CN109626837A - The manufacturing process of marble glass - Google Patents

The manufacturing process of marble glass Download PDF

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Publication number
CN109626837A
CN109626837A CN201910117885.6A CN201910117885A CN109626837A CN 109626837 A CN109626837 A CN 109626837A CN 201910117885 A CN201910117885 A CN 201910117885A CN 109626837 A CN109626837 A CN 109626837A
Authority
CN
China
Prior art keywords
glass
marble
manufacturing process
glaze
tempering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910117885.6A
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Chinese (zh)
Inventor
叶俊森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Building Energy Saving Glass (guizhou) Co Ltd
Original Assignee
Building Energy Saving Glass (guizhou) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Building Energy Saving Glass (guizhou) Co Ltd filed Critical Building Energy Saving Glass (guizhou) Co Ltd
Priority to CN201910117885.6A priority Critical patent/CN109626837A/en
Publication of CN109626837A publication Critical patent/CN109626837A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/02Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/04Tempering or quenching glass products using gas
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • C03C2218/119Deposition methods from solutions or suspensions by printing
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/30Aspects of methods for coating glass not covered above
    • C03C2218/32After-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Finishing Walls (AREA)

Abstract

The invention discloses a kind of manufacturing process of marble glass, the technology that the manufacturing process of the marble glass passes through digital printing, nanometer glass crystalline inorganic glaze spray printing to glass surface is formed into marble grain, then nanometer glass crystalline inorganic glaze is made to combine together with glass by high temperature sintering, glaze sintering is completed at the same time with glass tempering.The manufacturing process of marble glass proposed by the present invention, it is intended to solve existing marble glass need surface resin coating, difference of hardness not scratch-resistant, pattern can not combine together with glass, the technical problem of weatherability difference.

