CN109608717A - 一种安全鞋鞋头的配方 - Google Patents

一种安全鞋鞋头的配方 Download PDF

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CN109608717A
CN109608717A CN201811613518.7A CN201811613518A CN109608717A CN 109608717 A CN109608717 A CN 109608717A CN 201811613518 A CN201811613518 A CN 201811613518A CN 109608717 A CN109608717 A CN 109608717A
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parts
agent
antioxidant
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safe shoe
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赵伟
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TIANJIN TIANXING KESHENG LEATHER PRODUCTS Co Ltd
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    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00Footwear characterised by the material
    • A43B1/10Footwear characterised by the material made of rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0095Mixtures of at least two compounding ingredients belonging to different one-dot groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2411/00Characterised by the use of homopolymers or copolymers of chloroprene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明是一种安全鞋鞋头的配方,包括丁腈橡胶50份;氯丁橡胶40份;氟橡胶20‑25份;古马隆树脂15‑26份;丙烯酸树脂15‑25份;聚氧乙烯醚抗静电剂2.3‑4.8份;抗氧化剂1.5‑3.7份;补强剂2‑4份;耐磨剂EVA3.2‑4份;防老剂2.3‑5.4份;促进剂NS2.6‑4.7份;氧化锌3份;聚氨酯发泡剂2份;增塑剂DOP4.5‑6.8份;滑石粉6.5‑8份;钛白粉1.2‑3份。本发明的安全鞋鞋头具有很好的耐酸碱性、耐热性、耐油性、绝缘性、防静电性能和强度,适于多种环境穿着。

Description

一种安全鞋鞋头的配方
技术领域
本发明涉及一种安全鞋制造技术领域,尤其涉及一种安全鞋鞋头的配方。
背景技术
鞋子是以皮、布、木、草、塑料丝等为材料制作的穿在脚上、走路时着地的东西,鞋子有着悠久的发展史。大约在5000多年前的仰韶文化时期,就出现了兽皮缝制的最原始的鞋。鞋子是人保护脚不受伤的工具。最早人们为了在特殊情况下不让脚难受或者受伤,就发明了毛皮鞋子。鞋子发展到现在,就形成了这个样子。各种样式功能的鞋子随处可见。随着我国制鞋技术的不断进步以及全球鞋用材料的日益更新,安全鞋类品种逐步多样化,高档化。国内安全鞋的设计及技术要求开始与国外逐步接轨,一般要求安全鞋具有良好的耐油、防静电、防刺穿、耐酸碱及绝缘等性能。因此,需要提供一种具有优良性能的安全鞋头。
发明内容
本发明旨在为制作安全鞋鞋头给予一定的指导,而提供一种安全鞋鞋头的配方。
本发明为实现上述目的,采用以下技术方案:
一种安全鞋鞋头的配方,其组成成分及其质量份数分别为:
丁腈橡胶50份;
氯丁橡胶40份;
氟橡胶20-25份;
古马隆树脂15-26份;
丙烯酸树脂15-25份;
聚氧乙烯醚抗静电剂2.3-4.8份;
抗氧化剂1.5-3.7份;
补强剂2-4份;
耐磨剂EVA3.2-4份;
防老剂2.3-5.4份;
促进剂NS2.6-4.7份;
氧化锌3份;
聚氨酯发泡剂2份;
增塑剂DOP4.5-6.8份;
滑石粉6.5-8份;
钛白粉1.2-3份。
特别的,上述安全鞋鞋头的配方,其组成成分及其质量份数分别为:
丁腈橡胶50份;
氯丁橡胶40份;
氟橡胶22份;
古马隆树脂17份;
丙烯酸树脂20份;
聚氧乙烯醚抗静电剂3.2份;
抗氧化剂2.8份;
补强剂2.6份;
耐磨剂EVA3.5份;
防老剂2.9份;
促进剂NS3.5份;
氧化锌3份;
聚氨酯发泡剂2份;
增塑剂DOP5份;
滑石粉7份;
钛白粉1.8份。
所述抗氧化剂为抗氧剂1076。
所述补强剂为炭黑。
所述防老剂为防老剂4010NA。
本发明的有益效果是:本发明的安全鞋鞋头具有很好的耐酸碱性、耐热性、耐油性、绝缘性和防静电性能,而且鞋头具有很好的强度,适于多种环境穿着。
具体实施方式
下面结合实施例对本发明作进一步说明:
具体实施例1:
一种安全鞋鞋头的配方,其组成成分及其质量份数分别为:
丁腈橡胶50份;
氯丁橡胶40份;
氟橡胶22份;
古马隆树脂17份;
丙烯酸树脂20份;
聚氧乙烯醚抗静电剂3.2份;
抗氧化剂2.8份;
补强剂2.6份;
耐磨剂EVA3.5份;
防老剂2.9份;
促进剂NS3.5份;
氧化锌3份;
聚氨酯发泡剂2份;
增塑剂DOP5份;
滑石粉7份;
钛白粉1.8份。
所述抗氧化剂为抗氧剂1076。
所述补强剂为炭黑。
所述防老剂为防老剂4010NA。
具体实施例2:
一种安全鞋鞋头的配方,其组成成分及其质量份数分别为:
丁腈橡胶50份;
氯丁橡胶40份;
氟橡胶25份;
古马隆树脂26份;
丙烯酸树脂15份;
聚氧乙烯醚抗静电剂2.3份;
抗氧化剂3.7份;
补强剂2份;
耐磨剂EVA4份;
防老剂2.3份;
促进剂NS4.7份;
氧化锌3份;
聚氨酯发泡剂2份;
增塑剂DOP6.8份;
滑石粉6.5份;
钛白粉3份。
所述抗氧化剂为抗氧剂1076。
所述补强剂为炭黑。
所述防老剂为防老剂4010NA。
具体实施例3:
一种安全鞋鞋头的配方,其组成成分及其质量份数分别为:
丁腈橡胶50份;
氯丁橡胶40份;
氟橡胶20份;
古马隆树脂15份;
丙烯酸树脂25份;
聚氧乙烯醚抗静电剂4.8份;
抗氧化剂1.5份;
补强剂4份;
耐磨剂EVA3.2份;
防老剂5.4份;
促进剂NS2.6份;
氧化锌3份;
聚氨酯发泡剂2份;
增塑剂DOP4.5份;
滑石粉8份;
钛白粉1.2份。
所述抗氧化剂为抗氧剂1076。
所述补强剂为炭黑。
所述防老剂为防老剂4010NA。
本发明的安全鞋鞋头加入了丁腈橡胶和氟橡胶,使安全鞋鞋头具有很好的耐酸碱性和耐热性,而且氟橡胶的加入使鞋头具有很好的耐油性,古马隆树脂使安全鞋鞋头具有很好的绝缘性,聚氧乙烯醚抗静电剂使鞋头具有防静电性能,炭黑和耐磨剂EVA增强了鞋头的强度,本安全鞋鞋头适用于多种环境穿着。
上面对本发明进行了示例性描述,显然本发明具体实现并不受上述方式的限制,只要采用了本发明的方法构思和技术方案进行的各种改进,或未经改进直接应用于其它场合的,均在本发明的保护范围之内。

