CN102173716B - Analogous ceramic high-temperature resistant friction material and preparation method thereof - Google Patents
Analogous ceramic high-temperature resistant friction material and preparation method thereof Download PDFInfo
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- CN102173716B CN102173716B CN 201110045089 CN201110045089A CN102173716B CN 102173716 B CN102173716 B CN 102173716B CN 201110045089 CN201110045089 CN 201110045089 CN 201110045089 A CN201110045089 A CN 201110045089A CN 102173716 B CN102173716 B CN 102173716B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
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- Ceramic Engineering (AREA)
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Braking Arrangements (AREA)
Abstract
The invention discloses an analogous ceramic high-temperature resistant friction material and a preparation method thereof, which are used for solving the technical problem of poor heat resistance of the traditional friction material. The analogous ceramic high-temperature resistant friction material is prepared by replacing a phenolic resin adhesive in an organically synthesized friction material with an inorganic liquid water-soluble aluminum silicate adhesive, and the heat resistance of the friction material is enhanced because the analogous ceramic high-temperature resistant friction material does not contain organic components. The analogous ceramic high-temperature resistant friction material is not reduced in friction coefficient after being ablated at the high temperature of 600 DEG C; and in addition, the friction material with ceramic characteristics is prepared by discarding a high-temperature sintering process of the traditional ceramic friction material on the aspect of a preparation process and adopting a preparation process of the organically synthesized friction material, thereby the cost is greatly lowered.
Description
Technical field
The present invention relates to a kind of high-temperature resistant friction material, is a kind ceramic high-temperature resistant friction material specifically.The preparation method who also relates to this kind ceramic high-temperature resistant friction material.
Background technique
Along with vehicle to environmental protection, high speed and heavily loaded future development, people have higher requirement to the performance of automobile brake material, particularly when high-temperature brake, stability and the Security of material are most important.At present brake system of car mainly use semimetal friction material, without asbestos organic friction material (NAO), powder metallurgy friction material, ceramic frication material etc.Semimetal friction material, have the simple characteristics of preparation process without asbestos organic friction material, but heat resistance is relatively poor, powder metallurgy friction material, ceramic frication material heat resistance are better, but complicated process of preparation, and cost is high.
Document 1 " patent publication No. is the Chinese patent of CN02119505.6 " discloses a kind of asbestos-free friction material and manufacture method.The composition and ratio of this friction material: resin 10~20%, Iron Ore Powder 5~25%, dead burnt magnesite 1~10%, ferrophosphorus breeze 1~5%, aluminium oxide 1~10%, silica 1~7%, barite 1~20%, wollastonite 1~15%, carbon black 1~8%, calcium carbonate 1~15%, graphite 1~10%, tyre talc 1~10%, vegetable fiber 1~20%, sepiolite 1~20%, Steel Fibre 1~5%, zine stearate 0.1~4%.Manufacturing technique method: raw material is mixed rear 110~130 ℃ of lower preheatings 30 minutes, weighing certain material, to put into mould hot-forming under 165~170 ℃ temperature and 25MPa, 5~20 minutes dwell times, first 140 ℃ of sulfurations 1.5~2 hours, vulcanized 4~8 hours at 165 ℃ again after the pressure release.The characteristics of this class friction material are that the frictional behaviour adjustability is good, and preparation process is simple; But because the restriction of resin glue, heat resistance is relatively poor, when temperature is higher than 300 ℃ heat fade will occur, and wear rate increases, and maximum operation (service) temperature is not higher than 400 ℃.
Document 2 " patent publication No. is the Chinese patent of CN01115331.8 " discloses a kind of ceramic friction material and manufacture method that contains Steel Fibre, the composition of material is: copper powder and glass putty 53~69%, chopped Steel Fibre 10~40%, iron powder 0~10%, inorganic oxide or mineral 3~8%, graphite 5~12%, molybdenum disulfide 0~4%.Manufacturing process is: cold moudling under 150~300MPa pressure, under the reducing gas protection, carry out sintering, 700~920 ℃ of sintering temperatures, pressure 1~2MPa, 3~8 hours time.The resistance to heat of this metalloid ceramic frication material is good, heat fade can not occur under 500 ℃ of operating conditions; But preparation process process conditions more complicated, cost is high.
Summary of the invention
In order to overcome the deficiency of existing friction material poor heat resistance, the invention provides a kind ceramic high-temperature resistant friction material.By replacing phenolic resin or the modified phenolic resin adhesive in the organic synthesis friction material with inorganic binder, preparation class ceramic high-temperature resistant friction material since in the class ceramic high-temperature resistant friction material without organic principle, can improve the heat resistance of friction material.
The invention still further relates to the preparation method of this kind ceramic high-temperature resistant friction material.