Description

The manufacturing process of marble glass
Technical field
The present invention relates to glassmaking art more particularly to a kind of manufacturing process of marble glass.
Background technique
Marble has beautiful color, decorative pattern, there is higher compression strength and good physical and chemical performance, resource distribution Extensively, easy to process, with the development of economy, marble application range constantly expands, and dosage is increasing, in people's lives It plays an important role.
But marble is a kind of non-renewable raw material, and exploitation excessively will lead to the destruction of ecological environment, therefore, and Dali The processing technologys such as the raw material of stone is exploited, cutting is polished are more complex, and processing cost is high;With the development of science and technology, being attempted to develop Marble glass increases decorative effect, but the marble glass of the prior art is to allow glass surface also to form marble pattern It is usually all made of by way of UV printing or silk-screen printing, this mode is complicated for operation, low output, manufactured marble A series of problems, such as glass meeting colored is not single, corrosion-resistant, and texture is easy to fall off.
Summary of the invention
The main object of the present invention is to provide a kind of manufacturing process of marble glass, it is intended to solve existing marble glass Need surface resin coating, difference of hardness not scratch-resistant, pattern can not combine together with glass, the technical problem of weatherability difference.
To achieve the above object, marble glass proposed by the present invention manufacturing process the following steps are included:
(1) it chooses image: choosing natural marble plate, carry out stereoscan with multi-angle high definition scanning machine, formed big Fibrous gypsum texture picture file;
(2) image procossing: required for being compiled the marble grain in the picture file using image processing software Lines;
(3) prepare substrate: being processed into the glass baseplate of required specification and external form as required with float glass, cleaning is dry It is net spare;
(4) picture file handled well in step (2) digital printing: is input to ink-jet printer, the inkjet printing The nanometer glass crystalline inorganic glaze that machine is selected in the glass substrate surface spray printing forms corresponding Dali in picture file Stone pattern reason;
(5) it dries: the stone pattern glass printed at the uniform velocity being walked into the dryer that excess temperature is 153 DEG C, makes spray printing in the glass The nanometer glass crystalline inorganic glaze moisture of glass substrate surface evaporates, and the pattern fixation that glaze is formed is not flowed.
(6) tempering: the glass after drying and processing is sent to through dedicated temperature curve annealing furnace steel, the work of annealing furnace first segment First nanometer glass crystalline inorganic glaze is melted, glass is heated into melting state, melted at this time by the second segment working time The inorganic glaze of glass crystal and the glass baseplate of melting merge integrally, and control system, which is started to work, is delivered to temperature descending section for glass Start the work of third period, control wind pressure cools down and is kept fixed the time, and glaze combines together with glass after cooling, surface glass Change, forms marble glass.
Preferably, in step (5), drying is to dry the glass baseplate after digital printing in the case where temperature is 153 DEG C of environment 10 minutes.
Preferably, the temperature in step (6) when tempering is 680 DEG C -730 DEG C.
Preferably, 4-10 minutes a length of when heating in step (6) when tempering, it is 3-8 minutes a length of when then cooling down.
It preferably, further include choosing other patterns other than marble grain as picture file in step (1).
It preferably, include that tempering when glass tempering is shaped to flat tempered glass or semi-tempered glass or curved in step (6) Tempered glass.
Preferably, the manufacturing process of the marble glass further includes step (7) processing: by Dali manufactured after tempering Stone glass and PVB obtain SGP or EVA and are combined into laminated glass, or hollow big by being combined into structure glue, sealant, aluminum strip Marble-type glass.
The manufacturing process of marble glass proposed by the present invention compared with prior art, will by the technology of digital printing Nanometer glass crystalline inorganic glaze spray printing forms marble grain to glass surface, then makes nanoscale glass by high temperature sintering Glass crystalline inorganic glaze combines together with glass, and glaze sintering is completed at the same time with glass tempering;Such marble glass color It is abundant, wear-resisting, sun-proof, corrosion-resistant, with extensive.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with The structure shown according to these attached drawings obtains other attached drawings.
Fig. 1 is the manufacturing process flow diagram of marble glass of the present invention.
The embodiments will be further described with reference to the accompanying drawings for the realization, the function and the advantages of the object of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiment is only a part of the embodiments of the present invention, instead of all the embodiments.Base Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts it is all its His embodiment, shall fall within the protection scope of the present invention.
It is to be appreciated that the directional instruction (such as up, down, left, right, before and after ...) of institute is only used in the embodiment of the present invention In explaining in relative positional relationship, the motion conditions etc. under a certain particular pose (as shown in the picture) between each component, if should When particular pose changes, then directionality instruction also correspondingly changes correspondingly.
In addition, the description for being such as related to " first ", " second " in the present invention is used for description purposes only, and should not be understood as Its relative importance of indication or suggestion or the quantity for implicitly indicating indicated technical characteristic.Define as a result, " first ", The feature of " second " can explicitly or implicitly include at least one of the features.In the description of the present invention, " multiple " contain Justice is at least two, such as two, three etc., unless otherwise specifically defined.
