CN109604069A - A kind of coal flotation agent - Google Patents
A kind of coal flotation agent Download PDFInfo
- Publication number
- CN109604069A CN109604069A CN201811384711.8A CN201811384711A CN109604069A CN 109604069 A CN109604069 A CN 109604069A CN 201811384711 A CN201811384711 A CN 201811384711A CN 109604069 A CN109604069 A CN 109604069A
- Authority
- CN
- China
- Prior art keywords
- parts
- coal
- flotation
- base oil
- flotation agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003245 coal Substances 0.000 title claims abstract description 52
- 239000008396 flotation agent Substances 0.000 title claims abstract description 23
- 239000002199 base oil Substances 0.000 claims abstract description 22
- 238000011084 recovery Methods 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 7
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 7
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 7
- 239000001760 fusel oil Substances 0.000 claims abstract description 7
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 7
- 239000004571 lime Substances 0.000 claims abstract description 7
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 238000004064 recycling Methods 0.000 claims description 6
- 238000005188 flotation Methods 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 5
- 238000000034 method Methods 0.000 description 7
- 238000000926 separation method Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000007667 floating Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002956 ash Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/018—Mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/08—Coal ores, fly ash or soot
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention belongs to coal finishing technology fields, more particularly to a kind of flotation agent for coal flotation, a kind of coal flotation agent is provided, relatively stable, disposable addition is formulated, specific aim is good, effect is good, used technical solution are as follows: raw materials used according to following weight: 100-150 parts of commercial recovery base oil, 30-50 parts of fusel oil, 3-7 parts of sodium metasilicate, 2-6 parts of graphene, 1-5 parts of lime.
Description
Technical field
The invention belongs to coal finishing technology fields, and in particular to a kind of flotation agent for coal flotation.
Background technique
Flotation coal separation method be using on the basis of coal particles Surface Physical Chemistry property different characteristic to coal particles into
A kind of coal preparation method of row sorting, and a kind of coal preparation method being widely used at present.All there is hydrophobic on coal particles surface
Property, while flotation agent is added and improves its hydrophobicity, the mine liquid table of flotation device can be floated on by various process coal particles
Face, it is final to recycle.
The flotation agent that flotation coal separation utilizes plays an important role to coal separation effect.And in traditional flotation coal preparation technique, it uses
Collecting agent treats coal grain in coal separation mud and spoil mud have different compatibility and selectivity, to formed hydrophobic cleaned coal and
The tiny group of hydrophily coal slime, and foaming agent then there is different floatings to take speed out of the cleaned coal of formation and the tiny group of coal slime
Degree, and then an opposite cleaned coal froth bed and coal slime layering are constantly formed, finally successfully realize FLOTATION SEPARATION.Because of traditional technology
Flotation agent used uses plurality of raw materials classification storage and addition, and equipment investment is bigger, technology is relative complex；And each component
It is complex in the technology adjustment of flotation site, it is higher to the skill requirement of operator and random bigger than normal.
Summary of the invention
The invention overcomes the deficiencies of the prior art, and provides a kind of coal flotation agents, and formula is relatively stable, once
Property addition, specific aim is good, effect is good.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention are as follows: a kind of coal flotation agent, it is raw materials used to press
According to following weight: 100-150 parts of commercial recovery base oil, 30-50 parts of fusel oil, 3-7 parts of sodium metasilicate, graphene 2-6
Part, 1-5 parts of lime.
The commercial recovery base oil is the mixture of matter base oil and lighter body in recycling, volume ratio 0.1-
0.5:1-3。
Compared with the prior art, the invention has the beneficial effects that: the present invention is used as using commercial recovery base oil and catches choosing
Agent, can efficiently use commercial recovery base oil, while matter base oil is mixed with lighter body in using, and can improve one
Cost is reduced, while also can satisfy the technique requirement of flotation.Coal flotation agent using when can be used as one-component add, avoid
The addition multi-pipelines such as collecting agent and foaming agent addition respectively, simplifies process flow.Coal flotation agent is to different types of coal difference
Floatation process has good flotation effect, improves clean coal yield, reduces cleans ash, adaptable.
Specific embodiment
Embodiment 1
A kind of coal flotation agent, raw materials used according to following weight: 150 parts of commercial recovery base oil, 50 parts of fusel oil,
7 parts of sodium metasilicate, 6 parts of graphene, 5 parts of lime.
The commercial recovery base oil be recycling in matter base oil and lighter body mixture, volume ratio 0.1:
3。
Embodiment 2
A kind of coal flotation agent, raw materials used according to following weight: 100 parts of commercial recovery base oil, fusel oil 30-50
Part, 3 parts of sodium metasilicate, 2 parts of graphene, 1 part of lime.
The commercial recovery base oil be recycling in matter base oil and lighter body mixture, volume ratio 0.5:
1。
Embodiment 3
A kind of coal flotation agent, raw materials used according to following weight: 120 parts of commercial recovery base oil, 40 parts of fusel oil,
4 parts of sodium metasilicate, 5 parts of graphene, 3 parts of lime.
The commercial recovery base oil be recycling in matter base oil and lighter body mixture, volume ratio 0.3:
1.5。
Embodiment 4
A kind of coal flotation agent, raw materials used according to following weight: 130 parts of commercial recovery base oil, 35 parts of fusel oil,
6 parts of sodium metasilicate, 5 parts of graphene, 4 parts of lime.
