CN109607685A - Device and method for measuring characteristic pollution index of reverse osmosis influent water - Google Patents

Device and method for measuring characteristic pollution index of reverse osmosis influent water Download PDF

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Publication number
CN109607685A
CN109607685A CN201910053491.9A CN201910053491A CN109607685A CN 109607685 A CN109607685 A CN 109607685A CN 201910053491 A CN201910053491 A CN 201910053491A CN 109607685 A CN109607685 A CN 109607685A
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reverse osmosis
characteristic
water
pollution index
csdi
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刘炎伟
郭俊文
滕维忠
李鹏
陈浩
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Xian Thermal Power Research Institute Co Ltd
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Thermal Power Research Institute
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/001Upstream control, i.e. monitoring for predictive control
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

本发明公开了一种反渗透进水特征污染指数测定装置和方法,该装置包括与反渗透系统连通的反渗透进水管路,连接在反渗透进水管路上的取样管路,设置在取样管路上的特征污染物监测装置,特征污染物监测装置的出口为排水管路,还包括与特征污染物监测装置连接的特征污染指数计算系统;特征污染物监测装置利用激光监测水样中特征污染物的数量、体积和粒径分布指标,将数据传输到特征污染指数计算系统;特征污染指数计算系统计算出反渗透进水水质特征污染指数CSDI,计算公式为CSDI=Q/Qb,当计算的CSDI=1时,表示水质合格;CSDI<0.5时表示水质优;CSDI>1.5时表示水质差;解决了目前不能连续在线监测反渗透进水污染物的问题。

The invention discloses a device and a method for determining a characteristic pollution index of reverse osmosis influent water. The device comprises a reverse osmosis water inlet pipeline communicated with a reverse osmosis system, a sampling pipeline connected to the reverse osmosis water inlet pipeline, and arranged on the sampling pipeline The characteristic pollutant monitoring device, the outlet of the characteristic pollutant monitoring device is a drainage pipeline, and also includes a characteristic pollution index calculation system connected with the characteristic pollutant monitoring device; the characteristic pollutant monitoring device uses lasers to monitor the characteristic pollutants in water samples. Quantity, volume and particle size distribution indicators, and transmit the data to the characteristic pollution index calculation system; the characteristic pollution index calculation system calculates the reverse osmosis influent water quality characteristic pollution index CSDI, the calculation formula is CSDI=Q/Q b , when the calculated CSDI =1, it means the water quality is qualified; CSDI<0.5 means the water quality is excellent; CSDI>1.5 means the water quality is poor; it solves the problem that the current continuous online monitoring of reverse osmosis influent pollutants is not possible.

