CN109577040A - A kind of pigment printing binding agent and preparation method thereof bright in luster and excellent fastness - Google Patents
A kind of pigment printing binding agent and preparation method thereof bright in luster and excellent fastness Download PDFInfo
- Publication number
- CN109577040A CN109577040A CN201811304969.2A CN201811304969A CN109577040A CN 109577040 A CN109577040 A CN 109577040A CN 201811304969 A CN201811304969 A CN 201811304969A CN 109577040 A CN109577040 A CN 109577040A
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- China
- Prior art keywords
- bright
- emulsifier
- luster
- pigment printing
- excellent fastness
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a kind of pigment printing binding agents and preparation method thereof bright in luster and excellent fastness, described adhesive includes butyl acrylate, emulsifier and crosslinking agent, crosslinking agent application methylene diacrylamide in described adhesive, the butyl acrylate, emulsifier and crosslinking agent in after emulsion polymerization state through adding methylene diacrylamide before radiation treatment, by mass percentage, the additive amount of the methylene diacrylamide is 0.1 ‰~the 0.3 ‰ of lotion total amount, the crosslinking agent is hydroxymethyl acrylamide, acrylamide and methylene diacrylamide etc., the emulsifier is ionic emulsifying agent, by butyl acrylate, crosslinking agent and emulsifier, deionized water prepares 1kg by required solid content, through 15~20min of Over emulsfication, it is taken out after carrying out Co60 gamma-rays irradiation appropriate time, filter lotion And pH value 6.5~7 is adjusted, which can effectively improve the dry and wet crock fastness on cotton, and preparation process is simple.
Description
Technical field
The present invention relates to pigment printing binding agent technical field, specially a kind of bright in luster and excellent fastness coating print
Flower adhesive and preparation method thereof.
Background technique
Radiation method composite adhesives technical principle: Co60 decay generates gamma-rays, under gamma-rays effect, butyl acrylate
Polymerization reaction occurs for equal monomers, generates polymer binder, and feature: gamma-rays penetration power is strong, and partial size is more equal when reacting in this way
It is even, stable, and molecular weight is high, and adhesive fastness is strong, and product is also relatively stable, and production product tinctorial yield is high, bright-colored；Production
It reacts at normal temperature in the process, does not have to heating, energy conservation and environmental protection, with the continuous development of radiation-induced emulsion polymerization technology, to product
The requirement of quality also constantly improves, then the requirement to pigment printing binding agent fastness will also improve.
Summary of the invention
The purpose of the present invention is to provide a kind of pigment printing binding agents and its preparation side bright in luster and excellent fastness
Method, to solve the problems, such as to propose that pigment printing binding agent fastness is lower in above-mentioned background technique.
To achieve the above object, the invention provides the following technical scheme: the invention discloses a kind of bright in luster and fastness
Excellent pigment printing binding agent, including butyl acrylate, emulsifier and crosslinking agent, added with methene double third in described adhesive
Acrylamide.
Preferably, the butyl acrylate, emulsifier and crosslinking agent in after emulsion polymerization state through radiation treatment.
Preferably, the additive amount of the different methylene diacrylamide by mass percentage be lotion total amount 0.1 ‰~
0.3‰。
Preferably, the crosslinking agent is hydroxymethyl acrylamide, one kind or several of acrylamide and methylene diacrylamide
The mixture of kind, the emulsifier are ionic emulsifying agent.
Preferably, pigment printing binding agent described bright in luster and excellent fastness, preparation method are by following mistake
Journey preparation:
By butyl acrylate, crosslinking agent and emulsifier, deionized water prepares 1kg by required solid content, through Over emulsfication 15~
20min takes out after carrying out Co60 gamma-rays irradiation appropriate time, filters lotion and adjust pH value 6.5~7.0.
Preferably, the crosslinking agent be hydroxymethyl acrylamide, one of acrylamide and methylene diacrylamide or
Several mixtures, the emulsifier are ionic emulsifying agent.
Preferably, described to be passed through after addition methylene diacrylamide directly in the mixing formula of butyl acrylate and emulsifier
Radiation method preparation.
Preferably, the emulsifier is ionic emulsifying agent.
Preferably, the methylene diacrylamide by mass percentage, additive amount be mixing formula 0.1 ‰~
0.3‰。
Compared with prior art, the beneficial effects of the present invention are:
1, the methylene diacrylamide of different amounts can make adhesive reach good dry and wet crock fastness on cotton,
Due to containing unsaturated bond in methylene diacrylamide structure, with high activity, high temperature or Qiang Guanghui self-crosslinking are encountered,
It is slightly soluble in water, ethyl alcohol, and hygroscopicity very little, is helped well again fastness is improved, especially on cotton, with other crosslinking agents
Cooperation can reach better effect.
