CN109624536A - A kind of preparation method and applications of reusable transfer pre-coating film - Google Patents
A kind of preparation method and applications of reusable transfer pre-coating film Download PDFInfo
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- CN109624536A CN109624536A CN201811627940.8A CN201811627940A CN109624536A CN 109624536 A CN109624536 A CN 109624536A CN 201811627940 A CN201811627940 A CN 201811627940A CN 109624536 A CN109624536 A CN 109624536A
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- Prior art keywords
- holographic
- coating
- coating film
- preparation
- basement membrane
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/42—Applications of coated or impregnated materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/80—Packaging reuse or recycling, e.g. of multilayer packaging
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Holo Graphy (AREA)
Abstract
The preparation method and applications of the reusable transfer pre-coating film of one kind of the invention, comprising the following steps: step 1: getting out basement membrane, and basement membrane inner surface is handled by corona treatment;Step 2: by the basement membrane inner surface of corona is then passed through baking oven and dried by coating machine coating precoating film resin obtained in step 1;Step 3: the holographic working version with holographic pattern is prepared;Step 4: the basement membrane by coating precoating film resin in step 2 and after drying is preheated by the pre- hot-rolling of moulding press, then the basement membrane after preheating is molded by moulding press, it is in close contact the one side of basement membrane coating precoating film resin with the holographic working version prepared, obtains the reusable transfer pre-coating film for being replicated with the identical holographic pattern of holographic working version.Preparation method of the invention reduces process flow, reduces production cost, the transfer pre-coating film overlapping investment after removing is produced, and plays the effect of environmental protection, and holographic pattern increases security feature and aesthetics.
Description
Technical field
The present invention relates to anti-counterfeiting packing material fields, more particularly to a kind of preparation side of reusable transfer pre-coating film
Method and its application.
Background technique
Pre-coating film be hot melt adhesive or low-temperature resins and film substrate are combined by special equipment one kind it is pollution-free,
Tacky environment-friendly type covering material, it is the environmental protection technology of sustainable development, which realizes protection environment, protection is good for
Health, the purpose of safety in production.In pre-coating film production and use process, the pollution of toxic gas will not occur, therefore, be effectively improved
Working environment eliminates the fire hazard of production site and product storage;Pre-coating film product does not have hazard residue substance, can answer extensively
For the packaging of books and periodicals, food, tobacco and wine, drug etc., potential threat is not constituted to consumer;The tune of adhesive is eliminated simultaneously
Match, process procedures, the entire coating process such as film and drying can be completed within several seconds, be able to achieve high speed, efficiently, it is high
Quality overlay film;Pre-coating film improves the color saturation of printed matter and clarity, significantly increases its artistic effect, and to printing
Product play a protective role, and are allowed to water-fast, moisture resistance, fast light, prevent pollution, anti-chemical corrosion, extend service life, greatly improve
The durability of printed matter, collection and ornamental value, improve value-added content of product.
Aluminium plating transfer paper is one of aluminized paper.Common aluminized paper was tectorial paper of aluminizing in packages printing in the past,
The production technology of this material is to aluminize on a plastic film first, then directly glues the film with aluminium coated with adhesive
It is attached to paper surface.Plastic film due to being pasted onto paper surface cannot degrade, and can generate and largely be difficult to handle or return
The waste of receipts, pollutes natural environment or destroys.And the production technology of aluminium plating transfer paper is different, is moulding first
It aluminizes on material film, then strips down the aluminum transfer on film, paste paper surface with adhesive, and film is received
It can also be coated with again after volume.Material can be saved in this way, reduce production cost, moreover it is possible to prevent from generating when useless film regeneration it is toxic,
Pernicious gas or because of environmental pollution caused by can not degrading after discarded, and the aluminium coated on discarded paper can also be natural in a short time
Dusting incorporates soil ecology chain, will not pollute natural environment, be qualified degradable package material.Comply fully with low-carbon,
Energy-saving environmental protection concept.
Existing pre-coating film can only all produce pre-coating film tectorial paper, and then tectorial paper is discarded due to having basement membrane on paper
It is easy to pollute the environment into environment.For environmental protection and reduce the purpose of cost, exploitation transfer precoating membrane material, benefit
Process flow can be reduced in transfer membrane production link with transfer pre-coating film production transfer paper, reduce production cost.Transfer precoating
Membrane pressure print holographic pattern can increase the security feature and aesthetics of product paper, and the pre-coating film overlapping investment after removing is raw
It produces, the effect of environmental protection can be played.
