CN109619366A - A kind of efficient feed mildew inhibitor and preparation method thereof - Google Patents
A kind of efficient feed mildew inhibitor and preparation method thereof Download PDFInfo
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- 239000003112 inhibitor Substances 0.000 title claims abstract description 89
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims abstract description 160
- 235000019260 propionic acid Nutrition 0.000 claims abstract description 80
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims abstract description 80
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims abstract description 16
- 239000008139 complexing agent Substances 0.000 claims abstract description 13
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001530 fumaric acid Substances 0.000 claims abstract description 8
- 239000004334 sorbic acid Substances 0.000 claims abstract description 8
- 235000010199 sorbic acid Nutrition 0.000 claims abstract description 8
- 229940075582 sorbic acid Drugs 0.000 claims abstract description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003463 adsorbent Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims description 46
- 239000000463 material Substances 0.000 claims description 34
- 150000001875 compounds Chemical class 0.000 claims description 25
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- XJMWHXZUIGHOBA-UHFFFAOYSA-N azane;propanoic acid Chemical compound N.CCC(O)=O XJMWHXZUIGHOBA-UHFFFAOYSA-N 0.000 claims description 5
- 239000011229 interlayer Substances 0.000 claims description 5
- 239000010410 layer Substances 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 3
- 230000003449 preventive effect Effects 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 241000235342 Saccharomycetes Species 0.000 abstract description 5
- 241000192125 Firmicutes Species 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 230000002401 inhibitory effect Effects 0.000 abstract 2
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 230000001408 fungistatic effect Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 239000006101 laboratory sample Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000726221 Gemma Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 206010020718 hyperplasia Diseases 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3526—Organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3481—Organic compounds containing oxygen
- A23L3/3508—Organic compounds containing oxygen containing carboxyl groups
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of efficient feed mildew inhibitor and preparation method thereof, which calculates as mass fraction, and composition and content are as follows: propionic acid type mould inhibitor 40-65%；Adsorbent 18-30%；Sorbic acid 8-20%；Fumaric acid 8-20%；Complexing agent 1-5%.Contain sorbic acid, fumaric acid and complexing agent in efficient feed mildew inhibitor provided by the invention, wherein sorbic acid fills up the inhibiting effect to saccharomycete；Fumaric acid fills up the inhibiting effect to other moulds and gram-positive bacteria；Complexing agent effectively controls the release of free propionic acid, plays continual and steady antibacterial synergistic effect to propionic acid.
Description
Technical field
The present invention relates to microbial preparation fields more particularly to a kind of efficient feed mildew inhibitor and preparation method thereof.
Background technique
In actual life, temperature, humidity, mycotic spore are three mouldy necessary conditions, and people way comfort temperature is exactly
The growth temperature of mould；The transmission of mould not only influences the beauty of body surface, can also break through paint film in the mould of submerged growth
It causes to crack and flake off, leads to object damage；The mould of hyperplasia can also threaten the health of human body and biology simultaneously；Existing market
In common mould inhibitor be one-component propionic acid type mould inhibitor, and since the component of propionic acid type mould inhibitor is single, propionic acid
Gemma is supported to most of mould, well as mould inhibitor, Gram-negative bacteria has relatively good fungistatic effect but to Gram-positive
The fungistatic effects such as bacterium, saccharomycete are unobvious；The fungistatic effect of propionic acid type mould inhibitor is unstable simultaneously: the mould proof mechanism of propionic acid is trip
From propionic acid and cell wall constituent react, drain cell moisture and cause microorganism dead；In conjunction with propionic acid there is no antibacterial work
With；If free propionic acid content ratio is too high and volatile ingredient is caused to waste in.
To sum up, the generally existing following problems of mould inhibitor in the prior art: 1. propionic acid are as mould inhibitor to Gram-positive
The fungistatic effects such as bacterium, saccharomycete are unobvious；2. free propionic acid content ratio is too high and volatile ingredient is caused to waste.
Therefore, unknown to fungistatic effects such as gram-positive bacteria, saccharomycete as mould inhibitor for existing mould inhibitor propionic acid
Aobvious and free propionic acid content ratio is too high and volatile the problems such as causing ingredient to waste, and becomes those skilled in the art and urgently solves
Certainly the technical issues of.
Summary of the invention
The present invention is that solve existing mould inhibitor fungistatic effect unobvious and too high from propionic acid content ratio and volatile make
The problems such as wasting at ingredient provides a kind of efficient feed mildew inhibitor and preparation method thereof.
