CN109607998A - A kind of novel greasy filth degradation biological reaction kettle and its operating method - Google Patents

A kind of novel greasy filth degradation biological reaction kettle and its operating method Download PDF

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Publication number
CN109607998A
CN109607998A CN201910086740.4A CN201910086740A CN109607998A CN 109607998 A CN109607998 A CN 109607998A CN 201910086740 A CN201910086740 A CN 201910086740A CN 109607998 A CN109607998 A CN 109607998A
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motor
reaction vessel
greasy filth
lead screw
reaction kettle
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CN201910086740.4A
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CN109607998B (en
Inventor
贺利乐
罗飞
张凯
韩行
孙昱
刘颖
李育
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Shenzhen Wanzhida Technology Co ltd
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Xian University of Architecture and Technology
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/26Reducing the size of particles, liquid droplets or bubbles, e.g. by crushing, grinding, spraying, creation of microbubbles or nanobubbles

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)

Abstract

The invention discloses a kind of novel greasy filth degradation biological reaction kettle and its operating methods, comprising: supporting mechanism;Reaction vessel, reaction vessel are mounted on supporting mechanism;Reaction vessel is provided with feed opening, discharge port and gas outlet;Stirring structure, including first motor and turntable;First motor is mounted on supporting mechanism, and turntable is rotatably set in reaction vessel;The output shaft of first motor is connected with turntable;Grind mechanism, including the second motor, lead screw and mill;The output shaft of second motor is connected with lead screw, and lead screw is set in reaction vessel, and mill is equipped on lead screw;It is aerated mechanism, including gas source and gas pipeline;The gas outlet of gas source is connected with the air inlet of gas pipeline, and the gas outlet of gas pipeline is set in reaction vessel.The present invention can effectively solve the problem that the problem of greasy filth is with microorganism insufficient contact in biological respinse kettle, and degradation efficiency can be improved.

