CN109607685A - A kind of feed water by reverse osmosis feature pollution index measurement device and method - Google Patents

A kind of feed water by reverse osmosis feature pollution index measurement device and method Download PDF

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Publication number
CN109607685A
CN109607685A CN201910053491.9A CN201910053491A CN109607685A CN 109607685 A CN109607685 A CN 109607685A CN 201910053491 A CN201910053491 A CN 201910053491A CN 109607685 A CN109607685 A CN 109607685A
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China
Prior art keywords
water
reverse osmosis
feed water
pollution index
csdi
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Pending
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CN201910053491.9A
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Chinese (zh)
Inventor
刘炎伟
郭俊文
滕维忠
李鹏
陈浩
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Xian Thermal Power Research Institute Co Ltd
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Thermal Power Research Institute
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Priority to CN201910053491.9A priority Critical patent/CN109607685A/en
Publication of CN109607685A publication Critical patent/CN109607685A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/001Upstream control, i.e. monitoring for predictive control
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The invention discloses a kind of feed water by reverse osmosis feature pollution index measurement device and methods, the device includes the feed water by reverse osmosis pipeline being connected to counter-infiltration system, the sampling line being connected on feed water by reverse osmosis pipeline, characteristic contamination monitoring device on sampling line is set, the outlet of characteristic contamination monitoring device is discharge pipe line, further includes the feature pollution index computing system connecting with characteristic contamination monitoring device;Characteristic contamination monitoring device transfers data to feature pollution index computing system using quantity, volume and the particle diameter distribution index of characteristic contamination in laser monitoring water sample;Feature pollution index computing system calculates feed water by reverse osmosis water quality characteristic pollution index CSDI, calculation formula CSDI=Q/Qb, as the CSDI=1 of calculating, indicate that water quality is qualified;Indicate that water quality is excellent when CSDI < 0.5;Water quality inferiority is indicated when CSDI > 1.5;It solves the problems, such as continuously monitor feed water by reverse osmosis pollutant on-line at present.

