CN109575753A - One kind is for steel surface water-base epoxy type anticorrosive paint and preparation method thereof - Google Patents

One kind is for steel surface water-base epoxy type anticorrosive paint and preparation method thereof Download PDF

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CN109575753A
CN109575753A CN201811502949.6A CN201811502949A CN109575753A CN 109575753 A CN109575753 A CN 109575753A CN 201811502949 A CN201811502949 A CN 201811502949A CN 109575753 A CN109575753 A CN 109575753A
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fillers
pigments
agent
parts
added
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许超
周强
高征南
齐正斌
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Anqing Huapu Environmental Protection Materials Technology Co Ltd
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Anqing Huapu Environmental Protection Materials Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/327Aluminium phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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Abstract

The present invention discloses one kind for steel surface water-base epoxy type anticorrosive paint and preparation method thereof, belongs to technical field of paint preparation.The anticorrosive paint includes the component of following mass fraction: 28~44 parts of filming emulsion, being formed a film 7~11 parts of curing agent, 5~12 parts of antirust pigments and fillers, 10~13 parts of pigments and fillers, 8~18 parts of constitution pigments and fillers, 0.5~4 part of auxiliary agent of coloring, 0.5~3 part of nano assistant, 10~40 parts of solvent.The present invention is using deionized water as decentralized medium, and instead of traditional organic solvent, to reduce VOC emission and the harm to environment and human body, which is a kind of Environmentally friendly coatings;The present invention carries out surface in advance to nanoparticle and is modified, and is then added in water-base epoxy type lotion, can effectively weaken nanoparticle and be prone to the phenomenon that reuniting, and nanoparticle is enable to play the role of enhancing coating comprehensive performance.The service life length of coating of the present invention, easy construction, advantage of lower cost, have many advantages, such as high added value.