Description

A kind of novel greasy filth degradation biological reaction kettle and its operating method
Technical field
The invention belongs to chemical machinery technical fields, are related to a kind of reaction kettle, and in particular to a kind of novel greasy filth degradation life Object reaction kettle and its operating method.
Background technique
Petroleum is very important the energy, and daily economic life, industrial production, space flight military project require petroleum as the energy And raw material, therefore also referred to as " industrial blood ".In the exploitation of petroleum, storage, transport and use process, due to third party The case where factors such as reason or natural calamity, crude oil will appear evaporating, emitting, dripping or leaking of liquid or gas, lead to a large amount of oil products and soil and other impurities Form greasy filth.Greasy filth is mostly the mixture of water, mud, oil and other impurities, can be made to soil environment, air, health of human body Seem extremely urgent at serious harm, therefore to the processing of greasy filth.
Currently, being broadly divided into three classes to the processing method of greasy filth both at home and abroad: Pintsch process technology, modulation-mechanically decoupled place Reason technology and biologic treating technique.Pintsch process technology refers to heats oily sludge in the absence of oxygen, passes through complexity The hydrocarbons in greasy filth are separated in hydration reaction and cracking, and the advantages of this method is rate of recovery height, the disadvantage is that needing A large amount of heat is wanted, equipment investment is higher.Modulation-mechanically decoupled processing technique be by adding demulsifier and being stirred, from And by oil, water, mud three phase separation, this method treatment effeciency is high, but preposition pretreating process adaptability is poor.Biological treatment skill The cardinal principle of art is petroleum hydrocarbon as carbon source and is utilized by microorganism, carries out assimilation degradation, makes its permineralization, be changed into nothing Harmful inorganic substances (CO2And H2O process);This method not will cause secondary pollution, and processing cost is low, excellent result, As the main direction of development for handling greasy filth diversification from now on.However since greasy filth viscosity is big, adhesive force is strong etc., characteristics are being reacted It is difficult to be sufficiently mixed with bacterium solution in kettle, contact, the phenomenon that there are layering, agglomeration and viscous walls, will be greatly reduced reaction rate, increase Cost.
To sum up, a kind of novel greasy filth degradation biological reaction kettle is needed.
Summary of the invention
It is above-mentioned to solve the purpose of the present invention is to provide a kind of novel greasy filth degradation biological reaction kettle and its operating method Existing one or more technical problem.The present invention can effectively solve the problem that greasy filth and microorganism insufficient contact in biological respinse kettle The problem of, degradation efficiency can be improved.
In order to achieve the above objectives, the invention adopts the following technical scheme:
A kind of novel greasy filth degradation biological reaction kettle, comprising:
Supporting mechanism is used to support the greasy filth degradation biological reaction kettle;
Reaction vessel, reaction vessel are mounted on supporting mechanism;Reaction vessel is provided with feed opening, discharge port and outlet Mouthful, reaction vessel is for holding microbial inoculum and greasy filth to be processed;
Stirring structure, including first motor and turntable;First motor is mounted on supporting mechanism, and turntable is rotatably arranged In in reaction vessel;The output shaft of first motor is connected with turntable, and first motor can drive turntable to rotate;
Grind mechanism, including the second motor, lead screw and mill;The output shaft of second motor is connected with lead screw, and lead screw is set It is placed in reaction vessel, mill is installed on lead screw;When lead screw rotates, mill can be moved along the axis of lead screw;
It is aerated mechanism, including gas source and gas pipeline;The gas outlet of gas source is connected with the air inlet of gas pipeline, gas transmission The gas outlet of pipeline is set in reaction vessel.
A further improvement of the present invention is that, further includes: control mechanism, the signal output end of control mechanism is respectively with first The signal receiving end of motor and the second motor is connected;
Control mechanism includes power switch, PLC control circuit and frequency converter;PLC control circuit is for controlling the second motor Positive and negative rotation, frequency converter is for adjusting first motor revolving speed.
A further improvement of the present invention is that first motor is connect by first shaft coupling with turntable;Second motor passes through Second shaft coupling is connect with lead screw.
A further improvement of the present invention is that being machined with the groove of predetermined thickness on turntable, groove is for driving mixed liquor The flowing of body.
A further improvement of the present invention is that being machined with strip notch that is different in size and being parallel to each other on mill.
A further improvement of the present invention is that reaction vessel is cylindrical-shaped structure, it is made of organic glass.
A further improvement of the present invention is that the both ends of the lead screw in reaction vessel are provided with the light of preset length Bar, the mobile limit for mill.
A further improvement of the present invention is that aeration mechanism specifically includes: air blower, steam hose, circulating line and exposure Tracheae;
Air blower is for providing air, and the gas outlet of air blower is connected with the air inlet of steam hose, steam hose Gas outlet is connected with circulating line air inlet;
