CN109608804A - A kind of fire-retardant AES-PVC composite material - Google Patents
A kind of fire-retardant AES-PVC composite material Download PDFInfo
- Publication number
- CN109608804A CN109608804A CN201811437757.1A CN201811437757A CN109608804A CN 109608804 A CN109608804 A CN 109608804A CN 201811437757 A CN201811437757 A CN 201811437757A CN 109608804 A CN109608804 A CN 109608804A
- Authority
- CN
- China
- Prior art keywords
- parts
- fire
- aes
- retardant
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of fire-retardant AES-PVC composite material, parts by weight are composed of the following components: AES is 70 parts -80 parts；PVC is 10 parts -20 parts；Silicone resin is 5 parts -10 parts；Fire retardant is 14 parts -16 parts；Compatilizer is 0.2 part -0.4 part；Antioxidant is 0.1 part -0.5 part.The technical program is compatilizer by glass fibre, when material is by load, AES-PVC can quickly and effectively be transmitted to load on glass fibre, the network skeleton structure effectively evenly dispersed load formed by glass fibre, it reduces matrix resin and bears load, improve the mechanical property of entire composite material.PVC itself has certain anti-flammability, its addition can reduce the requirement of fire retardant, greatly reduces the cost of fire-retardant AES material.
Description
Technical field
The invention belongs to technical field of polymer materials, particularly relate to a kind of fire-retardant AES-PVC composite material.
Background technique
Acrylonitrile-ethylene propylene diene rubber-styrene (AES) is a kind of engineering plastics of high comprehensive performance, and size is steady
Qualitative good, insulating properties is good, and oil resistant, moulding processability is relatively good, but its flame retardant property is bad, and which greatly limits it one
Application on a little fields.
Polyvinyl chloride (PVC) is also a kind of general-purpose plastics of high comprehensive performance, but the flame retardant effect of polyvinyl chloride is not
Good, AES and PVC blend can have the two-fold advantage of engineering plastics and general-purpose plastics, increase the use scope of composite material,
But its fire-retardant can limit it in the application in some fields.
Summary of the invention
The object of the present invention is to provide a kind of fire-retardant AES-PVC composite materials, total to solve AES and PVC in the prior art
The low problem of the flame retardant property of mixed composite material.
The present invention is achieved by the following technical solutions:
A kind of fire-retardant AES-PVC composite material, composed of the following components by weight:
The fire retardant is phosphorus-nitrogen containing flame retardant WRO1 or WRO2.
The compatilizer is the alkali-free glass fibre of Silane coupling agent KH550 processing.
The antioxidant is three (2,4- di-t-butyl) phenyl-phosphites, four [β-(3,5- di-tert-butyl-hydroxy phenyl)
Propionic acid] pentaerythritol ester or 1,3,5- trimethyls -2,4, one of 6- (3,5- di-t-butyl -4- hydroxyphenylmethyl) benzene or one
Kind combination of the above.
Any of the above-described flame-retarding high performance AES-PVC composite material and preparation method thereof, comprising the following steps:
1) 70 parts -80 parts of AES, 10 parts -20 parts of PVC, 5 parts of -10 parts of silicone resin, 14 parts -16 parts fire-retardant are weighed
Agent, 0.2 part -0.4 part of compatilizer and 0.1 part -0.5 part of antioxidant are mixed and stirred for uniformly, obtaining mixture；
2) by mixture extruding pelletization obtained in step 1) to get arrive AES-PVC composite material.
The step 2) specifically:
Mixture obtained in step 1) is put into extruding pelletization in the hopper of double screw extruder, wherein described double
Screw extruder includes six humidity provinces sequentially arranged, 150~170 DEG C of area's temperature, two 180~200 DEG C of area's temperature, 3rd area
180~200 DEG C of temperature, four 180~200 DEG C of area's temperature, five 180~200 DEG C of area's temperature, six 180~200 DEG C of area's temperature, head
180~200 DEG C of temperature；200~260r/min of screw speed.
The beneficial effects of the present invention are:
PVC itself has certain anti-flammability, its addition can reduce the requirement of fire retardant, greatly reduces fire-retardant
The cost of AES material.
PVC is easily decomposed under hot conditions, it should be noted that the processing temperature range of scheme is narrow, and strict control is needed to add
Work temperature.
Specific embodiment
Carry out the technical solution that the present invention will be described in detail by the following examples, embodiment below is merely exemplary, only
It can be used to explanation and illustration technical solution of the present invention, and be not to be construed as the limitation to technical solution of the present invention.