To achieve the above object, the invention adopts the following technical scheme:
There is provided a kind of preparation methods of efficient feed mildew inhibitor for the first aspect of the invention, comprising the following steps:
The propionic acid type mould inhibitor is added to reaction kettle step 1, liquefied ammonia is passed through in Xiang Suoshu reaction kettle, while right
The reaction kettle interlayer cools down to ensure that reacts goes on smoothly；
Step 2, to after reaction, a certain amount of complexing agent be added in Xiang Suoshu reaction kettle, and filled in step 1
Divide after being mixed and obtains propionic acid complex compound in case stand-by；
A certain amount of adsorbent is added into feed mixing machine for step 3, and opens the blender in the feed mixing machine,
The propionic acid complex compound obtained in step 2 is slowly added into the feed mixing machine simultaneously, to the propionic acid complex compound
After all pouring into, the feed mixing machine continues mixed material to be stirred certain time；
Feed mixing machine described in step 4, step 3 continues to be stirred after a certain period of time mixed material, successively to institute
It states and a certain amount of sorbic acid and fumaric acid is added in feed mixing machine, and stir to obtain uniform mould inhibitor material；
The uniform mould inhibitor material obtained in step 5, step 4 is raised after being sieved by oscillating granulator to get efficient
Expect mould inhibitor, finished product packing is carried out to the efficient feed mildew inhibitor；
Wherein, according to the mass fraction, each composition of the efficient feed mildew inhibitor and its dosage are as follows:
Further, propionic acid type mould inhibitor described in step 1 is the combination of one or more of propionic acid and propionic acid ammonium.
Further, the molar ratio of liquefied ammonia described in step 1 and the propionic acid type mould inhibitor is 1:10-1:3.
Further, reaction kettle described in step 1 is 3 cubes of reaction kettles or 4 cubes of reaction kettles or 5 cubes of reaction kettles or 6
Cube reaction kettle or 7 cubes of reaction kettles or 8 cubes of reaction kettles.
Further, the mass ratio of complexing agent described in the propionic acid type mould inhibitor in step 1 and step 2 is 10:1-
45:1。
Further, in step 3 after the propionic acid complex compound all pours into, the feed mixing machine is to mixed material
Continue to be stirred 10-40min.
Further, the propionic acid complex compound obtained in step 2 is slowly added in step 3 into the feed mixing machine
Flow be 0.2-0.5T/hr, and keep by sprinkling and stirring keep it is evenly dispersed,
Further, uniform mould inhibitor material described in step 5 is sieved with 40-80 mesh partial size by oscillating granulator.
Further, two layers of hermetic bag sealing packaging is carried out to the efficient feed mildew inhibitor in step 5.
There is provided a kind of height prepared according to above-mentioned efficient feed mildew inhibitor preparation method for the second aspect of the invention
Imitate Midew preventive for feed.
The present invention by adopting the above technical scheme, compared with prior art, has the following technical effect that
(1) formula of the invention compounds other mould proof substances, fills up the antimicrobial spectrum of propionic acid vacancy,
(2) the effective ratio for the propionic acid that dissociates in propionic acid can be effectively controlled in the present invention, and the consumption according to the propionic acid that dissociates continues
Will be in conjunction with propionic acid release at free propionic acid, anti-mold effect is stablized lasting.
Specific embodiment
The present invention is described in more detail below by specific embodiment, for a better understanding of the present invention,
But following embodiments are not intended to limit the scope of the invention.
Embodiment 1
The embodiment of the invention provides a kind of preparation methods of efficient feed mildew inhibitor, calculate as mass fraction, composition
It is as follows with content:
Above-mentioned formula carries out preparing material according to the following steps:
The propionic acid type mould inhibitor is added to reaction kettle step 1, liquefied ammonia is passed through in Xiang Suoshu reaction kettle, while right
The reaction kettle interlayer cools down to ensure that reacts goes on smoothly；
Step 2, to after reaction, a certain amount of complexing agent be added in Xiang Suoshu reaction kettle, and filled in step 1
Divide after being mixed and obtains propionic acid complex compound in case stand-by；
A certain amount of adsorbent is added into feed mixing machine for step 3, and opens the blender in the feed mixing machine,
The propionic acid complex compound obtained in step 2 is slowly added into the feed mixing machine simultaneously, to the propionic acid complex compound
After all pouring into, the feed mixing machine continues mixed material to be stirred certain time；
Feed mixing machine described in step 4, step 3 continues to be stirred after a certain period of time mixed material, successively to institute
It states and a certain amount of sorbic acid and fumaric acid is added in feed mixing machine, and stir to obtain uniform mould inhibitor material；
The uniform mould inhibitor material obtained in step 5, step 4 is raised after being sieved by oscillating granulator to get efficient
Expect mould inhibitor, finished product packing is carried out to the efficient feed mildew inhibitor.
