CN109576096A - Low bubble machine washing weight greasy dirt detergent of one kind and preparation method thereof - Google Patents

Low bubble machine washing weight greasy dirt detergent of one kind and preparation method thereof Download PDF

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Publication number
CN109576096A
CN109576096A CN201811531904.1A CN201811531904A CN109576096A CN 109576096 A CN109576096 A CN 109576096A CN 201811531904 A CN201811531904 A CN 201811531904A CN 109576096 A CN109576096 A CN 109576096A
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CN
China
Prior art keywords
greasy dirt
low bubble
machine
dirt detergent
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811531904.1A
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Chinese (zh)
Inventor
杨帆
李永峰
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China University of Petroleum Beijing
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China University of Petroleum Beijing
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Filing date
Publication date
Application filed by China University of Petroleum Beijing filed Critical China University of Petroleum Beijing
Priority to CN201811531904.1A priority Critical patent/CN109576096A/en
Publication of CN109576096A publication Critical patent/CN109576096A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D2111/40

Abstract

The present invention provides a kind of low bubble machine washing weight greasy dirt detergents.By weight percentage, the raw material composition of the low bubble machine washing weight greasy dirt detergent includes: organic base 1%-5%, complexing agent 1%-5%, dispersing agent 1%-10%, builder 0.5%-5%, soap base 1%-5%, surfactant 0.1%-5%, pH adjusting agent 1%-10%, corrosion inhibiter 0.1%-2%, defoaming agent 0.1%-3%, water surplus.High-efficiency heavy oil dirt cleaning agent provided by the present invention is a kind of low alveolitoid cleaning agent, when that will clean, the amount of foam is controlled while reduced levels, still being able to make cleaning agent has an efficient cleaning performance, also, the cleaning agent have the characteristics that preferable biological degradability, on lacquer painting without influence.

