CN109628009A - The cold mounting basement membrane of the super low noise of crystal - Google Patents
The cold mounting basement membrane of the super low noise of crystal Download PDFInfo
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- CN109628009A CN109628009A CN201811651765.6A CN201811651765A CN109628009A CN 109628009 A CN109628009 A CN 109628009A CN 201811651765 A CN201811651765 A CN 201811651765A CN 109628009 A CN109628009 A CN 109628009A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/50—Adhesives in the form of films or foils characterised by a primer layer between the carrier and the adhesive
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
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- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
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- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/16—Metal
- C09J2400/163—Metal in the substrate
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J2423/00—Presence of polyolefin
- C09J2423/10—Presence of homo or copolymers of propene
- C09J2423/106—Presence of homo or copolymers of propene in the substrate
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2429/00—Presence of polyvinyl alcohol
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J2475/00—Presence of polyurethane
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Abstract
The invention belongs to technical field of membrane, and in particular to a kind of cold mounting basement membrane.The cold mounting basement membrane of the super low noise of crystal, it is characterized by: being made of substratum transparent, aluminium layer, molding Information Level, coating layer, antireflection layer and bidirectional stretching polypropylene film, substratum transparent, aluminium layer, molding Information Level, coating layer, antireflection layer, bidirectional stretching polypropylene film are successively combined into one;The dosage of substratum transparent is 4g/m2, the dosage of aluminium layer is 2-3g/m2, the dosage of coating layer is 3.5-4g/m2, the dosage of antireflection layer is 2-3g/m2, the dosage of the bidirectional stretching polypropylene film is 10-12g/m2;The molding Information Level are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 microns, form molding Information Level.The film has the characteristics that transparent good, low noise.
Description
Technical field
The invention belongs to technical field of membrane, and in particular to a kind of cold mounting basement membrane.
Background technique
The transparency of existing cold mounting basement membrane is poor.
Summary of the invention
The purpose of the present invention is to provide a kind of cold mounting basement membrane of the super low noise of crystal, which has the characteristics that the transparency is good.
To achieve the goals above, the technical solution used in the present invention is: the cold mounting basement membrane of the super low noise of crystal, feature
It is: is made of substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5 and bidirectional stretching polypropylene film 6,
Substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5, bidirectional stretching polypropylene film 6 are successively combined into one
Body;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 2-3g/m2, the dosage of coating layer 4 is 3.5-4g/m2, antireflection layer
5 dosage is 2-3g/m2, the dosage of the bidirectional stretching polypropylene film 6 is 10-12g/m2;
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro-
Rice forms molding Information Level.
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 84-
87%, neopelex 2-4%, curing agent 4-6%, polyurethane 2-4%, polyvinyl alcohol 5-8%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 55-58%, silane
Coupling agent 2-5%, organic solvent 40-43%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is toluene di-isocyanate(TDI) or methyl diphenylene diisocyanate.
The silane coupling agent is KH550, KH570;The organic solvent is ethyl alcohol or isopropanol.
The preparation of the cold mounting basement membrane of the super low noise of above-mentioned crystal, it includes the following steps:
1) material of one layer of antireflection layer is coated in the upper surface of bidirectional stretching polypropylene film 6, drying obtains antireflection layer 5;?
The upper surface of antireflection layer 5 is coated with one layer of gloss oil, forms coating layer 4;
2) metal laser holography version is directly born against on coating layer 4, fringe depths are 3~4 microns, form molding Information Level
3;
3) using equipment of aluminizing, aluminium wire is heated to 1500 DEG C or so melting evaporations, and the condensation that distils, on the information layer 3
One layer of aluminium layer is uniformly steamed, aluminium layer 2 is formed;
4) in the material of the upper surface of aluminium layer 2 coating layer of transparent glue-line, rubberised layer 1 is formed.
The beneficial effects of the present invention are: using substratum transparent and antireflection layer, which has the characteristics that the transparency is good.Due to
Polyurethane is used in substratum transparent, which also has the characteristics that low noise (absorbing sound and lowering noise effect is good).
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention.