In the present embodiment, propionic acid type mould inhibitor described in step 1 is the group of one or more of propionic acid and propionic acid ammonium
It closes.The molar ratio of liquid nitrogen described in step 1 and the propionic acid type mould inhibitor is 1:4.Reaction kettle described in step 1 is 3 cubes anti-
Answer kettle.The mass ratio of complexing agent described in the propionic acid type mould inhibitor and step 2 in step 1 is 41.56:1.
In the present embodiment, in step 3 after the propionic acid complex compound all pours into, the feed mixing machine is to mixing
Material continues to be stirred 15min.The propionic acid obtained in step 2 is slowly added in step 3 into the feed mixing machine
The flow of complex compound is 0.2-0.5T/hr, and keeps keeping evenly dispersed by sprinkling and stirring,
In the present embodiment, uniform mould inhibitor material described in step 5 passes through oscillating granulator mistake with 40-80 mesh partial size
Sieve.Two layers of hermetic bag sealing packaging is carried out to the efficient feed mildew inhibitor in step 5.
Embodiment 2
The embodiment of the invention provides a kind of preparation methods of efficient feed mildew inhibitor, calculate as mass fraction, composition
It is as follows with content:
Above-mentioned formula carries out preparing material according to the following steps:
The propionic acid type mould inhibitor is added to reaction kettle step 1, liquefied ammonia is passed through in Xiang Suoshu reaction kettle, while right
The reaction kettle interlayer cools down to ensure that reacts goes on smoothly；
Step 2, to after reaction, a certain amount of complexing agent be added in Xiang Suoshu reaction kettle, and filled in step 1
Divide after being mixed and obtains propionic acid complex compound in case stand-by；
A certain amount of adsorbent is added into feed mixing machine for step 3, and opens the blender in the feed mixing machine,
The propionic acid complex compound obtained in step 2 is slowly added into the feed mixing machine simultaneously, to the propionic acid complex compound
After all pouring into, the feed mixing machine continues mixed material to be stirred certain time；
Feed mixing machine described in step 4, step 3 continues to be stirred after a certain period of time mixed material, successively to institute
It states and a certain amount of sorbic acid and fumaric acid is added in feed mixing machine, and stir to obtain uniform mould inhibitor material；
The uniform mould inhibitor material obtained in step 5, step 4 is raised after being sieved by oscillating granulator to get efficient
Expect mould inhibitor, finished product packing is carried out to the efficient feed mildew inhibitor.
In the present embodiment, propionic acid type mould inhibitor described in step 1 is the group of one or more of propionic acid and propionic acid ammonium
It closes.The molar ratio of liquid nitrogen described in step 1 and the propionic acid type mould inhibitor is 1:6.Reaction kettle described in step 1 is 5 cubes anti-
Answer kettle.The mass ratio of complexing agent described in the propionic acid type mould inhibitor and step 2 in step 1 is 10:1.
In the present embodiment, in step 3 after the propionic acid complex compound all pours into, the feed mixing machine is to mixing
Material continues to be stirred 14min.The propionic acid obtained in step 2 is slowly added in step 3 into the feed mixing machine
The flow of complex compound is 0.2-0.5T/hr, and keeps keeping evenly dispersed by sprinkling and stirring,
In the present embodiment, uniform mould inhibitor material described in step 5 passes through oscillating granulator mistake with 40-80 mesh partial size
Sieve.Two layers of hermetic bag sealing packaging is carried out to the efficient feed mildew inhibitor in step 5.
Embodiment 3
The embodiment of the invention provides a kind of preparation methods of efficient feed mildew inhibitor, calculate as mass fraction, composition
It is as follows with content:
Above-mentioned formula carries out preparing material according to the following steps:
The propionic acid type mould inhibitor is added to reaction kettle step 1, liquefied ammonia is passed through in Xiang Suoshu reaction kettle, while right
The reaction kettle interlayer cools down to ensure that reacts goes on smoothly；
Step 2, to after reaction, a certain amount of complexing agent be added in Xiang Suoshu reaction kettle, and filled in step 1
Divide after being mixed and obtains propionic acid complex compound in case stand-by；
A certain amount of adsorbent is added into feed mixing machine for step 3, and opens the blender in the feed mixing machine,
The propionic acid complex compound obtained in step 2 is slowly added into the feed mixing machine simultaneously, to the propionic acid complex compound
After all pouring into, the feed mixing machine continues mixed material to be stirred certain time；
Feed mixing machine described in step 4, step 3 continues to be stirred after a certain period of time mixed material, successively to institute
It states and a certain amount of sorbic acid and fumaric acid is added in feed mixing machine, and stir to obtain uniform mould inhibitor material；
The uniform mould inhibitor material obtained in step 5, step 4 is raised after being sieved by oscillating granulator to get efficient
Expect mould inhibitor, finished product packing is carried out to the efficient feed mildew inhibitor.