Circulating line is fixedly installed on the top cover inner wall of reaction vessel, and circulating line is provided with one or more outlets Mouthful, each gas outlet is mounted on an aeration tube, and the axis of each aeration tube is parallel with lead screw axis;Each aeration tube Outlet end is provided with multiple solarization air caps, and solarization air cap is close to the bottom of reaction vessel.
Further, first motor is threephase asynchronous.
A kind of operating method of novel greasy filth degradation biological reaction kettle, comprising the following steps:
Step 1, starting aeration mechanism, keeps being passed through gas into reaction vessel by gas source and gas pipeline;
Step 2, mill is moved to bottom restraining position, from the feed opening of reaction vessel by microbial inoculum and to be processed Greasy filth is placed in reaction vessel;
Step 3, start rabbling mechanism, by first motor drive turntable rotation, to the mixing liquid in reaction vessel into Row stirring;Start grinding mechanism simultaneously, it is made to work according to preset time interval, drives lead screw to turn by the second motor It is dynamic, move up and down mill;
Step 4, sampling observation, according to the revolving speed and the second motor of sampling survey and the result of observation adjustment first motor Positive and negative rotation time interval;
Step 5, after the completion of degradation, by liquid from the discharge port of reaction vessel be discharged, close grinding mechanism, rabbling mechanism and It is aerated mechanism.
Compared with prior art, the invention has the following advantages:
The present invention is triturable greasy filth degradation biological reaction kettle, real in the rotation and the moving back and forth of mill of turntable Now to the stirring of greasy filth, grinding and refinement, be able to solve greasy filth be easily layered, agglomerate during stir process, viscous wall and with The uneven problem of bacterium solution mixing, to be greatly improved the treatment effeciency of greasy filth.Apparatus of the present invention use biologic treating technique not It only not will cause secondary pollution, and processing cost is low, meet the theory of contemporary Green Development, current production can be put into In life, there is biggish economic benefit and social effect.In addition to this, apparatus of the present invention apply also for having similar greasy filth In the reaction process of the other materials of characteristic, there is good versatility, good productivity effect can be brought for relevant enterprise.
Detailed description of the invention
Fig. 1 is the overall structure signal of the triturable novel greasy filth degradation biological reaction kettle of one kind of the embodiment of the present invention Figure;
Fig. 2 is the stereochemical structure signal of the triturable novel greasy filth degradation biological reaction kettle of one kind of the embodiment of the present invention Figure;
Fig. 3 is the mill structural schematic diagram in the embodiment of the present invention;
Fig. 4 is the turntable structure schematic diagram in the embodiment of the present invention;
In Fig. 1 to Fig. 4:
1-rabbling mechanism, 1-1-first motor, 1-2-first shaft coupling, 1-3-turntable;
2-reaction vessels, 2-1-feed opening, 2-2-gas outlet;
3-grinding mechanisms, 3-1-lead screw, 3-2-mill, the second motor of 3-3-second shaft coupling, 3-4-;
4-control mechanisms;
5-aeration mechanisms, 5-1-circulating line air inlet, 5-2-steam hose, 5-3-circulating line, 5-4-aeration Pipe, 5-5-solarization air cap, 5-6-air blower;
6-supporting mechanisms.
Specific embodiment
Invention is further described in detail in the following with reference to the drawings and specific embodiments.
Referring to Fig. 1, a kind of novel greasy filth degradation biological reaction kettle of the invention, comprising: rabbling mechanism 1, reaction vessel 2, mechanism 3, control mechanism 4, aeration mechanism 5 and supporting mechanism 6 are ground.
Rabbling mechanism 1 is made of first shaft coupling 1-2, first motor 1-1 and turntable 1-3, is provided on the surface turntable 1-3 The groove of certain predetermined thickness can guarantee the rotational flow for more efficiently driving liquid during stirring greasy filth, make It is more fully mixed.In addition to this, first motor 1-1 can adjust revolving speed by control mechanism 4, be anti-according to practical condition Suitable revolving speed should be provided.
Reaction vessel 2 is made of organic glass, conveniently can intuitively observe the reactiveness of device.Container cap is adopted It is made of metal material, is disposed with feed opening 2-1 and gas outlet 2-2 thereon, and container cap lower surface is welded with ring pipe Road 5-3.
It grinds mechanism 3 and lead screw 3-1 rotation is driven by second shaft coupling 3-3 by the second motor 3-4, match on lead screw 3-1 Conjunction has mill 3-2, and there are four cyclic annular notches at the edge of mill 3-2, is fitted close just with the outer surface aeration tube 5-4.Therefore work as When second motor 3-4 is rotated in the forward direction, lead screw 3-1 is also rotated forward with it, and mill 3-2 is that guiding is vertical with aeration tube 5-4 at this time Move down, when mill 3-2 is moved to minimum restraining position, lead screw is non-threaded, and mill no longer moves, at this time turntable 1-3 after Continuous rotation, to achieve the purpose that grinding.After a period of time, the second motor 3-4 reversion, lead screw 3-1 are adjusted by control mechanism 4 Also it inverts therewith, due to the effect of centrifugal force and buoyancy, mill 3-2 centre bore screw thread is matched with lead screw 3-1, with aeration tube 5- 4 move straight up for guiding.As described above, by control the second motor 3-4 positive and negative rotation, just can control mill on move down It is dynamic, to achieve the purpose that grind greasy filth and refined, the production problem encountered in actual production can be efficiently solved.
