CN109621636A - A kind of municipal waste combustion flue gas purification system - Google Patents

A kind of municipal waste combustion flue gas purification system Download PDF

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Publication number
CN109621636A
CN109621636A CN201811360564.0A CN201811360564A CN109621636A CN 109621636 A CN109621636 A CN 109621636A CN 201811360564 A CN201811360564 A CN 201811360564A CN 109621636 A CN109621636 A CN 109621636A
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CN
China
Prior art keywords
flue gas
spray
adsorbent
decontamination device
municipal waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811360564.0A
Other languages
Chinese (zh)
Inventor
罗光前
孙瑞泽
李学平
邹仁杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huazhong University of Science and Technology
Shenzhen Huazhong University of Science and Technology Research Institute
Original Assignee
Huazhong University of Science and Technology
Shenzhen Huazhong University of Science and Technology Research Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huazhong University of Science and Technology, Shenzhen Huazhong University of Science and Technology Research Institute filed Critical Huazhong University of Science and Technology
Priority to CN201811360564.0A priority Critical patent/CN109621636A/en
Publication of CN109621636A publication Critical patent/CN109621636A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • B01D46/023Pockets filters, i.e. multiple bag filters mounted on a common frame
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/60Heavy metals or heavy metal compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

Abstract

The invention belongs to domestic wastes to utilize related fields, and disclose a kind of municipal waste combustion flue gas purification system, the system includes flue gas purifying equipment and adsorbent reactivation equipment, in which: flue gas purifying equipment includes sequentially connected cooling device, spray flying dust decontamination device, spray Ca-base adsorbent desulfurizer, spray active carbon decontamination device, air-introduced machine and bag filter;Adsorbent reactivation equipment includes sequentially connected recyclable device, regenerating unit and spray treatment fluid decontamination device.The present invention can effectively remove the pollutant in flue gas by flue gas purifying equipment, wherein can be realized the recycling of waste while adsorbing pollutant using the flying dust trapped in bag filter as first step adsorbent;In addition, the present invention is additionally provided with catalyst regeneration equipment, desorption reaction occurs by heating the pollutant for making to inactivate on adsorbent, to form reproducing adsorbent, and is sent into spray flying dust decontamination device and is reused, production cost can be effectively reduced.