Description

A kind of feed water by reverse osmosis feature pollution index measurement device and method
Technical field
The present invention relates to the reverse osmosis equipments in water treatment system, and in particular to a kind of feed water by reverse osmosis feature pollution index Measurement device and method.
Background technique
Water pollution index is to represent the technical indicator of the pollutant loads such as particle in water, bacterium, colloid.By calculating sample The speed that product water blocks 0.45 μm of miillpore filter calculates the pollution index value of water, manually measures to realize.
Reverse osmosis technology is widely used in the water treatment field of power plant and other industries, and water pollution index (SDI) is anti- The important water inlet index of permeability apparatus, the method generallyd use are monitored with SDI analyzer.Although existing SDI is automatic at present Measurement device, but because it is only that can not achieve real time on-line monitoring and expensive, so power plant instead of manual operation Generally use the manual measurement device of the lower SDI of price.But SDI has its limitation in the application:
1) SDI cannot be monitored on-line continuously and be reacted variation water quality situation in time, be unfavorable for searching variation water quality original in time Cause is unfavorable for the operation steady in a long-term of reverse osmosis membrane;
2) easily there is biggish error in different people operation;
3) temperature when test film and measurement of different manufacturers production will affect measurement result.
Therefore, no matter from the angle of safe and stable operation, or from the angle increased economic efficiency, in feed water by reverse osmosis Impurity carry out the development trend that real time on-line monitoring becomes inevitable.Propose thus feed water by reverse osmosis feature pollution index this New concept, and realize and it is monitored on-line.
Summary of the invention
In order to overcome deficiency existing for SDI measuring method, the purpose of the present invention is to provide a kind of feed water by reverse osmosis features Pollution index measurement device and method, the problem of feed water by reverse osmosis pollutant must not be monitored on-line continuously with solution.
In order to achieve the above object, the present invention adopts the following technical scheme:
A kind of feed water by reverse osmosis feature pollution index measurement device, including the feed water by reverse osmosis being connected to counter-infiltration system 1 The characteristic contamination monitoring dress on sampling line 3 is arranged in pipeline 2, the sampling line 3 being connected on feed water by reverse osmosis pipeline 2 4 are set, i.e. the entrance of characteristic contamination monitoring device 4 is sampling line 3, and the outlet of characteristic contamination monitoring device 4 is drainpipe Road 5 further includes the feature pollution index computing system 6 connecting with characteristic contamination monitoring device 4.
The feed water by reverse osmosis feature pollution index measurement device is applied to power plant, petrochemical industry, metallurgy industry and is related to raw water Pretreatment and reverse osmosis treatment field;It is dirty for monitoring the feature for the treatment of nature water water outlet and feed water by reverse osmosis in water process on-line Contaminate object.
The sampling line 3 is arranged at the feed water by reverse osmosis pipeline 2 of high pressure pump inlet.
Valve is provided on the sampling line 3 and discharge pipe line 5.
The water inlet feature pollution index measuring method of the feed water by reverse osmosis feature pollution index measurement device, it is reverse osmosis When system 1 operates normally, the valve of sampling line 3 and discharge pipe line 5 is opened, adjustment flow of inlet water to preset value connects measurement The characteristic contamination monitoring device 4 on sampling line 3 is arranged in using characteristic contamination in laser monitoring water sample in installation's power source Quantity, volume and particle diameter distribution index transfer data to feature pollution index computing system 6;Feature pollution index calculates system System 6 calculates feed water by reverse osmosis water quality characteristic pollution index CSDI, calculation formula CSDI=Q/Qb, wherein Q is water sample particle Pollutant sum, QbIndicate that water quality is qualified as the CSDI=1 of calculating for a reference value of setting;Water quality is indicated when CSDI < 0.5 It is excellent;Water quality inferiority is indicated when CSDI > 1.5;Water sample after the detection of characteristic contamination monitoring device 4, passes through 5 outlet of discharge pipe line. According to 1 influent quality of feed water by reverse osmosis water quality characteristic pollution index CSDI real-time monitoring counter-infiltration system, when pretreatment system goes out When water water quality is unqualified, pretreatment system dosing and operating parameter are adjusted in time, it is ensured that pretreatment system effluent quality is qualified;It is logical Monitoring feed water by reverse osmosis water quality characteristic pollution index is crossed, guarantees that 1 influent quality of counter-infiltration system meets standard, mitigates reverse osmosis membrane Pollution, extend the service life of reverse osmosis membrane.
