CN109593431A - A kind of concrete-bridge cooling and insulating type protective coating - Google Patents

A kind of concrete-bridge cooling and insulating type protective coating Download PDF

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Publication number
CN109593431A
CN109593431A CN201811395829.0A CN201811395829A CN109593431A CN 109593431 A CN109593431 A CN 109593431A CN 201811395829 A CN201811395829 A CN 201811395829A CN 109593431 A CN109593431 A CN 109593431A
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parts
modified
bridge
viscosity
concrete
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CN109593431B (en
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严周
程承
杨澍桔
杨坚强
李果
王翔
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Yunnan Transportation And Transportation Career Academy
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Yunnan Transportation And Transportation Career Academy
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of concrete-bridge cooling and insulating type protective coatings, it includes the raw material of following parts by weight: 100 parts of liquid epoxies, 15-25 parts of curing agent, 8-15 parts of composite pigment, 20-40 parts of compounded mix, 0.2-1 part of anti-settling agent, 0.5-1 part of anti-crack fiber;A kind of concrete-bridge of the invention cooling and insulating type protective coating, can reflected sunlight, be effectively reduced bridge surface temperature, improve bridge service life.

Description

A kind of concrete-bridge cooling and insulating type protective coating
Technical field
The present invention relates to paint field more particularly to a kind of concrete-bridge cooling and insulating type protective coatings.
Background technique
Concrete-bridge is to use armored concrete as the bridge of main construction material.In middle-size and small-size river valley and hydraulic engineering In service bridge etc. be widely adopted.
Concrete-bridge is chronically exposed under sunlight, and exposing to the weather can generate weathering aging, and is exposed under the sun warm Degree temperature rising can be accelerated, and then accelerate the damage of bridge.
Therefore, insulating moulding coating comes into being, and insulating moulding coating refers to that a kind of blocking having recently been developed, reflected sunlight are closely red The functional coating of outer heat, makes roof insulation cool down, energy-saving.With heat-insulated, waterproof, antirust, anti-corrosion, short time limit, see Fast characteristic is imitated, replaces water sprinkler system, heat-preservation cotton, foam sponge, interlayer iron sheet etc. comprehensively.Insulating moulding coating divides from characteristic principle There are mainly three types of classes, isolation conduction type insulating moulding coating, reflective insulation coating and Radiation Heat-insulated Paint.In addition to above-mentioned three type Type insulating moulding coating, external heat insulating function coating has already appeared a kind of thermal insulation paint, in addition to having the excellent of above-mentioned insulating moulding coating Other than point, more for peculiar heat insulation effect.
Number of patent application: 201610505736.3, a kind of heat-reflecting insulating coating discloses a kind of heat-reflecting heat-insulating painting Material, is prepared: 10-20 parts of water, 10-20 parts of acrylic emulsion, hollow glass microbead 15-by the raw material of following parts by weight 25 parts, 5-15 parts of pigment, 15-25 parts of titanium dioxide, 15-25 parts of alumina silicate, 20-30 parts of calcium carbonate, Sodium Polyacrylate 3- 9 parts, 10-20 parts of heat-insulated synergist, 0.5-5 parts of antifreezing agent.Heat-reflecting insulating coating provided by the invention can be prevented effectively The heat of the sun is accumulated in body surface to heat up, and can carry out heat heat loss through radiation cooling automatically, antibiotic property, high abrasion resistance, It is easy for construction, it is high-efficient.
Above-mentioned insulating moulding coating is heated up with preventing the heat of the sun from accumulating in body surface, but in High aititude hot area, Solar radiation intensity is big, and accumulation of heat effect is obvious, and heat dissipation effect is bad, still will lead to concrete-bridge aging aggravation.
Summary of the invention
The purpose of the present invention is to solve the shortcomings of the prior art and to provide a kind of concrete-bridge cooling and insulating type anti- Protect coating, can reflected sunlight, be effectively reduced bridge surface temperature, improve bridge service life.
In order to achieve the above objectives, the present invention is achieved through the following technical solutions.
A kind of concrete-bridge cooling and insulating type protective coating, it includes the raw material of following parts by weight: liquid epoxy tree 100 parts of rouge, 15-25 parts of curing agent, 8-15 parts of composite pigment, 20-40 parts of compounded mix, 0.2-1 part of anti-settling agent, cracking resistance is fine 0.5-1 part of dimension;
Liquid epoxies viscosity at 25 DEG C is 450-600cP, and epoxide equivalent is 180-220, solidification temperature It is 5 DEG C -10 DEG C;
The curing agent is that modified fatty amine class I liquid I curing agent and modified polyamide resinoid compound, the modification For fatty amines resin at 25 DEG C, viscosity is 8-12cP, and amine value is 550-750mg KOH/g;The modified polyamide class tree For rouge at 25 DEG C, viscosity is 9-11cP, and amine value is 650mg KOH/g;The mass ratio of modified fatty amine and modified polyamide is 2: 3—8;
The composite pigment is glass microballoon, and the glass microballoon surface cladding is pigment coating;The glass microballoon Refractive index is 1.80-1.95, and particle size range is 15 μm-125 μm;
The compounded mix includes rutile type nano titanic oxide and anatase nano-titanium dioxide, rutile type nano Titanium dioxide and anatase nano-titanium dioxide are as follows: 1:0.4-0.8;
The anti-settling agent is titanate coupling agent;
The anti-crack fiber is hollow vinal, internal to fill paraffin.
A kind of concrete-bridge of the invention cooling and insulating type protective coating, can reflected sunlight, bridge is effectively reduced Surface temperature improves bridge service life.
Specific embodiment
Below with reference to embodiment, the present invention will be further described, but is not limited to the content on specification.
A kind of concrete-bridge cooling and insulating type protective coating, it includes the raw material of following parts by weight: liquid epoxy tree 100 parts of rouge, 15-25 parts of curing agent, 8-15 parts of composite pigment, 20-40 parts of compounded mix, 0.2-1 part of anti-settling agent, cracking resistance is fine 0.5-1 part of dimension;
