CN109608092A - Friction material and preparation method thereof for making automobile brake lining plate - Google Patents

Friction material and preparation method thereof for making automobile brake lining plate Download PDF

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Publication number
CN109608092A
CN109608092A CN201910047713.6A CN201910047713A CN109608092A CN 109608092 A CN109608092 A CN 109608092A CN 201910047713 A CN201910047713 A CN 201910047713A CN 109608092 A CN109608092 A CN 109608092A
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CN
China
Prior art keywords
parts
friction material
brake lining
powder
hot pressing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910047713.6A
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Chinese (zh)
Inventor
谢黔川
王丹膺
张仁才
邓勇
陈金春
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Chongqing Hongyu Friction Products Co Ltd
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Chongqing Hongyu Friction Products Co Ltd
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Priority to CN201910047713.6A priority Critical patent/CN109608092A/en
Publication of CN109608092A publication Critical patent/CN109608092A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/122Phenol-formaldehyde condensation polymers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/02Composition of linings ; Methods of manufacturing
    • F16D69/027Compositions based on metals or inorganic oxides
    • F16D69/028Compositions based on metals or inorganic oxides containing fibres
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00362Friction materials, e.g. used as brake linings, anti-skid materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0082Production methods therefor
    • F16D2200/0086Moulding materials together by application of heat and pressure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Braking Arrangements (AREA)

Abstract

The present invention provides a kind of for making the friction material of automobile brake lining plate, it is characterised in that: the raw material components and parts by weight that the friction material includes are as follows: 1-4 parts of Teflon powder, 7-15 parts of nitrile rubber modified phenolic resin, 2-7 parts of aramid fiber, 4-8 parts of vermiculite power, 4-10 parts of calcium hydroxide, 15-30 parts of barium sulfate, 3-0 parts of red copper fiber, 7-15 parts of graphite, 3-10 parts of rubber powder, 1-6 parts of zirconium silicate, 15-30 parts of potassium titanate, 0.5-2 parts of aluminium oxide.Said components are added in high speed plow harrow batch mixer and are uniformly mixed, is fitted into mold and carries out hot pressing, finally 170 DEG C is heated to from room temperature in an oven, constant heatingrate 3 hours, keeps the temperature 5 hours at 170 DEG C;It is cooled to come out of the stove lower than 80 DEG C with oven temperature and brake lining can be obtained.The brake lining produced using raw material of the present invention and method can effectively be avoided vehicle in the locking of rainwater weather running vehicle wheel, the generation of vehicle whipping, the installation accident such as tumble, improve the security performance of vehicle.