1) 70 parts of AES, 10 parts of PVC, 5 parts of silicone resin, 14 parts of WRO1,0.2 part of glass fibre, 0.1 part are weighed
Irganox1010 is mixed and stirred for uniformly, obtaining mixture.
2) by mixture extruding pelletization obtained in step 1) to get arrive AES-PVC composite material.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and the temperature of the first humidity province is 150 DEG C, the
The temperature of two humidity provinces is 180 DEG C, and the temperature of third humidity province is 180 DEG C, and the temperature of the 4th humidity province is 180 DEG C, the 5th temperature
The temperature for spending area is 180 DEG C, and the temperature of the 6th humidity province is 180 DEG C, and the head temperature of double screw extruder is 180 DEG C, screw rod
Revolving speed is 200r/min.
Embodiment 2
1) 80 parts of AES, 20 parts of PVC, 10 parts of silicone resin, 16 parts of WRO2,0.4 part of glass fibre, 0.1 part are weighed
Irganox168,0.2 part of Irganox1010,0.2 part of Irganox1330 are mixed and stirred for uniformly, obtaining mixture.
2) by mixture extruding pelletization obtained in step 1) to get arrive AES-PVC composite material.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and the temperature of the first humidity province is 170 DEG C, the
The temperature of two humidity provinces is 200 DEG C, and the temperature of third humidity province is 200 DEG C, and the temperature of the 4th humidity province is 200 DEG C, the 5th temperature
The temperature for spending area is 200 DEG C, and the temperature of the 6th humidity province is 200 DEG C, and the head temperature of double screw extruder is 200 DEG C, screw rod
Revolving speed is 260r/min.
Embodiment 3
1) 75 parts of AES, 15 parts of PVC, 8 parts of silicone resin, 15 parts of WRO1,0.3 part of glass fibre, 0.1 part are weighed
Irganox168,0.2 part of Irganox1010 are mixed and stirred for uniformly, obtaining mixture.
2) by mixture extruding pelletization obtained in step 1) to get arrive AES-PVC composite material.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and the temperature of the first humidity province is 160 DEG C, the
The temperature of two humidity provinces is 190 DEG C, and the temperature of third humidity province is 190 DEG C, and the temperature of the 4th humidity province is 190 DEG C, the 5th temperature
The temperature for spending area is 190 DEG C, and the temperature of the 6th humidity province is 190 DEG C, and the head temperature of double screw extruder is 190 DEG C, screw rod
Revolving speed is 230r/min.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And deformation, the scope of the present invention are extremely equally limited by appended claims.
Claims (4)
1. a kind of fire-retardant AES-PVC composite material, it is characterised in that: composed of the following components by weight:
2. fire-retardant AES-PVC composite material according to claim 1, it is characterised in that: the fire retardant is the resistance of phosphorus nitrogen system
Fire agent WRO1 or WRO2.
3. fire-retardant energy AES-PVC composite material according to claim 1, it is characterised in that: the compatilizer is silane idol
Join the alkali-free glass fibre of agent KH550 processing.
