosage of coating layer 4 is 3.7g/m2, the dosage of antireflection layer 5 is 2.5g/m2, the dosage of the bidirectional stretching polypropylene film 6 For 11g/m2
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro- Rice forms molding Information Level;
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 85%, Neopelex 3%, curing agent 5%, polyurethane 2%, polyvinyl alcohol 5%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 56%, and silane is even Join agent 3%, organic solvent 41%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is methyl diphenylene diisocyanate.
The silane coupling agent is KH570;The organic solvent is isopropanol.
By transparent experiment, the film transparency is good.It is tested by noise, the film absorbing sound and lowering noise effect is good.
Embodiment 3:
As shown in Figure 1, the cold mounting basement membrane of the super low noise of crystal, by substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, Antireflection layer 5 and bidirectional stretching polypropylene film 6 form, substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5, Bidirectional stretching polypropylene film 6 is successively combined into one;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 3g/m2, apply The dosage of layer of cloth 4 is 4g/m2, the dosage of antireflection layer 5 is 3g/m2, the dosage of the bidirectional stretching polypropylene film 6 is 12g/ m2
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro- Rice forms molding Information Level;
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 87%, Neopelex 2%, curing agent 4%, polyurethane 2%, polyvinyl alcohol 5%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 58%, and silane is even Join agent 2%, organic solvent 40%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is toluene di-isocyanate(TDI).
The silane coupling agent is KH550;The organic solvent is ethyl alcohol.
By transparent experiment, the film transparency is good.It is tested by noise, the film absorbing sound and lowering noise effect is good.
Embodiment 4:
As shown in Figure 1, the cold mounting basement membrane of the super low noise of crystal, by substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, Antireflection layer 5 and bidirectional stretching polypropylene film 6 form, substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5, Bidirectional stretching polypropylene film 6 is successively combined into one;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 2g/m2, apply The dosage of layer of cloth 4 is 3.5g/m2, the dosage of antireflection layer 5 is 2g/m2, the dosage of the bidirectional stretching polypropylene film 6 is 10g/m2
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro- Rice forms molding Information Level;
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 84%, Neopelex 4%, curing agent 4%, polyurethane 3%, polyvinyl alcohol 5%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 55%, and silane is even Join agent 5%, organic solvent 40%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is toluene di-isocyanate(TDI).
The silane coupling agent is KH550;The organic solvent is ethyl alcohol.
By transparent experiment, the film transparency is good.It is tested by noise, the film absorbing sound and lowering noise effect is good.
The bound of each raw material cited by the present invention and each raw material of the present invention, section value, can realize this hair It is bright, embodiment numerous to list herein.

Claims (6)

1. the cold mounting basement membrane of the super low noise of crystal, it is characterised in that: by substratum transparent (1), aluminium layer (2), molding Information Level (3), apply Layer of cloth (4), antireflection layer (5) and bidirectional stretching polypropylene film (6) composition, substratum transparent (1), aluminium layer (2), molding Information Level (3), coating layer (4), antireflection layer (5), bidirectional stretching polypropylene film (6) are successively combined into one;The dosage of substratum transparent (1) For 4g/m2, the dosage of aluminium layer (2) is 2-3g/m2, the dosage of coating layer (4) is 3.5-4g/m2, the dosage of antireflection layer (5) is 2- 3g/m2, the dosage of the bidirectional stretching polypropylene film (6) is 10-12g/m2
The molding Information Level (3) are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro- Rice forms molding Information Level.
2. the cold mounting basement membrane of the super low noise of crystal according to claim 1, it is characterised in that: the material of the substratum transparent (1) Material is according to mass percent meter, including following components: acrylate adhesive 84-87%, neopelex 2-4%, Curing agent 4-6%, polyurethane 2-4%, polyvinyl alcohol 5-8%.
3. the cold mounting basement membrane of the super low noise of crystal according to claim 1, it is characterised in that: the material of the antireflection layer (5) According to mass percent meter, including following components: nano silicon oxide 55-58%, silane coupling agent 2-5%, organic solvent 40- 43%.
4. the cold mounting basement membrane of the super low noise of crystal according to claim 1, it is characterised in that: the material of the aluminium layer (2) For aluminium;The material of the coating layer (4) is gloss oil.
5. the cold mounting basement membrane of the super low noise of crystal according to claim 2, it is characterised in that: the curing agent is that toluene two is different Cyanate or methyl diphenylene diisocyanate.
6. the cold mounting basement membrane of the super low noise of crystal according to claim 3, it is characterised in that: the silane coupling agent is KH550,KH570;The organic solvent is ethyl alcohol or isopropanol.
CN201811651765.6A 2018-12-31 2018-12-31 The cold mounting basement membrane of the super low noise of crystal Pending CN109628009A (en)

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CN1654495A (en) * 2004-02-10 2005-08-17 上海明田纸塑有限公司 Supertransparent self-adhesive latex product and its production method and use
CN201183342Y (en) * 2007-10-23 2009-01-21 姜喜文 Novel spray-drawing medium material with cold lamination film
CN202480509U (en) * 2012-03-14 2012-10-10 常州市展明纸塑复合材料有限公司 Cold laminating film
CN103820051A (en) * 2014-02-27 2014-05-28 山东泰宝防伪技术产品有限公司 Preparation method of digital holographic false-proof adhesive tape
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