CN109627609A - One kind superconducting EPT rubber packing item - Google Patents
One kind superconducting EPT rubber packing item Download PDFInfo
- Publication number
- CN109627609A CN109627609A CN201811611389.8A CN201811611389A CN109627609A CN 109627609 A CN109627609 A CN 109627609A CN 201811611389 A CN201811611389 A CN 201811611389A CN 109627609 A CN109627609 A CN 109627609A
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- Prior art keywords
- parts
- agent
- rubber packing
- ept rubber
- packing item
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to one kind to superconduct EPT rubber packing item, raw material including following mass fraction: EPDM raw rubber is 100 parts, and reinforcing agent carbon black N550 is 80-160 parts, conductive black is 6-16 parts, plasticizer is 30-100 parts, homogenizing agent is 3-8 parts, zinc oxide is 5-10 parts, stearic acid is 2-6 parts, surfactant is 1-5 parts, hygroscopic agent is 8-12 parts, vulcanizing agent is 1-2 parts, promotor is 3-6 parts.The present invention only need to add a small amount of conductive filler using the EPDM rubber of low cost as carrier, have oxidative resistance, the advantages that ozone-resistant and anti-erosion, while electric conductivity is very good, can be applied to communication terminal, notebook computer, digital audiovisual and communication equipment etc., to meet middle- and high-end applications.
Description
Technical field
The present invention relates to electromangnetic spectrum fields, and in particular to one kind superconducts EPT rubber packing item.
Background technique
In recent years, with science and technology and electronics industry high speed development, it is various digitlization, high frequency electronic apparatus set
The standby electromagnetic wave for having radiated a large amount of different wave lengths and frequency to space at work, so as to cause new environmental pollution-electromagnetism
Wave interference and radiofrequency interference.The electromagnetic interference that electromagnetic radiation generates not only influences the performance realization of electronic product, but also
Caused electromagnetic pollution can cause serious harm to the mankind and other organisms therefrom.To solve caused by electromagenetic wave radiation
Interference and leakage, mainly shielded using electromagnetic shielding material, realize electronic and electrical equipment mutually reconciled with environment, Xiang Gongcun
Electromagnetic compatible environment.
Currently, conductive rubber in the market, high score base-material mainly uses silicon-based rubber material, although silicon-based rubber material
Material has good electric property, weatherability and high-low temperature resistant stability etc., but their current prices are higher, especially have
The silicon rubber of property, price are higher.
There are also the conductive rubbers of some ethylene propylene diene rubber matrixes production, due to adding a large amount of conductive filler (metal powder
The accountings such as end are 70% or more), processing performance is had a greatly reduced quality, and can only be made some molded products, is not able to satisfy extrusion molding
The demand of product.
Summary of the invention
The purpose of the present invention is to overcome the above shortcomings and to provide one kind to superconduct EPT rubber packing item, with low
The EPDM rubber of cost is carrier, only need to add a small amount of conductive filler, has oxidative resistance, ozone-resistant and anti-erosion etc. are excellent
Point, while electric conductivity is very good, can be applied to communication terminal, notebook computer, digital audiovisual and communication equipment etc., with
Meet middle- and high-end applications.
The object of the present invention is achieved like this:
One kind superconducting EPT rubber packing item, the raw material including following mass fraction: EPDM raw rubber is 100 parts, is mended
Strong agent carbon black N550 is 80-160 parts, conductive black is 6-16 parts, plasticizer is 30-100 parts, homogenizing agent is 3-8 parts, zinc oxide
For 5-10 parts, stearic acid be 2-6 parts, surfactant is 1-5 parts, hygroscopic agent is 8-12 parts, vulcanizing agent is 1-2 parts, promotor
It is 3-6 parts.
Preferably, the ratio between mass parts of the conductive black, plasticizer, homogenizing agent are 2:10-18:1.
Preferably, the vulcanizing agent uses sulfur cross-linking system.
Preferably, the plasticizer is paraffin oil, DOP or tri- kinds of DOS mixing.
Preferably, the promotor is tri- kinds of TMTD, DTDM and CZ mixing.
The beneficial effects of the present invention are:
The present invention only need to add a small amount of conductive filler using the EPDM rubber of low cost as carrier, have oxidative resistance, ozone-resistant
And the advantages that anti-erosion, while electric conductivity is very good, can be applied to communication terminal, notebook computer, digital audiovisual and
Communication equipment etc., to meet middle- and high-end applications.