Description

A kind of municipal waste combustion flue gas purification system
Technical field
The invention belongs to domestic wastes to utilize related fields, more particularly, to a kind of municipal waste combustion Flue gas purification system.
Background technique
With the continuous quickening of urbanization process, the yield and accumulating amount of domestic waste increase year by year, seriously affect The development in city and ecological environment.Therefore, how most important to domestic waste progress harmless treatment.
Currently, the processing mode of domestic waste is to fill, based on compost and burning.But the method for landfill takes up an area face Product is big, and the toxic and harmful gas of generation be easy to cause secondary pollution, polluted underground water while breeding germ.Compost treatment at This is higher, and product fertilizer efficiency is too low, and there are security risk, is not suitable for promoting and applying.Rubbish directly burn volume reduction decrement and There is apparent advantage in terms of resource utilization, be most commonly seen trash processing way.
But a large amount of dust, sulfur-containing compound and heavy metal etc. can be generated during municipal waste combustion, these Pollutant can cause greatly to pollute with flue gas emission into atmosphere to environment, it is therefore desirable to generate to during incineration firing Flue gas purified.
Summary of the invention
Aiming at the above defects or improvement requirements of the prior art, the present invention provides a kind of municipal waste combustion flue gases Purification system, wherein generating the feature and its regenerated technique of adsorbent needs of a large amount of pernicious gases during combining incineration firing Feature accordingly devises flue gas purifying equipment and adsorbent reactivation equipment, can effectively solve the problems, such as that smoke pollution is serious, simultaneously It is also equipped with the effect of adsorbent reclaiming, is therefore particularly suitable for the application of municipal waste combustion.
To achieve the above object, the invention proposes a kind of municipal waste combustion flue gas purification system, feature exists In the system includes flue gas purifying equipment and adsorbent reactivation equipment, in which:
The flue gas purifying equipment includes that sequentially connected cooling device, spray flying dust decontamination device, spray Ca-base adsorbent are de- Sulphur device, spray active carbon decontamination device, air-introduced machine and bag filter, the flue gas that municipal waste combustion generates pass through first Smoke inlet, which enters, removes the flue gas of macromolecule hydrocarbon substance to remove macromolecule hydrocarbon substance in the cooling device again successively Into in the spray flying dust decontamination device, spray Ca-base adsorbent desulfurizer and spray active carbon decontamination device, in above-mentioned each dress It sets and removes sulfide and heavy metal under the action of adsorbent, last flue gas enters the bag filter by the air-introduced machine In to remove particulate matter, the clean flue gas generated after particulate matter removing is flowed out from exhanst gas outlet;
The adsorbent reactivation equipment include sequentially connected recyclable device, regenerating unit and spray treatment fluid decontamination device, In the flue gas purifying equipment adsorbent absorption sulfide and heavy metal after inactivate and collected by the recyclable device, then by It is sent into the regenerating unit and carries out desorption reaction generation reproducing adsorbent, the pollutant generated in desorption reaction is handled by the spray Liquid decontamination device absorbs.
As it is further preferred that the spray flying dust decontamination device, the spray Ca-base adsorbent desulfurizer and the spray Active carbon decontamination device is made of two chambers respectively, and flue gas enters from a chamber and flows out from another chamber, above-mentioned dress The deflector tilted down is installed on the wall surface set, and bottom is provided with accumulator tank, the inactivation adsorbent is received Collection.
As it is further preferred that the cooling device top is water-cooling wall, lower part is accumulator tank, for will be in flue gas The macromolecule hydrocarbons such as tar are condensed into liquid and are recycled.
As it is further preferred that the particulate matter of bag filter absorption is flying dust in the spray flying dust decontamination device Source.
As it is further preferred that the macromolecule hydrocarbon substance recycled in the cooling device carries out recycling benefit as the energy With.