Description

Low bubble machine washing weight greasy dirt detergent of one kind and preparation method thereof
Technical field
The present invention relates to a kind of low bubble machine washing weight greasy dirt detergents and preparation method thereof, belong to greasy dirt detergent technology neck Domain.
Background technique
Cleaning agent on the market is mostly used surfactant now, but surfactant often generates a large amount of foam, When using machine laundry methods cleaning high-speed rail bogie, since the pressure of spray head is high (8Kg), the cleaning agent ejected has very Big foam, once generating, foam is bigger, and the water column ejected is high containing foam volume, beat on the object of cleaning dynamics compared with It is small, cleaning force is influenced, in addition, foam volume is excessive, liquid level in pond is will lead to and rises, be increased beyond warning line, machine can stop Operating (engine of cleaning robot beside service sink, if liquid level overflows, can jeopardize engine again).
Therefore, a kind of low bubble machine washing weight greasy dirt detergent is developed, is still one of this field urgent problem to be solved.
Summary of the invention
In order to solve the above technical problems, the purpose of the present invention is to provide a kind of low bubble machine washing weight greasy dirt detergent and its systems Preparation Method has many advantages, such as that low bubble, cleaning effect are good.
In order to achieve the above objectives, machine-washing weight greasy dirt detergent the present invention provides a kind of low bubble by weight percentage should The raw material of low bubble machine washing weight greasy dirt detergent, which forms, includes:
Organic base 1%-5%, complexing agent 1%-5%, dispersing agent 1%-10%, builder 0.5%-5%, soap base 1%- 5%, surfactant 0.1%-5%, pH adjusting agent 1%-10%, corrosion inhibiter 0.1%-2%, defoaming agent 0.1%-3%, more than water Amount.
Machine-wash in weight greasy dirt detergent in above-mentioned low bubble, it is preferable that the organic base include monoethanolamine, triethanolamine and The combination of one or more of diethanol amine.
In above-mentioned low bubble machine washing weight greasy dirt detergent, it is preferable that the complexing agent includes glycolic, 1-hydroxy ethylene-1,1-diphosphonic The combination of acid and one or more of sodium gluconate.
In above-mentioned low bubble machine washing weight greasy dirt detergent, it is preferable that the dispersing agent includes sodium tripolyphosphate, hexa metaphosphoric acid The combination of one or more of sodium and polyacrylamide.
In above-mentioned low bubble machine washing weight greasy dirt detergent, it is preferable that the builder includes potassium pyrophosphate, five water metasilicic acids The combination of one or more of sodium and sodium borate decahydrate.
Machine-wash in weight greasy dirt detergent in above-mentioned low bubble, it is preferable that the soap base include octanoic acid, lauric acid, palmitinic acid and The combination of one or more of stearic acid.
In above-mentioned low bubble machine washing weight greasy dirt detergent, it is preferable that the surfactant includes polyethers surface-active Agent.
In above-mentioned low bubble machine washing weight greasy dirt detergent, it is preferable that the pH adjusting agent includes potassium hydroxide.More preferably The pH value on ground, the low bubble machine washing weight greasy dirt detergent is 12-13.
In above-mentioned low bubble machine washing weight greasy dirt detergent, it is preferable that the corrosion inhibiter includes ternary polycarboxylic acids and/or poly- third Olefin(e) acid.
In above-mentioned low bubble machine washing weight greasy dirt detergent, it is preferable that the defoaming agent includes polyethers defoaming agent and/or has Machine silicon defoaming agent.
Low bubble machine washing weight greasy dirt detergent of the invention can according to need a certain amount of pigment of addition and mix colours.
The preparation method of above-mentioned low bubble machine washing weight greasy dirt detergent provided by the invention is the following steps are included: in stirring condition Under, the various raw materials other than pH adjusting agent are mixed in proportion, continues stirring to being completely dissolved, pH value tune is added Agent is saved, pH value is adjusted to suitable range, the low bubble machine washing weight greasy dirt detergent is prepared.
