CN109603687A - A kind of methanol oxidator in efficient silver-colored formaldehyde device - Google Patents
A kind of methanol oxidator in efficient silver-colored formaldehyde device Download PDFInfo
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- CN109603687A CN109603687A CN201811378889.1A CN201811378889A CN109603687A CN 109603687 A CN109603687 A CN 109603687A CN 201811378889 A CN201811378889 A CN 201811378889A CN 109603687 A CN109603687 A CN 109603687A
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- silver
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- methanol
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Abstract
The invention discloses the methanol oxidators in a kind of efficient silver-colored formaldehyde device, including tank body (1), silver catalyst layer (2) and cooling tube (3), cooling tube (3) setting is in tank body (1), the bottom of tank body (1) is provided with truncated cone-shaped structure, the side of truncated cone-shaped structure is provided with feed inlet, silver catalyst layer (2) are provided at feed inlet, the top of tank body (1) is provided with formaldehyde outlet (4), and feed inlet and formaldehyde outlet (4) are connected to tank body (1).Feed inlet is changed to the side of the truncated cone-shaped structure of the tank base of methanol oxidator by the methanol oxidator in efficient silver-colored formaldehyde device of the invention at the top of methanol oxidator, the response area of methanol and silver catalyst can be greatly improved, reaction efficiency is improved, so as to reduce the volume of methanol oxidator.
Description
Technical field
The present invention relates to the methanol oxidators in a kind of efficient silver-colored formaldehyde device.
Background technique
In silver-colored formaldehyde production process, it is mainly following that methanol mixed gas reoxidizes the chemical reaction in device:
Oxidation reaction
CH3OH+1/2O2→CH2O+H2O (1)
Dehydrogenation reaction
CH3OH→CH2O+H2 (2)
Side reaction chemical equation in reaction process:
CH3OH+3/2O2→CO2+2H2O (3)
CH3OH→CO+2H2O……… (4)
CH3OH+H2→CH4+H2O……… (5)
CH3OH+O2→HCOOH+H2O (6)
Formaldehyde industry conventional oxidation device at present, shape are vertical and cylindrical equipment, can generally be divided into three sections from top to bottom:
Upper section is oxidator top cover；Middle section is the combination of catalyst case and quench zone；The settable cooling section of lower section (being set as needed).
Using the technological deficiency of traditional oxidator:
A, since oxidator quench zone uses tubular heat exchanger form, the temperature of the catalyst layer above upper perforated plate is
630~650 DEG C, since upper perforated plate and heat exchanger tube are welded using austenitic stainless steel, at this temperature, austenitic stainless steel
In the sensitizing temperature being the most easily damaged, lattice is coarse, is especially easy to generate intercrystalline corrosion in the heat affected area of welding, when
Between it is long, will the heat affected area of upper perforated plate generate fire check, leak.In oxidator leakage area, local temperature is relatively low, first
The oxidation reaction of alcohol is insufficient, causes unit consumption higher, and the material after repair welding due to welding heat affected zone changes, and will continue to leak
Water.So the number of tubes of oxidator leak reaches 5~10% of heat exchanger tube or so, unit consumption is in 450kg formaldehyde/t formaldehyde
(37%), oxidator must just be replaced.Usually 3 years or so replacement oxidators.General oxidator expense in formaldehyde plant accounts for
To 20% or so.
B, the heat exchanger tube of oxidator, tube sheet is using stainless steel, and shell side generally uses carbon to reduce manufacturing cost
Steel material.Inside tube side, since the gas phase temperature after reaction is relatively high, the thermal expansion coefficient (17.9) of heat exchanger tube stainless steel is again
It is far longer than the thermal expansion coefficient (11.3~13) of shell side carbon steel, so the stress that heat exchanger tube jacks up tube sheet is very big, by calculating,
The thermal stress of one 50,000 tons of oxidator in operation reaches 48 tons or so, answers although using expansion joint to offset the heat of part
Power, but there is the heat affected area especially for tube sheet and heat exchange tube portion is fatal damage at high temperature to thermal stress.