Description

A kind of feed water by reverse osmosis feature pollution index measurement device and method
Technical field
The present invention relates to the reverse osmosis equipments in water treatment system, and in particular to a kind of feed water by reverse osmosis feature pollution index Measurement device and method.
Background technique
Water pollution index is to represent the technical indicator of the pollutant loads such as particle in water, bacterium, colloid.By calculating sample The speed that product water blocks 0.45 μm of miillpore filter calculates the pollution index value of water, manually measures to realize.
Reverse osmosis technology is widely used in the water treatment field of power plant and other industries, and water pollution index (SDI) is anti- The important water inlet index of permeability apparatus, the method generallyd use are monitored with SDI analyzer.Although existing SDI is automatic at present Measurement device, but because it is only that can not achieve real time on-line monitoring and expensive, so power plant instead of manual operation Generally use the manual measurement device of the lower SDI of price.But SDI has its limitation in the application:
1) SDI cannot be monitored on-line continuously and be reacted variation water quality situation in time, be unfavorable for searching variation water quality original in time Cause is unfavorable for the operation steady in a long-term of reverse osmosis membrane;
2) easily there is biggish error in different people operation;
3) temperature when test film and measurement of different manufacturers production will affect measurement result.
Therefore, no matter from the angle of safe and stable operation, or from the angle increased economic efficiency, in feed water by reverse osmosis Impurity carry out the development trend that real time on-line monitoring becomes inevitable.Propose thus feed water by reverse osmosis feature pollution index this New concept, and realize and it is monitored on-line.
Summary of the invention
In order to overcome deficiency existing for SDI measuring method, the purpose of the present invention is to provide a kind of feed water by reverse osmosis features Pollution index measurement device and method, the problem of feed water by reverse osmosis pollutant must not be monitored on-line continuously with solution.
In order to achieve the above object, the present invention adopts the following technical scheme:
A kind of feed water by reverse osmosis feature pollution index measurement device, including the feed water by reverse osmosis being connected to counter-infiltration system 1 The characteristic contamination monitoring dress on sampling line 3 is arranged in pipeline 2, the sampling line 3 being connected on feed water by reverse osmosis pipeline 2 4 are set, i.e. the entrance of characteristic contamination monitoring device 4 is sampling line 3, and the outlet of characteristic contamination monitoring device 4 is drainpipe Road 5 further includes the feature pollution index computing system 6 connecting with characteristic contamination monitoring device 4.
The feed water by reverse osmosis feature pollution index measurement device is applied to power plant, petrochemical industry, metallurgy industry and is related to raw water Pretreatment and reverse osmosis treatment field;It is dirty for monitoring the feature for the treatment of nature water water outlet and feed water by reverse osmosis in water process on-line Contaminate object.
The sampling line 3 is arranged at the feed water by reverse osmosis pipeline 2 of high pressure pump inlet.
Valve is provided on the sampling line 3 and discharge pipe line 5.
The water inlet feature pollution index measuring method of the feed water by reverse osmosis feature pollution index measurement device, it is reverse osmosis When system 1 operates normally, the valve of sampling line 3 and discharge pipe line 5 is opened, adjustment flow of inlet water to preset value connects measurement The characteristic contamination monitoring device 4 on sampling line 3 is arranged in using characteristic contamination in laser monitoring water sample in installation's power source Quantity, volume and particle diameter distribution index transfer data to feature pollution index computing system 6;Feature pollution index calculates system System 6 calculates feed water by reverse osmosis water quality characteristic pollution index CSDI, calculation formula CSDI=Q/Qb, wherein Q is water sample particle Pollutant sum, QbIndicate that water quality is qualified as the CSDI=1 of calculating for a reference value of setting;Water quality is indicated when CSDI < 0.5 It is excellent;Water quality inferiority is indicated when CSDI > 1.5;Water sample after the detection of characteristic contamination monitoring device 4, passes through 5 outlet of discharge pipe line. According to 1 influent quality of feed water by reverse osmosis water quality characteristic pollution index CSDI real-time monitoring counter-infiltration system, when pretreatment system goes out When water water quality is unqualified, pretreatment system dosing and operating parameter are adjusted in time, it is ensured that pretreatment system effluent quality is qualified;It is logical Monitoring feed water by reverse osmosis water quality characteristic pollution index is crossed, guarantees that 1 influent quality of counter-infiltration system meets standard, mitigates reverse osmosis membrane Pollution, extend the service life of reverse osmosis membrane.
Compared to the prior art the present invention, has the advantages that
(1) it can continuously monitor feed water by reverse osmosis water quality characteristic pollution index on-line, and react variation water quality situation in time, gram The deficiency that can only measure feed water by reverse osmosis pollution index manually in the past is taken.
(2) when on-line monitoring feed water by reverse osmosis water quality characteristic pollution index is unqualified, pretreatment system can be adjusted in time and added The operating conditions such as medicine and operating parameter, it is ensured that pretreatment effluent quality is qualified.
(3) indexs such as the granule number of particulate pollutant, particle diameter distribution and volumetric concentration in feed water by reverse osmosis can be monitored, can be had The classification and feature of body embodiment water pollutant.
(4) measurement result is more accurate sensitiveer, during eliminating measurement pollution index, artificial operating error, measurement The influence of diaphragm and temperature to result.
(5) implementation process is simple, good application effect, and easy to accomplish.
Detailed description of the invention
Attached drawing 1 is feed water by reverse osmosis feature pollution index measurement device schematic diagram of the present invention.
Specific embodiment
With reference to the accompanying drawing and specific embodiment, the present invention is described in further detail.
As shown in Figure 1, the present invention is a kind of feed water by reverse osmosis feature pollution index measurement device, it is related to counter-infiltration system 1, feed water by reverse osmosis pipeline 2, sampling line 3, characteristic contamination monitoring device 4, discharge pipe line 5 and feature pollution index calculate system System 6.At the water inlet for being equipped with counter-infiltration system 1, the feed water by reverse osmosis pipeline 2 of high pressure pump inlet is selected, is provided at this The sampling line 3 of valve, by 3 connection features pollutant monitoring device 4 of sampling line, characteristic contamination monitoring device 4, which utilizes, to swash The indexs such as quantity, volume and particle diameter distribution of characteristic contamination in light detection water sample, after the detection of characteristic contamination monitoring device 4 Water sample, by 5 outlet of discharge pipe line, feature pollution index computing system 6 receive characteristic contamination monitoring device 4 transmit it is anti- Quantity, volumetric concentration and the particle size distribution data of particulate pollutant, calculate reverse osmosis according to a reference value of setting in infiltration water inlet Water water quality characteristic pollution index CSDI is penetrated into, feed water by reverse osmosis water quality is characterized.
Operating procedure are as follows: when counter-infiltration system 1 operates normally, open the valve of sampling line 3 and discharge pipe line 5, adjustment Flow of inlet water connects measurement device power supply, in characteristic contamination monitoring device 4 and feature pollution index computing system to preset value Data are read in 6.
Embodiment 1:
Certain power plant uses phreatic water as water source, and uses ultrafiltration as in-line coagulation technique, and water quality is good.Feature is dirty Total particle pollutant is between 1~25 in the feed water by reverse osmosis of dye 4 METHOD FOR CONTINUOUS DETERMINATION of object monitoring device, through feed water by reverse osmosis water quality Feature pollution index CSDI is calculated, CSDI < 0.5, and water quality is excellent.The pollution index of the same period is measured, SDI is 0.2 or so, much smaller than super Filter out water specified value 3.
Embodiment 2:
Certain power plant uses surface water as water source, and uses more medium filter and charcoal filter as reverse osmosis pre- Treatment process, water quality are poor.Total particle pollutant is 200 in the feed water by reverse osmosis of 4 METHOD FOR CONTINUOUS DETERMINATION of characteristic contamination monitoring device Between~380, calculated through feed water by reverse osmosis water quality characteristic pollution index CSDI, CSDI > 1.5, water quality inferiority.Measure the dirt of the same period Staining index, SDI are much larger than 3 between 4.4~5.4.