It the present invention also provides a kind of heavy oil dirt cleaning method, is passed through using above-mentioned low bubble high-efficiency heavy oil dirt cleaning agent The method that the mode counterweight greasy dirt of machine spray is cleaned.
Specific embodiment according to the present invention, it is preferable that every kilogram of low bubble machine washing weight greasy dirt detergent cleaning 1 is flat The surface with heavy oil dirt of square rice or so.
Specific embodiment according to the present invention, it is preferable that method includes the following steps:
Low bubble is machine-washed into again greasy dirt detergent and water (preferably according to extension rate 1:16 (500kg cleaning agent stoste: 8t water) Clean water) it is mixed and made into working solution, and it is heated to 70 DEG C;
Then the working solution is used to carry out 30 minutes with the pressure (sprinkler pressure) of 8MPa to the workpiece with heavy oil dirt Spray, using 50-60 DEG C of hot water to workpiece carry out spray drying, complete cleaning.
High-efficiency heavy oil dirt cleaning agent provided by the present invention is a kind of low alveolitoid cleaning agent, the amount control of foam when that will clean System while reduced levels still is able to that cleaning agent is made to have efficient cleaning performance, also, the cleaning agent has preferable life Object degradability, on lacquer painting without influence the features such as.
Detailed description of the invention
Fig. 1 is the workpiece state before cleaning.
Fig. 2 is the workpiece state after cleaning.
Specific embodiment
In order to which technical characteristic of the invention, purpose and beneficial effect are more clearly understood, now to skill of the invention Art scheme carries out described further below, but should not be understood as that limiting the scope of the invention.
Embodiment 1
The present invention provides a kind of low bubble machine washing weight greasy dirt detergents, and by weight percentage, low bubble machine washing heavy oil is dirty The raw material of cleaning agent forms
Monoethanolamine 2.9%, glycolic 0.2%, 1-hydroxy ethylidene-1,1-diphosphonic acid 3.4%, calgon 0.8%, ten are hydrated Sodium tetraborate 1.7%, octanoic acid 4%, polyether surfactant 1.7%, potassium hydroxide, polyacrylic acid 1.2%, polyethers defoaming Agent 0.5%, water surplus.
Wherein, potassium hydroxide is pH adjusting agent, and dosage should ensure that the pH of the low bubble machine washing weight greasy dirt detergent reaches 12.5。
Embodiment 2
The present invention provides a kind of low bubble machine washing weight greasy dirt detergents, and by weight percentage, low bubble machine washing heavy oil is dirty The raw material of cleaning agent forms
Diethanol amine 2.9%, glycolic 0.2%, 1-hydroxy ethylidene-1,1-diphosphonic acid 3.4%, sodium tripolyphosphate 1.2%, five water are inclined Sodium metasilicate 1.7%, lauric acid 4%, polyether surfactant 1.7%, potassium hydroxide, ternary polycarboxylic acids 1.2%, polyethers disappear Infusion 0.5%, water surplus.
Wherein, potassium hydroxide is pH adjusting agent, and dosage should ensure that the pH of the low bubble machine washing weight greasy dirt detergent reaches 12.7。
Embodiment 3
The present invention provides a kind of low bubble machine washing weight greasy dirt detergents, and by weight percentage, low bubble machine washing heavy oil is dirty The raw material of cleaning agent forms
Triethanolamine 2.9%, 1-hydroxy ethylidene-1,1-diphosphonic acid 3.4%, sodium tripolyphosphate 1.2%, sodium borate decahydrate 1.7%, stearic acid 4%, polyether surfactant 1.7%, potassium hydroxide, polyacrylic acid 1.2%, polyethers defoaming agent 0.5%, water surplus.
Wherein, potassium hydroxide is pH adjusting agent, and dosage should ensure that the pH of the low bubble machine washing weight greasy dirt detergent reaches 12.4。
Embodiment 4
The present invention provides a kind of low bubble machine washing weight greasy dirt detergents, and by weight percentage, low bubble machine washing heavy oil is dirty The raw material of cleaning agent forms
Diethanol amine 2.9%, 1-hydroxy ethylidene-1,1-diphosphonic acid 3.4%, polyacrylamide 1.2%, metasilicate pentahydrate sodium 1.7%, Palmitinic acid 4%, polyether surfactant 1.7%, potassium hydroxide, ternary polycarboxylic acids 1.2%, organic silicon defoamer 0.2%, water Surplus.