Control mechanism 4 is other than having the function of connection and cutting off the power, additionally it is possible to control the positive and negative rotation of the second motor 3-4 And the revolving speed of first motor 1-1 has more extensively so that apparatus of the present invention can preferably adapt to actual production environment Application range.
It is aerated mechanism 5 and air is sent by circulating line 5-3 by steam hose 5-2 by air blower 5-6, be then passed through four again Root aeration tube 5-4, gas are overflowed from intensive solarization air cap 5-5, a large amount of small bubble populations are formed, to mention for aerobic microbiological For sufficient oxygen.
Supporting mechanism 6 is welded by steel plate and pillar, can stablize it is safe other mechanisms are fixed, guarantee device it is suitable Sharp efficient use.
To sum up, for the characteristics such as greasy filth viscosity is big, adhesive force is strong, rabbling mechanism is provided in reaction kettle of the invention, is ground Grinding machine structure and control mechanism are able to solve greasy filth and are difficult to be sufficiently mixed with bacterium solution, contact, and there are showing for layering, agglomeration and viscous wall As being greatly improved reaction rate, reducing cost, there is preferable economic benefit.
Embodiment
The triturable novel greasy filth degradation biological reaction kettle of one kind of the embodiment of the present invention, by supporting mechanism 6, rabbling mechanism 1, mechanism 5, control mechanism 4, grinding mechanism 3 and reaction vessel 2 is aerated to form.
Support construction 6 is that rectangle steel plate and supporting leg are welded, and corresponding position has threaded hole on steel plate, for fixing it Its mechanism.There is a circular hole on the steel plate on upper layer, be fixed with bearing in circular hole, sealed using sealing ring, for constraining turning for turntable It is dynamic.Supporting mechanism 6 divides for upper layer and lower layer, the fixed reaction vessel 2 in upper layer and electrical control cabinet, the fixed threephase asynchronous machine of lower layer And air blower.Rabbling mechanism 1 drives turntable 1-3 rotation by first motor 1-1, and first motor 1-1 is fixed on branch in rabbling mechanism 1 On lower layer's steel plate of support mechanism 6, the motor shaft of first motor 1-1 drives turntable 1-3 rotation, turntable by first shaft coupling 1-2 The flowing of fluted, to make turntable 1-3 strong in rotation in this way drive mixing liquid is processed on 1-3.Mechanism 5 is aerated by rousing Blower 5-6 connects composition with aeration tube with holes, and air is sent in annular steel pipe by air blower 5-6 by steam hose 5-2, and It has been evenly arranged four direct piping outlets on annular steel pipe, has there is intensive aperture in outlet end, air overflows from these apertures Out, a large amount of small bubbles are generated, to provide sufficient oxygen for microbial degradation greasy filth.Control mechanism 4 is equipped with frequency conversion The power control cabinet of device and PLC control circuit, control mechanism is by power switch, PLC control circuit/time relay and frequency converter group At.PLC control circuit/time relay can be realized the positive and negative rotation of the second motor 3-4, and frequency converter can adjust first motor 1- 1 revolving speed.Grinding mechanism 3 is made of the second motor 3-4, lead screw 3-1 and mill 3-2.When the second motor 3-4 is rotated forward, silk Thick stick 3-1 is also rotated forward, and mill 3-2 is to move down with four aeration tube 5-4;When the second motor 3--4 reversion, lead screw 3-1 Also it inverts, mill 3-2 is moved up.There is strip notch that is different in size, being parallel to each other on mill 3-2, therefore in mill 3-2 During moving up and down, the greasy filth of agglomeration can be subjected to cutting, filtering, refinement.In addition to this, when mill be moved to it is minimum When position, the bulk greasy filth that mill and turntable can be mingled with centre is ground.Mill is moved to minimum in order to prevent Or enforceable displacement still occurs in the case where highest (limiting), do not have to process spiral shell at the both ends of lead screw in the present invention Line, so just this problem of effective solution.Reaction vessel uses cylindrical tube closed structure.
The operating method of the triturable novel greasy filth degradation biological reaction kettle of one kind of the invention, comprising the following steps:
Step 1, make to be aerated the normal work of mechanism 5 by control mechanism 4 first, this measure can not only prevent aeration tube 5-4 It is blocked by greasy filth and is prevented liquid from flowing back to air blower 5-6 from steam hose 5-2 and equipment is damaged.
Step 2, mill 3-2 is then adjusted to by bottom position by control mechanism 4, then added respectively from feed opening 2-1 Enter greasy filth and microbial inoculum.
Step 3, then by control mechanism 4 make rabbling mechanism 1 start to work, while make grind mechanism according to setting when Between be spaced and also start to work.
Step 4, in equipment running process, it can adjust first motor 1-1's according to sampling survey and the result of observation Revolving speed and the time interval of the second motor 3-4 positive and negative rotation.
Step 5, after the completion of degradation, liquid is excluded from discharge port, is then shut off rabbling mechanism 1 and aeration mechanism 5, it is necessary When reaction kettle can be cleaned.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that A specific embodiment of the invention is only limitted to this, for those of ordinary skill in the art to which the present invention belongs, is not taking off Under the premise of from present inventive concept, several simple deduction or replace can also be made, all shall be regarded as belonging to the present invention by institute Claims of submission determine scope of patent protection.