In the present invention unless specifically defined or limited otherwise, term " connection ", " fixation " etc. shall be understood in a broad sense, For example, " fixation " may be a fixed connection, it may be a detachable connection, or integral;It can be mechanical connection, be also possible to Electrical connection;It can be directly connected, the connection inside two elements or two can also be can be indirectly connected through an intermediary The interaction relationship of a element, unless otherwise restricted clearly.It for the ordinary skill in the art, can basis Concrete condition understands the concrete meaning of above-mentioned term in the present invention.
It in addition, the technical solution between each embodiment of the present invention can be combined with each other, but must be general with this field Based on logical technical staff can be realized, it will be understood that when the combination of technical solution appearance is conflicting or cannot achieve this The combination of technical solution is not present, also not the present invention claims protection scope within.
The present invention proposes a kind of manufacturing process of marble glass.
Referring to Fig. 1, in embodiments of the present invention, the manufacturing process of the marble glass the following steps are included:
(1) it chooses image: choosing natural marble plate, carry out stereoscan with multi-angle high definition scanning machine, formed big Fibrous gypsum texture picture file;
(2) image procossing: required for being compiled the marble grain in the picture file using image processing software Lines;
(3) prepare substrate: being processed into the glass baseplate of required specification and external form as required with float glass, cleaning is dry It is net spare;
(4) picture file handled well in step (2) digital printing: is input to ink-jet printer, the inkjet printing The nanometer glass crystalline inorganic glaze that machine is selected in the glass substrate surface spray printing forms corresponding Dali in picture file Stone pattern reason;
(5) it dries: the stone pattern glass printed at the uniform velocity being walked into the dryer that excess temperature is 153 DEG C, makes spray printing in the glass The nanometer glass crystalline inorganic glaze moisture of glass substrate surface evaporates, and the pattern fixation that glaze is formed is not flowed.
(6) tempering: the glass after drying and processing is sent to through dedicated temperature curve annealing furnace steel, the work of annealing furnace first segment First nanometer glass crystalline inorganic glaze is melted, glass is heated into melting state, melted at this time by the second segment working time The inorganic glaze of glass crystal and the glass baseplate of melting merge integrally, and control system, which is started to work, is delivered to temperature descending section for glass Start the work of third period, control wind pressure cools down and is kept fixed the time, and glaze combines together with glass after cooling, surface glass Change, forms marble glass.
The manufacturing process of marble glass proposed by the present invention compared with prior art, will by the technology of digital printing Nanometer glass crystalline inorganic glaze spray printing forms marble grain to glass surface, then makes nanoscale glass by high temperature sintering Glass crystalline inorganic glaze combines together with glass, and glaze sintering is completed at the same time with glass tempering;Such marble glass color It is abundant, wear-resisting, sun-proof, corrosion-resistant, with extensive.
Specifically, in the present embodiment, by after nanometer glass crystalline inorganic glaze spray printing to glass surface, it is micro- that 40 are formed The thick glaze layer of rice;Then by dryer, 10 points are dried to nanometer glass crystalline inorganic glaze in the case where 153 DEG C Clock, 40 microns of thick glaze layers can be down to 12 microns.
Further, the glass after drying is sent to annealing furnace tempering and is formed.When tempering, the temperature of annealing furnace is 680 DEG C- It 730 DEG C, heats duration 4-10 minutes, cools down duration 3-8 minutes, tempering processing, glass and glaze are carried out to glass according to this condition Material can merge more preferable, and the texture of formation is colour-fast, scratch-resistant.
Specifically, 6 primary colours of the inorganic glaze selection of glass crystal used in step (4), including yellow, red, blue, green, It is black, white, all CMYK and RGB color can be simulated;The inorganic frit particles degree of the glass crystal reaches nanoscale, extremely finely, It includes glass powder and natural pigment in toughening process with glass frit, make glaze have stronger anti-scratch, UV resistance Line and weatherability.
It specifically, in other embodiments, further include the other patterns chosen other than marble grain in step (1) As picture file.Such as can be the pattern etc. of grain pattern, photo, designed, designed, without limitation, can determine completely System, with extensive.
It specifically, include that glass tempering is shaped to flat tempered glass or semi-tempered glass or curved tempering glass in step (6) Glass.In glass tempering, as the temperature rises, a variety of different chemistry and organic variation can occur for inside glass, can make At flat tempered glass or semi-tempered glass or curved tempered glass, or the shape needed.
Specifically, after glass tempering forms marble glass, manufactured marble glass and PVB can also be obtained SGP Or EVA is combined into laminated glass;Or by being combined into hollow marble glass with structure glue, sealant, aluminum strip.
The above description is only a preferred embodiment of the present invention, is not intended to limit the scope of the invention, all at this Under the design of invention, using equivalent structure transformation made by description of the invention and accompanying drawing content, or directly/it is used in it indirectly He is included in scope of patent protection of the invention relevant technical field.