Wherein, potassium hydroxide is pH adjusting agent, and dosage should ensure that the pH of the low bubble machine washing weight greasy dirt detergent reaches 12.5。
Embodiment 5
The present invention provides a kind of low bubble machine washing weight greasy dirt detergents, and by weight percentage, low bubble machine washing heavy oil is dirty The raw material of cleaning agent forms
Monoethanolamine 2.9%, sodium gluconate 3.4%, calgon 0.8%, potassium pyrophosphate 1.7%, lauric acid 4%, polyether surfactant 1.7%, potassium hydroxide, polyacrylic acid 1.2%, organic silicon defoamer 0.2%, water surplus.
Wherein, potassium hydroxide is pH adjusting agent, and dosage should ensure that the pH of the low bubble machine washing weight greasy dirt detergent reaches 12.6。
Embodiment 6
The present invention provides a kind of low bubble machine washing weight greasy dirt detergents, and by weight percentage, low bubble machine washing heavy oil is dirty The raw material of cleaning agent forms
Triethanolamine 2.9%, sodium gluconate 3.4%, polyacrylamide 1.2%, potassium pyrophosphate 1.7%, octanoic acid 4%, Polyether surfactant 1.7%, potassium hydroxide, ternary polycarboxylic acids 1.2%, organic silicon defoamer 0.2%, water surplus.
Wherein, potassium hydroxide is pH adjusting agent, and dosage should ensure that the pH of the low bubble machine washing weight greasy dirt detergent reaches 12.5。
Embodiment 7
The present invention provides a kind of low bubble machine washing weight greasy dirt detergents, and by weight percentage, low bubble machine washing heavy oil is dirty The raw material of cleaning agent forms
Monoethanolamine 2.9%, sodium gluconate 3.4%, ternary polycarboxylic acids 1.2%, potassium pyrophosphate 1.7%, octanoic acid 4%, Polyether surfactant 1.7%, sodium tripolyphosphate 1.0%, metasilicate pentahydrate sodium 1.0%, sodium gluconate 4.0%, lemon Sour sodium 1.0%, potassium hydroxide, organic silicon defoamer 0.2%, water surplus.
Wherein, potassium hydroxide is pH adjusting agent, and dosage should ensure that the pH of the low bubble machine washing weight greasy dirt detergent reaches 12.5。
The low bubble machine washing weight greasy dirt detergent of 1-7 of the embodiment of the present invention can be prepared according to the following steps: in stirring bar Under part, the various raw materials other than pH adjusting agent are mixed in proportion, continues stirring to being completely dissolved, pH value is added PH value is adjusted to suitable range by regulator, and the low bubble machine washing weight greasy dirt detergent is prepared.
Embodiment 8
A kind of heavy oil dirt cleaning method is present embodiments provided, is cleaned using the low bubble high-efficiency heavy oil dirt of embodiment 7 The agent method that counterweight greasy dirt is cleaned in such a way that machine sprays, comprising the following steps:
According to 500kg cleaning agent stoste: low bubble machine washing weight greasy dirt detergent and clean water are mixed and made into working solution by 8t water, And it is heated to 70 DEG C;
Then the spray for using working solution to carry out with the pressure (sprinkler pressure) of 8MPa to the workpiece with heavy oil dirt 30 minutes Leaching carries out spray drying to workpiece using 50-60 DEG C of hot water, completes cleaning.
The workpiece state for cleaning front and back is as depicted in figs. 1 and 2.
The detection that correlated performance is carried out to the low bubble high-efficiency heavy oil dirt cleaning agent of embodiment 7, follows the steps below:
1, working solution (preparing in the way of embodiment 7) is fitted into test tube, injection is repeatedly sucked with syringe and (is inhaled Enter cleaning agent, then inject back into mother liquor), the ratio of foam height and whole height is observed, every ratio of 20 seconds records;
2, how long is the whole defoaming needs of record.Concrete outcome is as shown in table 1.
Table 1
As can be seen from Table 1, working solution is configured to using the cleaning agent of embodiment 7, foam height highest only accounts for entirety The 0.18 of height, i.e., 18%, and can be defoamed completely in 140 seconds, this illustrates that the cleaning agent of embodiment 7 is a kind of low bubble Cleaning agent has good antifoam performance.