Description

Friction material and preparation method thereof for making automobile brake lining plate
Technical field
The present invention relates to field of automobile, especially a kind of friction material for making automobile brake lining plate and Preparation method.
Background technique
In daily life, we are often it can be found that in humidity or have a small amount of water between the contact surface of two opposite slidings It is bigger than frictional force under conditions of being completely dried under conditions of point, such as: go friction glass that can feel when our hand is very dry Smoother is obtained, goes friction glass that can feel very jerky when hand is perspired or has a small amount of moisture.In automotive brake, especially There is also this phenomenons in the braking process of drum brake, in general, the vehicle using drum brake is travelled in dry pavement When can normal retarding braking, once travelled in the rainy day, the case where wheel lock up when being easy for braking, vehicle whipping.Invention People by for a long time observe and the study found that when vehicle under conditions of splashing on rainy day or road surface slippery situation, water when driving, brake It has a small amount of moisture between brake lining and brake drum to immerse but will not be completely sunk in the water, at this point, brake lining is in State semi-moist immerses a small amount of moisture between the hole of friction material but is unlikely to form moisture film between rubbing surface, due to portion Point friction material softens so that the coefficient of friction of friction material becomes larger, the rubbing surface of brake when eventually leading to vehicle braking Between frictional force become larger suddenly, braking moment increases extremely, and wheel shifts to an earlier date locking, gently then generates whipping, heavy then cause to overturn Accident seriously jeopardizes driver and passenger's safety.
Summary of the invention
Aiming at the problem that background technique, the present invention provides a kind of for making the friction material and its system of automobile brake lining plate Preparation Method, to solve in the prior art, automobile is travelled in rainwater weather, and the brake lining of brake is led under the conditions of being in semi-moist Moment of friction is caused to increase extremely, to cause unsafe problem such as wheel of vehicle locking, whipping.
To achieve the purpose of the present invention, the present invention provides a kind of for making the friction material of automobile brake lining plate, It is characterized in that: the raw material components and parts by weight that the friction material includes are as follows: 1-4 parts of Teflon powder, acrylonitrile butadiene rubber modified phenol 7-15 parts of urea formaldehyde, 2-7 parts of aramid fiber, 4-8 parts of vermiculite power, 4-10 parts of calcium hydroxide, 15-30 parts of barium sulfate, red copper fiber 3-0 parts, 7-15 parts of graphite, 3-10 parts of rubber powder, 1-6 parts of zirconium silicate, 15-30 parts of potassium titanate, 0.5-2 parts of aluminium oxide.
The present invention also provides a kind of for making the preparation method of the friction material of automobile brake lining plate, the friction material The raw material components and parts by weight that material includes are as follows: 1-4 parts of Teflon powder, 7-15 parts of nitrile rubber modified phenolic resin, aramid fiber is fine 2-7 parts of dimension, 4-8 parts of vermiculite power, 4-10 parts of calcium hydroxide, 15-30 parts of barium sulfate, 3-0 parts of red copper fiber, 7-15 parts of graphite, rubber 3-10 parts of rubber powder, 1-6 parts of zirconium silicate, 15-30 parts of potassium titanate, 0.5-2 parts of aluminium oxide;It is characterized by: the preparation method packet Include following steps:
It is S1, Teflon powder, Si modification phenolic resin, aramid fiber, vermiculite power, calcium hydroxide, barium sulfate, red copper is fine Dimension, graphite, rubber powder, zirconium silicate, potassium titanate, aluminium oxide, which are added to be uniformly mixed in high speed plow harrow batch mixer, obtains mixing;
S2, by the step S1 mixing obtained be fitted into mold carry out hot pressing obtain compacting crude product, hot pressing temperature be 155 DEG C ± 5 DEG C, hot pressing pressure 150kg/cm2, hot pressing time is ± 5 seconds 300 seconds;
S3, compacting crude product is heat-treated according to the following steps:
1) compacting crude product is put into baking oven from room temperature and is heated to 170 DEG C, when heating at the uniform velocity heats up, and the heating-up time is 3 small When, 5 hours are kept the temperature at 170 DEG C;
2) 80 DEG C are cooled in baking oven hereinafter, coming out of the stove.
The concrete condition of each raw material component is as follows in the present invention:
Teflon powder is the powder of polytetrafluoroethylene (PTFE), and molecular weight is light, Yi Tianjia, also with no self-coagulation, without quiet Electrical effect, intermiscibility are good, molecular weight is low, good dispersion, self-lubrication are high.
Nitrile rubber modified phenolic resin is to be made modified by the functional group of nitrile rubber come phenol-formaldehyde resin modified Phenolic resin has preferable mobility and flexibility.
Aramid fiber full name is poly- phenyl-diformyl phenylenediamine, have superhigh intensity, high-modulus and high temperature resistant, acid-fast alkali-proof, The excellent performances such as light-weight, insulation, anti-aging, life cycle length, can effectively increase brake block matrix strength.
Vermiculite power is by generating when certain granite hydration, and crystal structure is monoclinic system, in terms of its shape Like mica, belong to silicate, be a kind of natural, inorganic, nontoxic minerals, there is preferable heat-insulated, sound insulation and fire resistance, The noise generated when can effectively reduce brake.
The pH value that brake block matrix can be improved after calcium hydroxide addition, makes automobile brake lining plate in alkaline state, slows down The corrosion rate of automobile brake lining plate.
Barium sulfate is used as that filler is nontoxic, be insoluble in water, insoluble in acid, plays reinforcing effect, can enhance automobile brake lining plate Anti-aging property and weatherability, so that its non-aging is become fragile.
The conductivity of heat that automobile brake lining plate can be improved after the addition of red copper fiber can quickly absorb the heat that braking generates, and prevent Only friction surface temperature steeply rises.
Graphite has good chemical stability, acidproof, alkaline-resisting and organic solvent-resistant the corrosion of energy, due to its spy at normal temperature Some layer structures make it have preferable lubricity, can effectively adjust the coefficient of friction of automobile brake lining plate.
Rubber powder is nitrile rubber powder, and brake block hardness can suitably be adjusted by adding the component, improves the comfortable of braking Property.
Zirconium silicate intensity is high, and hardness is high, wearability is good, fusing point is high, can effectively improve automobile brake lining plate after addition High temperature antifading.
