CN109604124A - A kind of node anti-corrosion method that submarine pipeline penetrating ground logs in - Google Patents

A kind of node anti-corrosion method that submarine pipeline penetrating ground logs in Download PDF

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Publication number
CN109604124A
CN109604124A CN201811525232.3A CN201811525232A CN109604124A CN 109604124 A CN109604124 A CN 109604124A CN 201811525232 A CN201811525232 A CN 201811525232A CN 109604124 A CN109604124 A CN 109604124A
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CN
China
Prior art keywords
layer
node
resin glue
submarine pipeline
epoxide
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Granted
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CN201811525232.3A
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Chinese (zh)
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CN109604124B (en
Inventor
王文龙
林贻海
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China National Offshore Oil Corp CNOOC
CNOOC China Ltd Zhanjiang Branch
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China National Offshore Oil Corp CNOOC
CNOOC China Ltd Zhanjiang Branch
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Priority to CN201811525232.3A priority Critical patent/CN109604124B/en
Publication of CN109604124A publication Critical patent/CN109604124A/en
Application granted granted Critical
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/002Pretreatement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/28Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218Pretreatment, e.g. heating the substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • F16L58/04Coatings characterised by the materials used
    • F16L58/10Coatings characterised by the materials used by rubber or plastics
    • F16L58/1054Coatings characterised by the materials used by rubber or plastics the coating being placed outside the pipe
    • F16L58/1072Coatings characterised by the materials used by rubber or plastics the coating being placed outside the pipe the coating being a sprayed layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00Tubular articles, e.g. hoses, pipes

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a kind of node anti-corrosion method that submarine pipeline penetrating ground logs in, corrosion-inhibiting coating is made of epoxy primer, polypropylene thermal shrinkage band and fiber glass epoxy protective layer.It is characterized in that its construction technology are as follows: submarine pipeline node surface cleans derusting → surface preheating → priming paint coating → mid-frequency induction heating → with PP pyrocondensation belt package and winds entire the 1st layer of epoxide-resin glue of node → brushing → after surface coating initial set, continue to brush the 2nd layer of the 1st layer of epoxide-resin glue → winding the 3rd layer of glass fabric → brushing the 2nd layer of epoxide-resin glue → winding the 4th layer of glass fabric → brushing epoxide-resin glue, to surface coating initial set, continue to brush the 5th layer of epoxide-resin glue, completes the process after initial set.The present invention can solve conventional corrosion-inhibiting coating penetrating ground return drag log in when node erosion resistant coating be easy to damage, it is dilatory fall off, submarine pipeline return drag during because suffered resistance is excessive and the problem of be destroyed.

