CN109627825A - A kind of paper tire lacquer painting lacquer and preparation method thereof - Google Patents

A kind of paper tire lacquer painting lacquer and preparation method thereof Download PDF

Info

Publication number
CN109627825A
CN109627825A CN201910019202.3A CN201910019202A CN109627825A CN 109627825 A CN109627825 A CN 109627825A CN 201910019202 A CN201910019202 A CN 201910019202A CN 109627825 A CN109627825 A CN 109627825A
Authority
CN
China
Prior art keywords
lacquer
paper tire
painting
preparation
tung oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201910019202.3A
Other languages
Chinese (zh)
Inventor
孟梅林
孟雨村
盛容
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Polytechnic University
Original Assignee
Anhui Polytechnic University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Polytechnic University filed Critical Anhui Polytechnic University
Priority to CN201910019202.3A priority Critical patent/CN109627825A/en
Publication of CN109627825A publication Critical patent/CN109627825A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/06Artists' paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C09D191/005Drying oils
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Printing Methods (AREA)

Abstract

The invention discloses a kind of paper tire lacquer painting lacquer and preparation method thereof, belong to lacquer painting technical field, using lacquer and ripe pure tung oil as raw material, by the ratio for coordinating the two, and combine ultrasonic treatment mixing, mechanical shearing is carried out to tung oil using the mechanism of ultrasound, promote the degrees of fusion and sophistication of tung oil and lacquer, be conducive to being impregnated on paper tire, the cavitation of ultrasound forms cavitation thermal in tung oil and lacquer mixed liquor, be conducive to the reaction of tung oil and lacquer, promote reaction efficiency, preparation process is simple, configure the lacquer for being applicable in the creation of paper tire lacquer painting, be conducive to the development of paper tire lacquer painting, new research direction is researched and proposed simultaneously for lacquer painting from now on.