Description

One kind is for steel surface water-base epoxy type anticorrosive paint and preparation method thereof
Technical field:
The invention belongs to technical field of paint preparation, more particularly to it is a kind of for steel surface water-base epoxy type anticorrosive paint and Preparation method.
Background technique:
The resource that the whole world is wasted because of the corrosion of metal material every year accounts for about 1/5th of current year utilization rate, directly Economic loss is caused to account for 4.2% of gross national product or so, metallic material corrosion not only causes huge economic loss, but also Potential disaster may be caused to society.Although we are difficult to prevent the generation of corrosion, can by effective aseptic technic So that the carry out rate of corrosion is effectively inhibited.Currently, mainly using coating for the means of defence of steel surface corrosion Protection Code is contacted in metal surface one layer of anticorrosive paint of brushing with completely cutting off external corrosion medium with the direct of metallic matrix, from And play effective corrosion-resisting function.Traditional solvent type coating using organic solvent as decentralized medium, mainly include hydrocarbon, ketone, alcohol, Ester, ether etc., most of organic solvent are easy to volatilize, so that volatile organic compounds (VOC) is generated, and VOC can cause light Chemical fumes, this is also one of the main inducing of China's atmospheric haze in recent years.As people are for the attention of environmental protection, no dirt The principles such as dye, nuisanceless, the saving energy, economical and efficient have become the common recognition of domestic and international coatings enterprises development;And water-repellent preservation Coating is using water as decentralized medium, so as to greatly reduce the content of VOC, has become the master of the following anticorrosive paint development at present One of artificial delivery product, however the comprehensive performance of water-based anticorrosive paint still lags behind solvent type anticorrosive paint instantly, for this purpose, accelerating aqueous The research and development of epoxy type coating are important one of the developing direction in the field.
Due to the property of nano material itself, adding nano material in anticorrosive paint can effectively improve coating The performances such as mechanical, corrosion-resistant, acid and alkali-resistance.Chinese patent CN104403498A discloses a kind of novel aqueous epoxy anti-rust paint, It was found that the mechanical performance and corrosion resistance of film can be improved by adding nano zine oxide;Chinese patent CN 104559386A Disclose a kind of preparation method of nano silicon dioxide modifying water epoxy coating, the coating have extremely low VOC content and Excellent machinery and corrosion resistance;Chinese patent CN 106893452A discloses the painting of nano rare earth modified epoxy anti-corrosion Material and preparation method thereof, the coating have good uvioresistant performance and weather resistance.Although nano-material modified for utilizing The research and development of anticorrosive paint have made some progress, but there are still such or such some problems;Due to nanoparticle The special nature that son has, specific surface tension and specific surface area are larger, and interaction " attraction " makes nano material between particle Surface particle is unstable, Yi Jiju, and " reunion " phenomenon occurs, and the poor compatibility with organic media makes answering for nano ZnO Limitation is used, even if also will appear some agglomerations, in addition, how to enhance nanometer in the grinding of superfast blender, dispersion The lipophilicity of particle, make nanoparticle preferably with asphalt mixtures modified by epoxy resin lipid phase and hold, be this stage urgent need to resolve critical issue it One.
Summary of the invention:
It is an object of the invention to overcome the deficiencies of the prior art and provide one kind to apply for steel surface water-base epoxy type anti-corrosion The preparation method of material.It is provided by the invention a kind of for steel surface water corrosion-resistant epoxy paint, the water-base epoxy type anticorrosive paint Component including following mass fraction:, forming a film 7~11 parts of curing agent by 28~44 parts of filming emulsion, and 5~12 parts of antirust pigments and fillers, 10~13 parts of pigments and fillers of coloring, 8~18 parts of constitution pigments and fillers, 0.5~4 part of auxiliary agent, 0.5~3 part of nano assistant, solvent 10~40 Part.
The filming emulsion is aqueous epoxy emulsion;The film forming curing agent is aqueous epoxy curing agent;The antirust face Filler is any one of aluminium triphosphate, trbasic zinc phosphate, ferrophosphorus powder, ferrotitanium powder or the mixing more than any two;The coloring face Filler is iron oxide red;The constitution pigments and fillers are barium sulfate, talcum powder, mica powder, wollastonite, diatomite, Kaolin expansion The mixing of any two or wantonly three kinds or more of vermiculite;The auxiliary agent is levelling agent, wetting agent, organic silicon defoamer, dispersing agent, increasing Thick dose, anti-flash rusting agent, the mixing of wantonly three kinds of antisettling agent or wantonly four kinds or more;The solvent is deionized water.