Description

A kind of node anti-corrosion method that submarine pipeline penetrating ground logs in
Technical field
The present invention relates to Offshore Engineering fields, anti-more particularly to a kind of node that submarine pipeline penetrating ground logs in Rotten method.
Background technique
Submarine pipeline refers between Offshore Units and plays between Offshore Units and land terminal medium translocation Pipeline, submarine pipeline node refer to the junction between finished product submarine pipeline.2 kinds of the node corrosion-inhibiting coating of submarine pipeline routine, Respectively 3LPE erosion resistant coating (being made of epoxy primer and polyethylene thermal contraction strap) and 3LPP erosion resistant coating are (by epoxy primer and poly- third Alkene shrink belt composition);When submarine pipeline carries out back dragging penetrating ground, node corrosion-inhibiting coating is easy to damage and destroys, sternly It can even draw and fall off when weight;The outer anti-corrosion failure of submarine pipeline can not only be made, protect submarine pipeline cannot;And node anti-corrosion Layer return drag in fall off, returning for submarine pipeline can be blocked and drag channel, increase submarine pipeline returning resistance during dragging, work as seabed Pipeline itself return drag stress excessive or stress concentrate when, be more easily damaged, cause submarine pipeline penetrating ground return drag unsuccessfully.
Wherein most similar retrieval is as follows:
State Intellectual Property Office discloses the patent document of Publication No. CN107774545A, Yi Zhongtian on March 9th, 2018 Right gas long distance pipeline anti-corrosion method, it is characterised in that carry out as follows: the preparation of transition coating: being 3 according to weight ratio: 2 ratio by novolac epoxy resin glue and organic solvent be placed in reaction kettle be thoroughly mixed uniformly after, sequentially add metal oxygen Compound and phthalic anhydride are uniformly mixed up to transition coating;The preparation of function coating: being 8:1's according to weight ratio Ratio weighs suitable Kynoar powder and basalt fibre, is dissolved in tetrahydrofuran solution respectively.Heating gathers inclined fluorine Ethylene powder and tetrahydrofuran solution make it dissolve, and basalt fibre ultrasonic disperse is in tetrahydrofuran solution, and then ultrasound is mixed Nano-bentonite and molybdenum disulfide is added after closing 30-40min, obtains function coating after mixing;The coating of coating: incited somebody to action It crosses coating to be uniformly applied on duct wall, after 30min, function coating is mixed with organic solvent of ketone, was uniformly applied to It crosses on layer material, curing of coatings after 1 hour.
Zai You State Intellectual Property Office discloses the patent text of Publication No. CN 108869898A on November 23rd, 2018 It offers, a kind of insulation antiseptic petroleum pipeline, which is characterized in that the insulation antiseptic petroleum pipeline includes pipeline outer-layer, is arranged in institute It states the protective layer on pipeline outer-layer side, the insulating layer that the pipeline outer-layer other side is set, be arranged in the insulating layer one The pipeline lining of side is dashed forward with the integrally formed water conservancy diversion protrusion of the pipeline lining, setting in the pipeline lining and the water conservancy diversion Play the corrosion-resistant coating on surface;The protective layer is plastic protective film for plastics layer;The insulating layer includes reflective insulation layer, is arranged in institute The rubber layer stated the froth bed of reflective insulation layer side, the froth bed side is set;The corrosion-resistant coating is anti-for organosilicon Etching ground layer.
Zai You State Intellectual Property Office discloses the patent document of Publication No. CN 107701856A on 2 16th, 2018, A kind of corrosion-resistant pipeline configuration, it is characterized in that, including pipeline and the corrosion protective covering for being coated on pipeline external, the section shape of pipeline Shape is cirque structure, and the inner wall of corrosion protective covering is cylindrical structure and is interference fitted with pipeline outer wall, corrosion protective covering Outer wall is positive hexagonal structure, and several first grooves are uniformly provided on the inner wall of corrosion protective covering, are equipped with sealing in the first groove Pad, gasket fit with pipeline outer wall.
By retrieval, it has not been found that having process flow with the method for the present invention and the similar submarine pipeline of composed structure Or the method for pipeline corrosion protection.
Summary of the invention
In order to overcome above-mentioned deficiency, present invention aims at providing, and a kind of node that submarine pipeline penetrating ground logs in is anti- Rotten method.
To achieve the goals above, the technical solution adopted by the present invention is that: a kind of section that submarine pipeline penetrating ground logs in Point anti-corrosion method, node corrosion-inhibiting coating are made of epoxy primer, polypropylene thermal shrinkage band and fiber glass epoxy protective layer;It is applied Work process flow includes: to carry out surface cleaning derusting → surface preheating → priming paint coating → Medium frequency induction to submarine pipeline node to add Heat → with PP pyrocondensation belt package winds entire the 1st layer of epoxide-resin glue of node → brushing → after surface coating initial set, continues to apply Brush the 1st layer of the 2nd layer of epoxide-resin glue → winding the 3rd layer of glass fabric → brushing the 2nd layer of glass fibers of epoxide-resin glue → winding The 4th layer of epoxide-resin glue of Wei Bu → brushing continues to brush the 5th layer of epoxide-resin glue, surface coating after surface coating initial set After initial set, i.e., corrosion-inhibiting coating is fully completed.