C, the formaldehyde plant for 100,000 tons or more, oxidator effective diameter are greater than φ 2600, the heat of middle section
It is relatively difficult for taking away, in order to reduce the drawbacks of shell side does not go out heat due to band among tube sheet, only using increasing tube spacing
Mode, but at this moment mixed gas is reduced by catalyst effective area, and oxidator has to be made big, caused by result
It is unit consumption height, production capacity is low.
D, the formaldehyde plant for 120,000 tons, the effective diameter φ 2800 of oxidator, oxidator catalyst chamber diameter phi 2900,
Oxidator shell side outer diameter φ 4000, in addition the adapter tube of stretching, it is shipping height that the maximum transport outer diameter of oxidator, which reaches φ 4600,
Limiting value, so the limit production capacity of silver-colored formaldehyde device, that is, 120,000 tons.
E, the critical defect of traditional oxidator: 1, oxidator is vulnerable part, will be replaced within 3 years or so, expensive；2, oxygen
Changing device maximum production capacity can only be to 120,000 ton, and the enlargement of formaldehyde plant is by fatal restriction；3, transportational process is restricted, design
It is almost the largest to 120,000 tons of formaldehyde plants；4, large-scale oxidator unit consumption is higher, operating difficulties.
Therefore, it is necessary to the methanol oxidators in a kind of efficient silver-colored formaldehyde device to solve the above problems.
Summary of the invention
Goal of the invention: the present invention in view of the drawbacks of the prior art, provides in a kind of efficient silver-colored formaldehyde device
Methanol oxidator.
Technical solution: in order to solve the above technical problems, the methanol oxidation in efficient silver-colored formaldehyde device of the invention
Device adopts the following technical scheme that
A kind of methanol oxidator in efficient silver-colored formaldehyde device, including tank body, silver catalyst layer and cooling tube, institute
It states cooling tube to be arranged in the tank body, the bottom of the tank body is provided with truncated cone-shaped structure, the side of the truncated cone-shaped structure
It is provided with feed inlet, the silver catalyst layer is provided at the feed inlet, the top of the tank body is provided with formaldehyde outlet, institute
It states feed inlet and formaldehyde outlet is connected to the tank body.
Further, the side of the truncated cone-shaped structure is provided with a circle feed inlet.It is arranged in the lower side of tank body
One circle feed inlet can effectively increase charging area.
Further, the side of the truncated cone-shaped structure is provided with the circle silver catalyst layer.Silver catalyst layer with
Feed inlet is correspondingly arranged.The one circle silver catalyst layer of side setting of truncated cone-shaped structure, can greatly increase methanol and catalyst
Response area improves oxidation efficiency.
Further, the silver catalyst layer is circumferentially divided into muti-piece silver catalyst block.By the silver catalysis of tank body surrounding
Oxidant layer is circumferentially divided into muti-piece, can be convenient piecemeal and replaces to silver catalyst.
Further, the following above and of every piece of silver catalyst block is respectively arranged with the first confined chamber and second close
Closed chamber, is provided with the second silver catalyst block in the first confined chamber described in first confined chamber and the second confined chamber, and described second
One end of silver catalyst block is contacted with the silver catalyst block, and the other end is provided with ejector apparatus.
Further, filling with inert gas in first confined chamber and/or the second confined chamber.By in the first confined chamber
And/or second confined chamber filling with inert gas prevent in feed inlet gas leakage to the first confined chamber and/or the second confined chamber.
Further, air pressure is higher than the air pressure of the feed inlet in first confined chamber and/or the second confined chamber.Make
The air pressure that air pressure in the first confined chamber and/or the second confined chamber is higher than feed inlet is obtained, the first confined chamber and/or second can be made
The leakage-preventing effect of confined chamber is more preferable.
It further, further include feed space, the feed space is connected to by feed inlet with the tank body, the silver catalysis
Oxidant layer is arranged in the feed space.Facilitate using feed space, by feeding because of catalyst and feed inlet into tank body.
Further, the cooling tube is mutually wound.The film-cooled heat of cooling tube can be greatly increased, and can be had
Effect reduces the stress at the both ends of cooling tube, improves the service life of oxidation unit.