In the present embodiment, propionic acid type mould inhibitor described in step 1 is the group of one or more of propionic acid and propionic acid ammonium
It closes.The molar ratio of liquid nitrogen described in step 1 and the propionic acid type mould inhibitor is 1:10-1:3.Reaction kettle described in step 1 is 3 vertical
Square reaction kettle or 4 cubes of reaction kettles or 5 cubes of reaction kettles or 6 cubes of reaction kettles or 7 cubes of reaction kettles or 8 cubes of reaction kettles.Step
The mass ratio of complexing agent described in the propionic acid type mould inhibitor and step 2 in rapid 1 is 30:1.
In the present embodiment, in step 3 after the propionic acid complex compound all pours into, the feed mixing machine is to mixing
Material continues to be stirred 10-40min.It is slowly added into the feed mixing machine described third obtained in step 2 in step 3
The flow of acid complex is 0.2-0.5T/hr, and keeps keeping evenly dispersed by sprinkling and stirring,
In the present embodiment, uniform mould inhibitor material described in step 5 passes through oscillating granulator mistake with 40-80 mesh partial size
Sieve.Two layers of hermetic bag sealing packaging is carried out to the efficient feed mildew inhibitor in step 5.
The fungicidal properties table of comparisons for present embodiments providing a kind of 1-3 and comparative example based on the above embodiment, such as 1 institute of table
Show, wherein comparative example is 65% propionic acid mould inhibitor, and test method is as follows:
Step 1 prepares feed, and it includes: corn 67% that feed formula is calculated as mass fraction；Dregs of beans 25；Pre- powder 6；Greatly
Soya-bean oil 2；
Step 2 adds height made from 65% propionic acid mould inhibitor and embodiment 1-3 according to the feed of additive amount 0.1% respectively
Imitate mould inhibitor；
Step 3, the ring that the laboratory sample of comparative example laboratory sample and embodiment 1-3 is placed in 30 DEG C of humidity 90% of temperature
Border, every 3 days detection total number of molds；It draws table and obtains table 1.
Table 1
As shown in table 1, experiment shows that high-effective antimold anti-mold effect made from 1-3 of the embodiment of the present invention is substantially better than 65%
Propionic acid mould inhibitor.
The present invention is unknown to fungistatic effects such as gram-positive bacteria, saccharomycete as mould inhibitor for existing mould inhibitor propionic acid
Aobvious and free propionic acid content ratio is too high and volatile the problems such as causing ingredient to waste, and it is mould proof that formula of the invention compounds other
Substance fills up the antimicrobial spectrum of propionic acid vacancy；And the effective ratio for the propionic acid that dissociates in propionic acid can be effectively controlled in the present invention, according to free
The consumption of propionic acid persistently will be in conjunction with propionic acid release at free propionic acid, and anti-mold effect is stablized lasting.
The specific embodiment of efficient feed mildew inhibitor of the present invention and preparation method thereof is described in detail above, but its
It is intended only as example, the present invention is not restricted to particular embodiments described above.To those skilled in the art, any
Equivalent modifications and substitutions to the present invention are also within the scope of the present invention.Therefore, spirit of the invention is not being departed from
With equal transformation made under range and modification, all should be contained within the scope of the invention.