The nano assistant is silane-modified nanometer Zinc oxide powder, and the silane-modified nanometer Zinc oxide powder is to pass through Following methods preparation: nano-zinc oxide powder being added in the round-bottomed flask containing dehydrated alcohol, silicon is added in ultrasonic disperse afterwards Alkane coupling agent KH550 (3-aminopropyltriethoxysilane) is mixed in flask with finely dispersed nano zine oxide, and It is heated to reflux a period of time under the conditions of certain temperature, takes out filtering after cooling, washed with dehydrated alcohol, it is then dry in 80 DEG C of vacuum Dry 12h in dry case, finally finely ground rear kept dry is spare in mortar.
The present invention is a kind of, and for steel surface water corrosion-resistant epoxy paint, specific preparation process is as follows:
(1) before weighing solid component, sieving processing is first carried out.
(2) according to the ratio of recipe ingredient mass fraction weigh respectively filming emulsion, film forming curing agent, antirust pigments and fillers, Colour pigments and fillers, constitution pigments and fillers, auxiliary agent, silane-modified nanometer Zinc oxide powder and solvent.
(3) it prepares coating component A: sequentially adding solvent, part of auxiliary under 500r/min revolving speed and silane-modified receive Rice Zinc oxide powder, stirs 5~10min;Coloring pigments and fillers and Some Constitution pigments and fillers are sequentially added to disperse in 1500r/min 10min, and appropriate zirconium pearl is added and grinds 0.5~1.5 hour, then zirconium pearl leads to cooling deionized water as abrasive media;It is added Filming emulsion reduction of speed to 1000r/min stir 15min;Antirust pigments and fillers are added under same revolving speed and remaining constitution face is filled out Material, stir 20min and be added thickener be adjusted to be suitable for viscosity range, finally through filtering stir evenly.
(4) prepare coating B component: aqueous epoxy curing agent and solvent stir evenly under 500r/min revolving speed, use plastics Bucket packaging, for use.
(5) coating component A is mixed with coating B component according to mass ratio 5: 1 when using, stirs evenly and is used In steel surface water-base epoxy type anticorrosive paint.
The technology of the present invention principle: easy to reunite the present invention overcomes nanoparticle and its aqueous epoxy emulsion compatibility is bad etc. Disadvantage, from the surface of nanoparticle, modification is started with, and Silane coupling agent KH550 is grafted on to the surface of nano zine oxide, to realize Modification to nano zine oxide.Modified nano zine oxide has good amphipathic property, to effectively reduce nanometer There is agglomeration in the coating in Zinc oxide particles, to enhance the comprehensive performance of coating.
After coating of the present invention is coated in steel surface prepares coating, evaluated with following standard:
(1) it paint film adhesion: is tested according to GB/T1720-1979;
(2) it paint film impact resistance: is tested according to GB/T1732-93;
(3) paint film salt spray resistance is tested according to GB/T1771-2007;
(4) it hardness of paint film: is tested according to GB/T6739-1996.
Traditional technology is compared, the present invention has following gain effect:
(1) the steel surface water-base epoxy type anticorrosive paint involved in the present invention that is used for is the generation using deionized water as decentralized medium For traditional organic solvent, to reduce VOC emission and the harm to environment and human body, which is a kind of environmentally friendly painting Material.
(2) the rock-steady structure unit that surface is modified, and formation is effectively grafted with silane coupling agent is carried out in advance to nanoparticle, It is then added in water-base epoxy type lotion, can effectively weaken nanoparticle and be prone to the phenomenon that reuniting, enable nanoparticle Enough play the role of enhancing coating comprehensive performance.
(3) nano-material surface has the groups such as high activity covalent bond and hydroxyl, can be formed between epoxy resin steady Fixed chemical bond, and nanoparticle is uniformly dispersed in coating system, in coating drying and forming-film, the presence meeting of nanoparticle Play the role of enhancing coating compactness, while can also enhance coating impermeabilisation ability, with improve coating corrosion resistance and Mechanical performance.
(4) due to the property of nano zine oxide, so that modified coating is removed contamination with certain sterilizing and anti-purple Outer property also has good effect for the weather resistance of coating.
(5) the service life length of the coating, easy construction, advantage of lower cost, the economic benefit with high added value.
Specific embodiment:
Here is to be further described by specific embodiment to the present invention, but the scope of protection of the present invention is not limited.
