CN109608885A - A kind of water resistance rubber gloves and preparation method thereof - Google Patents
A kind of water resistance rubber gloves and preparation method thereof Download PDFInfo
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- CN109608885A CN109608885A CN201811483941.XA CN201811483941A CN109608885A CN 109608885 A CN109608885 A CN 109608885A CN 201811483941 A CN201811483941 A CN 201811483941A CN 109608885 A CN109608885 A CN 109608885A
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- parts
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- water resistance
- rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/02—Direct processing of dispersions, e.g. latex, to articles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
- C08J2383/07—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2411/00—Characterised by the use of homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2457/00—Characterised by the use of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08J2457/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
Abstract
The invention discloses a kind of water resistance rubber gloves, it include: synthetic resin yarn gloves embryo and the rubber layer for being attached to the synthetic resin yarn gloves embryo outer surface, it is stained in the synthetic resin yarn gloves embryo by bonding agent and is connected to pearl bisque, the raw material of rubber layer poidometer by weight is as follows: 75-85 parts of neoprene, 82-100 parts of methyl vinyl silicone rubber, 10-15 parts of high abrasion furnace black, 1-5 parts of hydroxy silicon oil, 5-6 parts of dibutyl sebacate, 3-5 parts of softening agent, 3-6 parts of lead sulfate, 5-10 parts of zinc oxide, 2-10 parts of moisture absorption agent.Due to the use of spill resistant agent and softening agent, make the rubber gloves of preparation that there is better pliability and stickiness；The raw material of rubber layer is neoprene, methyl vinyl silicone rubber, high abrasion furnace black part hydroxy silicon oil, dibutyl sebacate, softening agent, lead sulfate, zinc oxide, moisture absorption agent, so that this rubber gloves has good alkali resistance and water resistance.
Description
Technical field
The present invention relates to water resistance rubber gloves technical field more particularly to a kind of water resistance rubber gloves and its preparation sides
Method.
Background technique
Rubber gloves is in use, it is often necessary to contact with greasy dirt, therefore have higher requirement to water resistance.At present
For, water resistance rubber gloves is prepared in the industry, due to pursuing the water resistance of rubber gloves, will use some pliabilitys and gas permeability
Natively very poor polarity latex (NBR latex) is added the effects of adding vulcanizing agent, crosslinking agent, last gloves system obtained
Product seem very stiff, not soft enough and fitting, poor air permeability, and gloves sweat is difficult that discharge, hand experience are uncomfortable, and wearing is not
It is convenient.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of water resistance rubber gloves proposed
And preparation method thereof.
To achieve the goals above, present invention employs following technical solutions:
A kind of water resistance rubber gloves, comprising: synthetic resin yarn gloves embryo and be attached to the synthetic resin yarn gloves embryo outer surface
Rubber layer, be stained with by bonding agent in the synthetic resin yarn gloves embryo and be connected to pearl bisque, the raw material of the rubber layer is by weighing
It is as follows to measure part poidometer: 75-85 parts of neoprene, 82-100 parts of methyl vinyl silicone rubber, 10-15 parts of high abrasion furnace black, hydroxyl
1-5 parts of base silicone oil, 5-6 parts of dibutyl sebacate, 3-5 parts of softening agent, 3-6 parts of lead sulfate, 5-10 parts of zinc oxide, moisture absorption agent
2-10 parts.
Preferably, calcium oxide is selected in the moisture absorption agent.
Preferably, the rubber layer outer surface is equipped with spill resistant oxidant layer, by the synthetic resin yarn gloves embryo of dipping process, then
It is placed in spill resistant agent dispersing liquid and impregnates with spill resistant agent of adhering, take out after cure drying.
Preferably, the spill resistant agent is one or more of paraffin oil, silicone oil, polyfluoro macromolecular organic compound
Combination.
Preferably, the condition impregnated in the spill resistant agent dispersing liquid is: 38-50 DEG C of temperature, impregnating 10-20 minutes.
Preferably, the softening agent the preparation method comprises the following steps:
A, C5 Petropols, C9 Petropols are placed in container respectively according to the proportion, are warming up to 30-40 DEG C, be mixed equal
After even, methyl anthranilate, naphthenic oil and glycerol are added into mixture, is mixed evenly；
B, ethyl acetate and limonene successively then is being added, is stirring 5-10min, is cooled to room temperature to get softening agent.
Preferably, the parts by weight of each raw material of the softening agent are as follows: 20-25 parts of C5 Petropols, C9 Petropols 8-
13 parts, 10-12 parts of glycerol, 10-13 parts of naphthenic oil, 8-12 parts of methyl anthranilate, 8-15 parts of ethyl acetate, limonene 6-
10 parts.