Claims (10)
1. a kind of preparation method of efficient feed mildew inhibitor, which comprises the following steps:
The propionic acid type mould inhibitor is added to reaction kettle step 1, liquefied ammonia is passed through in Xiang Suoshu reaction kettle, while to described
Reaction kettle interlayer cools down to ensure that reacts goes on smoothly；
Step 2, to which a certain amount of complexing agent after reaction, is added in step 1 in Xiang Suoshu reaction kettle, and carry out sufficiently mixed
Propionic acid complex compound is obtained after closing stirring in case stand-by；
A certain amount of adsorbent is added into feed mixing machine for step 3, and opens the blender in the feed mixing machine, simultaneously
The propionic acid complex compound obtained in step 2 is slowly added into the feed mixing machine, it is whole to the propionic acid complex compound
After pouring into, the feed mixing machine continues mixed material to be stirred certain time；
Feed mixing machine described in step 4, step 3 continues to be stirred after a certain period of time mixed material, successively to the feeding
Expect that a certain amount of sorbic acid and fumaric acid are added in mixing machine, and stirs to obtain uniform mould inhibitor material；
The uniform mould inhibitor material obtained in step 5, step 4 is anti-to get high-efficiency feed after being sieved by oscillating granulator
Mould dose, finished product packing is carried out to the efficient feed mildew inhibitor；
Wherein, according to the mass fraction, each composition of the efficient feed mildew inhibitor and its dosage are as follows:
2. the preparation method of efficient feed mildew inhibitor according to claim 1, which is characterized in that propionic acid described in step 1
Type mould inhibitor is the combination of one or more of propionic acid and propionic acid ammonium.
3. the preparation method of efficient feed mildew inhibitor according to claim 1, which is characterized in that liquefied ammonia described in step 1
Molar ratio with the propionic acid type mould inhibitor is 1:10-1:3.
4. the preparation method of efficient feed mildew inhibitor according to claim 1, which is characterized in that reacted described in step 1
Kettle is that 3 cubes of reaction kettles or 4 cubes of reaction kettles or 5 cubes of reaction kettles or 6 cubes of reaction kettles or 7 cubes of reaction kettles or 8 cubes are anti-
Answer kettle.
5. the preparation method of efficient feed mildew inhibitor according to claim 1, which is characterized in that described third in step 1
The mass ratio of complexing agent described in acid type mould inhibitor and step 2 is 10:1-45:1.
6. the preparation method of efficient feed mildew inhibitor according to claim 1, which is characterized in that described third in step 3
After acid complex all pours into, the feed mixing machine continues mixed material to be stirred 10-40min.
7. the preparation method of efficient feed mildew inhibitor according to claim 1, which is characterized in that the feeding in step 3
The flow that the propionic acid complex compound obtained in step 2 is slowly added in material mixing machine is 0.2-0.5T/hr, and keeps passing through spray
It spills and stirs and keep evenly dispersed.
8. the preparation method of efficient feed mildew inhibitor according to claim 1, which is characterized in that described in step 5 uniformly
Mould inhibitor material is sieved with 40-80 mesh partial size by oscillating granulator.
9. the preparation method of efficient feed mildew inhibitor according to claim 1, which is characterized in that the height in step 5
It imitates Midew preventive for feed and carries out two layers of hermetic bag sealing packaging.
10. high-efficiency feed prepared by a kind of preparation method of efficient feed mildew inhibitor as described in claim any one of 1-9 is mould proof
Agent.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101731451A (en) * | 2010-01-21 | 2010-06-16 | 鲁昊 | Compound mouldproof agent with acidizing effect and preparation method thereof |
| CN102488076A (en) * | 2011-11-07 | 2012-06-13 | 朝阳圣丰牧业有限公司 | Safe and efficient composite mildew preventive for feed |
| CN105341360A (en) * | 2015-12-07 | 2016-02-24 | 重庆华睿隆生物科技有限公司 | Carrier-free propionic acid solid feed mildew preventive and preparation and use thereof |
| CN106962655A (en) * | 2017-05-17 | 2017-07-21 | 上海邦成生物工程有限公司 | It is a kind of that there is composite mildew inhibitor of acidizing effect and its preparation method and application to feed |
-
2018
- 2018-12-29 CN CN201811642494.8A patent/CN109619366A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101731451A (en) * | 2010-01-21 | 2010-06-16 | 鲁昊 | Compound mouldproof agent with acidizing effect and preparation method thereof |
| CN102488076A (en) * | 2011-11-07 | 2012-06-13 | 朝阳圣丰牧业有限公司 | Safe and efficient composite mildew preventive for feed |
| CN105341360A (en) * | 2015-12-07 | 2016-02-24 | 重庆华睿隆生物科技有限公司 | Carrier-free propionic acid solid feed mildew preventive and preparation and use thereof |
| CN106962655A (en) * | 2017-05-17 | 2017-07-21 | 上海邦成生物工程有限公司 | It is a kind of that there is composite mildew inhibitor of acidizing effect and its preparation method and application to feed |
Non-Patent Citations (2)
| Title |
|---|
| 商成杰: "《新型染整助剂手册》", 31 October 2002, 中国纺织出版社 * |
| 方希修等: "《饲料添加剂与分析检测技术》", 30 September 2006, 中国农业大学出版社 * |
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Application publication date: 20190416 |