The technical solution adopted for the present invention to solve the technical problems: a kind ceramic high-temperature resistant friction material is that 15~30% reinforcing fiber, weight percentage are that 40~59% the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent, weight percentage are that 15~23% friction modifiers and weight percentage are that 10~14% filler is prepared from by weight percentage;
Described reinforcing fiber is several mixtures of appointing of polyacrylonitrile-based carbon fibre, asphalt base carbon fiber, copper fiber, ceramic fiber, glass fibre, non-asbestos deposit fibres or Steel Fibre;
Described friction modifiers is several mixtures of appointing of graphite, molybdenum disulfide, aluminium sesquioxide, silica, silicon carbide, silicon nitride or boron nitride;
Described filler is several mixtures of appointing of zine oxide, barium sulphate, white clay, calcium carbonate, Fluorspar Powder, breeze, chromite, magnesium oxide or diatomite in powder.
A kind of preparation method of above-mentioned class ceramic high-temperature resistant friction material, be characterized in may further comprise the steps: be that 10~14% filler and weight percentage are that 15~23% friction modifiers is added in the blender and mixes with weight percentage, then add weight percentage and be 15~30% reinforcing fiber and mix, to the reinforcing fiber Uniform Dispersion; Adding weight percentage and be 40~59% the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent stirs; Stir simultaneously and utilize the heating resistance collar heating in the stirrer bottom, the top takes blower blowing hot-air forced convection mode to promote moisture evaporation in the mixture to obtain at last powder-granule material; At room temperature powder-granule material is put into the mould compression and moulding, briquetting pressure 20~50MPa, pressurize 10~30 minutes; Blank after the moulding is put into the temperature programmed control air dry oven, open blower, heat-treat.
The invention has the beneficial effects as follows: because the water-soluble silicic acid aluminium of employing inorganic, fluid tackiness agent replaces the phenolic resin adhesive in the organic synthesis friction material, preparation class ceramic high-temperature resistant friction material, owing to without organic principle, having improved the heat resistance of friction material in the class ceramic high-temperature resistant friction material.The class ceramic high-temperature resistant friction material of the present invention preparation, friction factor is undamped after through 600 ℃ of high temperature ablations; Discard tradition aspect the preparation process high-sintering process of ceramic frication material adopts the preparation process of organic synthesis friction material, prepares the friction material with ceramic characteristics, the cost decrease.
Below in conjunction with embodiment the present invention is elaborated.
Embodiment
Embodiment 1: raw material form: filler 20g comprises zine oxide 5g, barium sulphate 5g, white clay 8g, calcium carbonate 2g; Friction modifiers 40g comprises graphite 14g, aluminium sesquioxide 12g, silica 1 4g; Reinforcing fiber 60g comprises polyacrylonitrile-based carbon fibre 15g, ceramic fiber 5g, asphalt base carbon fiber 15g, copper fiber 25g, the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 80g.
Preparation process: at first each filler 20g and friction modifiers 40g are added in the blender and mix, then add reinforcing fiber 60g and mix, to the fiber Uniform Dispersion.Adding the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 80g stirs.Stir simultaneously and utilize the heating resistance collar heating in the stirrer bottom, the top takes blower blowing hot-air forced convection mode to promote moisture evaporation in the mixture, and obtaining at last granularity is that 0.01~1mm and moisture content are 5~10% powder-granule material.At room temperature powder-granule material is put into the mould compression and moulding, briquetting pressure 20MPa, pressurize 30 minutes.Blank is put into the temperature programmed control air dry oven, open blower, heat-treat.
Embodiment 2: raw material form: filler 30g comprises zine oxide 5g, barium sulphate 8g, white clay 5g, calcium carbonate 7g, Fluorspar Powder 5g; Friction modifiers 50g comprises graphite 16g, aluminium sesquioxide 15g, silica 1 9g, and reinforcing fiber 40g comprises polyacrylonitrile-based carbon fibre 15g, glass fibre 10g, Steel Fibre 15g, the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 100g.
Preparation process: at first each filler 30g and friction modifiers 50g are added in the blender and mix, then add reinforcing fiber 40g and mix, to the fiber Uniform Dispersion.Adding the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 100g stirs.Stir simultaneously and utilize the heating resistance collar heating in the stirrer bottom, the top takes blower blowing hot-air forced convection mode to promote moisture evaporation in the mixture, and obtaining at last granularity is that 0.01~1mm and moisture content are 5~10% powder-granule material.At room temperature powder-granule material is put into the mould compression and moulding, briquetting pressure 45MPa, pressurize 15 minutes.Blank is put into the temperature programmed control air dry oven, open blower, heat-treat.
Embodiment 3: raw material form: filler 25g comprises zine oxide 4g, barium sulphate 3g, white clay 6g, calcium carbonate 2g, breeze 4g, chromite 6g; Friction modifiers 30g comprises graphite 9g, aluminium sesquioxide 21g; Reinforcing fiber 30g comprises polyacrylonitrile-based carbon fibre 10g, asphalt base carbon fiber 10g, copper fiber 10g; The water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 120g.
Preparation process: at first each filler 20g and friction modifiers 40g are added in the blender and mix, then add reinforcing fiber 60g and mix, to the fiber Uniform Dispersion.Adding the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 80g stirs.Stir simultaneously and utilize the heating resistance collar heating in the stirrer bottom, the top takes blower blowing hot-air forced convection mode to promote moisture evaporation in the mixture, and obtaining at last granularity is that 0.01~1mm and moisture content are 5~10% powder-granule material.At room temperature powder-granule material is put into the mould compression and moulding, briquetting pressure 50MPa, pressurize 120 minutes.Blank is put into the temperature programmed control air dry oven, open blower, heat-treat.