Specific embodiment
Embodiment 1:
One kind superconducting EPT rubber packing item, the raw material including following mass fraction: EPDM raw rubber is 100 parts, is mended
Strong agent carbon black N550 is 120 parts, conductive black is 10 parts, paraffin oil is 30 parts, DOP is 30 parts, DOS is 30 parts, homogenizing agent 5
Part, zinc oxide are 8 parts, stearic acid is 4 parts, Surfactant PEG -4000 is 5 parts, hygroscopic agent is 10 parts, sulphur powder 1.5
Part, TMTD are 2 parts, DTDM is 1.5 parts, CZ is 1.5 parts.
Embodiment 2:
One kind superconducting EPT rubber packing item, the raw material including following mass fraction: EPDM raw rubber is 100 parts, is mended
Strong agent carbon black N550 is 80 parts, conductive black is 6 parts, paraffin oil is 10 parts, DOP is 10 parts, DOS is 10 parts, homogenizing agent 3
Part, zinc oxide be 5 parts, stearic acid is 2 parts, Surfactant PEG -4000 is 3 parts, hygroscopic agent is 8 parts, sulphur powder is 2 parts,
TMTD is 3 parts, DTDM is 1.5 parts, CZ is 1.5 parts.
Embodiment 3:
One kind superconducting EPT rubber packing item, the raw material including following mass fraction: EPDM raw rubber is 100 parts, is mended
Strong agent carbon black N550 is 160 parts, conductive black is 16 parts, paraffin oil is 40 parts, DOP is 30 parts, DOS is 30 parts, homogenizing agent 8
Part, zinc oxide be 10 parts, stearic acid is 6 parts, Surfactant PEG -4000 is 1 part, hygroscopic agent is 12 parts, sulphur powder is 1 part,
TMTD is 2 parts, DTDM is 0.5 part, CZ is 0.5 part.
Comparative example 1:
It is same as Example 1, in addition to being added without conductive black.
Comparative example 2:
It is same as Example 1, the conductive black in addition to 10 parts of mass parts of conductive black to be substituted for 5 parts.
Comparative example 3:
It is same as Example 1, in addition to be 30 parts by the paraffin oil of mass parts, DOP is 30 parts, DOS is 30 parts and is substituted for mass parts
For 90 parts of paraffin oil.
Comparative example: 4:
It is same as Example 1, in addition to be 30 parts by the paraffin oil of mass parts, DOP is 30 parts, DOS is 30 parts and is substituted for mass parts
For 90 parts of DOP.
Comparative example 5:
It is same as Example 1, in addition to be 30 parts by the paraffin oil of mass parts, DOP is 30 parts, DOS is 30 parts and is substituted for mass parts
For 90 parts of DOS.
Comparative example 6:
It is same as Example 1, in addition to being added without homogenizing agent.
By embodiment 1-3 compared with comparative example 1-6 carries out performance, it see the table below:
It can be seen that the addition of the conductive black is very huge for the electric conductivity influence of product, DOP and DOS are in EPDM body
After routinely adding in system, poor processability can be caused, poor compatibility, and Plasticising system and conductive black, homogenizing agent it is reasonable
After cooperation, leads to the appearance for not causing conventional variation situation after adding, ensure that conductive EPDM excellent processability.
In addition to the implementation, all to use equivalent transformation or equivalent replacement the invention also includes there is an other embodiments
The technical solution that mode is formed should all be fallen within the scope of the hereto appended claims.
Claims (5)
1. one kind superconducts EPT rubber packing item, it is characterised in that: the raw material including following mass fraction: EPDM is raw
Glue is 100 parts, and reinforcing agent carbon black N550 is 80-160 parts, conductive black is 6-16 parts, plasticizer is 30-100 parts, homogenizing agent is
3-8 parts, zinc oxide be 5-10 parts, stearic acid is 2-6 parts, surfactant is 1-5 parts, hygroscopic agent is 8-12 parts, vulcanizing agent is
1-2 parts, promotor be 3-6 parts.
2. one kind according to claim 1 superconducts EPT rubber packing item, it is characterised in that: the conduction charcoal
The ratio between mass parts of black, plasticizer, homogenizing agent are 2:10-18:1.
3. one kind according to claim 1 superconducts EPT rubber packing item, it is characterised in that: the vulcanizing agent is adopted
With sulfur cross-linking system.