Embodiment 1: it is a kind of for steel surface water-base epoxy type anticorrosive paint component A by the raw material of following mass fraction ratio Composition, aqueous epoxy emulsion 32%, coloring pigments and fillers 10%, antirust pigments and fillers (aluminium triphosphate 2%, trbasic zinc phosphate 5%) 7%, Constitution pigments and fillers (barium sulfate 5%, talcum powder 3%, mica powder 1%) 9%, (levelling agent 0.7%, has wetting agent 0.2% auxiliary agent Machine silicon defoaming agent 0.3%, dispersing agent 0.1%, thickener 0.2%) 1.5%, nano assistant 0.5%, solvent 40%.
Component A preparation process: solvent, part of auxiliary and nano zinc oxide powder are sequentially added under 500r/min revolving speed Body stirs 10min;It sequentially adds coloring pigments and fillers and Some Constitution pigments and fillers disperses 10min under 1500r/min revolving speed, And be added 800g zirconium pearl (for adding the medium ground in grinding machinery to material) grind 1 hour, logical cooling go from Sub- water;Filming emulsion reduction of speed is added to 1000r/min stirring 15min;Antirust pigments and fillers and residue are added under same revolving speed Constitution pigments and fillers, stir 25min and be added thickener be adjusted to be suitable for viscosity range, finally through filtering stir evenly.
B component preparation process: aqueous epoxy curing agent 10% and solvent 10% stir 15min under 500r/min revolving speed.
Dope preparing process: by component A: B component=5: 1 mixes, stir evenly obtain for steel surface it is aqueous Epoxy type anticorrosive paint.
Embodiment 2: it is a kind of for steel surface water-base epoxy type anticorrosive paint component A by the raw material of following mass fraction ratio Composition, aqueous epoxy emulsion 38% colour pigments and fillers 12.5%, antirust pigments and fillers (aluminium triphosphate 2%, trbasic zinc phosphate 4%, iron Titanium valve 2.5%) 8.5%, constitution pigments and fillers (barium sulfate 4%, talcum powder 3%, expanded vermiculite 2%, wollastonite 3%) 12% help Agent (levelling agent 0.8%, wetting agent 0.2%, organic silicon defoamer 0.3%, dispersing agent 0.2%, thickener 0.4%, antisettling agent 0.6%) 2.5%, nano assistant 1.5%, solvent 25%.
Component A preparation process: solvent, part of auxiliary and nano zinc oxide powder are sequentially added under 500r/min revolving speed Body stirs 8min;It sequentially adds coloring pigments and fillers and Some Constitution pigments and fillers disperses 10min under 1500r/min revolving speed, and Be added 800g zirconium pearl (for add the medium ground in grinding machinery to material) grinding 1.5 hours, logical cooling go from Sub- water;Filming emulsion reduction of speed is added to 1000r/min stirring 15min;Antirust pigments and fillers and residue are added under same revolving speed Constitution pigments and fillers, stir 30min and be added thickener be adjusted to be suitable for viscosity range, finally through filtering stir evenly.
B component preparation process: aqueous epoxy curing agent 9% and solvent 11% stir 15min under 500r/min revolving speed.
Dope preparing process: by component A: B component=5: 1 mixes, stir evenly obtain for steel surface it is aqueous Epoxy type anticorrosive paint.
Embodiment 3: it is a kind of for steel surface water-base epoxy type anticorrosive paint component A by the raw material of following mass fraction ratio Composition, aqueous epoxy emulsion 43% colour pigments and fillers 13%, antirust pigments and fillers (aluminium triphosphate 3%, trbasic zinc phosphate 4%, ferrotitanium Powder 3%) 10%, constitution pigments and fillers (barium sulfate 4%, talcum powder 5%, kaolin 4%, wollastonite 3%) 16%, auxiliary agent (levelling Agent 1%, wetting agent 0.5%, organic silicon defoamer 0.5%, dispersing agent 0.5%, thickener 0.5%, antisettling agent 0.5%) 3.5%, nano assistant 2.5%, solvent 12%.
Component A preparation process: solvent, part of auxiliary and nano zinc oxide powder are sequentially added under 500r/min revolving speed Body stirs 10min;It sequentially adds coloring pigments and fillers and Some Constitution pigments and fillers disperses 10min under 1500r/min revolving speed, And 800g zirconium pearl (for adding the medium ground in grinding machinery to material) is added and grinds 0.5 hour, logical cooling is gone Ionized water;Filming emulsion reduction of speed is added to 1000r/min stirring 15min;Antirust pigments and fillers are added under same revolving speed and remain Remaining constitution pigments and fillers, stir 20min and be added thickener be adjusted to be suitable for viscosity range, finally through filtering stir evenly.
B component preparation process: aqueous epoxy curing agent 11% and solvent 9% stir 15min under 500r/min revolving speed.
Dope preparing process: by component A: B component=5: 1 mixes, stir evenly obtain for steel surface it is aqueous Epoxy type anticorrosive paint.
It should be appreciated that the purposes of these embodiments is merely to illustrate the present invention and is not intended to limit protection model of the invention It encloses.In addition, it should also be understood that, after reading the technical contents of the present invention, those skilled in the art can make the present invention each Kind change, modification and/or variation, all these equivalent forms are equally fallen within protection scope of the present invention.