Claims (10)

1. a kind of novel greasy filth degradation biological reaction kettle characterized by comprising
Supporting mechanism (6) is used to support the greasy filth degradation biological reaction kettle;
Reaction vessel (2), reaction vessel (2) are mounted on supporting mechanism (6);Reaction vessel (2) be provided with feed opening (2-1), Discharge port and gas outlet (2-2), reaction vessel (2) is for holding microbial inoculum and greasy filth to be processed;
Stirring structure, including first motor (1-1) and turntable (1-3);First motor (1-1) is mounted on supporting mechanism (6), is turned Disk (1-3) is rotatably set in reaction vessel (2);The output shaft of first motor (1-1) is connected with turntable (1-3), the One motor (1-1) can drive turntable (1-3) to rotate;
It grinds mechanism (3), including the second motor (3-4), lead screw (3-1) and mill (3-2);The output shaft of second motor (3-4) It is connected with lead screw (3-1), lead screw (3-1) is set in reaction vessel (2), and mill (3-2) is equipped on lead screw (3-1);Silk When thick stick (3-1) rotates, mill (3-2) can be mobile along the axis of lead screw (3-1);
It is aerated mechanism (5), including gas source and gas pipeline;The gas outlet of gas source is connected with the air inlet of gas pipeline, gas transmission The gas outlet of pipeline is set in reaction vessel (2).
2. a kind of novel greasy filth degradation biological reaction kettle according to claim 1, which is characterized in that further include: control machine Structure (4), the signal output end of control mechanism (4) the signal receiving end phase with first motor (1-1) and the second motor (3-4) respectively Connection;
Control mechanism (4) includes power switch, PLC control circuit and frequency converter;PLC control circuit is for controlling the second motor (3-4) positive and negative rotation, frequency converter is for adjusting first motor (1-1) revolving speed.
3. a kind of novel greasy filth degradation biological reaction kettle according to claim 1, which is characterized in that first motor (1-1) It is connect by first shaft coupling (1-2) with turntable (1-3);Second motor (3-4) passes through second shaft coupling (3-3) and lead screw (3- 1) it connects.
4. a kind of novel greasy filth degradation biological reaction kettle according to claim 1, which is characterized in that add on turntable (1-3) Work has the groove of predetermined thickness, and groove is used to drive the flowing of mixing liquid.
5. a kind of novel greasy filth degradation biological reaction kettle according to claim 1, which is characterized in that add on mill (3-2) Work has strip notch that is different in size and being parallel to each other.
6. a kind of novel greasy filth degradation biological reaction kettle according to claim 1, which is characterized in that reaction vessel (2) is Cylindrical-shaped structure is made of organic glass.
7. a kind of novel greasy filth degradation biological reaction kettle according to claim 1, which is characterized in that in reaction vessel (2) The both ends of lead screw (3-1) be provided with the polished rod of preset length, be used for the mobile limit of mill (3-2).
8. a kind of novel greasy filth degradation biological reaction kettle according to claim 1, which is characterized in that aeration mechanism (5) tool Body includes: air blower (5-6), steam hose (5-2), circulating line (5-3) and aeration tube (5-4);
For providing air, the gas outlet of air blower (5-6) is connected air blower (5-6) with the air inlet of steam hose (5-2), The gas outlet of steam hose (5-2) is connected with circulating line air inlet (5-1);
Circulating line (5-3) is fixedly installed on the top cover inner wall of reaction vessel (2), circulating line (5-3) be provided with one or Multiple gas outlets, each gas outlet are mounted on an aeration tube (5-4);The axis of each aeration tube (5-4) with lead screw (3- 1) axis is parallel;The outlet end of each aeration tube (5-4) is provided with multiple solarization air caps (5-5), and solarization air cap (5-5) leans on proximal response The bottom of container (2).
9. a kind of novel greasy filth degradation biological reaction kettle according to any one of claim 1 to 8, which is characterized in that the One motor (1-1) is threephase asynchronous.
10. the operating method of novel greasy filth degradation biological reaction kettle, feature described in a kind of any one of claims 1 to 9 It is, comprising the following steps:
Step 1, starting aeration mechanism (5) keeps being passed through gas into reaction vessel (2) by gas source and gas pipeline;
Step 2, mill (3-2) is moved to bottom restraining position, from the feed openings (2-1) of reaction vessel (2) by microbial bacteria Liquid and greasy filth to be processed merging reaction vessel (2);
Step 3, start rabbling mechanism (1), turntable (1-3) rotation is driven by first motor (1-1), in reaction vessel (2) Mixing liquid be stirred;Start grinding mechanism (3) simultaneously, it is made to work according to preset time interval, by the Two motors (3-4) drive lead screw (3-1) rotation, move up and down mill (3-2);
Step 4, sampling observation, according to the revolving speed and the second electricity of sampling survey and the result of observation adjustment first motor (1-1) The time interval of the positive and negative rotation of machine (3-4);
Step 5, after the completion of degradation, liquid is discharged from the discharge port of reaction vessel (2), closes grinding mechanism (3), rabbling mechanism (1) and mechanism (5) are aerated.
CN201910086740.4A 2019-01-29 2019-01-29 Oil sludge degradation biological reaction kettle and operation method thereof Active CN109607998B (en)