Further, described to carry out surface cleaning derusting to submarine pipeline node, cleaning result requires steel tube surface Contamination-free, derusting grade needs are tested so that derusting grade meets the requirement of Sa 2.5 in the specification of ISO 8504, and surface Depth of abrasion pattern meets 8503 specification 50-100 μ m of ISO.
Further, the described priming paint coating, steel tube surface primer uniformly and to meet base coat thickness big In 250 μm of requirement.
Further, the mid-frequency induction heating heats epoxy primer using medium-frequency heating coil, it is desirable that by It is hot uniform, and temperature will control within the scope of 175-210 DEG C, make liquid epoxy solidifying priming paint.
Further, PP pyrocondensation belt package winds entire node, and PP pyrocondensation belt and the tube body coating lap of splice are full Foot requires, after the completion of pyrocondensation belt package, Yao Jinhang appearance test and electric spark detection.
Further, the brushwork epoxy resin glue and winding glass fabric, it is desirable that brushwork epoxy resin glue is uniform And thickness reaches requirement, after epoxide-resin glue initial set, then is wound glass fabric, uniform winding is also wanted, in this mistake Guarantee no-sundries in journey, to ensure the quality of fiber glass epoxy protective layer.
Further, appearance test needs reach: PP pyrocondensation belt surface answers smooth, no wrinkle, bubble-free, without burning It is coked.
Further, leak detection voltage used in the described electric spark detection is 15kV, electric spark leak detector device according to NACE RP0274 code requirement carries out 100% leak detection to PP pyrocondensation belt, cannot find any leak source.
Detailed description of the invention
Fig. 1 is a kind of node anti-corrosion schematic diagram that submarine pipeline penetrating ground logs in of the present invention.
Wherein: 1, steel pipe tube body;2, tube body coating;3, epoxy primer;4, polypropylene thermal shrinkage band;5, fiber glass epoxy is anti- Sheath.
Specific embodiment
The preferred embodiments of the present invention will be described in detail with reference to the accompanying drawing, so that advantages and features of the invention energy It is easier to be readily appreciated by one skilled in the art, so as to make a clearer definition of the protection scope of the present invention.
Referring to Fig. 1, the embodiment of the present invention includes: surface cleaning derusting is carried out to submarine pipeline node, is carried out at this time clear It after clean, strictly tests to derusting grade, derusting grade therein meets the requirement of Sa 2.5 in the specification of ISO 8504, and surface Depth of abrasion pattern meets in the specification of ISO 8503 in 50-100 μ m.Lap-joint pre-processes followed by node, has pre-processed Surface preheating is carried out after finishing, and just can carry out priming paint coating in steel tube surface after preheating, primer is uniformly and thickness will expire Sufficient base coat thickness is greater than 250 μm;Epoxy primer is heated using medium-frequency heating coil after the completion of smearing, is required at this time heated Uniformly, and temperature will control within the scope of 175-210 DEG C, it is therefore an objective to make liquid epoxy solidifying priming paint;Priming paint carries out heating in medium frequency After the completion, propane gas gun is recycled to carry out the winding of PP pyrocondensation belt package, PP pyrocondensation belt and the tube body coating lap of splice meet It is required that after the completion of pyrocondensation belt package, Yao Jinhang appearance test and electric spark detection, it is ensured that pyrocondensation belt installation qualification, appearance test It is required that PP pyrocondensation belt surface answers smooth, no wrinkle, bubble-free, nothing to burn charing;And the practical leak detection voltage of electric spark testing requirements 100% leak detection is carried out to PP pyrocondensation belt according to 0274 code requirement of NACE RP for the electric spark leak detector device of 15kV, is examined extremely Until that cannot find any leak source;After pyrocondensation belt installation qualification, brushing second layer epoxide-resin glue and first layer winding glass are carried out Glass fiber cloth after epoxide-resin glue initial set, then is wound glass fabric, also wants uniform winding;It closes in this process Key needs to guarantee no-sundries, then gradually carries out according to construction technology, to ensure the quality of fiber glass epoxy protective layer;Hereafter Structure is epoxide-resin glue, epoxide-resin glue, glass fabric, epoxide-resin glue, glass fabric, epoxide-resin glue, epoxy Resin glue, i.e., after process are as follows: brush the 1st layer of epoxide-resin glue → after surface coating initial set after, continue brush the 2nd layer of asphalt mixtures modified by epoxy resin The 1st layer of rouge glue → winding the 3rd layer of glass fabric → brushing the 2nd layer of glass fabric → brushing the 4th of epoxide-resin glue → winding Layer epoxide-resin glue continues to brush the 5th layer of epoxide-resin glue, after surface coating is pre-hardening, at this time should after surface coating initial set Corrosion-inhibiting coating is fully completed.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright specification and accompanying drawing content is applied directly or indirectly in other relevant skills Art field, is included within the scope of the present invention.