In figure: 1- substratum transparent, 2- aluminium layer, 3- are molded Information Level, 4- coating layer, 5- antireflection layer, 6- biaxial stretching polypropylene
Alkene film.
Specific embodiment
For a better understanding of the present invention, below with reference to the embodiment content that the present invention is furture elucidated, but it is of the invention
Content is not limited solely to the following examples.
In following embodiments, the molding Information Level 3 are as follows: control molding temperature (170-190 DEG C), molding pressure (15-
20kg/cm2), using the thermoplastic deformation behavior of coating layer, metal laser holography version, which is directly born against on coating layer, (makes metal laser
Candy strip in holographic version is transferred on coating layer, forms molding Information Level).
In following embodiments, the preparation of the cold mounting basement membrane of the super low noise of the crystal, it includes the following steps:
1) material of one layer of antireflection layer is coated in the upper surface of bidirectional stretching polypropylene film 6, drying obtains antireflection layer 5;?
The upper surface of antireflection layer 5 is coated with one layer of gloss oil, forms coating layer 4;
2) metal laser holography version is directly born against on coating layer 4, fringe depths are 3~4 microns, form molding Information Level
3;
3) using equipment of aluminizing, aluminium wire is heated to 1500 DEG C or so melting evaporations, and the condensation that distils, on the information layer 3
One layer of aluminium layer is uniformly steamed, aluminium layer 2 is formed;
4) in the material of the upper surface of aluminium layer 2 coating layer of transparent glue-line, rubberised layer 1 is formed.
Embodiment 1:
As shown in Figure 1, the cold mounting basement membrane of the super low noise of crystal, by substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4,
Antireflection layer 5 and bidirectional stretching polypropylene film 6 form, substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5,
Bidirectional stretching polypropylene film 6 is successively combined into one;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 2g/m2, apply
The dosage of layer of cloth 4 is 3.5g/m2, the dosage of antireflection layer 5 is 2g/m2, the dosage of the bidirectional stretching polypropylene film 6 is
10g/m2;
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro-
Rice forms molding Information Level;
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 84%,
Neopelex 2%, curing agent 4%, polyurethane 2%, polyvinyl alcohol 8%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 55%, and silane is even
Join agent 5%, organic solvent 40%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is toluene di-isocyanate(TDI).
The silane coupling agent is KH550;The organic solvent is ethyl alcohol.
By transparent experiment, the film transparency is good.It is tested by noise, the film absorbing sound and lowering noise effect is good.
Embodiment 2:
As shown in Figure 1, the cold mounting basement membrane of the super low noise of crystal, by substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4,
Antireflection layer 5 and bidirectional stretching polypropylene film 6 form, substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5,
Bidirectional stretching polypropylene film 6 is successively combined into one;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 2.5g/m2,
The dosage of coating layer 4 is 3.7g/m2, the dosage of antireflection layer 5 is 2.5g/m2, the dosage of the bidirectional stretching polypropylene film 6
For 11g/m2;
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro-
Rice forms molding Information Level;
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 85%,
Neopelex 3%, curing agent 5%, polyurethane 2%, polyvinyl alcohol 5%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 56%, and silane is even
Join agent 3%, organic solvent 41%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is methyl diphenylene diisocyanate.
The silane coupling agent is KH570;The organic solvent is isopropanol.
By transparent experiment, the film transparency is good.It is tested by noise, the film absorbing sound and lowering noise effect is good.
Embodiment 3:
As shown in Figure 1, the cold mounting basement membrane of the super low noise of crystal, by substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4,
Antireflection layer 5 and bidirectional stretching polypropylene film 6 form, substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5,
Bidirectional stretching polypropylene film 6 is successively combined into one;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 3g/m2, apply
The dosage of layer of cloth 4 is 4g/m2, the dosage of antireflection layer 5 is 3g/m2, the dosage of the bidirectional stretching polypropylene film 6 is 12g/
m2;
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro-
Rice forms molding Information Level;
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 87%,
Neopelex 2%, curing agent 4%, polyurethane 2%, polyvinyl alcohol 5%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 58%, and silane is even
Join agent 2%, organic solvent 40%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is toluene di-isocyanate(TDI).