Embodiment 4: raw material form: filler 25g comprises zine oxide 4g, magnesium oxide 3g, white clay 6g, Fluorspar Powder 2g, diatomite in powder 4g, chromite 6g; Friction modifiers 30g comprises molybdenum disulfide 9g, silicon carbide 7g, silicon nitride 7g, boron nitride 7g; Reinforcing fiber 40g comprises polyacrylonitrile-based carbon fibre 10g, non-asbestos deposit fibres 10g, asphalt base carbon fiber 10g, copper fiber 5g, Steel Fibre 5g; The water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 110g.
Preparation process: at first each filler 20g and friction modifiers 30g are added in the blender and mix, then add reinforcing fiber 40g and mix, to the fiber Uniform Dispersion.Adding the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 110g stirs.Stir simultaneously and utilize the heating resistance collar heating in the stirrer bottom, the top takes blower blowing hot-air forced convection mode to promote moisture evaporation in the mixture, and obtaining at last granularity is that 0.01~1mm and moisture content are 5~10% powder-granule material.At room temperature powder-granule material is put into the mould compression and moulding, briquetting pressure 50MPa, pressurize 10 minutes.Blank is put into the temperature programmed control air dry oven, open blower, heat-treat.
The class ceramic high-temperature resistant friction material frictional behaviour test of the present invention's preparation: the class ceramic high-temperature resistant friction material of preparation is put into Muffle furnace ablated 600 ℃ of ablation temperatures 2 hours.Utilize QDM type speed-adjustable voltage-adjustable dry-type friction material test machine that the friction factor of material before and after ablating is measured, test is carried out according to the GB5763-1998 brake spacer for automobile, and test result sees the following form.
The inventor is in the disclosed process parameters range of technological scheme, and different parameter collocation are all tested, and have all obtained good effect.
Claims (2)
1. a kind ceramic high-temperature resistant friction material is that 30% reinforcing fiber, weight percentage are that 40% the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent, weight percentage are that 20% friction modifiers and weight percentage are that 10% filler is prepared from by weight percentage;
Described reinforcing fiber is several mixtures of appointing of polyacrylonitrile-based carbon fibre, asphalt base carbon fiber, ceramic fiber, glass fibre, non-asbestos deposit fibres or Steel Fibre;
Described friction modifiers is several mixtures of appointing of molybdenum disulfide, aluminium sesquioxide, silica, silicon carbide, silicon nitride or boron nitride;
Described filler is several mixtures of appointing of zine oxide, barium sulphate, white clay, calcium carbonate, Fluorspar Powder, breeze, chromite, magnesium oxide or diatomite in powder.
2. the preparation method of the described class ceramic high-temperature resistant of claim 1 friction material, it is characterized in that may further comprise the steps: be that 10% filler and weight percentage are that 20% friction modifiers is added in the blender and mixes with weight percentage, then add weight percentage and be 30% reinforcing fiber and mix, to the reinforcing fiber Uniform Dispersion; Adding weight percentage and be 40% the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent stirs; Stir simultaneously and utilize the heating resistance collar heating in the stirrer bottom, the top takes blower blowing hot-air forced convection mode to promote moisture evaporation in the mixture to obtain at last powder-granule material; At room temperature powder-granule material is put into the mould compression and moulding, briquetting pressure 20MPa, pressurize 30 minutes; Blank after the moulding is put into the temperature programmed control air dry oven, open blower, heat-treat.
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CN102618216A (en) * | 2012-02-27 | 2012-08-01 | 西北工业大学 | Ceramic-like friction material and preparation method thereof |
CN104087245A (en) * | 2014-07-01 | 2014-10-08 | 北京瑞斯福高新科技股份有限公司 | Friction material for brake-shoe of heavy axle-load wagon and preparation method of friction material |
CN104817819A (en) * | 2015-04-23 | 2015-08-05 | 中国地质大学(武汉) | Spherical silicon oxide filled composite friction material preparation method |
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CN107573897A (en) * | 2017-09-27 | 2018-01-12 | 武汉元丰摩擦材料有限公司 | A kind of high-temperature resistant friction material additive and preparation method thereof |
CN108003836A (en) * | 2017-11-29 | 2018-05-08 | 北京天仁道和新材料有限公司 | It is used to prepare the composite fibre and preparation method and ceramic frication material and preparation method and Ceramic Disc Brakes of ceramic frication material |
CN108331860A (en) * | 2018-04-04 | 2018-07-27 | 成都工业学院 | A kind of brake block |
CN109336615B (en) * | 2018-12-03 | 2021-06-22 | 中国科学院兰州化学物理研究所 | High-toughness, wear-resistant and friction-reducing sialon-tin composite material |
CN113929352B (en) * | 2020-06-29 | 2023-02-07 | 比亚迪股份有限公司 | Imitation ceramic material and preparation method and application thereof |
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