Compared to the prior art the present invention, has the advantages that
(1) it can continuously monitor feed water by reverse osmosis water quality characteristic pollution index on-line, and react variation water quality situation in time, gram The deficiency that can only measure feed water by reverse osmosis pollution index manually in the past is taken.
(2) when on-line monitoring feed water by reverse osmosis water quality characteristic pollution index is unqualified, pretreatment system can be adjusted in time and added The operating conditions such as medicine and operating parameter, it is ensured that pretreatment effluent quality is qualified.
(3) indexs such as the granule number of particulate pollutant, particle diameter distribution and volumetric concentration in feed water by reverse osmosis can be monitored, can be had The classification and feature of body embodiment water pollutant.
(4) measurement result is more accurate sensitiveer, during eliminating measurement pollution index, artificial operating error, measurement The influence of diaphragm and temperature to result.
(5) implementation process is simple, good application effect, and easy to accomplish.
Detailed description of the invention
Attached drawing 1 is feed water by reverse osmosis feature pollution index measurement device schematic diagram of the present invention.
Specific embodiment
With reference to the accompanying drawing and specific embodiment, the present invention is described in further detail.
As shown in Figure 1, the present invention is a kind of feed water by reverse osmosis feature pollution index measurement device, it is related to counter-infiltration system 1, feed water by reverse osmosis pipeline 2, sampling line 3, characteristic contamination monitoring device 4, discharge pipe line 5 and feature pollution index calculate system System 6.At the water inlet for being equipped with counter-infiltration system 1, the feed water by reverse osmosis pipeline 2 of high pressure pump inlet is selected, is provided at this The sampling line 3 of valve, by 3 connection features pollutant monitoring device 4 of sampling line, characteristic contamination monitoring device 4, which utilizes, to swash The indexs such as quantity, volume and particle diameter distribution of characteristic contamination in light detection water sample, after the detection of characteristic contamination monitoring device 4 Water sample, by 5 outlet of discharge pipe line, feature pollution index computing system 6 receive characteristic contamination monitoring device 4 transmit it is anti- Quantity, volumetric concentration and the particle size distribution data of particulate pollutant, calculate reverse osmosis according to a reference value of setting in infiltration water inlet Water water quality characteristic pollution index CSDI is penetrated into, feed water by reverse osmosis water quality is characterized.
Operating procedure are as follows: when counter-infiltration system 1 operates normally, open the valve of sampling line 3 and discharge pipe line 5, adjustment Flow of inlet water connects measurement device power supply, in characteristic contamination monitoring device 4 and feature pollution index computing system to preset value Data are read in 6.
Embodiment 1:
Certain power plant uses phreatic water as water source, and uses ultrafiltration as in-line coagulation technique, and water quality is good.Feature is dirty Total particle pollutant is between 1~25 in the feed water by reverse osmosis of dye 4 METHOD FOR CONTINUOUS DETERMINATION of object monitoring device, through feed water by reverse osmosis water quality Feature pollution index CSDI is calculated, CSDI < 0.5, and water quality is excellent.The pollution index of the same period is measured, SDI is 0.2 or so, much smaller than super Filter out water specified value 3.
Embodiment 2:
Certain power plant uses surface water as water source, and uses more medium filter and charcoal filter as reverse osmosis pre- Treatment process, water quality are poor.Total particle pollutant is 200 in the feed water by reverse osmosis of 4 METHOD FOR CONTINUOUS DETERMINATION of characteristic contamination monitoring device Between~380, calculated through feed water by reverse osmosis water quality characteristic pollution index CSDI, CSDI > 1.5, water quality inferiority.Measure the dirt of the same period Staining index, SDI are much larger than 3 between 4.4~5.4.