Description

A kind of paper tire lacquer painting lacquer and preparation method thereof
Technical field
The present invention relates to lacquer painting technical field, a kind of paper tire lacquer painting lacquer and preparation method thereof is particularly related to.
Background technique
Lacquer is also known as lacquer, is after manually extracting from lacquer tree, the natural products of processed preparation, lacquer is as unique The artistic medium of oriental cultural characteristic has more than 8000 years history, all distributes unique artistic charm, lacquer painting from ancient times to the present Creation be even more to add artistic color for the life of modern.
It is to hand over a kind of common mode at present that lacquer painting is made on mold, and the production method of bodiless lacquer is divided into from ancient times to the present Tread flaking and wooden two kinds of the tire, tread flaking are the molds with soil, gypsum, wooden model etc. for product, and the wooden tire mainly uses nanmu, camphorwood, beech The stonewoods such as wood are base, without tread flaking, are directly painted, process is identical as tread flaking cloth base, the preparation of both bodiless lacquers In method, the requirement to lacquer performance is looser, but the lacquer painting of paper tire is not available then, due at present to paper tire lacquer painting Study less, the requirement of related lacquer is also less, in order to promote the development of paper tire lacquer painting, grinds to the lacquer for being suitable for paper tire lacquer painting Studying carefully is crucial factor.
Summary of the invention
In view of this, it is an object of the invention to propose a kind of paper tire lacquer painting lacquer and preparation method thereof, to fill up existing There is the blank that paper tire lacquer painting lacquer is studied in technology.
Based on a kind of above-mentioned purpose paper tire lacquer painting lacquer provided by the invention, the lacquer includes following mass percent Ingredient: boiled wood oil 25-35%, lacquer 65-75%.
In some optional embodiments, the lacquer includes following mass percent ingredient: boiled wood oil 30%, lacquer 70%.
In some optional embodiments, the lacquer includes following mass percent ingredient: laccol 65-75%, Qi Duo Sugared 5-7%, glycoprotein 2-5%, laccase < 1%, surplus moisture.
In some optional embodiments, the boiled wood oil is ripe pure tung oil.
A kind of preparation method of paper tire lacquer painting lacquer, includes the following steps:
1) it takes boiled wood oil to carry out 300-400 mesh filtering and impurity removing, is then ultrasonically treated 1-5min;
2) it weighs lacquer and divides 3-5 batches to be added in the ripe pure tung oil in step (1), heating stirring 5- after being added every time 10min is ultrasonically treated 35-60min after all adding, obtains finished product.
In some optional embodiments, power ultrasonic in the step (1) is 70-180w, frequency 20-30kHz.
In some optional embodiments, the temperature of heating stirring is 28-43 DEG C in the step (2).
In some optional embodiments, the frequency being ultrasonically treated in the step (2) is 100-200kHz, temperature 17- 28℃。
From the above it can be seen that a kind of paper tire lacquer painting provided by the invention is with lacquer and ripe pure tung oil with lacquer Raw material configures the lacquer for being applicable in the creation of paper tire lacquer painting, is conducive to the development of paper tire lacquer painting, together by coordinating the ratio of the two When new research direction is researched and proposed for lacquer painting from now on.
It is mixed by being simply ultrasonically treated meanwhile the present invention also provides a kind of method for preparing paper tire lacquer painting lacquer It closes, mechanical shearing is carried out to tung oil using the mechanism of ultrasound, promotes the degrees of fusion and sophistication of tung oil and lacquer, favorably In being impregnated on paper tire, ultrasonic cavitation forms cavitation thermal in tung oil and lacquer mixed liquor, is conducive to tung oil With the reaction of lacquer, reaction efficiency is promoted.
Lacquer is modified using tung oil, on the one hand reduce the presence of harmful components laccol in lacquer to human body and It is injured caused by environment, the modification of another aspect tung oil, there is long-chain flexible structure due to being added, have and improve lacquer Flexibility, the conjugated triene structures of tung oil are conducive to the drying of lacquer, the efficiency that the promotion later period is manufactured.
Detailed description of the invention
Fig. 1 is the rice paper pictorial diagram that the embodiment of the present invention uses;
Fig. 2 is the lacquer schematic diagram of allotment of the embodiment of the present invention;
Fig. 3 is mopping of embodiment of the present invention schematic diagram;
Fig. 4 is the rice paper pictorial diagram after mopping of the embodiment of the present invention is dry;
Fig. 5 is tensile test of embodiment of the present invention figure.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, and reference Attached drawing, the present invention is described in more detail.
It discloses a kind of paper tire lacquer painting lacquer in the embodiment of the present invention, include mass percent in lacquer is respectively 25- 35% boiled wood oil and the natural paint ingredients of 65-75%.
In some optional embodiments, a kind of paper tire lacquer painting lacquer in the embodiment of the present invention includes quality hundred in lacquer Divide than being respectively 30% boiled wood oil and 70% natural paint ingredients, wherein the content of main ingredient is laccol 65- in lacquer 75%, urushipolysaccharide 5-7%, glycoprotein 2-5%, laccase < 1%, surplus moisture, boiled wood oil are skillful tung oil.
Component content is one of the factor for determining lacquer performance, and preparation process is to determine another factor of lacquer performance, is Research to the lacquer of paper tire lacquer painting comprehensively, therefore a kind of system of paper tire lacquer painting lacquer is disclosed in the embodiment of the present invention Preparation Method includes the following steps:
1) it takes boiled wood oil to carry out 300-400 mesh filtering and impurity removing, is then ultrasonically treated 1-5min;
2) it weighs lacquer and divides 3-5 batches to be added in the tung oil in step (1), heating stirring 5-10min after being added every time, It is ultrasonically treated 35-60min after all adding, obtains finished product.
In some optional embodiments, a kind of preparation method of paper tire lacquer painting lacquer is disclosed in the embodiment of the present invention, Include the following steps:
1) ripe pure tung oil 3kg is weighed by above-mentioned formula to be placed in barrel, and carry out 400 mesh filtering and impurity removings, it then will removal of impurities Ripe pure tung oil afterwards is 100w in power, handles 3min under the ultrasonic wave that frequency is 25kHz;
2) lacquer 7kg is weighed by above-mentioned formula, and in the ripe pure tung oil in point 5 batches of additions step (1), day is added every time So paint after heating and thermal insulation at 35 DEG C and stirring 8min, lacquer all add after frequency be 180kHz, temperature be 25 DEG C at It is ultrasonically treated 45min, obtains finished product.
In these cases, by changing ripe pure tung oil and the quality accounting of lacquer and respectively react item in preparation process Part studies the obtained lacquer performance of preparation, specific as follows:
1) lacquer of preparation is evenly coated on 07 year " Red Star " board rice paper, and is carried out at a temperature of 50-120 DEG C different Drying, then (test method is shown in Table for measurement drying time (film thickness after dry is at 100 ± 3 μm) and physical mechanical property 1).Test the results are shown in Table 2-3.
1 paint film physical mechanical property test method of table
Project Reference standard Title
Surface drying time GB/T1728-1979 Second method in paint film drying time measuring method
Surface gloss GB/T1743-1979 Gloss of film degree measuring method
Pencil hardness GB/T6739-2006 Pencil method measures hardness of paint film
Flexibility GB/T1731-1993 Paint film suppleness measuring method
Impact resistance GB/T1732-1993 Paint film impact resistance measuring method
2 paint film physical mechanical property test result of table
Project Surface drying time/min Pencil hardness Flexibility/mm Impact resistance/cm Surface gloss
Lacquer 175 5H 10 30 70
Lacquer 50 3H 4 55 88
Modified lacquer physical mechanical property performance is more excellent than lacquer, the hardness decline of modified lacquer, flexible The raising of property and impact resistance is the addition due to the boiled wood oil with long-chain flexible structure, destroy in lacquer laccol by In the inierpeneirating network structure that unsaturated terminal chain is formed in the autoxidation cross-linked polymeric stage.
Paint film physical mechanical property test result under the different drying temperature states of table 3
The surface drying time of paint film is very long, be due to laccase is a kind of more copper proteins, when drying temperature is more than 60 DEG C, Laccase protein matter can gradually by thermocoagulation and lose activity, meanwhile, the O being dissolved in water2As the raising of temperature and drop Low solubility, and then cause enzymatic film forming speed slack-off.From the entire performance of the aggregation of data of table 3, drying temperature at 80-90 DEG C most It is good.
2) it uses different paint uniformly to brush in dimensions as on 07 year " Red Star " board rice paper of 200 × 20mm, brushes Amount of paint is identical, brush it is smooth after, be dried using 80 DEG C of temperature, then carry out tensile test, every group measurement 3 times, take Average value.Measurement result is shown in Table 4, and experimentation is as shown in Fig. 1-5.
4 different component tension measurement result of table
The data of table 4 show that the tensile fracture of pure rice paper is 0.89kg, and when brushing upper lacquer, tensile fracture is 3.97kg is 4.4 times of pure rice paper intensity, and when painting the lacquer of different content component, tensile fracture is still better than pure rice paper, And the tensile fracture of number 3 and 4 is higher than the tensile fracture of number 2, test result is consistent with the test data flexibility of table 2, To illustrate that the combination of rice paper and lacquer can increase the intensity of rice paper, be conducive to the preservation of paper tire lacquer painting, while the paint prepared The flexibility of film promotes paper tire lacquer painting in the operability of preparation process, as lacquer 65%-75%+ boiled wood oil 25%-35% The lacquer overall performance of preparation is more excellent.
In the case using lacquer and ripe pure tung oil as raw material, by coordinating the ratio of the two, applicable paper tire is configured The lacquer of lacquer painting creation is conducive to the development of paper tire lacquer painting, while researching and proposing new research direction for lacquer painting from now on.
Meanwhile by being simply ultrasonically treated mixing, mechanical shearing is carried out to tung oil using the mechanism of ultrasound, is promoted The degrees of fusion and sophistication of tung oil and lacquer are conducive to being impregnated on paper tire, and ultrasonic cavitation is in tung oil and naturally It paints and forms cavitation thermal in mixed liquor, be conducive to the reaction of tung oil and lacquer, promote reaction efficiency, preparation process is simple.
Lacquer is modified using tung oil, on the one hand reduce the presence of harmful components laccol in lacquer to human body and It is injured caused by environment, the modification of another aspect tung oil, there is long-chain flexible structure due to being added, have and improve lacquer Flexibility, the conjugated triene structures of tung oil are conducive to the drying of lacquer, the efficiency that the promotion later period is manufactured.For paper tire paint The preparation cost of picture is low, and molding is fast, is conducive to industrialization large-scale production.
It should be understood by those ordinary skilled in the art that: the discussion of any of the above embodiment is exemplary only, not It is intended to imply that the scope of the present disclosure (including claim) is limited to these examples;Under thinking of the invention, above embodiments Or can also be combined between the technical characteristic in different embodiments, step can be realized with random order, and be existed such as Many other variations of the upper different aspect of the invention, for simplicity, they are not provided in details.
The embodiment of the present invention be intended to cover fall into all such replacements within the broad range of appended claims, Modifications and variations.Therefore, all within the spirits and principles of the present invention, any omission, modification, equivalent replacement, the improvement made Deng should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of paper tire lacquer painting lacquer, which is characterized in that the lacquer includes following mass percent ingredient: boiled wood oil 25- 35%, lacquer 65-75%.
2. paper tire lacquer painting lacquer according to claim 1, which is characterized in that the lacquer include following mass percent at Point: boiled wood oil 30%, lacquer 70%.
3. paper tire lacquer painting lacquer according to claim 1, which is characterized in that the lacquer includes following quality percentage Than ingredient: laccol 65-75%, urushipolysaccharide 5-7%, glycoprotein 2-5%, laccase < 1%, surplus moisture.
4. paper tire lacquer painting lacquer according to claim 1, which is characterized in that the boiled wood oil is ripe pure tung oil.
5. a kind of preparation method of paper tire lacquer painting lacquer, which comprises the steps of:
1) it takes boiled wood oil to carry out 300-400 mesh filtering and impurity removing, is then ultrasonically treated 1-5min;
2) it weighs lacquer and divides 3-5 batches to be added in the ripe pure tung oil in step (1), heating stirring 5-10min after being added every time, It is ultrasonically treated 35-60min after all adding, obtains finished product.
6. the preparation method of paper tire lacquer painting lacquer according to claim 1, which is characterized in that surpass in the step (1) The power of sound is 70-180w, frequency 20-30kHz.
7. the preparation method of paper tire lacquer painting lacquer according to claim 1, which is characterized in that add in the step (2) The temperature of thermal agitation is 28-43 DEG C.
8. the preparation method of paper tire lacquer painting lacquer according to claim 1, which is characterized in that surpass in the step (2) The frequency of sonication is 100-200kHz, and temperature is 17-28 DEG C.
CN201910019202.3A 2019-01-09 2019-01-09 A kind of paper tire lacquer painting lacquer and preparation method thereof Withdrawn CN109627825A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910019202.3A CN109627825A (en) 2019-01-09 2019-01-09 A kind of paper tire lacquer painting lacquer and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910019202.3A CN109627825A (en) 2019-01-09 2019-01-09 A kind of paper tire lacquer painting lacquer and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109627825A true CN109627825A (en) 2019-04-16