As it is further preferred that the regenerating unit includes carrier gas inlet, motor, conveyer belt, heating tape and adsorbent Outlet, wherein the heating tape is wrapped in outside the conveyer belt, inactivation adsorbent enters in the regenerating unit, in the heating Desorption reaction occurs under the action of band, the pollutant of generation enters in the spray treatment fluid decontamination device with carrier gas, and generation is again Raw adsorbent is discharged under the drive of the motor and conveyer belt from the adsorbent outlet.
As it is further preferred that the heating temperature of the regenerating unit is preferably 200 DEG C~300 DEG C, and it is further excellent It is selected as 250 DEG C.
As it is further preferred that the preferred CaCO of slurries sprayed in the spray treatment fluid decontamination device3Solution, Ca (OH)2 Solution, NaOH solution or AlCl3Solution.
As it is further preferred that the carrier gas is preferably nitrogen, argon gas or air.
As it is further preferred that the reproducing adsorbent, which is added in the spray flying dust decontamination device, carries out repetition benefit With.
In general, through the invention it is contemplated above technical scheme is compared with the prior art, mainly have below Technological merit:
1. the present invention purifies the flue gas generated during municipal waste combustion by flue gas purifying equipment, energy The pollutants such as sulfide and the heavy metal in flue gas are enough effectively removed, wherein using the flying dust trapped in bag filter as first Adsorbent is walked, can be realized the recycling of waste while adsorbing pollutant;In addition, adsorption effect is best but cost is opposite Higher active carbon can not only reduce the content of pollutant in flue gas as final step adsorbent, and can effectively drop Low production cost;
2. in addition, the present invention is additionally provided with catalyst regeneration equipment, by 200 DEG C~300 DEG C at a temperature of heat, make Desorption reaction occurs for the pollutant such as sulfide or heavy metal inactivated on adsorbent, to form reproducing adsorbent, and is sent into spray It is reused in flying dust decontamination device, the injected volume of the adsorbents such as active carbon can be further reduced, production is effectively reduced Cost;
3. simultaneously, the present invention recycles the macromolecule hydrocarbons substances such as tar in flue gas, the abundant of resource is realized It utilizes.
Detailed description of the invention
Fig. 1 is the structural schematic diagram for the municipal waste combustion flue gas purification system that the present invention constructs;
Fig. 2 is the work flow diagram of municipal waste combustion flue gas purification system provided by the invention.
In all the appended drawings, identical appended drawing reference is used to denote the same element or structure, in which:
1: smoke inlet, 2: cooling device, 3: recyclable device, 4: spray flying dust decontamination device, 5: spray Ca-base adsorbent desulfurization Device, 6: spray active carbon decontamination device, 7: air-introduced machine, 8: bag filter, 9: exhanst gas outlet, 10: spray treatment fluid decontamination device, 11: carrier gas inlet, 12: motor, 13: heating tape, 14: adsorbent outlet, 15: conveyer belt.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.As long as in addition, technical characteristic involved in the various embodiments of the present invention described below Not constituting a conflict with each other can be combined with each other.
As shown in Figure 1, the invention proposes a kind of municipal waste combustion flue gas purification systems, which is characterized in that should System includes flue gas purifying equipment and adsorbent reactivation equipment, in which:
The flue gas purifying equipment includes sequentially connected cooling device 2, spray flying dust decontamination device 4, spray Ca-base adsorbent Desulfurizer 5, spray active carbon decontamination device 6, air-introduced machine 7 and bag filter 8, the flue gas that municipal waste combustion generates are first It first passes through smoke inlet 1 to enter in the cooling device 2 to remove macromolecule hydrocarbon substance, removes the cigarette of macromolecule hydrocarbon substance Gas is sequentially entered again in the spray flying dust decontamination device 4, spray Ca-base adsorbent desulfurizer 5 and spray active carbon decontamination device 6, with Removing sulfide and heavy metal under the action of adsorbent includes flying dust, Ca-base adsorbent and active carbon in above-mentioned each device, most Flue gas is entered in the bag filter 8 by the air-introduced machine 7 to remove particulate matter, the cleaning generated after particulate matter removing afterwards Flue gas is flowed out from exhanst gas outlet 9;