Potassium titanate can not only greatly improve braking quality (high-temperature stability is superior), and can reduce brake noise, Significantly improve feel, the service life for greatly improving automobile brake lining plate etc. when touching on the brake pedal.
Aluminium oxide is the white solid for being insoluble in water, odorless, tasteless, quality is extremely hard, and production is adjusted by adding the component The coefficient of friction of product reaches the coefficient of friction of design.
Inventor is by research and test discovery, since nitrile rubber modified phenolic resin is than phenolic resin mobility Good, the compactness that phenolic resin and other components material can be made to be bonded is more preferable, and the hole between friction material is reduced, friction material Material substantially reduces the absorptivity of moisture, to substantially reduce influence of the moisture to the coefficient of friction of friction material;On the other hand, Due to Teflon powder self-lubrication with higher, and influenced by moisture it is small, after Teflon powder is added in friction material, even if Friction material, which absorbs a small amount of moisture, makes the coefficient of friction of some materials become larger, but due to the self-lubrication of Teflon, can be obvious The coefficient of friction of friction material is adjusted, the SimMan universal patient simulator of friction material can be also stably held in normal range (NR), Bu Huiyi Often increase;Inventor also found that Teflon powder and resin especially nitrile rubber modified phenolic resin compatibility are very good, energy The advantages of effectively playing above two material;Be added above two material in friction material, and by it is of the present invention match into Row is prepared, while being processed by the method for the invention, and obtained brake pad is used in the brake of vehicle, vehicle is worked as When the brake pad of rainwater weather traveling and brake is in state semi-moist, can effectively be avoided in vehicle braking moderating process The problem of coefficient of friction becomes larger suddenly between rubbing surface, thus prevent due to braking moment extremely rise and cause wheel lock up into And lead to the generation of the dangerous situations such as vehicle whipping, overturning.
Using method of the invention, have below the utility model has the advantages that wheel is effectively prevent to travel and brake in rainwater weather In the process, the brake lining of brake is in situation semi-moist, wheel lock up caused by becoming larger suddenly as braking moment, vehicle Whipping, tumbling etc. threatens the accident generation of driver and passenger's safety, substantially increases the safety of vehicle.
Detailed description of the invention
Detailed description of the invention of the invention is as follows:
Fig. 1 is that the brake lining made to the prior art carries out the braking moment figure of simulating brake test;
Fig. 2 is the braking moment figure that simulating brake test is carried out by the brake lining that the present invention makes.
Specific embodiment
Below with reference to embodiment, the invention will be further described.
In the present embodiment, the friction material for making automobile brake lining plate is prepared in following ratio: Teflon powder 1-4 Part, 7-15 parts of nitrile rubber modified phenolic resin, 2-7 parts of aramid fiber, 4-8 parts of vermiculite power, 4-10 parts of calcium hydroxide, barium sulfate 15-30 parts, 3-0 parts of red copper fiber, 7-15 parts of graphite, 3-10 parts of rubber powder, 1-6 parts of zirconium silicate, 15-30 parts of potassium titanate, oxidation 0.5-2 parts of aluminium.
In the actual production process, consider to take into account product effect and production cost, as prioritization scheme, Teflon powder Granularity is 1400 mesh;Calcium hydroxide is 1500 mesh powder of granularity;The length 3mm of red copper fiber, diameter 0.5mm;Graphite is day Right flakey specification, granularity are 60 mesh;The granularity of rubber powder is 1500 mesh;Aluminium oxide is 1500 mesh powder of granularity.
Specific preparation method the following steps are included:
S1, by Teflon powder, nitrile rubber modified phenolic resin, aramid fiber, vermiculite power, calcium hydroxide, barium sulfate, purple Copper fiber, graphite, rubber powder, zirconium silicate, potassium titanate, aluminium oxide are added in high speed plow harrow batch mixer by raw material proportioning and are uniformly mixed Obtain mixing;
S2, by the step S1 mixing obtained be fitted into mold carry out hot pressing obtain compacting crude product, hot pressing temperature be 155 DEG C ± 5 DEG C, hot pressing pressure 150kg/cm2, hot pressing time is ± 5 seconds 300 seconds;
S3, compacting crude product is heat-treated according to the following steps:
1) compacting crude product is put into baking oven from room temperature and is heated to 170 DEG C, when heating at the uniform velocity heats up, and the heating-up time is 3 small When, 5 hours are kept the temperature at 170 DEG C;
2) 80 DEG C are cooled in baking oven hereinafter, coming out of the stove.
In order to verify the technical effects of the present invention, inventor is made using friction material of the present invention and preparation method Brake lining (for sake of convenience hereinafter referred to as " new brake liner "), and it is existing to pressing by the operating condition on rainy day on bench test machine The brake lining (hereinafter referred to as " old brake lining ") and new brake liner for having technology to make are simulated retardation test, obtain Following result:
The braking moment figure that simulating brake test is carried out to old brake lining as shown in Fig. 1, it can be seen from the figure that In rainy day operating condition, braking moment curve of output is unstable, and braking process end braking torque becomes larger suddenly, usual braking moment More than 700N.m, wheel just will appear the case where locking leads to vehicle whipping, it is clear that it can be seen from the figure that braking moment is Through far beyond 700N.m, it is breakneck that vehicle travels in this case.
Attached drawing 2 is the braking moment figure that simulating brake test is carried out to new brake liner, it can be seen from the figure that in the rainy day Under operating condition, braking moment curve of output is steady, is maintained at 240N.m or so, the case where braking moment increases extremely does not occur, That is to say, it is bright, using the vehicle of this brake lining, wheel can effectively be avoided to embrace in the case where brake lining is in semi-moist The accident generation for extremely leading to vehicle whipping, tumbling.
On the other hand, inventor rubs to new brake liner by the requirement of bis- class friction plate of standard GB/T 5763-2008 It wipes coefficient and wear rate is tested, as a result as shown in the table:
The coefficient of friction and wear rate that can be seen that new brake liner from the data in table are in the model of national Specification In enclosing, meet the technical requirements of bis- class friction plate of GB5763-2008.
Thus illustrate, new brake liner under the conditions of semi-moist can effectively by stable friction factor in the normal range, keep away Exempt from output torque to increase extremely, meanwhile, in dry conditions, the coefficient of friction and wear rate of new brake liner also comply with national mark Standard meets normal use needs.