Family

ID=66061587

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910019202.3A Withdrawn CN109627825A (en) 2019-01-09 2019-01-09 A kind of paper tire lacquer painting lacquer and preparation method thereof

Country Status (1)

Country Link
CN (1) CN109627825A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108129989A (en) * 2017-12-25 2018-06-08 中山市得高行知识产权中心(有限合伙) A kind of colour wear resistant raw lacquer coating and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108129989A (en) * 2017-12-25 2018-06-08 中山市得高行知识产权中心(有限合伙) A kind of colour wear resistant raw lacquer coating and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
段久芳: "《天然高分子材料》", 30 September 2016, 华中科技大学出版社 *
雷骏志等: "《大漆涂装技术》", 31 August 1988, 北京航空学院出版社 *

Similar Documents

Publication Publication Date Title
CN104589438B (en) A kind of antique-imitation method of jujube wood
CN101049791A (en) Method for fabricating wheat stalk picture
CN101767510A (en) Production process of antique engraving wood
CN101892331A (en) Method for performing antique treatment on leather surface
CN104372611A (en) Preparation process for imitating ancient silk painting antique
CN105111827B (en) A kind of preparation method of rainbow silver paste
CN109627825A (en) A kind of paper tire lacquer painting lacquer and preparation method thereof
CN103621918A (en) Production process of salted and fermented soya paste
CN106182264B (en) A kind of jujube wood does aging method
CN101791928A (en) Method for processing simulated wood grains on product surface
CN105127434A (en) Preparing method of mirror-like silver paste
KR20090125342A (en) Manufacturing method of functional grain
CN108669218A (en) A kind of drying means of control banana chip browning rate
CN107030848A (en) A kind of preparation method of environment protecting fiber board fungus resistant coating
CN102150802A (en) Areca nut flavoring agent and preparation method thereof
CN101402217B (en) Process for producing furniture
KR101461359B1 (en) Sugarcraft work manufacturing method using royal icing
CN102173273B (en) Flour picture and manufacturing method thereof
CN104480238A (en) Antique treatment method for surface of leather
CN107384203A (en) A kind of processing method of colored raw lacquer
CN108891188B (en) Corn leaf picture and its making method
CN114058743B (en) Preparation process of simulated crocodile skin
CN1709991A (en) Wood-grain-imitating water-based coating and its production process
CN100528604C (en) Production method of sand and stone solid artistic drawing
CN105034105A (en) Populus bark picture processing treatment liquid

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20190416