2, the present invention application Co60 decay generate gamma-rays, and under gamma-rays effect, the monomers such as butyl acrylate occur poly-
Reaction is closed, the binder molecule amount of generation is high, and adhesive fastness is strong, and product is stablized, and tinctorial yield is high, and it is bright-colored, in production process
It reacts at normal temperature, does not have to heating, energy conservation and environmental protection.Using function additive appropriate, significantly improve pigment printing binding agent
Crock fastness and hairy effect.
Specific embodiment
The embodiment of the present application is by providing a kind of pigment printing binding agent and its preparation side bright in luster and excellent fastness
Method solves the problems, such as the crock fastness of pigment printing binding agent and fluffing in the prior art, the double propylene of the methene of different amounts
Amide can make adhesive reach good dry and wet crock fastness on cotton, due to containing not in methylene diacrylamide structure
Saturated bond, therefore there is high activity, high temperature or Qiang Guanghui self-crosslinking are encountered, water, ethyl alcohol, and hygroscopicity very little are slightly soluble in,
It is helped well again fastness is improved, especially on cotton, better effect can be reached with the cooperation of other crosslinking agents.
The present invention provides a kind of technical solution: the invention discloses a kind of pigment printing bright in luster and excellent fastness is viscous
Mixture, including butyl acrylate, emulsifier and crosslinking agent are added with methylene diacrylamide in adhesive.
Preferably, butyl acrylate, emulsifier and crosslinking agent in after emulsion polymerization state through radiation treatment.
Preferably, the additive amount of different methylene diacrylamide by mass percentage be lotion total amount 0.1 ‰~
0.3‰。
Preferably, crosslinking agent is hydroxymethyl acrylamide, acrylamide and methylene diacrylamide it is one or more of
Mixture, the emulsifier are ionic emulsifying agent.
Preferably, pigment printing binding agent bright in luster and excellent fastness, preparation method are by following process system
Standby:
By butyl acrylate, crosslinking agent and emulsifier, deionized water prepares 1kg by required solid content, through Over emulsfication 15~
20min takes out after carrying out Co60 gamma-rays irradiation appropriate time, filters lotion and adjust pH value 6.5~7.0.
Preferably, crosslinking agent is hydroxymethyl acrylamide, one or more of acrylamide and methylene diacrylamide
Mixture, the emulsifier be ionic emulsifying agent.
Preferably, directly in the mixing formula of butyl acrylate and emulsifier add methylene diacrylamide after through radiating
Method preparation.
Preferably, emulsifier is ionic emulsifying agent.
Preferably, by mass percentage, additive amount is 0.1 ‰~the 0.3 ‰ of mixing formula to methylene diacrylamide.
It is clearly and completely described below in conjunction with the technical solution in the embodiment of the present invention, it is clear that described reality
Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without making creative work belongs to what the present invention protected
Range.
Embodiment one:
Pigment printing binding agent a kind of bright in luster and excellent fastness, pigment printing bright in luster and excellent fastness are viscous
The component material of mixture includes: butyl acrylate, emulsifier and crosslinking agent, is added with methylene diacrylamide in adhesive, and third
Olefin(e) acid butyl ester, emulsifier and crosslinking agent be in emulsion polymerization state before add methylene diacrylamide.
Preferably, by mass percentage, the additive amount of methylene diacrylamide is the 0.1 ‰ of lotion total amount.
Preferably, crosslinking agent is hydroxymethyl acrylamide, the mixture of acrylamide and methylene diacrylamide, emulsifier
For ionic emulsifying agent.
In the present embodiment, pigment printing binding agent bright in luster and excellent fastness includes the following steps:
By butyl acrylate, crosslinking agent and emulsifier, deionized water prepares 1kg by required solid content, and 0.1 ‰ methenes are added
Bisacrylamide takes out after carrying out Co60 gamma-rays irradiation appropriate time through Over emulsfication 15min, filters lotion and adjust PH
Value 6.5, by cotton color fastness detection fastness can achieve 3.5-4.0 grades of dry friction, 2.5 grades of wet friction or more.