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Citations (6)

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Publication number Priority date Publication date Assignee Title
CN205115249U (en) * 2015-10-15 2016-03-30 陕西汇丰悦石油科技开发有限公司 Fatlute microbiological treatment device
RU2584031C1 (en) * 2014-12-05 2016-05-20 Открытое акционерное общество "Куйбышевский нефтеперерабатывающий завод" Method of processing oil sludge and cleaning oil contaminated soil
CN206334383U (en) * 2016-12-30 2017-07-18 浙江扬帆新材料股份有限公司 A kind of light trigger purifying crystal device for preventing crystal from gluing wall
CN107983292A (en) * 2017-12-15 2018-05-04 李进田 A kind of swing solid-liquid reaction kettle
CN207324934U (en) * 2017-07-10 2018-05-08 安徽沃尔德新材料有限公司 A kind of high-molecular water paint raw mill plant
CN108405604A (en) * 2018-02-11 2018-08-17 中国环境科学研究院 Oily sludge microbial degradation and aeration-extracting Combined Treatment station and processing method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2584031C1 (en) * 2014-12-05 2016-05-20 Открытое акционерное общество "Куйбышевский нефтеперерабатывающий завод" Method of processing oil sludge and cleaning oil contaminated soil
CN205115249U (en) * 2015-10-15 2016-03-30 陕西汇丰悦石油科技开发有限公司 Fatlute microbiological treatment device
CN206334383U (en) * 2016-12-30 2017-07-18 浙江扬帆新材料股份有限公司 A kind of light trigger purifying crystal device for preventing crystal from gluing wall
CN207324934U (en) * 2017-07-10 2018-05-08 安徽沃尔德新材料有限公司 A kind of high-molecular water paint raw mill plant
CN107983292A (en) * 2017-12-15 2018-05-04 李进田 A kind of swing solid-liquid reaction kettle
CN108405604A (en) * 2018-02-11 2018-08-17 中国环境科学研究院 Oily sludge microbial degradation and aeration-extracting Combined Treatment station and processing method

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