The silane coupling agent is KH550;The organic solvent is ethyl alcohol.
By transparent experiment, the film transparency is good.It is tested by noise, the film absorbing sound and lowering noise effect is good.
Embodiment 4:
As shown in Figure 1, the cold mounting basement membrane of the super low noise of crystal, by substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4,
Antireflection layer 5 and bidirectional stretching polypropylene film 6 form, substratum transparent 1, aluminium layer 2, molding Information Level 3, coating layer 4, antireflection layer 5,
Bidirectional stretching polypropylene film 6 is successively combined into one;The dosage of substratum transparent 1 is 4g/m2, the dosage of aluminium layer 2 is 2g/m2, apply
The dosage of layer of cloth 4 is 3.5g/m2, the dosage of antireflection layer 5 is 2g/m2, the dosage of the bidirectional stretching polypropylene film 6 is
10g/m2;
The molding Information Level 3 are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro-
Rice forms molding Information Level;
The material of the substratum transparent 1 is according to mass percent meter, including following components: acrylate adhesive 84%,
Neopelex 4%, curing agent 4%, polyurethane 3%, polyvinyl alcohol 5%;
The material of the antireflection layer 5 is according to mass percent meter, including following components: nano silicon oxide 55%, and silane is even
Join agent 5%, organic solvent 40%.
The material of the aluminium layer 2 is aluminium;The material of the coating layer 4 is gloss oil.
The curing agent is toluene di-isocyanate(TDI).
The silane coupling agent is KH550;The organic solvent is ethyl alcohol.
By transparent experiment, the film transparency is good.It is tested by noise, the film absorbing sound and lowering noise effect is good.
The bound of each raw material cited by the present invention and each raw material of the present invention, section value, can realize this hair
It is bright, embodiment numerous to list herein.
Claims (6)
1. the cold mounting basement membrane of the super low noise of crystal, it is characterised in that: by substratum transparent (1), aluminium layer (2), molding Information Level (3), apply
Layer of cloth (4), antireflection layer (5) and bidirectional stretching polypropylene film (6) composition, substratum transparent (1), aluminium layer (2), molding Information Level
(3), coating layer (4), antireflection layer (5), bidirectional stretching polypropylene film (6) are successively combined into one;The dosage of substratum transparent (1)
For 4g/m2, the dosage of aluminium layer (2) is 2-3g/m2, the dosage of coating layer (4) is 3.5-4g/m2, the dosage of antireflection layer (5) is 2-
3g/m2, the dosage of the bidirectional stretching polypropylene film (6) is 10-12g/m2;
The molding Information Level (3) are as follows: directly bear against metal laser holography version on coating layer, fringe depths are 3~4 micro-
Rice forms molding Information Level.
2. the cold mounting basement membrane of the super low noise of crystal according to claim 1, it is characterised in that: the material of the substratum transparent (1)
Material is according to mass percent meter, including following components: acrylate adhesive 84-87%, neopelex 2-4%,
Curing agent 4-6%, polyurethane 2-4%, polyvinyl alcohol 5-8%.
3. the cold mounting basement membrane of the super low noise of crystal according to claim 1, it is characterised in that: the material of the antireflection layer (5)
According to mass percent meter, including following components: nano silicon oxide 55-58%, silane coupling agent 2-5%, organic solvent 40-
43%.
4. the cold mounting basement membrane of the super low noise of crystal according to claim 1, it is characterised in that: the material of the aluminium layer (2)
For aluminium;The material of the coating layer (4) is gloss oil.
5. the cold mounting basement membrane of the super low noise of crystal according to claim 2, it is characterised in that: the curing agent is that toluene two is different
Cyanate or methyl diphenylene diisocyanate.
6. the cold mounting basement membrane of the super low noise of crystal according to claim 3, it is characterised in that: the silane coupling agent is
KH550,KH570;The organic solvent is ethyl alcohol or isopropanol.
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CN108728009A (en) * | 2018-04-28 | 2018-11-02 | 浙江福莱新材料股份有限公司 | A kind of anti-reflection antireflective cold lamination film and preparation method thereof |
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