The adsorbent reactivation equipment includes sequentially connected recyclable device 3, regenerating unit and spray treatment fluid decontamination device 10, it inactivates and is collected by the recyclable device 3 after the adsorbent absorption sulfide and heavy metal in the flue gas purifying equipment, so After be admitted to the regenerating unit and carry out desorption reaction and generate reproducing adsorbent, the pollutant generated in desorption reaction is by the spray Treatment fluid decontamination device 10 absorbs.
Further, the spray flying dust decontamination device 4, the spray Ca-base adsorbent desulfurizer 5 and the spray active carbon are de- Dirty device 6 is made of two chambers respectively, and flue gas enters from a chamber and flows out from another chamber, to guarantee that flue gas fills Point with adsorbent haptoreaction, the deflector tilted down is installed on the wall surface of above-mentioned apparatus, and bottom is provided with recycling Slot is collected inactivation adsorbent.
Further, 2 top of cooling device is water-cooling wall, lower part is accumulator tank, for tar in flue gas etc. is big Molecular hydrocarbon is condensed into liquid and is recycled.
Further, the particulate matter that the bag filter 8 adsorbs is the source of flying dust in the spray flying dust decontamination device 4.
Further, the macromolecule hydrocarbons substances such as the tar recycled in the cooling device 2 are recycled as the energy.
Further, the regenerating unit includes that carrier gas inlet 11, motor 12, conveyer belt 15, heating tape 13 and adsorbent go out Mouth 14, wherein the heating tape 13 is wrapped in outside the conveyer belt 15, the inactivation adsorbent passes through screw(-type) feeder and is sent into In the regenerating unit, desorption reaction occurs under the action of heating tape 13, the pollutant of generation enters the spray with carrier gas In treatment fluid decontamination device 10, the reproducing adsorbent of generation is under the drive of the motor 12 and conveyer belt 15 from the adsorbent 14 discharge of outlet.
Further, the heating temperature of the regenerating unit is preferably 200 DEG C~300 DEG C, and further preferably 250 DEG C.
Further, the preferred CaCO of slurries sprayed in the spray treatment fluid decontamination device 103Solution, Ca (OH)2Solution, NaOH solution or AlCl3Solution.
Further, the carrier gas is preferably nitrogen, argon gas or air.
Further, the reproducing adsorbent is added in the spray flying dust decontamination device 4 and is reused.
The specific workflow of municipal waste combustion flue gas purification system provided by the invention is as shown in Fig. 2, city The flue gas that house refuse burning generates enters cooling device 2, the macromolecule hydrocarbons object such as tar in flue gas from the smoke inlet 1 Matter is collected after condensing on water-cooling wall by the accumulator tank of lower part;The flue gas for removing macromolecule hydrocarbon substance is de- into the spray flying dust In dirty device 4, flying dust in bag filter 8 is as adsorbent by the sulfide and heavy metal adsorption heel row in flue gas Out;The flue gas of discharge enters in the spray Ca-base adsorbent desulfurizer 5, and sulfide therein adsorbs heel row by Ca-base adsorbent Out and enter in the spray active carbon decontamination device 6, active carbon is as adsorbent by the sulfide and heavy metal adsorption in flue gas After discharge it;Flue gas enters the bag filter 8 to remove particulate matter under the action of air-introduced machine 7, and what is finally generated is clean Neat stress is flowed out from exhanst gas outlet 9;
Absorption in above-mentioned spray flying dust decontamination device 4, spray Ca-base adsorbent desulfurizer 5 and spray active carbon decontamination device 6 Agent, which is inactivated after adsorbing sulfide and heavy metal and collected by the accumulator tank of bottom, to be entered in the recyclable device 3, is given by spiral Material machine enters in regenerating unit, and desorption reaction occurs under the action of heating tape 13, the pollutant of generation with carrier gas into Enter in the spray treatment fluid decontamination device 10, the reproducing adsorbent of generation is under the drive of the motor 12 and conveyer belt 15 from suction Attached dose of 14 discharge of outlet, and be admitted in the spray flying dust decontamination device 4 and reused as adsorbent.
As it will be easily appreciated by one skilled in the art that the foregoing is merely illustrative of the preferred embodiments of the present invention, not to The limitation present invention, any modifications, equivalent substitutions and improvements made within the spirit and principles of the present invention should all include Within protection scope of the present invention.