Claims (10)

  1. The weight greasy dirt detergent 1. a kind of low bubble is machine-washed, by weight percentage, the raw material group of the low bubble machine washing weight greasy dirt detergent At including:
    Organic base 1%-5%, complexing agent 1%-5%, dispersing agent 1%-10%, builder 0.5%-5%, soap base 1%-5%, table Face activating agent 0.1%-5%, pH adjusting agent 1%-10%, corrosion inhibiter 0.1%-2%, defoaming agent 0.1%-3%, water surplus.
  2. The weight greasy dirt detergent 2. low bubble according to claim 1 is machine-washed, wherein the organic base includes monoethanolamine, three The combination of one or more of ethanol amine and diethanol amine.
  3. The weight greasy dirt detergent 3. low bubble according to claim 1 is machine-washed, wherein the complexing agent includes glycolic, hydroxyl The combination of one or more of ethylene-diphosphonic acid and sodium gluconate.
  4. The weight greasy dirt detergent 4. low bubble according to claim 1 is machine-washed, wherein the dispersing agent include sodium tripolyphosphate, The combination of one or more of calgon and polyacrylamide.
  5. The weight greasy dirt detergent 5. low bubble according to claim 1 is machine-washed, wherein the builder includes potassium pyrophosphate, five The combination of one or more of water sodium metasilicate and sodium borate decahydrate.
  6. The weight greasy dirt detergent 6. low bubble according to claim 1 is machine-washed, wherein the soap base includes octanoic acid, lauric acid, palm fibre The combination of one or more of palmitic acid acid and stearic acid.
  7. The weight greasy dirt detergent 7. low bubble according to claim 1 is machine-washed, wherein the surfactant includes polyethers table Face activating agent;
    Preferably, the pH adjusting agent includes potassium hydroxide;It is highly preferred that the low bubble is machine-washed, the pH value of weight greasy dirt detergent is 12-13。
  8. The weight greasy dirt detergent 8. low bubble according to claim 1 is machine-washed, wherein the corrosion inhibiter includes ternary polycarboxylic acids And/or polyacrylic acid.
  9. The weight greasy dirt detergent 9. low bubble according to claim 1 is machine-washed, wherein the defoaming agent includes polyethers defoaming agent And/or organic silicon defoamer.
  10. 10. a kind of heavy oil dirt cleaning method is weight greasy dirt detergent of being machine-washed using the described in any item low bubbles of claim 1-9 The method that counterweight greasy dirt is cleaned by way of spray;
    Preferably, every kilogram of low bubble machine washing weight greasy dirt detergent cleans 1 square metre of the surface with heavy oil dirt;
    Preferably, method includes the following steps:
    The low bubble machine washing weight greasy dirt detergent and water (preferably clean water) are mixed and made into working solution according to extension rate 1:16, And it is heated to 70 DEG C;
    Then the spray for using the working solution to carry out with the pressure of 8MPa to the workpiece with heavy oil dirt 30 minutes, using 50- 60 DEG C of hot water carries out spray drying to workpiece, completes cleaning.
CN201811531904.1A 2018-12-14 2018-12-14 Low bubble machine washing weight greasy dirt detergent of one kind and preparation method thereof Pending CN109576096A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811531904.1A CN109576096A (en) 2018-12-14 2018-12-14 Low bubble machine washing weight greasy dirt detergent of one kind and preparation method thereof

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Publication Number Publication Date
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103074174A (en) * 2012-12-29 2013-05-01 江苏飞拓界面工程科技有限公司 Cleaning agent for heavy oil dirt
CN103484884A (en) * 2013-09-13 2014-01-01 武汉玻尔科技股份有限公司 Low-foam middle-cloud-point environment-friendly water base metal cleaner composition and preparing method thereof
CN103937628A (en) * 2014-05-12 2014-07-23 苏州禾川化学技术服务有限公司 High-alkalinity non-foaming spraying cleaning agent
CN108034954A (en) * 2017-11-30 2018-05-15 珠海横琴思国科技发展有限公司 A kind of anti-rust cleaning agent of aluminium and aluminium alloy and preparation method thereof
CN108425123A (en) * 2018-06-14 2018-08-21 如皋市华阳铝制品有限公司 A kind of anti-rust cleaning agent and preparation method thereof of aluminium and aluminium alloy
CN108486588A (en) * 2018-05-31 2018-09-04 江苏恒加机械工程有限公司 A kind of aqua type metal cleaner

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103074174A (en) * 2012-12-29 2013-05-01 江苏飞拓界面工程科技有限公司 Cleaning agent for heavy oil dirt
CN103484884A (en) * 2013-09-13 2014-01-01 武汉玻尔科技股份有限公司 Low-foam middle-cloud-point environment-friendly water base metal cleaner composition and preparing method thereof
CN103937628A (en) * 2014-05-12 2014-07-23 苏州禾川化学技术服务有限公司 High-alkalinity non-foaming spraying cleaning agent
CN108034954A (en) * 2017-11-30 2018-05-15 珠海横琴思国科技发展有限公司 A kind of anti-rust cleaning agent of aluminium and aluminium alloy and preparation method thereof
CN108486588A (en) * 2018-05-31 2018-09-04 江苏恒加机械工程有限公司 A kind of aqua type metal cleaner
CN108425123A (en) * 2018-06-14 2018-08-21 如皋市华阳铝制品有限公司 A kind of anti-rust cleaning agent and preparation method thereof of aluminium and aluminium alloy

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Application publication date: 20190405