Claims (5)

1.一种反渗透进水特征污染指数测定装置,其特征在于:包括与反渗透系统(1)连通的反渗透进水管路(2),连接在反渗透进水管路(2)上的取样管路(3),设置在取样管路(3)上的特征污染物监测装置(4),即特征污染物监测装置(4)的入口为取样管路(3),特征污染物监测装置(4)的出口为排水管路(5),还包括与特征污染物监测装置(4)连接的特征污染指数计算系统(6)。1. a reverse osmosis water inlet characteristic pollution index measuring device, is characterized in that: comprise the reverse osmosis water inlet pipeline (2) communicated with the reverse osmosis system (1), be connected to the sampling on the reverse osmosis water inlet pipeline (2) The pipeline (3), the characteristic pollutant monitoring device (4) arranged on the sampling pipeline (3), that is, the inlet of the characteristic pollutant monitoring device (4) is the sampling pipeline (3), and the characteristic pollutant monitoring device ( The outlet of 4) is a drainage pipeline (5), and also includes a characteristic pollution index calculation system (6) connected with the characteristic pollutant monitoring device (4). 2.根据权利要求1所述的一种反渗透进水特征污染指数测定装置,其特征在于:所述反渗透进水特征污染指数测定装置应用于发电厂、石化、冶金行业涉及原水预处理和反渗透处理领域;用于在线监测水处理中原水预处理出水和反渗透进水的特征污染物。2. a kind of reverse osmosis influent characteristic pollution index measuring device according to claim 1, is characterized in that: described reverse osmosis influent characteristic pollution index measuring device is applied to power plant, petrochemical, metallurgy industry involving raw water pretreatment and The field of reverse osmosis treatment; it is used for online monitoring of characteristic pollutants in raw water pretreatment effluent and reverse osmosis influent in water treatment. 3.根据权利要求1所述的一种反渗透进水特征污染指数测定装置,其特征在于:所述取样管路(3)设置在高压泵入口的反渗透进水管路(2)处。3. The device for measuring the characteristic pollution index of reverse osmosis inflow water according to claim 1, wherein the sampling pipeline (3) is arranged at the reverse osmosis water inflow pipeline (2) at the inlet of the high-pressure pump. 4.根据权利要求1所述的一种反渗透进水特征污染指数测定装置,其特征在于:所述取样管路(3)和排水管路(5)上均设置有阀门。4 . The device for measuring the characteristic pollution index of reverse osmosis influent water according to claim 1 , wherein the sampling pipeline ( 3 ) and the drainage pipeline ( 5 ) are both provided with valves. 5 . 5.权利要求1至4任一项所述的反渗透进水特征污染指数测定装置的进水特征污染指数测定方法,其特征在于:反渗透系统(1)正常运行时,打开取样管路(3)和排水管路(5)的阀门,调整进水流量到预设值,接通测定装置电源,设置在取样管路(3)上的特征污染物监测装置(4)利用激光监测水样中特征污染物的数量、体积和粒径分布指标,将数据传输到特征污染指数计算系统(6);特征污染指数计算系统(6)计算出反渗透进水水质特征污染指数CSDI,计算公式为CSDI=Q/Qb,其中,Q为水样颗粒污染物总数,Qb为设定的基准值,当计算的CSDI=1时,表示水质合格;CSDI<0.5时表示水质优;CSDI>1.5时表示水质差;经特征污染物监测装置(4)检测后的水样,通过排水管路(5)外排。根据反渗透进水水质特征污染指数CSDI实时监测反渗透系统(1)进水水质,当预处理系统出水水质不合格时,及时调整预处理系统加药和运行参数,确保预处理系统出水水质合格;通过监测反渗透进水水质特征污染指数,保证反渗透系统(1)进水水质满足标准,减轻反渗透膜的污染,延长反渗透膜的使用寿命。5. the influent characteristic pollution index measuring method of the reverse osmosis inflow characteristic pollution index measuring device according to any one of claims 1 to 4, it is characterized in that: during the normal operation of the reverse osmosis system (1), open the sampling pipeline ( 3) and the valve of the drainage pipeline (5), adjust the influent flow to the preset value, turn on the power supply of the measuring device, and the characteristic pollutant monitoring device (4) installed on the sampling pipeline (3) uses laser to monitor the water sample The quantity, volume and particle size distribution index of the characteristic pollutants in the medium are transmitted to the characteristic pollution index calculation system (6); the characteristic pollution index calculation system (6) calculates the reverse osmosis influent water quality characteristic pollution index CSDI, and the calculation formula is: CSDI=Q/Q b , where Q is the total number of particulate pollutants in the water sample, and Q b is the set reference value. When the calculated CSDI=1, it means the water quality is qualified; when CSDI<0.5, it means the water quality is excellent; CSDI>1.5 When the water quality is poor, the water sample detected by the characteristic pollutant monitoring device (4) is discharged through the drainage pipeline (5). Real-time monitoring of the reverse osmosis system according to the pollution index CSDI of the reverse osmosis influent water quality characteristics (1) Influent water quality, when the effluent quality of the pretreatment system is unqualified, adjust the dosing and operating parameters of the pretreatment system in time to ensure that the effluent quality of the pretreatment system is qualified ; By monitoring the characteristic pollution index of the reverse osmosis influent water quality, ensure that the influent water quality of the reverse osmosis system (1) meets the standard, reduce the pollution of the reverse osmosis membrane, and prolong the service life of the reverse osmosis membrane.
CN201910053491.9A 2019-01-21 2019-01-21 Device and method for measuring characteristic pollution index of reverse osmosis influent water Pending CN109607685A (en)

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Cited By (2)

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CN111562351A (en) * 2020-05-28 2020-08-21 中国大唐集团科学技术研究院有限公司华中电力试验研究院 An automatic monitoring device and method for the water quality pollution index of reverse osmosis equipment
CN116395799A (en) * 2023-03-17 2023-07-07 广州大学 A Method for Measuring Pollution Index of Reverse Osmosis Influent Filter Cake Layer Based on Cascade Filtration

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CN116395799A (en) * 2023-03-17 2023-07-07 广州大学 A Method for Measuring Pollution Index of Reverse Osmosis Influent Filter Cake Layer Based on Cascade Filtration

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