Embodiment two
Pigment printing binding agent a kind of bright in luster and excellent fastness, pigment printing bright in luster and excellent fastness are viscous
The component material of mixture includes: butyl acrylate, emulsifier and crosslinking agent, is added with methylene diacrylamide in adhesive, and third
Olefin(e) acid butyl ester, emulsifier and crosslinking agent be in emulsion polymerization state before add methylene diacrylamide.
Preferably, by mass percentage, the additive amount of methylene diacrylamide is the 0.2 ‰ of lotion total amount.
Preferably, crosslinking agent is hydroxymethyl acrylamide, the mixture of acrylamide and methylene diacrylamide, emulsifier
For ionic emulsifying agent.
In the present embodiment, pigment printing binding agent bright in luster and excellent fastness includes the following steps:
By butyl acrylate, crosslinking agent and emulsifier, deionized water prepares 1kg by required solid content, and 0.2 ‰ methenes are added
Bisacrylamide takes out after carrying out Co60 gamma-rays irradiation appropriate time through Over emulsfication 15min, filters lotion and adjust PH
Value 6.5, by cotton color fastness detection fastness can achieve 4.0 grades of dry friction, 3.0 grades of wet friction or more.
Embodiment three
Pigment printing binding agent a kind of bright in luster and excellent fastness, pigment printing bright in luster and excellent fastness are viscous
The component material of mixture includes: butyl acrylate, emulsifier and crosslinking agent, is added with methylene diacrylamide in adhesive, and third
Olefin(e) acid butyl ester, emulsifier and crosslinking agent be in emulsion polymerization state before add methylene diacrylamide.
Preferably, by mass percentage, the additive amount of methylene diacrylamide is the 0.25 ‰ of lotion total amount.
Preferably, crosslinking agent is hydroxymethyl acrylamide, the mixture of acrylamide and methylene diacrylamide, emulsifier
For ionic emulsifying agent.
In the present embodiment, pigment printing binding agent bright in luster and excellent fastness includes the following steps:
By butyl acrylate, crosslinking agent and emulsifier, deionized water prepares 1kg by required solid content, and 0.25 ‰ first are added
Bisacrylamide is pitched, through Over emulsfication 15min, is taken out after carrying out Co60 gamma-rays irradiation appropriate time, filters lotion and adjust
PH value 6.5, by cotton color fastness detection fastness can achieve 4.0-4.5 grades of dry friction, 3.5 grades of wet friction or more.
Example IV
Pigment printing binding agent a kind of bright in luster and excellent fastness, pigment printing bright in luster and excellent fastness are viscous
The component material of mixture includes: butyl acrylate, emulsifier and crosslinking agent, is added with methylene diacrylamide in adhesive, and third
Olefin(e) acid butyl ester, emulsifier and crosslinking agent be in emulsion polymerization state before add methylene diacrylamide.
Preferably, by mass percentage, the additive amount of methylene diacrylamide is the 0.3 ‰ of lotion total amount.
Preferably, crosslinking agent is hydroxymethyl acrylamide, the mixture of acrylamide and methylene diacrylamide；Emulsifier
For ionic emulsifying agent.
In the present embodiment, pigment printing binding agent bright in luster and excellent fastness includes the following steps:
By butyl acrylate, crosslinking agent and emulsifier, deionized water prepares 1kg by required solid content, and 0.3 ‰ methenes are added
Bisacrylamide takes out after carrying out Co60 gamma-rays irradiation appropriate time through Over emulsfication 15min, filters lotion and adjust PH
Value 6.5, by cotton color fastness detection fastness can achieve 4.0-4.5 grades of dry friction, 3.5 grades of wet friction or more.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (9)
1. a kind of pigment printing binding agent bright in luster and excellent fastness, it is characterised in that: including butyl acrylate, emulsifier
And crosslinking agent, methylene diacrylamide is added in described adhesive.
2. pigment printing binding agent according to claim 1 bright in luster and excellent fastness, it is characterised in that: described third
Olefin(e) acid butyl ester, emulsifier and crosslinking agent be in emulsion polymerization state after through adding methylene diacrylamide before radiation treatment.
3. pigment printing binding agent according to claim 2 bright in luster and excellent fastness, it is characterised in that: press quality
Percentage meter, the additive amount of the methylene diacrylamide are 0.1 ‰~the 0.3 ‰ of lotion total amount.
4. pigment printing binding agent according to claim 1 to 2 bright in luster and excellent fastness, it is characterised in that: described
Crosslinking agent is hydroxymethyl acrylamide, acrylamide and methylene diacrylamide etc.；The emulsifier is ionic emulsifying agent.