Summary of the invention
In light of the defects in the prior art, the purpose of the invention is to provide a kind of reusable transfer pre-coating films
Preparation method and applications reduce process flow, reduce production cost, the transfer pre-coating film overlapping investment after removing is produced,
The effect for playing environmental protection can increase security feature and aesthetics using the holographic pattern in the transfer paper of transfer pre-coating film.
The object of the present invention is achieved like this:
The preparation method of the reusable transfer pre-coating film of one kind of the invention, comprising the following steps:
Step 1: getting out basement membrane, and basement membrane inner surface is handled by corona treatment, generates basement membrane inner surface free
Base reaction, makes basement membrane inner surface dyne value reach 38-42;
Step 2: by the basement membrane inner surface of corona passes through coating machine even spread pre-coating film tree obtained in step 1
Rouge is then dried by baking oven;
Step 3: the holographic working version with holographic pattern is prepared;And holographic working version is installed in mold pressing roll;
Step 4: the basement membrane by coating precoating film resin in step 2 and after drying carries out pre- by the pre- hot-rolling of moulding press
Then basement membrane after preheating is molded by moulding press by heat, make the one side of basement membrane coating precoating film resin and prepare
Holographic working version is in close contact, and is molded by mold pressing roll, obtains being replicated with weighing for the identical holographic pattern of holographic working version
The transfer pre-coating film utilized again.
The preparation method of the reusable transfer pre-coating film of above-mentioned one kind, wherein the basement membrane in step 1 be PET,
One of BOPP or PE.
The preparation method of the reusable transfer pre-coating film of above-mentioned one kind, wherein the precoating film resin in step 2
Dry-coated amount be 0.5g/m2-1.2g/m2, Coating Speed 90m/min-150m/mi n.
The preparation method of the reusable transfer pre-coating film of above-mentioned one kind, wherein the precoating film resin in step 2
Including following components and parts by weight:
The preparation method of the reusable transfer pre-coating film of above-mentioned one kind, wherein the oven temperature in step 2 is
80℃-130℃。
The preparation method of the reusable transfer pre-coating film of above-mentioned one kind, wherein the holographic working version in step 3
Preparation method the following steps are included:
S1: there is the holographic pattern of special style using litho machine production;Holographic pattern be holographic light beam, holographic vegetarian noodles,
Holographic trash ice, holographic at least one of cluster and hololens;
S2: the holographic pattern that S1 is obtained is replicated on substrate, then carries out curing process;
S3: the substrate after solidifying in S2 carries out electroplating processes twice, obtains the holographic work for being replicated with above-mentioned holographic pattern
Make version, or the substrate after directly using S2 to solidify is as holographic working version.
The preparation method of the reusable transfer pre-coating film of above-mentioned one kind, wherein the holographic working version in step 3
Material position nickel plate, PET sheet, BOPP plate, PVC board, one of PC plate.
The preparation method of the reusable transfer pre-coating film of above-mentioned one kind, wherein the temperature of the pre- hot-rolling in step 4
Degree is 90 DEG C -150 DEG C.
The application of the reusable transfer pre-coating film of above-mentioned one kind, wherein the preparation for transfer paper.
The application of the reusable transfer pre-coating film of above-mentioned one kind, wherein the preparation method of transfer paper includes following
Step:
M1: carried out in the one side with holographic pattern of reusable transfer pre-coating film it is vacuum aluminum-coated, thus shape
At vacuum aluminium coated layer;
M2: adhesive layer, the another side and base of adhesive layer are formed on the vacuum aluminium coated layer in M1 after coating binder coating
Paper is compound;The coating weight of adhesive coating is 0.5-2.0g/m2;
M3: the reusable transfer in the base paper after will be compound in M2 precoats film stripping, vacuum aluminium coated layer after removing
On be replicated with holographic pattern identical with reusable transfer pre-coating film and base paper surface be bonded in by adhesive layer, remove
Transfer pre-coating film afterwards can reuse in M1;
M4: the vacuum aluminum-coated layer surface after M3 removes transfer pre-coating film is coated with polyurethane coating, the painting of polyurethane coating
Cloth amount is 0.5-1.5g/m2, to form layer of polyurethane, finally obtain the transfer paper with holographic pattern.
The transfer pre-coating film of the preparation method manufacture of the reusable transfer pre-coating film of one kind through the invention has
Vision and good, the at low cost advantage of antifalse effect, reusable transfer pre-coating film can reduce process flow, be effectively reduced
Production cost, environmental protection are reusable, and holographic pattern can guarantee reusable transfer pre-coating film and using transfer precoating
The transfer paper of film preparation has security feature and exquisite appearance.