Claims (5)

1.一种安全鞋鞋头的配方,其特征在于,其组成成分及其质量份数分别为:
丁腈橡胶50份;氯丁橡胶40份;氟橡胶20-25份;古马隆树脂15-26份;丙烯酸树脂15-25份;聚氧乙烯醚抗静电剂2.3-4.8份;抗氧化剂1.5-3.7份;补强剂2-4份;耐磨剂EVA3.2-4份;防老剂2.3-5.4份;促进剂NS2.6-4.7份;氧化锌3份;聚氨酯发泡剂2份;增塑剂DOP4.5-6.8份;滑石粉6.5-8份;钛白粉1.2-3份。
2.根据权利要求1所述的一种安全鞋鞋头的配方,其特征在于,其组成成分及其质量份数分别为:
丁腈橡胶50份;氯丁橡胶40份;氟橡胶22份;古马隆树脂17份;丙烯酸树脂20份;聚氧乙烯醚抗静电剂3.2份;抗氧化剂2.8份;补强剂2.6份;耐磨剂EVA3.5份;防老剂4010NA2.9份;促进剂NS3.5份;氧化锌3份;聚氨酯发泡剂2份;增塑剂DOP5份;滑石粉7份;钛白粉1.8份。
3.根据权利要求1所述的一种安全鞋鞋头的配方,其特征在于,所述抗氧化剂为抗氧剂1076。
4.根据权利要求1所述的一种安全鞋鞋头的配方,其特征在于,所述补强剂为炭黑。
5.根据权利要求1所述的一种安全鞋鞋头的配方,其特征在于,所述防老剂为防老剂4010NA。
CN201811613518.7A 2018-12-27 2018-12-27 一种安全鞋鞋头的配方 Pending CN109608717A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111909440A (zh) * 2020-07-29 2020-11-10 丁国南 一种耐高温eva发泡鞋及其制备方法
CN114209122A (zh) * 2021-12-07 2022-03-22 上海安瑞达实业有限公司 一种耐酸碱耐高温橡胶鞋底及安全鞋的制备工艺

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111909440A (zh) * 2020-07-29 2020-11-10 丁国南 一种耐高温eva发泡鞋及其制备方法
CN114209122A (zh) * 2021-12-07 2022-03-22 上海安瑞达实业有限公司 一种耐酸碱耐高温橡胶鞋底及安全鞋的制备工艺

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Application publication date: 20190412