Claims (5)

1. a kind of feed water by reverse osmosis feature pollution index measurement device, it is characterised in that: including what is be connected to counter-infiltration system (1) Feed water by reverse osmosis pipeline (2), the sampling line (3) being connected on feed water by reverse osmosis pipeline (2) are arranged on sampling line (3) Characteristic contamination monitoring device (4), i.e., the entrance of characteristic contamination monitoring device (4) be sampling line (3), characteristic contamination The outlet of monitoring device (4) is discharge pipe line (5), further includes that the feature pollution connecting with characteristic contamination monitoring device (4) refers to Number computing system (6).
2. a kind of feed water by reverse osmosis feature pollution index measurement device according to claim 1, it is characterised in that: described anti- Infiltration water inlet feature pollution index measurement device is applied to power plant, petrochemical industry, metallurgy industry are related to treating nature water and reverse osmosis Process field;For monitoring the characteristic contamination for the treatment of nature water water outlet and feed water by reverse osmosis in water process on-line.
3. a kind of feed water by reverse osmosis feature pollution index measurement device according to claim 1, it is characterised in that: described to take Sample pipeline (3) is arranged at the feed water by reverse osmosis pipeline (2) of high pressure pump inlet.
4. a kind of feed water by reverse osmosis feature pollution index measurement device according to claim 1, it is characterised in that: described to take Valve is provided on sample pipeline (3) and discharge pipe line (5).
5. the water inlet feature pollution of the described in any item feed water by reverse osmosis feature pollution index measurement devices of Claims 1-4 refers to Number measuring methods, it is characterised in that: when counter-infiltration system (1) operates normally, open sampling line (3) and discharge pipe line (5) Valve, adjustment flow of inlet water to preset value connect measurement device power supply, the characteristic contamination prison being arranged on sampling line (3) Device (4) are surveyed using quantity, volume and the particle diameter distribution index of characteristic contamination in laser monitoring water sample, transfer data to spy It levies pollution index computing system (6);Feature pollution index computing system (6) calculates feed water by reverse osmosis water quality characteristic pollution index CSDI, calculation formula CSDI=Q/Qb, wherein Q is water sample particulate pollutant sum, QbFor a reference value of setting, when calculating When CSDI=1, indicate that water quality is qualified;Indicate that water quality is excellent when CSDI < 0.5;Water quality inferiority is indicated when CSDI > 1.5;Through characteristic contamination Water sample after monitoring device (4) detection, passes through discharge pipe line (5) outlet.According to feed water by reverse osmosis water quality characteristic pollution index CSDI real-time monitoring counter-infiltration system (1) influent quality, when pretreatment system effluent quality is unqualified, adjustment pretreatment in time System dosing and operating parameter, it is ensured that pretreatment system effluent quality is qualified;Pass through monitoring feed water by reverse osmosis water quality characteristic pollution Index guarantees that counter-infiltration system (1) influent quality meets standard, mitigates the pollution of reverse osmosis membrane, extend the use of reverse osmosis membrane Service life.
CN201910053491.9A 2019-01-21 2019-01-21 A kind of feed water by reverse osmosis feature pollution index measurement device and method Pending CN109607685A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111562351A (en) * 2020-05-28 2020-08-21 中国大唐集团科学技术研究院有限公司华中电力试验研究院 Automatic monitoring device and method for water quality pollution index of reverse osmosis equipment inlet water

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Publication number Priority date Publication date Assignee Title
CN111562351A (en) * 2020-05-28 2020-08-21 中国大唐集团科学技术研究院有限公司华中电力试验研究院 Automatic monitoring device and method for water quality pollution index of reverse osmosis equipment inlet water

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