Further, convex top is provided at the top of the tank body, the highest on the convex top is arranged in the formaldehyde outlet
Place.Facilitate formaldehyde to be discharged from top of the tank, and siltation will not be formed in tank body.
The utility model has the advantages that the methanol oxidator in efficient silver-colored formaldehyde device of the invention aoxidizes feed inlet from methanol
It is changed to the side of the truncated cone-shaped structure of the tank base of methanol oxidator at the top of device, methanol and silver catalyst can be greatly improved
Response area, improve reaction efficiency, so as to reduce the volume of methanol oxidator.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the methanol oxidator in efficient silver-colored formaldehyde device of the invention；
Fig. 2 is the section view at the silver catalyst layer of the methanol oxidator in efficient silver-colored formaldehyde device of the invention
Figure.
Specific embodiment
In the following with reference to the drawings and specific embodiments, the present invention is furture elucidated, it should be understood that these embodiments are merely to illustrate
It the present invention rather than limits the scope of the invention, after the present invention has been read, those skilled in the art are to of the invention each
The modification of kind equivalent form falls within the application range as defined in the appended claims.
Refering to Figure 1, the methanol oxidator in efficient silver-colored formaldehyde device of the invention, including tank body 1, silver
Catalyst layer 2 and cooling tube 3, cooling tube 3 are arranged in tank body 1, and the bottom of tank body 1 is provided with truncated cone-shaped structure, truncated cone-shaped knot
The side of structure is provided with feed inlet, and silver catalyst layer 2 is provided at feed inlet, and the top of tank body 1 is provided with formaldehyde outlet 4, into
Material mouth and formaldehyde outlet 4 are connected to tank body 1.Be provided with cooling liquid inlet and cooling liquid outlet outside tank body 1, cooling liquid inlet and
Cooling liquid outlet is connect with the both ends of cooling tube 3 respectively.By cooling liquid inlet and cooling liquid outlet to the intracorporal cooling tube of tank
Middle circulation pours coolant liquid.
Wherein, it is preferred that the side of truncated cone-shaped structure is provided with a circle feed inlet.In one circle of lower side setting of tank body
Feed inlet can effectively increase charging area.Preferably, the side of truncated cone-shaped structure is provided with a circle silver catalyst layer 2.Silver is urged
Agent layer is correspondingly arranged with feed inlet.Truncated cone-shaped structure side setting one circle silver catalyst layer, can greatly increase methanol with
The response area of catalyst improves oxidation efficiency.
Preferably, silver catalyst layer 2 is circumferentially divided into muti-piece silver catalyst block.By the silver catalyst layer of tank body surrounding along week
To muti-piece is divided into, it can be convenient piecemeal and silver catalyst replaced.Preferably, the following above and of every piece of silver catalyst block point
It is not provided with the first confined chamber 22 and the second confined chamber 23, is provided with the second silver catalyst block 21 in the first confined chamber 22, second
One end of silver catalyst block 21 is contacted with silver catalyst block, and the other end is provided with ejector apparatus 24.Wherein, 22 He of the first confined chamber
One end that second confined chamber 23 is contacted with silver catalyst layer is provided with the opening with the cooperation of silver catalyst layer, convenient to silver catalyst
Layer is replaced.Second silver catalyst block 21 is pushed up upwards using ejector apparatus 24, slowly replaces original silver catalyst block,
And this mode is used, facilitate the automatic replacement of realization.Wherein, ejector apparatus 24 can use various means in the prior art
It realizes, such as linear motor, ejection, the second silver catalyst block directly can be carried out to the second silver catalyst block using its output end
Ejection is carried out to former silver catalyst block, until the second silver catalyst block is substituted into former silver catalyst block, realizes silver catalyst more
It changes.Stepper motor can also be used, the output end of stepper motor is become by straight line output using existing transmission mechanism, thus real
Now to the ejection of the second silver catalyst block.Wherein, ejector apparatus 24 is arranged in the first confined chamber 22 below silver catalyst layer
In, influence of the tank body to ejector apparatus 24 after capable of effectively avoiding heating.