A kind of preparation method of water resistance rubber gloves, includes the following steps:
S1: being weighed by formula each component, then will after methyl vinyl silicone rubber and neoprene mix, be put into colloidal sol kettle into
The processing of row colloidal sol, obtains mixture A；
S2: mixture A obtained in step S1 is put into kneader and is mediated, high abrasion furnace black, hydroxyl silicon are then sequentially added
Oil, dibutyl sebacate, softening agent, lead sulfate, zinc oxide, moisture absorption agent obtain mixture B after mixing；
S3: mixture B is put into digester, by electrically heated mode, digester is heated to 120 DEG C, in digester
Interior vapor (steam) temperature keeps 1.5h to be reacted at this temperature at 165 DEG C；
S4: synthetic resin yarn gloves embryo is immersed in the rubber cement of mixture B, again by the synthetic resin yarn gloves embryo of dipping process
It is placed in spill resistant agent dispersing liquid and impregnates with spill resistant agent of adhering, take out after cure drying, be finally synthesizing in resin yarn gloves embryo
It is stained with by bonding agent and is connected to pearl bisque.
Compared with prior art, the beneficial effects of the present invention are: a kind of water resistance rubber gloves provided by the invention and its
Preparation method makes the rubber gloves of preparation have better pliability and stickiness due to the use of spill resistant agent and softening agent；
The raw material of rubber layer is neoprene, methyl vinyl silicone rubber, high abrasion furnace black part hydroxy silicon oil, two fourth of decanedioic acid
Ester, softening agent, lead sulfate, zinc oxide, moisture absorption agent, so that this rubber gloves has good alkali resistance and water resistance.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Embodiment 1
A kind of water resistance rubber gloves, comprising: synthetic resin yarn gloves embryo and be attached to the synthetic resin yarn gloves embryo outer surface
Rubber layer, be stained with by bonding agent in the synthetic resin yarn gloves embryo and be connected to pearl bisque, the raw material of the rubber layer is by weighing
It is as follows to measure part poidometer: 75-85 parts of neoprene, 82-100 parts of methyl vinyl silicone rubber, 10-15 parts of high abrasion furnace black, hydroxyl
1-5 parts of base silicone oil, 5-6 parts of dibutyl sebacate, 3-5 parts of softening agent, 3-6 parts of lead sulfate, 5-10 parts of zinc oxide, moisture absorption agent
2-10 parts.
Specifically, calcium oxide is selected in the moisture absorption agent.
Specifically, the rubber layer outer surface is equipped with spill resistant oxidant layer, by the synthetic resin yarn gloves embryo of dipping process, then
It is placed in spill resistant agent dispersing liquid and impregnates with spill resistant agent of adhering, take out after cure drying.
Specifically, the spill resistant agent is one or more of paraffin oil, silicone oil, polyfluoro macromolecular organic compound
Combination.
Specifically, the condition impregnated in the spill resistant agent dispersing liquid is: 38-50 DEG C of temperature, impregnating 10-20 minutes.
Specifically, the softening agent the preparation method comprises the following steps:
A, C5 Petropols, C9 Petropols are placed in container respectively according to the proportion, are warming up to 30-40 DEG C, be mixed equal
After even, methyl anthranilate, naphthenic oil and glycerol are added into mixture, is mixed evenly；
B, ethyl acetate and limonene successively then is being added, is stirring 5-10min, is cooled to room temperature to get softening agent.
Preferably, the parts by weight of each raw material of the softening agent are as follows: 20-25 parts of C5 Petropols, C9 Petropols 8-
13 parts, 10-12 parts of glycerol, 10-13 parts of naphthenic oil, 8-12 parts of methyl anthranilate, 8-15 parts of ethyl acetate, limonene 6-
10 parts.
A kind of preparation method of water resistance rubber gloves, includes the following steps:
S1: being weighed by formula each component, then will after methyl vinyl silicone rubber and neoprene mix, be put into colloidal sol kettle into
The processing of row colloidal sol, obtains mixture A；
S2: mixture A obtained in step S1 is put into kneader and is mediated, high abrasion furnace black, hydroxyl silicon are then sequentially added
Oil, dibutyl sebacate, softening agent, lead sulfate, zinc oxide, moisture absorption agent obtain mixture B after mixing；
S3: mixture B is put into digester, by electrically heated mode, digester is heated to 120 DEG C, in digester
Interior vapor (steam) temperature keeps 1.5h to be reacted at this temperature at 165 DEG C；
S4: synthetic resin yarn gloves embryo is immersed in the rubber cement of mixture B, again by the synthetic resin yarn gloves embryo of dipping process
It is placed in spill resistant agent dispersing liquid and impregnates with spill resistant agent of adhering, take out after cure drying, be finally synthesizing in resin yarn gloves embryo
It is stained with by bonding agent and is connected to pearl bisque.
A kind of water resistance rubber gloves provided by the invention and preparation method thereof, due to making for spill resistant agent and softening agent
With, make preparation rubber gloves have better pliability and stickiness；
The raw material of rubber layer is neoprene, methyl vinyl silicone rubber, high abrasion furnace black part hydroxy silicon oil, two fourth of decanedioic acid
Ester, softening agent, lead sulfate, zinc oxide, moisture absorption agent, so that this rubber gloves has good alkali resistance and water resistance.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of water resistance rubber gloves characterized by comprising synthetic resin yarn gloves embryo and be attached to the synthetic resin yarn
The rubber layer of gloves embryo outer surface, interior be stained with by bonding agent of the synthetic resin yarn gloves embryo are connected to pearl bisque, the rubber
The raw material poidometer by weight of layer is as follows: 75-85 parts of neoprene, 82-100 parts of methyl vinyl silicone rubber, high abrasion furnace
10-15 parts black, 1-5 parts of hydroxy silicon oil, 5-6 parts of dibutyl sebacate, 3-5 parts of softening agent, 3-6 parts of lead sulfate, zinc oxide 5-10
Part, 2-10 parts of moisture absorption agent.