4. one kind according to claim 1 superconducts EPT rubber packing item, it is characterised in that: the plasticizer is
Paraffin oil, DOP or tri- kinds of DOS mixing.
5. one kind according to claim 1 superconducts EPT rubber packing item, it is characterised in that: the promotor is
Tri- kinds of TMTD, DTDM and CZ mixing.
Priority Applications (1)
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CN201811611389.8A CN109627609A (en) | 2018-12-27 | 2018-12-27 | One kind superconducting EPT rubber packing item |
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CN201811611389.8A CN109627609A (en) | 2018-12-27 | 2018-12-27 | One kind superconducting EPT rubber packing item |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110204837A (en) * | 2019-06-17 | 2019-09-06 | 昆山依森琳川密封科技有限公司 | Gas diaphragm pump diaphragm seal cushion material and its diaphragm seal pad manufacturing process |
CN112063335A (en) * | 2020-08-03 | 2020-12-11 | 深圳市飞荣达科技股份有限公司 | Dustproof plug with shielding function and preparation method thereof |
CN112831188A (en) * | 2021-01-25 | 2021-05-25 | 安徽欣鼎高分子材料有限公司 | Rubber composition with conductivity and preparation method thereof |
CN113417555A (en) * | 2021-07-01 | 2021-09-21 | 上海荣南科技股份有限公司 | Automobile anti-pinch strip and preparation process thereof |
BE1028176B1 (en) * | 2020-04-01 | 2021-11-04 | Van De Wiele Rubber N V | PROCEDURE FOR MANUFACTURING AN ELECTRICALLY CONDUCTIVE RUBBER |
CN115746463A (en) * | 2022-10-10 | 2023-03-07 | 河北新华联汽车零部件有限公司 | Sealing strip material and preparation method thereof |
CN115926329A (en) * | 2022-12-12 | 2023-04-07 | 河南平高电气股份有限公司 | Ethylene propylene diene monomer rubber-based electromagnetic shielding sealing material and preparation method thereof |
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CN106700274A (en) * | 2015-08-04 | 2017-05-24 | 太仓冠联高分子材料有限公司 | Rubber for sealing strip of automobile and preparation method of rubber |
CN107868348A (en) * | 2017-12-03 | 2018-04-03 | 深圳市罗庚电气有限公司 | A kind of high flame resistance conduction ethylene propylene diene rubber and preparation method thereof |
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2018
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CN106700274A (en) * | 2015-08-04 | 2017-05-24 | 太仓冠联高分子材料有限公司 | Rubber for sealing strip of automobile and preparation method of rubber |
CN107868348A (en) * | 2017-12-03 | 2018-04-03 | 深圳市罗庚电气有限公司 | A kind of high flame resistance conduction ethylene propylene diene rubber and preparation method thereof |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110204837A (en) * | 2019-06-17 | 2019-09-06 | 昆山依森琳川密封科技有限公司 | Gas diaphragm pump diaphragm seal cushion material and its diaphragm seal pad manufacturing process |
BE1028176B1 (en) * | 2020-04-01 | 2021-11-04 | Van De Wiele Rubber N V | PROCEDURE FOR MANUFACTURING AN ELECTRICALLY CONDUCTIVE RUBBER |
CN112063335A (en) * | 2020-08-03 | 2020-12-11 | 深圳市飞荣达科技股份有限公司 | Dustproof plug with shielding function and preparation method thereof |
CN112831188A (en) * | 2021-01-25 | 2021-05-25 | 安徽欣鼎高分子材料有限公司 | Rubber composition with conductivity and preparation method thereof |
CN113417555A (en) * | 2021-07-01 | 2021-09-21 | 上海荣南科技股份有限公司 | Automobile anti-pinch strip and preparation process thereof |
CN115746463A (en) * | 2022-10-10 | 2023-03-07 | 河北新华联汽车零部件有限公司 | Sealing strip material and preparation method thereof |
CN115926329A (en) * | 2022-12-12 | 2023-04-07 | 河南平高电气股份有限公司 | Ethylene propylene diene monomer rubber-based electromagnetic shielding sealing material and preparation method thereof |
CN115926329B (en) * | 2022-12-12 | 2024-07-05 | 河南平高电气股份有限公司 | Ethylene propylene diene monomer-based electromagnetic shielding sealing material and preparation method thereof |
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