Preferably, filling with inert gas in the first confined chamber 22 and/or the second confined chamber 23.By in the first confined chamber 22
And/or 23 filling with inert gas of the second confined chamber prevents in feed inlet gas leakage to the first confined chamber 22 and/or the second confined chamber
23.Preferably, air pressure is higher than the air pressure of feed inlet in the first confined chamber 22 and/or the second confined chamber 23.So that the first confined chamber
22 and/or second air pressure in confined chamber 23 be higher than the air pressure of feed inlet, the first confined chamber 22 and/or the second confined chamber can be made
23 leakage-preventing effect is more preferable.
It preferably, further include feed space 25, feed space 25 is connected to by feed inlet with tank body 1, and the setting of silver catalyst layer 2 exists
In feed space 25.Facilitate using feed space, by feeding because of catalyst and feed inlet into tank body.Preferably, cooling tube 3 is mutual
Winding.The film-cooled heat of cooling tube can be greatly increased, and the stress at the both ends of cooling tube can be effectively reduced, improves oxidation
The service life of device.Preferably, the top of tank body 1 is provided with convex top, and the highest point on convex top is arranged in formaldehyde outlet 4.It is convenient
Formaldehyde is discharged from top of the tank, and siltation will not be formed in tank body.The top and bottom of tank body 1 are respectively arranged with the first opening
With the second opening, the first opening of upper end connection of cooling tube 3, the second opening of lower end connection.Wherein, it is preferred that first, which is open, is
Water outlet, the second opening are water inlet.It can also be to set water inlet for the first opening, the second opening is set as water outlet.Figure
Only part cooling tube 3 and the connection of the first opening and the second opening are marked in 1, not by whole cooling tubes 3 and first
The connection of opening and the second opening is all drawn.
Methanol oxidator in efficient silver-colored formaldehyde device of the invention is by feed inlet from the top of methanol oxidator
It is changed to the side of the tank body of methanol oxidator, the response area of methanol and silver catalyst can be greatly improved, improves reaction efficiency,
So as to reduce the volume of methanol oxidator.
Claims (10)
1. the methanol oxidator in a kind of efficient silver-colored formaldehyde device, which is characterized in that including tank body (1), silver catalyst
Layer (2) and cooling tube (3), in the tank body (1), the bottom of the tank body (1) is provided with rotary table for cooling tube (3) setting
Shape structure, the side of the truncated cone-shaped structure are provided with feed inlet, and the silver catalyst layer (2) is provided at the feed inlet,
The top of the tank body (1) is provided with formaldehyde outlet (4), and the feed inlet and formaldehyde outlet (4) connect with the tank body (1)
It is logical.
2. the methanol oxidator in efficient silver-colored formaldehyde device as described in claim 1, which is characterized in that the rotary table
The side of shape structure is provided with a circle feed inlet.
3. the methanol oxidator in efficient silver-colored formaldehyde device as described in claim 1, which is characterized in that the rotary table
The side of shape structure is provided with the circle silver catalyst layer (2).
4. the methanol oxidator in efficient silver-colored formaldehyde device as claimed in claim 3, which is characterized in that the silver is urged
Agent layer (2) is circumferentially divided into muti-piece silver catalyst block.
5. the methanol oxidator in efficient silver-colored formaldehyde device as claimed in claim 4, which is characterized in that described in every piece
The following above and of silver catalyst block is respectively arranged with the first confined chamber (22) and the second confined chamber (23), first confined chamber
(22) and in the second confined chamber (23) first confined chamber (22) it is provided with the second silver catalyst block (21), second silver medal is urged
One end of agent block (21) is contacted with the silver catalyst block, and the other end is provided with ejector apparatus (24).
6. the methanol oxidator in efficient silver-colored formaldehyde device as claimed in claim 5, which is characterized in that described first
Filling with inert gas in confined chamber (22) and/or the second confined chamber (23).
7. the methanol oxidator in efficient silver-colored formaldehyde device as claimed in claim 6, which is characterized in that described first
Air pressure is higher than the air pressure of the feed inlet in confined chamber (22) and/or the second confined chamber (23).
8. the methanol oxidator in efficient silver-colored formaldehyde device as described in claim 1, which is characterized in that further include into
Expect room (25), the feed space (25) is connected to by feed inlet with the tank body (1), and the silver catalyst layer (2) is arranged in institute
It states in feed space (25).