Specific embodiment
Below in conjunction with embodiment, the preparation method of the transfer pre-coating film reusable to one kind of the invention and its answer
With being described further.
Embodiment 1
A kind of preparation method of reusable transfer pre-coating film, comprising the following steps:
Step 1: getting out PET basement membrane, PET basement membrane inner surface is handled by corona treatment, corona machine power
14kW, speed 80m/min, make PET basement membrane inner surface generate radical reaction, and PET basement membrane inner surface dyne value reaches 38;
Step 2: by the PET basement membrane inner surface of corona passes through coating machine even spread pre-coating film obtained in step 1
Resin, precoating film resin includes following components and parts by weight:
Ethylene-vinyl acetate mixture (EVA) has weatherability, ethylene acrylic acid co polymer (EAA) and vinyl chloride-vinyl acetate resin
With caking property.
The melt index of ethylene acrylic acid co polymer is 10-17g/10min;
The dry-coated amount for precoating film resin is 0.5g/m2-1.2g/m2, Coating Speed 90m/min-150m/min;It will be above-mentioned
Obtained even spread has the PET basement membrane of precoating film resin to dry by baking oven, speed 100m/min, oven temperature 110
℃;
Step 3: the holographic working version with holographic pattern is prepared;And holographic working version is installed in mold pressing roll;It is holographic
Working version the preparation method is as follows:
S1: there is holographic pattern acrylic board of the holographic light beam in conjunction with hololens using litho machine production;
S2: the holographic pattern acrylic board that S1 is obtained is replicated in PET base material using UV-cured resin, and substrate is thick
Degree is 50 μm, then carries out curing process using UV solidification instrument;
S3: the PET base material after solidifying in S2 carries out electroplating processes twice, obtains the holography for being replicated with above-mentioned holographic pattern
Work nickel plate, and holography work nickel plate is mounted in the mold pressing roll of moulding press;
Step 4: by step 2 coating precoating film resin and dry after PET basement membrane by moulding press pre- hot-rolling into
Row preheating, the temperature of pre- hot-rolling are 150 DEG C, are then molded the basement membrane after preheating by moulding press, keep basement membrane coating pre-
The one side and the holographic working version prepared for applying film resin are in close contact, and are molded by mold pressing roll, pressure is in roller
6kg/cm2, pressure is 6kg/cm under roller2, the running tension of basement membrane is 25N, and molding speed is 40m/min, this hair can be obtained
Bright reusable transfer pre-coating film.
Reusable transfer pre-coating film of the invention can be used in the preparation of transfer paper, repeat using of the invention
Utilize transfer pre-coating film transfer paper preparation method the following steps are included:
M1: carried out in the one side with holographic pattern of reusable transfer pre-coating film it is vacuum aluminum-coated, thus shape
At vacuum aluminium coated layer;Speed of aluminizing is 550m/min, and preferred aluminum layer thickness is 40nm;
M2: adhesive layer, the another side and base of adhesive layer are formed on the vacuum aluminium coated layer in M1 after coating binder coating
Paper is compound;The coating weight of adhesive coating is 1.1g/m2;
M3: the reusable transfer in the base paper after will be compound in M2 precoats film stripping, vacuum aluminium coated layer after removing
On be replicated with holographic pattern identical with reusable transfer pre-coating film and base paper surface be bonded in by adhesive layer, remove
Transfer pre-coating film afterwards can reuse in M1;
M4: the vacuum aluminum-coated layer surface after M3 removes transfer pre-coating film is coated with polyurethane coating, the painting of polyurethane coating
Cloth amount is 0.8g/m2, to form layer of polyurethane, finally obtain the transfer paper with holographic pattern.
The recycling number of reusable transfer pre-coating film in embodiment 1 is 20 times or more, in the same of environmental protection
When reduce the production cost of enterprise.
The transfer pre-coating film of the preparation method manufacture of the reusable transfer pre-coating film of one kind through the invention has
Vision and good, the at low cost advantage of antifalse effect, reusable transfer pre-coating film can reduce process flow, be effectively reduced
Production cost, environmental protection are reusable, and holographic pattern can guarantee reusable transfer pre-coating film and using transfer precoating
The transfer paper of film preparation has security feature and exquisite appearance.
Above embodiments are used for illustrative purposes only, rather than limitation of the present invention, the technology people in relation to technical field
Member, without departing from the spirit and scope of the present invention, can also make various transformation or modification, therefore all equivalent
Technical solution also should belong to scope of the invention, should be limited by each claim.