Liquid epoxies is a kind of modified liquid epoxy resin of low viscosity, and under the conditions of 25 DEG C, viscosity is 450- 600cP, epoxide equivalent, being capable of (5 DEG C-10 DEG C) of lower temperature solidifications 180-220.
Curing agent is that modified fatty amine class I liquid I curing agent and modified polyamide resinoid compound, modified fat amine The amine value of resin is 550-750mg KOH/g.
Viscosity: 25 DEG C, 8-12cP), the amine value of modified polyamide resinoid is 650mg KOH/g, viscosity: 25 DEG C, 9- 11cP, composite modified fatty amine: the mass ratio of modified polyamide is 2:3-8, and the two compounds the curing agent to be formed and accounts for resin quality Score 15% -25%, it is final to realize that meeting construction operation time is no earlier than 90min, requirement of the surface drying earlier than 4h.
Composite pigment is by the glass microballoon with retroreflecting function, and ranges of indices of refraction is 1.80-1.95, partial size model Enclosing is 15 μm -125 μm, and it is pigment coating that outer cladding infrared projection type system pigment coating, which is formed by functional form pigments and fillers, Sunlight is not absorbed, realizes the transmission of sunlight, retroreflecting type glass microballoon can realize back the sunlight that transmission is come in The reflection returned, to sunlight without or it is a small amount of absorb, to have the purpose of cooling.Its quality accounts for resin quality score 8% -15%.It is pigment coating be using based material-black is that pigment black is four pyromellitic imides, red is Bis- (3, the 5- 3,5-dimethylphenyl) acid imides of tetrabasic carboxylic acid-carry out plated film on hollow glass micropearl surface using cladding process.
Compounded mix be heat reflection functional form filler, mainly include modified rutile type nano titanic oxide and A small amount of modified anatase nano-titanium dioxide, rutile type nano titanic oxide and anatase nano-titanium dioxide are as follows: 1:0.4-0.8, modification are to carry out coupling agent surface modification to nanoscale titanium dioxide surface, are reflected having sunlight When, improve to the reflection function of ultraviolet light, surface coupling agent modification the purpose is to reduce reduce titanium dioxide in the coating to painting Layer carries out atomizing, improves service life.It is 20% -40% that compounded mix, which accounts for resin quality score,.
Anti-settling agent is titanate coupling agent, accounts for resin quality score 0.5% -1%.
Increase anti-crack fiber profile material is polyvinyl alcohol (PVA) type doughnut, which is with hollow structure;In order to Heat-proof quality is further increased, to phase-change material filling is carried out in the nano polymer fibers of hollow structure, phase-change material is stone Wax.Account for resin quality score 0.5% -1%.
Specific example one: 100 parts of liquid epoxies, 15 parts of curing agent, 15 parts of composite pigment, 20 parts of compounded mix, resist Split 0.2 part of fiber, 0.5 part of anti-settling agent, 0.5-1 part of anti-crack fiber;
Under the conditions of 25 DEG C, viscosity is the liquid epoxies of 450cP, and epoxide equivalent, can be at minimum 5 DEG C or more 180 Brushing construction requirement simultaneously solidifies.
In curing agent, modified fatty amine: the mass ratio of modified polyamide is 2:3, modified fat amine resins (550mg KOH/g, viscosity: 25 DEG C, 8cP), modified polyamide resinoid (650mg KOH/g, viscosity: 25 DEG C, 9cP).
Composite pigment is the glass microballoon with retroreflecting function, ranges of indices of refraction 1.80, particle size range 125 μm;
Compounded mix be heat reflection functional form filler, mainly include modified rutile type nano titanic oxide and A small amount of modified anatase nano-titanium dioxide, rutile type nano titanic oxide and anatase nano-titanium dioxide are as follows: 1:0.4。
Specific example two: 100 parts of liquid epoxies, 15 parts of curing agent, 8 parts of composite pigment, 30 parts of compounded mix, anti-settling 1 part of agent, 0.5-1 part of anti-crack fiber;
Liquid epoxies is under the conditions of 25 DEG C, viscosity 600cP, epoxide equivalent 220, can minimum 25 DEG C with On meet brushing construction requirement and solidify
In curing agent, modified fatty amine: the mass ratio of modified polyamide is 1:4, modified fat amine resins (750mg KOH/g, viscosity: 25 DEG C, 12cP), modified polyamide resinoid (650mg KOH/g, viscosity: 25 DEG C, 11cP).
Composite pigment is the glass microballoon with retroreflecting function, and ranges of indices of refraction 1.95, particle size range is 15 μ m;
Compounded mix be heat reflection functional form filler, mainly include modified rutile type nano titanic oxide and A small amount of modified anatase nano-titanium dioxide, rutile type nano titanic oxide and anatase nano-titanium dioxide are as follows: 1:0.8。
Specific example three: 100 parts of liquid epoxies, 20 parts of curing agent, 11 parts of composite pigment, 30 parts of compounded mix, resist Fiber 1 is split to divide;0.8 part of anti-settling agent, 0.5-1 part of anti-crack fiber;
Liquid epoxies is under the conditions of 25 DEG C, viscosity 500cP, epoxide equivalent 200, can minimum 10 DEG C with On meet brushing construction requirement and solidify.
In curing agent, modified fatty amine: the mass ratio of modified polyamide is 2:3, modified fat amine resins (650mg KOH/g, viscosity: 25 DEG C, 10cP), modified polyamide resinoid (650mg KOH/g, viscosity: 25 DEG C, 10cP).
Composite pigment is the glass microballoon with retroreflecting function, and ranges of indices of refraction 1.88, particle size range is 70 μ m;
Compounded mix be heat reflection functional form filler, mainly include modified rutile type nano titanic oxide and A small amount of modified anatase nano-titanium dioxide, rutile type nano titanic oxide and anatase nano-titanium dioxide are as follows: 1:0.6。
A kind of concrete-bridge of the invention cooling and insulating type protective coating, can reflected sunlight, bridge is effectively reduced Surface temperature improves bridge service life.
Obviously, above embodiment of the invention be only to clearly illustrate example of the present invention, and not be Restriction to embodiments of the present invention.For those of ordinary skill in the art, on the basis of the above description also It can make other variations or changes in different ways.Here all embodiments can not be exhaustive.It is all to belong to this The obvious changes or variations that the technical solution of invention is extended out are still in the scope of protection of the present invention.