9. the methanol oxidator in efficient silver-colored formaldehyde device as described in claim 1, which is characterized in that the cooling
(3) are managed mutually to wind.
10. the methanol oxidator in efficient silver-colored formaldehyde device as described in claim 1, which is characterized in that the tank
Convex top is provided at the top of body (1), the highest point on the convex top is arranged in the formaldehyde outlet (4).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811378889.1A CN109603687B (en) | 2018-11-19 | 2018-11-19 | Methanol oxidizer in efficient silver-process formaldehyde device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811378889.1A CN109603687B (en) | 2018-11-19 | 2018-11-19 | Methanol oxidizer in efficient silver-process formaldehyde device |
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| Publication Number | Publication Date |
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| CN109603687A true CN109603687A (en) | 2019-04-12 |
| CN109603687B CN109603687B (en) | 2021-08-24 |
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| CN201811378889.1A Active CN109603687B (en) | 2018-11-19 | 2018-11-19 | Methanol oxidizer in efficient silver-process formaldehyde device |
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101380544A (en) * | 2007-09-07 | 2009-03-11 | 巴布考克及威尔考克斯公司 | Catalyst particulate diverter |
| CN102091572A (en) * | 2011-01-20 | 2011-06-15 | 宋晓轩 | Polymer reactor for synthesizing rubber |
| WO2011093749A2 (en) * | 2010-02-01 | 2011-08-04 | Infra Technologies Ltd | Process for producing synthetic liquid hydrocarbons and reactor for fischer-tropsch synthesis |
| CN202028401U (en) * | 2011-03-10 | 2011-11-09 | 青岛华拓电力环保有限公司 | Automatic screen replacing device for filtering denitration catalyst |
| CN202400599U (en) * | 2011-12-22 | 2012-08-29 | 中国科学院宁波材料技术与工程研究所 | Automatic feeding device |
| CN204799235U (en) * | 2015-06-29 | 2015-11-25 | 天津市先权工贸发展有限公司 | Chemistry catalytic converter |
| CN105617947A (en) * | 2014-10-27 | 2016-06-01 | 中国石油化工股份有限公司 | Fixed bed-fluidized bed reactor and application thereof |
| CN107628987A (en) * | 2017-09-20 | 2018-01-26 | 南京红太阳生物化学有限责任公司 | A kind of method of membrane reactor production 2,2` bipyridyls |
| CN108636308A (en) * | 2018-05-02 | 2018-10-12 | 侯建华 | A kind of universal chlorination microreactor of tubular type |
-
2018
- 2018-11-19 CN CN201811378889.1A patent/CN109603687B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101380544A (en) * | 2007-09-07 | 2009-03-11 | 巴布考克及威尔考克斯公司 | Catalyst particulate diverter |
| WO2011093749A2 (en) * | 2010-02-01 | 2011-08-04 | Infra Technologies Ltd | Process for producing synthetic liquid hydrocarbons and reactor for fischer-tropsch synthesis |
| CN102091572A (en) * | 2011-01-20 | 2011-06-15 | 宋晓轩 | Polymer reactor for synthesizing rubber |
| CN202028401U (en) * | 2011-03-10 | 2011-11-09 | 青岛华拓电力环保有限公司 | Automatic screen replacing device for filtering denitration catalyst |
| CN202400599U (en) * | 2011-12-22 | 2012-08-29 | 中国科学院宁波材料技术与工程研究所 | Automatic feeding device |
| CN105617947A (en) * | 2014-10-27 | 2016-06-01 | 中国石油化工股份有限公司 | Fixed bed-fluidized bed reactor and application thereof |
| CN204799235U (en) * | 2015-06-29 | 2015-11-25 | 天津市先权工贸发展有限公司 | Chemistry catalytic converter |
| CN107628987A (en) * | 2017-09-20 | 2018-01-26 | 南京红太阳生物化学有限责任公司 | A kind of method of membrane reactor production 2,2` bipyridyls |
| CN108636308A (en) * | 2018-05-02 | 2018-10-12 | 侯建华 | A kind of universal chlorination microreactor of tubular type |
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