5. -4 any pigment printing binding agent bright in luster and excellent fastness according to claim 1, preparation side
Method:
By butyl acrylate, crosslinking agent and emulsifier, deionized water prepares 1kg by required solid content, through Over emulsfication 15~
20min takes out after carrying out Co60 gamma-rays irradiation appropriate time, filters lotion and adjust pH value 6.5~7.
6. pigment printing binding agent according to claim 5 bright in luster and excellent fastness, it is characterised in that: the friendship
Connection agent is hydroxymethyl acrylamide, acrylamide and methylene diacrylamide etc.；The emulsifier is ionic emulsifying agent.
7. pigment printing binding agent according to claim 1 bright in luster and excellent fastness, preparation method: described third
It is prepared after directly adding methylene diacrylamide in the mixing formula of olefin(e) acid butyl ester and emulsifier through radiation method.
8. pigment printing binding agent according to claim 7 bright in luster and excellent fastness, it is characterised in that: the cream
Agent is ionic emulsifying agent.
9. pigment printing binding agent according to claim 7 bright in luster and excellent fastness, it is characterised in that: the first
Pitch bisacrylamide by mass percentage, additive amount is 0.1 ‰~the 0.3 ‰ of mixing formula.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811304969.2A CN109577040A (en) | 2018-11-05 | 2018-11-05 | A kind of pigment printing binding agent and preparation method thereof bright in luster and excellent fastness |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811304969.2A CN109577040A (en) | 2018-11-05 | 2018-11-05 | A kind of pigment printing binding agent and preparation method thereof bright in luster and excellent fastness |
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| Publication Number | Publication Date |
|---|---|
| CN109577040A true CN109577040A (en) | 2019-04-05 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811304969.2A Pending CN109577040A (en) | 2018-11-05 | 2018-11-05 | A kind of pigment printing binding agent and preparation method thereof bright in luster and excellent fastness |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112267316A (en) * | 2020-11-06 | 2021-01-26 | 安徽聚合辐化化工有限公司 | Pigment printing adhesive |
| CN113737547A (en) * | 2021-08-30 | 2021-12-03 | 安徽聚合辐化化工有限公司 | High-glossiness adhesive and preparation method thereof |
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| WO2000053641A1 (en) * | 1999-03-11 | 2000-09-14 | Snf S.A. | Novel polymer thickening agents and uses thereof particularly in printing pastes for textiles and in cosmetics |
| CN105862466A (en) * | 2016-05-04 | 2016-08-17 | 合肥聚合辐化技术有限公司 | Pigment printing bonding agent prepared with radiation method and preparing method thereof |
| CN106854257A (en) * | 2015-12-09 | 2017-06-16 | 上海乐贤新材料科技有限公司 | A kind of hydrate colour adhesive agent emulsion |
| CN108277665A (en) * | 2017-12-21 | 2018-07-13 | 合肥聚合辐化技术有限公司 | Soft and big tearing strength printing adhesive and preparation method thereof on cloth cover |
| CN108341951A (en) * | 2017-01-25 | 2018-07-31 | 翁秋梅 | A kind of dynamic aggregation object and its application with hybrid cross-linked structure |
-
2018
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|---|---|---|---|---|
| WO2000053641A1 (en) * | 1999-03-11 | 2000-09-14 | Snf S.A. | Novel polymer thickening agents and uses thereof particularly in printing pastes for textiles and in cosmetics |
| CN106854257A (en) * | 2015-12-09 | 2017-06-16 | 上海乐贤新材料科技有限公司 | A kind of hydrate colour adhesive agent emulsion |
| CN105862466A (en) * | 2016-05-04 | 2016-08-17 | 合肥聚合辐化技术有限公司 | Pigment printing bonding agent prepared with radiation method and preparing method thereof |
| CN108341951A (en) * | 2017-01-25 | 2018-07-31 | 翁秋梅 | A kind of dynamic aggregation object and its application with hybrid cross-linked structure |
| CN108277665A (en) * | 2017-12-21 | 2018-07-13 | 合肥聚合辐化技术有限公司 | Soft and big tearing strength printing adhesive and preparation method thereof on cloth cover |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112267316A (en) * | 2020-11-06 | 2021-01-26 | 安徽聚合辐化化工有限公司 | Pigment printing adhesive |
| CN113737547A (en) * | 2021-08-30 | 2021-12-03 | 安徽聚合辐化化工有限公司 | High-glossiness adhesive and preparation method thereof |
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Application publication date: 20190405 |