4. fire-retardant AES-PVC composite material according to claim 1, it is characterised in that: the antioxidant is three (2,4- bis-
Tert-butyl) phenyl-phosphite, four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters or 1,3,5- front threes
Base -2,4, one of 6- (3,5- di-t-butyl -4- hydroxyphenylmethyl) benzene or more than one combinations.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811437757.1A CN109608804A (en) | 2018-11-27 | 2018-11-27 | A kind of fire-retardant AES-PVC composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811437757.1A CN109608804A (en) | 2018-11-27 | 2018-11-27 | A kind of fire-retardant AES-PVC composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109608804A true CN109608804A (en) | 2019-04-12 |
Family
ID=66006402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811437757.1A Withdrawn CN109608804A (en) | 2018-11-27 | 2018-11-27 | A kind of fire-retardant AES-PVC composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109608804A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103740025A (en) * | 2013-12-27 | 2014-04-23 | 安徽科聚新材料有限公司 | Glass fiber reinforced inflaming retarding AES (Acrylonitrile-Ethylene propylene diene monomer-Styrene) composite material and preparation method thereof |
| CN106751341A (en) * | 2016-12-14 | 2017-05-31 | 安徽江淮汽车集团股份有限公司 | A kind of flame-retarding high performance AES composite material and preparation method thereof |
| CN106928623A (en) * | 2017-03-20 | 2017-07-07 | 安徽江淮汽车集团股份有限公司 | A kind of flame-retarding high performance AES PVC composites and preparation method thereof |
| CN107254133A (en) * | 2017-07-21 | 2017-10-17 | 安徽江淮汽车集团股份有限公司 | A kind of fire-retardant AES composite material of high tenacity and preparation method thereof |
| CN108752832A (en) * | 2018-06-20 | 2018-11-06 | 安徽江淮汽车集团股份有限公司 | A kind of AES-PVC composite material and preparation methods |
-
2018
- 2018-11-27 CN CN201811437757.1A patent/CN109608804A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103740025A (en) * | 2013-12-27 | 2014-04-23 | 安徽科聚新材料有限公司 | Glass fiber reinforced inflaming retarding AES (Acrylonitrile-Ethylene propylene diene monomer-Styrene) composite material and preparation method thereof |
| CN106751341A (en) * | 2016-12-14 | 2017-05-31 | 安徽江淮汽车集团股份有限公司 | A kind of flame-retarding high performance AES composite material and preparation method thereof |
| CN106928623A (en) * | 2017-03-20 | 2017-07-07 | 安徽江淮汽车集团股份有限公司 | A kind of flame-retarding high performance AES PVC composites and preparation method thereof |
| CN107254133A (en) * | 2017-07-21 | 2017-10-17 | 安徽江淮汽车集团股份有限公司 | A kind of fire-retardant AES composite material of high tenacity and preparation method thereof |
| CN108752832A (en) * | 2018-06-20 | 2018-11-06 | 安徽江淮汽车集团股份有限公司 | A kind of AES-PVC composite material and preparation methods |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108102213B (en) | Flame-retardant polypropylene composition and preparation method and application thereof | |
| CN102337029B (en) | Halogen-free flame-retardant nylon 66 composite material and preparation method thereof | |
| CN102850650A (en) | Basalt fiber reinforced polypropylene composite material and preparation method thereof | |
| CN103849142A (en) | Lightweight flame retardant modified polyamide material and its preparation method | |
| CN104086970A (en) | High-efficiency bromine-silicon flame-retardant weather-resistant polycarbonate composite material and preparation method thereof | |
| CN103881221A (en) | Flame-retardant and antistatic nylon composite material and preparation method thereof | |
| CN109957169A (en) | A kind of flame-retardant organosilane cross-linked poly-ethylene Insulation Material and its preparation method and application | |
| CN103740038B (en) | High glaze halogen-free flame retardant ABS material and preparation method thereof | |
| CN103059539A (en) | High-performance halogen-free flame-retardant PC/ABS alloy material and preparation process thereof | |
| CN103146058B (en) | Toughened polypropylene composite material and preparation method thereof | |
| CN106967295A (en) | A kind of halogen-free flame-proof antistatic nylon composite materials and preparation method thereof | |
| CN103396645B (en) | A kind of flame retardant plastics and preparation method thereof | |
| CN107057258A (en) | It is a kind of for sheathing material of LCD TV capacitor and preparation method thereof | |
| CN109735046A (en) | Fire-retardant heat-staple ABS composite material of enhancing of one kind and preparation method thereof | |
| CN103694695B (en) | A kind of fiber glass reinforced halogen-free flame retardant PA6/PS alloy material and preparation method thereof | |
| CN105385118A (en) | High-CTI-value flame-retardant and reinforced PBT (polybutylene terephthalate) composite material | |
| CN102702672A (en) | High-light-transmission high-light-shading ABS (acrylonitrile butadiene styrene) material and preparation method thereof | |
| CN109608804A (en) | A kind of fire-retardant AES-PVC composite material | |
| CN103709712A (en) | Heat-resistant hydrolysis-resistant PC/ASA (polycarbonate/acrylonitrile-styrene-acrylate graft copolymer) alloy material | |
| CN104672612B (en) | Flame retardant polypropylene material and preparation method thereof | |
| CN106366686A (en) | Plastic wood material for manufacturing flame retardant door plank and preparation method of plastic wood | |
| CN109666254A (en) | A kind of high tenacity AES composite material | |
| CN104387742A (en) | High-temperature-resistant PC composite material | |
| CN113773628A (en) | Flame-retardant PC composition and preparation method thereof | |
| CN104672839A (en) | Flame-retardant toughening type PC composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190412 |
|
| WW01 | Invention patent application withdrawn after publication |