2. a kind of water resistance rubber gloves according to claim 1, it is characterised in that: oxidation is selected in the moisture absorption agent
Calcium.
3. a kind of water resistance rubber gloves according to claim 1, it is characterised in that: the rubber layer outer surface is equipped with anti-
Water-sprinkling oxidant layer by the synthetic resin yarn gloves embryo of dipping process, then is placed in spill resistant agent dispersing liquid and impregnates with spill resistant of adhering
After cure drying is taken out in agent.
4. a kind of water resistance rubber gloves according to claim 3, it is characterised in that: the spill resistant agent be paraffin oil,
The combination of one or more of silicone oil, polyfluoro macromolecular organic compound.
5. a kind of water resistance rubber gloves according to claim 3, it is characterised in that: soaked in the spill resistant agent dispersing liquid
The condition of bubble is: 38-50 DEG C of temperature, impregnating 10-20 minutes.
6. a kind of water resistance rubber gloves according to claim 1, it is characterised in that: the preparation method of the softening agent
Are as follows:
A, C5 Petropols, C9 Petropols are placed in container respectively according to the proportion, are warming up to 30-40 DEG C, be mixed equal
After even, methyl anthranilate, naphthenic oil and glycerol are added into mixture, is mixed evenly；
B, ethyl acetate and limonene successively then is being added, is stirring 5-10min, is cooled to room temperature to get softening agent.
7. a kind of water resistance rubber gloves according to claim 1, it is characterised in that: the weight of each raw material of the softening agent
It is as follows to measure part: 20-25 parts of C5 Petropols, 8-13 parts of C9 Petropols, 10-12 parts of glycerol, 10-13 parts of naphthenic oil, adjacent amino
8-12 parts of methyl benzoate, 8-15 parts of ethyl acetate, 6-10 parts of limonene.
8. a kind of preparation method of water resistance rubber gloves described in claim 1, characterized by the following steps:
S1: being weighed by formula each component, then will after methyl vinyl silicone rubber and neoprene mix, be put into colloidal sol kettle into
The processing of row colloidal sol, obtains mixture A；
S2: mixture A obtained in step S1 is put into kneader and is mediated, high abrasion furnace black, hydroxyl silicon are then sequentially added
Oil, dibutyl sebacate, softening agent, lead sulfate, zinc oxide, moisture absorption agent obtain mixture B after mixing；
S3: mixture B is put into digester, by electrically heated mode, digester is heated to 120 DEG C, in digester
Interior vapor (steam) temperature keeps 1.5h to be reacted at this temperature at 165 DEG C；
S4: synthetic resin yarn gloves embryo is immersed in the rubber cement of mixture B, again by the synthetic resin yarn gloves embryo of dipping process
It is placed in spill resistant agent dispersing liquid and impregnates with spill resistant agent of adhering, take out after cure drying, be finally synthesizing in resin yarn gloves embryo
It is stained with by bonding agent and is connected to pearl bisque.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811483941.XA CN109608885A (en) | 2018-12-06 | 2018-12-06 | A kind of water resistance rubber gloves and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811483941.XA CN109608885A (en) | 2018-12-06 | 2018-12-06 | A kind of water resistance rubber gloves and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109608885A true CN109608885A (en) | 2019-04-12 |
Family
ID=66006502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811483941.XA Pending CN109608885A (en) | 2018-12-06 | 2018-12-06 | A kind of water resistance rubber gloves and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN109608885A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101416795A (en) * | 2007-10-27 | 2009-04-29 | Sar控股国际有限公司 | Silicone steamer |
| CN108276731A (en) * | 2017-12-22 | 2018-07-13 | 江苏国立化工科技有限公司 | Environment-friendly long-acting rubber softener and preparation method thereof |
| CN108442128A (en) * | 2018-03-08 | 2018-08-24 | 山东星宇手套有限公司 | A kind of water resistance rubber gloves and preparation method thereof |
-
2018
- 2018-12-06 CN CN201811483941.XA patent/CN109608885A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101416795A (en) * | 2007-10-27 | 2009-04-29 | Sar控股国际有限公司 | Silicone steamer |
| CN108276731A (en) * | 2017-12-22 | 2018-07-13 | 江苏国立化工科技有限公司 | Environment-friendly long-acting rubber softener and preparation method thereof |
| CN108442128A (en) * | 2018-03-08 | 2018-08-24 | 山东星宇手套有限公司 | A kind of water resistance rubber gloves and preparation method thereof |
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Application publication date: 20190412 |
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