Claims (10)
1. a kind of preparation method of reusable transfer pre-coating film, which comprises the following steps:
Step 1: getting out basement membrane, and the basement membrane inner surface is handled by corona treatment, generates the basement membrane inner surface
Radical reaction makes the basement membrane inner surface dyne value reach 38-42;
Step 2: by the basement membrane inner surface of corona passes through coating machine even spread pre-coating film tree obtained in the step 1
Rouge is then dried by baking oven;
Step 3: the holographic working version with holographic pattern is prepared;And holographic working version is installed in mold pressing roll;
Step 4: the basement membrane by coating precoating film resin in the step 2 and after drying carries out pre- by the pre- hot-rolling of moulding press
Then basement membrane after preheating is molded by moulding press by heat, make the one side of basement membrane coating precoating film resin and prepare
The holography working version is in close contact, and is molded by mold pressing roll, obtains being replicated with the identical hologram of the holographic working version
The reusable transfer pre-coating film of line.
2. a kind of preparation method of reusable transfer pre-coating film as described in claim 1, which is characterized in that the step
Basement membrane in rapid one is one of PET, BOPP or PE.
3. a kind of preparation method of reusable transfer pre-coating film as described in claim 1, which is characterized in that the step
The dry-coated amount of precoating film resin in rapid two is 0.5g/m2-1.2g/m2, Coating Speed 90m/min-150m/min.
4. a kind of preparation method of reusable transfer pre-coating film as described in claim 1, which is characterized in that the step
Precoating film resin in rapid two includes following components and parts by weight:
The melt index of the ethylene acrylic acid co polymer is 10-17g/10min.
5. a kind of preparation method of reusable transfer pre-coating film as described in claim 1, which is characterized in that the step
Oven temperature in rapid two is 80 DEG C -130 DEG C.
6. a kind of preparation method of reusable transfer pre-coating film as described in claim 1, which is characterized in that the step
The preparation method of holographic working version in rapid three the following steps are included:
S1: there is the holographic pattern of special style using litho machine production;The holographic pattern be holographic light beam, holographic vegetarian noodles,
Holographic trash ice, holographic at least one of cluster and hololens;
S2: the obtained holographic pattern of the S1 is replicated on substrate, curing process is then carried out;
S3: the substrate after solidifying in the S2 carries out electroplating processes twice, obtains the holographic work for being replicated with above-mentioned holographic pattern
Make version, or the substrate after directly using the S2 to solidify is as holographic working version.
7. a kind of preparation method of reusable transfer pre-coating film as described in claim 1, which is characterized in that the step
One of the material position nickel plate of holographic working version in rapid three, PET sheet, BOPP plate, PVC board, PC plate.
8. a kind of preparation method of reusable transfer pre-coating film as described in claim 1, which is characterized in that the step
The temperature of pre- hot-rolling in rapid four is 90 DEG C -150 DEG C.
9. such as the application of the reusable transfer pre-coating film of one kind of claim 1 method preparation, which is characterized in that for turning
The preparation of paper transfer.
10. a kind of application of reusable transfer pre-coating film as claimed in claim 9, which is characterized in that the transfer
The preparation method of paper the following steps are included:
M1: carried out in the one side with holographic pattern of the reusable transfer pre-coating film it is vacuum aluminum-coated, thus shape
At vacuum aluminium coated layer;
M2: adhesive layer, the another side of the adhesive layer are formed after coating binder coating on the vacuum aluminium coated layer in the M1
It is compound with base paper;The coating weight of the adhesive coating is 0.5-2.0g/m2;
M3: the reusable transfer in the base paper after will be compound in the M2 precoats film stripping, the Vacuum Deposition after removing
It is replicated with holographic pattern identical with the reusable transfer pre-coating film on aluminium layer and is bonded in by the adhesive layer
The base paper surface, the transfer pre-coating film after removing can reuse in the M1;
M4: the vacuum aluminum-coated layer surface after the M3 removes transfer pre-coating film is coated with polyurethane coating, the polyurethane coating
Coating weight be 0.5-1.5g/m2, to form layer of polyurethane, finally obtain the transfer paper with holographic pattern.
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CN112211035A (en) * | 2019-07-10 | 2021-01-12 | 苏州苏大维格科技集团股份有限公司 | Manufacturing method of high-registration-precision packaging paper |
CN112428716A (en) * | 2020-11-20 | 2021-03-02 | 江西萤火虫电子商务有限公司 | Novel foam shaft printing method |
CN114438820A (en) * | 2022-01-07 | 2022-05-06 | 浙江亚欣包装材料有限公司 | Production method of paper capable of improving bonding fastness of printing ink |
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