Claims (7)

1. a kind of manufacturing process of marble glass, which comprises the following steps:
(1) it chooses image: choosing natural marble plate, carry out stereoscan with multi-angle high definition scanning machine, form marble Texture picture file;
(2) marble grain in the picture file image procossing: is compiled into required line using image processing software Road;
(3) prepare substrate: being processed into the glass baseplate of required specification and external form as required with float glass, clean up standby With;
(4) digital printing: the picture file handled well in step (2) is input to ink-jet printer, the ink-jet printer exists The selected nanometer glass crystalline inorganic glaze of the glass substrate surface spray printing, forms corresponding marble grain in picture file Reason;
(5) it dries: the stone pattern glass printed at the uniform velocity being walked into the dryer that excess temperature is 153 DEG C, makes spray printing in the glass base The nanometer glass crystalline inorganic glaze moisture on material surface evaporates, and the pattern fixation that glaze is formed is not flowed.
(6) tempering: the glass after drying and processing is sent to through dedicated temperature curve annealing furnace steel, the work of annealing furnace first segment first will Nanometer glass crystalline inorganic glaze melts, and glass is heated into melting state by the second segment working time, the glass melted at this time Crystalline inorganic glaze and the glass baseplate of melting merge integrally, and glass is delivered to temperature descending section and started by control system start-up operation The work of third period, control wind pressure cool down and are kept fixed the time, and glaze combines together with glass after cooling, surface vitreous, shape At marble glass.
2. the manufacturing process of marble glass as described in claim 1, which is characterized in that in step (5), drying is in temperature For the glass baseplate after digital printing is dried 10 minutes under 153 DEG C of environment.
3. the manufacturing process of marble glass as described in claim 1, which is characterized in that the temperature in step (6) when tempering It is 680 DEG C -730 DEG C.
4. the manufacturing process of marble glass as claimed in claim 3, which is characterized in that the heating in step (6) when tempering It is Shi Changwei 4-10 minutes, 3-8 minutes a length of when then cooling down.
5. the manufacturing process of marble glass as described in claim 1, which is characterized in that further include choosing to remove in step (1) Other patterns other than marble grain are as picture file.
6. the manufacturing process of marble glass as described in claim 1, which is characterized in that include by glass reinforced plastic in step (6) Tempering is shaped to flat tempered glass or semi-tempered glass or curved tempered glass when change.
7. the manufacturing process of marble glass as described in claim 1, which is characterized in that further include step (7) processing: by steel Manufactured marble glass and PVB obtain SGP or EVA and are combined into laminated glass after change, or by with structure glue, sealant, aluminium Item is combined into hollow marble glass.
CN201910117885.6A 2019-02-15 2019-02-15 The manufacturing process of marble glass Pending CN109626837A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910117885.6A CN109626837A (en) 2019-02-15 2019-02-15 The manufacturing process of marble glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910117885.6A CN109626837A (en) 2019-02-15 2019-02-15 The manufacturing process of marble glass

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Publication Number Publication Date
CN109626837A true CN109626837A (en) 2019-04-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112629132A (en) * 2020-12-22 2021-04-09 长虹美菱股份有限公司 Digital printing process glass door applied to refrigerator and production process thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1325829A (en) * 2000-05-30 2001-12-12 漳州市德信铝玻制造有限公司 Process for preparing high-strenth multi-colour glass
CN104861779A (en) * 2015-04-27 2015-08-26 汤振华 Glass printing nanoscale ink and printing method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1325829A (en) * 2000-05-30 2001-12-12 漳州市德信铝玻制造有限公司 Process for preparing high-strenth multi-colour glass
CN104861779A (en) * 2015-04-27 2015-08-26 汤振华 Glass printing nanoscale ink and printing method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112629132A (en) * 2020-12-22 2021-04-09 长虹美菱股份有限公司 Digital printing process glass door applied to refrigerator and production process thereof

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