Claims (1)

1. a kind of concrete-bridge cooling and insulating type protective coating, it is characterised in that: it includes the raw material of following parts by weight: liquid 100 parts of body epoxy resin, 15-25 parts of curing agent, 8-15 parts of composite pigment, 20-40 parts of compounded mix, anti-settling agent 0.2-1 Part, 0.5-1 part of anti-crack fiber;
Liquid epoxies viscosity at 25 DEG C is 450-600cP, and epoxide equivalent is 180-220, solidification temperature 5 ℃—10℃;
The curing agent is that modified fatty amine class I liquid I curing agent and modified polyamide resinoid compound, the modified fat For amine resins at 25 DEG C, viscosity is 8-12cP, and amine value is 550-750mg KOH/g;The modified polyamide resinoid At 25 DEG C, viscosity is 9-11cP, and amine value is 650mg KOH/g;The mass ratio of modified fatty amine and modified polyamide is 2: 3—8;
The composite pigment is glass microballoon, and the glass microballoon surface cladding is pigment coating;The glass microballoon refraction Rate is 1.80-1.95, and particle size range is 15 μm-125 μm;
The compounded mix includes rutile type nano titanic oxide and anatase nano-titanium dioxide, rutile type nano dioxy Change titanium and anatase nano-titanium dioxide are as follows: 1:0.4-0.8;
The anti-settling agent is titanate coupling agent;
The anti-crack fiber is hollow vinal, internal to fill paraffin.
CN201811395829.0A 2018-11-22 2018-11-22 Cooling and heat insulation type protective coating for concrete bridge Expired - Fee Related CN109593431B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111823681A (en) * 2020-07-13 2020-10-27 巩义市泛锐熠辉复合材料有限公司 Heat-insulation composite board and preparation method thereof

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