The commercial recovery base oil be recycling in matter base oil and lighter body mixture, volume ratio 0.2:
2.8。
By taking the coal sample of Linfen coal preparation plant as an example, coal ash is divided into 15%, and the thin mud part less than 0.04mm accounts for 18%, enters
Material floatation concentration is 100-120g/L, after coal flotation agent disposably adds.Detailed process are as follows: 1, the output tail after dense-medium separation
Coal；2, tail coal enters ore pulp generation bucket generation ore pulp after crushing and screening；3, coal flotation agent is added at one time in premix bucket
It is premixed with ore pulp；4, premix, into flotation device flotation；5, the cleaned coal foam of emersion enters cleaned coal bucket and send filters pressing output cleaned coal,
Tail coal water enters tailing pit, and filters pressing output tail coal mud is sent in underflow.
With the increase of coal flotation agent dosage, become better and better to the flotation effect of coal sample, scrape bubble the time also accordingly shorten；
When coal flotation agent ratio being used to use sec-octyl alcohol and diesel oil as flotation agent, the yield of concentrate is higher, therefore, is reaching same effect
When coal composite floating chemical dosage more save, reduce production cost；Simultaneously use composite floating chemical when, scrape bubble the time it is also shorter,
Flotation speed faster, improves production efficiency.
Above embodiment is merely exemplary to illustrate the principle of the present invention and its effect, and is not intended to limit the present invention.For
Person skilled in the art all without departing from the spirit and scope of the present invention, modifies above-described embodiment or is improved.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by tool usually intellectual in all act technical fields
At all equivalent modifications or change, should be covered by the claims of the present invention.
Claims (2)
1. a kind of coal flotation agent, it is characterised in that: raw materials used according to following weight: commercial recovery base oil 100-
150 parts, 30-50 parts of fusel oil, 3-7 parts of sodium metasilicate, 2-6 parts of graphene, 1-5 parts of lime.
2. a kind of coal flotation agent according to claim 1, it is characterised in that: the commercial recovery base oil is in recycling
The mixture of matter base oil and lighter body, volume ratio 0.1-0.5:1-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811384711.8A CN109604069A (en) | 2018-11-20 | 2018-11-20 | A kind of coal flotation agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811384711.8A CN109604069A (en) | 2018-11-20 | 2018-11-20 | A kind of coal flotation agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109604069A true CN109604069A (en) | 2019-04-12 |
Family
ID=66004397
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811384711.8A Pending CN109604069A (en) | 2018-11-20 | 2018-11-20 | A kind of coal flotation agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109604069A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114870999A (en) * | 2022-05-07 | 2022-08-09 | 南方科技大学 | Coal flotation reagent, preparation method thereof and coal flotation method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0185640A2 (en) * | 1984-12-18 | 1986-06-25 | CIMENTS D'OBOURG, Société Anonyme | Flotation reagent and method for recovering coal from coal-containing material |
| CN101322959A (en) * | 2007-06-16 | 2008-12-17 | 新疆八一钢铁集团有限责任公司 | Use of cold rolling waste emulsified mixture in coal slurry flotation |
| CN101823025A (en) * | 2010-04-01 | 2010-09-08 | 西安科技大学 | Coal flotation agent and preparation method thereof |
| CN101898171A (en) * | 2009-06-01 | 2010-12-01 | 李艺 | Compound coal flotation agent |
| CN106964494A (en) * | 2017-05-17 | 2017-07-21 | 太原工业学院 | A kind of low-cost high-efficiency flotation agent for coal slurry |
| CN107225048A (en) * | 2017-07-01 | 2017-10-03 | 山东金城柯瑞化学有限公司 | Coal flotation agent |
-
2018
- 2018-11-20 CN CN201811384711.8A patent/CN109604069A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0185640A2 (en) * | 1984-12-18 | 1986-06-25 | CIMENTS D'OBOURG, Société Anonyme | Flotation reagent and method for recovering coal from coal-containing material |
| CN101322959A (en) * | 2007-06-16 | 2008-12-17 | 新疆八一钢铁集团有限责任公司 | Use of cold rolling waste emulsified mixture in coal slurry flotation |
| CN101898171A (en) * | 2009-06-01 | 2010-12-01 | 李艺 | Compound coal flotation agent |
| CN101823025A (en) * | 2010-04-01 | 2010-09-08 | 西安科技大学 | Coal flotation agent and preparation method thereof |
| CN106964494A (en) * | 2017-05-17 | 2017-07-21 | 太原工业学院 | A kind of low-cost high-efficiency flotation agent for coal slurry |
| CN107225048A (en) * | 2017-07-01 | 2017-10-03 | 山东金城柯瑞化学有限公司 | Coal flotation agent |
Non-Patent Citations (1)
| Title |
|---|
| 孙传尧: "《选矿工程师手册（第1侧）上卷：选矿通论》", 31 March 2015, 冶金工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114870999A (en) * | 2022-05-07 | 2022-08-09 | 南方科技大学 | Coal flotation reagent, preparation method thereof and coal flotation method |
| CN114870999B (en) * | 2022-05-07 | 2023-06-27 | 南方科技大学 | Coal flotation reagent, preparation method thereof and coal flotation method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190412 |