Claims (8)

1. a kind of node anti-corrosion method that submarine pipeline penetrating ground logs in, it is characterised in that: its node corrosion-inhibiting coating is by epoxy Priming paint, polypropylene thermal shrinkage band and fiber glass epoxy protective layer composition;Its construction technology process include: to submarine pipeline node into Row surface cleaning derusting → surface preheating → priming paint coating → mid-frequency induction heating → PP pyrocondensation belt package is used to wind entire node The 1st layer of epoxide-resin glue of → brushing → and after surface coating initial set, continue to brush the 1st layer of glass of the 2nd layer of epoxide-resin glue → winding The 3rd layer of glass fiber cloth → brushing the 2nd layer of epoxide-resin glue → winding the 4th layer of epoxide-resin glue of glass fabric → brushing, to table After coating materials initial set, continue to brush the 5th layer of epoxide-resin glue, after surface coating initial set, i.e., corrosion-inhibiting coating is fully completed.
2. a kind of node anti-corrosion method that submarine pipeline penetrating ground logs according to claim 1, it is characterised in that: institute That states carries out surface cleaning derusting to submarine pipeline node, and cleaning result requires steel tube surface contamination-free, and derusting grade needs It tests so that derusting grade meets the requirement of Sa 2.5 in the specification of ISO 8504, and surface depth of abrasion pattern meets ISO 8503 50-100 μ m in specification.
3. a kind of node anti-corrosion method that submarine pipeline penetrating ground logs according to claim 1, it is characterised in that: institute The priming paint coating stated uniformly and will will meet the requirement that base coat thickness is greater than 250 μm in steel tube surface primer.
4. a kind of node anti-corrosion method that submarine pipeline penetrating ground logs according to claim 1, it is characterised in that: institute The mid-frequency induction heating stated heats epoxy primer using medium-frequency heating coil, it is desirable that is heated evenly, and temperature will control Within the scope of 175-210 DEG C, make liquid epoxy solidifying priming paint.
5. a kind of node anti-corrosion method that submarine pipeline penetrating ground logs according to claim 1, it is characterised in that: institute The PP pyrocondensation belt package stated winds entire node, and PP pyrocondensation belt and tube body coating overlap, and after the completion of pyrocondensation belt package, to carry out outer It sees and examines and electric spark detection.
6. a kind of node anti-corrosion method that submarine pipeline penetrating ground logs according to claim 1, it is characterised in that: institute The brushwork epoxy resin glue and winding glass fabric stated, it is desirable that brushwork epoxy resin glue is uniform, after epoxide-resin glue initial set, It is wound glass fabric again, also wants uniform winding, guarantees no-sundries in this process to ensure that fiber glass epoxy protects The quality of layer.
7. a kind of node anti-corrosion method that submarine pipeline penetrating ground logs according to claim 5, it is characterised in that: institute Stating appearance test and needing to reach makes the surfacing of PP pyrocondensation belt, no wrinkle, bubble-free, nothing burn charing.
8. a kind of node anti-corrosion method that submarine pipeline penetrating ground logs according to claim 5, it is characterised in that: institute Stating leak detection voltage used in electric spark detection is 15kV, and electric spark leak detector device is according to 0274 code requirement of NACE RP to PP Pyrocondensation belt carries out 100% leak detection, until not finding any leak source.
CN201811525232.3A 2018-12-13 2018-12-13 Node anticorrosion method for submarine pipeline through stratum landing Active CN109604124B (en)

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CN106318274A (en) * 2016-08-25 2017-01-11 中国石油天然气集团公司 Polypropylene hot melt adhesive, preparation method thereof and preparation method of polypropylene contraction band
CN108869898A (en) * 2017-05-16 2018-11-23 十堰利兹传媒有限公司 Insulation antiseptic petroleum pipeline
CN107701856A (en) * 2017-09-29 2018-02-16 镇江市星耀智能装备有限公司 A kind of corrosion-resistant pipeline configuration
CN107774545A (en) * 2017-10-30 2018-03-09 中石化重庆天然气管道有限责任公司 A kind of Long-distance Transmission Pipeline anti-corrosion method

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