Claims (10)

1. a kind of municipal waste combustion flue gas purification system, which is characterized in that the system includes flue gas purifying equipment and suction Attached dose of generating apparatus again, in which:
The flue gas purifying equipment includes sequentially connected cooling device (2), spray flying dust decontamination device (4), spray Ca-base adsorbent Desulfurizer (5), spray active carbon decontamination device (6), air-introduced machine (7) and bag filter (8), municipal waste combustion generate Flue gas pass through smoke inlet (1) first and enter to remove macromolecule hydrocarbon substance in the cooling device (2), remove macromolecular The flue gas of hydrocarbons sequentially enters the spray flying dust decontamination device (4), spray Ca-base adsorbent desulfurizer (5) and spray activity again In charcoal decontamination device (6), with removing sulfide and heavy metal, last flue gas pass through under the action of adsorbent in above-mentioned each device The air-introduced machine (7) enters to remove particulate matter in the bag filter (8), the clean flue gas generated after particulate matter removing from Exhanst gas outlet (9) outflow;
The adsorbent reactivation equipment includes sequentially connected recyclable device (3), regenerating unit and spray treatment fluid decontamination device (10), it inactivates and is received by the recyclable device (3) after the adsorbent absorption sulfide and heavy metal in the flue gas purifying equipment Collection is then fed to the regenerating unit and carries out desorption reaction generation reproducing adsorbent, the pollutant quilt generated in desorption reaction The spray treatment fluid decontamination device (10) absorbs.
2. municipal waste combustion flue gas purification system as described in claim 1, which is characterized in that the spray flying dust decontamination Device (4), the spray Ca-base adsorbent desulfurizer (5) and the spray active carbon decontamination device (6) are respectively by two chambers group At flue gas enters from a chamber and flows out from another chamber, is equipped with the water conservancy diversion tilted down on the wall surface of above-mentioned apparatus Plate, and bottom is provided with accumulator tank, inactivation adsorbent is collected.
3. municipal waste combustion flue gas purification system as claimed in claim 1 or 2, which is characterized in that the cooling dress Set that top is water-cooling wall, lower part is accumulator tank, for recycling the macromolecule hydrocarbon material condensation in flue gas at liquid.
4. the municipal waste combustion flue gas purification system as described in claims 1 to 3 any one, which is characterized in that institute The particulate matter for stating bag filter (8) absorption is the source of flying dust in spray flying dust decontamination device (4).
5. the municipal waste combustion flue gas purification system as described in Claims 1 to 4 any one, which is characterized in that institute The macromolecule hydrocarbon substance recycled in cooling device (2) is stated to be recycled as the energy.
6. municipal waste combustion flue gas purification system as claimed in any one of claims 1 to 5, wherein, which is characterized in that institute Stating regenerating unit includes carrier gas inlet (11), motor (12), conveyer belt (15), heating tape (13) and adsorbent outlet (14), Described in heating tape (13) be wrapped in that the conveyer belt (15) is external, and inactivation adsorbent enters in the regenerating unit, described plus Desorption reaction occurs under the action of tropical (13), the pollutant of generation enters the spray treatment fluid decontamination device (10) with carrier gas In, the reproducing adsorbent of generation is arranged under the drive of the motor (12) and conveyer belt (15) from the adsorbent outlet (14) Out.
7. the municipal waste combustion flue gas purification system as described in claim 1~6 any one, which is characterized in that institute The heating temperature for stating regenerating unit is preferably 200 DEG C~300 DEG C, and further preferably 250 DEG C.
8. the municipal waste combustion flue gas purification system as described in claim 1~7 any one, which is characterized in that institute State the preferred CaCO of slurries sprayed in spray treatment fluid decontamination device (10)3Solution, Ca (OH)2Solution, NaOH solution or AlCl3It is molten Liquid.
9. the municipal waste combustion flue gas purification system as described in claim 1~8 any one, which is characterized in that institute Stating carrier gas is preferably nitrogen, argon gas or air.
10. municipal waste combustion flue gas purification system as claimed in any one of claims 1 to 9 wherein, which is characterized in that institute It states reproducing adsorbent and is added in the spray flying dust decontamination device (4) and reused.
CN201811360564.0A 2018-11-15 2018-11-15 A kind of municipal waste combustion flue gas purification system Pending CN109621636A (en)

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Application Number Priority Date Filing Date Title
CN201811360564.0A CN109621636A (en) 2018-11-15 2018-11-15 A kind of municipal waste combustion flue gas purification system

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1332334A (en) * 2000-07-10 2002-01-23 清华大学 Comprehensive garbage incinerating tail gas purifying method and equipment
CN103239985A (en) * 2013-05-14 2013-08-14 中国环境科学研究院 Efficient coal-fired flue gas sulfur removal and mercury removal method and device
CN104353325A (en) * 2014-11-12 2015-02-18 上海锅炉厂有限公司 Device and method for removing mercury from boiler flue gas of power station
CN207951096U (en) * 2018-02-07 2018-10-12 李观德 Incineration firing device for purifying and treating tail gas
CN209317379U (en) * 2018-11-15 2019-08-30 华中科技大学 A kind of municipal waste combustion flue gas purification system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1332334A (en) * 2000-07-10 2002-01-23 清华大学 Comprehensive garbage incinerating tail gas purifying method and equipment
CN103239985A (en) * 2013-05-14 2013-08-14 中国环境科学研究院 Efficient coal-fired flue gas sulfur removal and mercury removal method and device
CN104353325A (en) * 2014-11-12 2015-02-18 上海锅炉厂有限公司 Device and method for removing mercury from boiler flue gas of power station
CN207951096U (en) * 2018-02-07 2018-10-12 李观德 Incineration firing device for purifying and treating tail gas
CN209317379U (en) * 2018-11-15 2019-08-30 华中科技大学 A kind of municipal waste combustion flue gas purification system

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