Claims (2)

1. a kind of for making the friction material of automobile brake lining plate, it is characterised in that: the raw material group that the friction material includes Point and parts by weight are as follows: 1-4 parts of Teflon powder, 7-15 parts of nitrile rubber modified phenolic resin, 2-7 parts of aramid fiber, vermiculite power 4-8 parts, 4-10 parts of calcium hydroxide, 15-30 parts of barium sulfate, 3-0 parts of red copper fiber, 7-15 parts of graphite, 3-10 parts of rubber powder, silicic acid 1-6 parts of zirconium, 15-30 parts of potassium titanate, 0.5-2 parts of aluminium oxide.
2. a kind of for making the preparation method of the friction material of automobile brake lining plate, the raw material components that the friction material includes And parts by weight are as follows: 1-4 parts of Teflon powder, 7-15 parts of nitrile rubber modified phenolic resin, 2-7 parts of aramid fiber, vermiculite power 4-8 Part, 4-10 parts of calcium hydroxide, 15-30 parts of barium sulfate, 3-0 parts of red copper fiber, 7-15 parts of graphite, 3-10 parts of rubber powder, zirconium silicate 1-6 parts, 15-30 parts of potassium titanate, 0.5-2 parts of aluminium oxide;It is characterized by: the preparation method comprises the following steps:
It is S1, Teflon powder, nitrile rubber modified phenolic resin, aramid fiber, vermiculite power, calcium hydroxide, barium sulfate, red copper is fine Dimension, graphite, rubber powder, zirconium silicate, potassium titanate, aluminium oxide, which are added to be uniformly mixed in high speed plow harrow batch mixer, obtains mixing;
S2, by the step S1 mixing obtained be fitted into mold carry out hot pressing obtain compacting crude product, hot pressing temperature be 155 DEG C ± 5 DEG C, Hot pressing pressure is 150kg/cm2, hot pressing time is ± 5 seconds 300 seconds;
S3, compacting crude product is heat-treated according to the following steps:
1) compacting crude product being put into baking oven from room temperature and is heated to 170 DEG C, when heating, at the uniform velocity heats up, and the heating-up time is 3 hours, 170 DEG C keep the temperature 5 hours;
2) 80 DEG C are cooled in baking oven hereinafter, coming out of the stove.
CN201910047713.6A 2019-01-18 2019-01-18 Friction material and preparation method thereof for making automobile brake lining plate Pending CN109608092A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111022534A (en) * 2019-12-17 2020-04-17 重庆红宇摩擦制品有限公司 Friction material for preventing mutual material transfer between brake block and brake disc
CN116813280A (en) * 2023-07-07 2023-09-29 广州兴业混凝土搅拌有限公司 Corrosion-resistant high-fracture-resistance recycled aggregate pervious concrete and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111022534A (en) * 2019-12-17 2020-04-17 重庆红宇摩擦制品有限公司 Friction material for preventing mutual material transfer between brake block and brake disc
CN111022534B (en) * 2019-12-17 2021-05-04 重庆红宇摩擦制品有限公司 Friction material for preventing mutual material transfer between brake block and brake disc
CN116813280A (en) * 2023-07-07 2023-09-29 广州兴业混凝土搅拌有限公司 Corrosion-resistant high-fracture-resistance recycled aggregate pervious concrete and preparation method thereof
CN116813280B (en) * 2023-07-07 2024-05-31 广州兴业混凝土搅拌有限公司 Corrosion-resistant high-fracture-resistance recycled aggregate pervious concrete and preparation method thereof

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