Claims (2)

1. one kind is used for steel surface water-base epoxy type anticorrosive paint, it is characterised in that the anticorrosive paint includes following mass fraction Component:, forming a film 7~11 parts of curing agent by 28~44 parts of filming emulsion, 5~12 parts of antirust pigments and fillers, colours 10~13 parts of pigments and fillers, 8~18 parts of constitution pigments and fillers, 0.5~4 part of auxiliary agent, 0.5~3 part of nano assistant, 10~40 parts of solvent;The filming emulsion is water Property epoxy emulsion;The film forming curing agent is aqueous epoxy curing agent;The antirust pigments and fillers be aluminium triphosphate, trbasic zinc phosphate, Any one of ferrophosphorus powder, ferrotitanium powder or the mixing more than any two;The coloring pigments and fillers are iron oxide red;The constitution face Filler is barium sulfate, talcum powder, mica powder, wollastonite, diatomite, any two or wantonly three kinds or more in Kaolin expansion vermiculite Mixing;The auxiliary agent be levelling agent, wetting agent, organic silicon defoamer, dispersing agent, thickener, anti-flash rusting agent, in antisettling agent Wantonly three kinds or wantonly four kinds or more of mixing;The solvent is deionized water;The nano assistant is silane-modified nano oxidized Zinc powder body, the silane-modified nanometer Zinc oxide powder are prepared by the following method: nano-zinc oxide powder is added to In round-bottomed flask containing dehydrated alcohol, ultrasonic disperse, the rear Silane coupling agent KH550 that is added is received in flask with finely dispersed Rice zinc oxide mixing, and a period of time is heated to reflux under the conditions of certain temperature, filtering is taken out after cooling, is washed with dehydrated alcohol It washs, then the dry 12h in 80 DEG C of vacuum ovens, finally finely ground rear kept dry is spare in mortar.
2. a kind of preparation method for steel surface water-base epoxy type anticorrosive paint according to claim 1, feature exist In this method, specific preparation process is as follows:
(1) before weighing solid component, sieving processing is first carried out;
(2) filming emulsion, film forming curing agent, antirust pigments and fillers, coloring are weighed respectively according to the ratio of recipe ingredient mass fraction Pigments and fillers, constitution pigments and fillers, auxiliary agent, silane-modified nanometer Zinc oxide powder and solvent;
(3) it prepares coating component A: sequentially adding solvent, part of auxiliary and silane-modified nano oxygen under 500r/min revolving speed Change zinc powder body, stirs 5~10min;Coloring pigments and fillers and Some Constitution pigments and fillers are sequentially added, are dispersed in 1500r/min 10min, and appropriate zirconium pearl is added and grinds 0.5~1.5 hour, lead to cooling deionized water, filming emulsion reduction of speed is added to 1000r/ Min stirs 15min, and antirust pigments and fillers and remaining constitution pigments and fillers are added under same revolving speed, stirs 20min and thickening is added Agent is adjusted to be suitable for viscosity range, finally stirs evenly obtained coating component A through filtering;
(4) it prepares coating B component: aqueous epoxy curing agent and solvent being stirred evenly under 500r/min revolving speed, use plastic barrel Packaging, for use;
(5) coating component A is mixed with coating B component according to mass ratio 5: 1 when using, stirs evenly and obtains for steel Aqueous surface epoxy type anticorrosive paint.
CN201811502949.6A 2018-12-10 2018-12-10 One kind is for steel surface water-base epoxy type anticorrosive paint and preparation method thereof Pending CN109575753A (en)

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Cited By (8)

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CN110054961A (en) * 2019-04-09 2019-07-26 河北晨阳工贸集团有限公司 A kind of aqueous priming paint and preparation method thereof
CN112625545A (en) * 2020-12-17 2021-04-09 台州来智科技有限公司 Processing production method of anticorrosive latex paint
CN113444422A (en) * 2021-06-30 2021-09-28 国网河南省电力公司西峡县供电公司 Insulator metal connecting seat anticorrosive paint and application method thereof
CN113736347A (en) * 2021-09-02 2021-12-03 华南理工大学 Nano antibacterial epoxy resin coating for stainless steel water supply pipe and preparation method and application thereof
CN114213940A (en) * 2022-01-27 2022-03-22 广德辉龙环保科技有限公司 Coating for protecting surfaces of rhombic bag cages
CN114464347A (en) * 2022-04-13 2022-05-10 西安宏星电子浆料科技股份有限公司 Temperature-resistant anti-aging insulating medium slurry and preparation method thereof
CN114907743A (en) * 2022-03-28 2022-08-16 张家港市天源制漆涂装有限公司 Water-based dip-coating paint
CN114958142A (en) * 2022-06-09 2022-08-30 苏州佩琦材料科技有限公司 Structural color heavy-duty anticorrosive paint and preparation method thereof

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CN112625545A (en) * 2020-12-17 2021-04-09 台州来智科技有限公司 Processing production method of anticorrosive latex paint
CN113444422A (en) * 2021-06-30 2021-09-28 国网河南省电力公司西峡县供电公司 Insulator metal connecting seat anticorrosive paint and application method thereof
CN113736347A (en) * 2021-09-02 2021-12-03 华南理工大学 Nano antibacterial epoxy resin coating for stainless steel water supply pipe and preparation method and application thereof
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CN114213940A (en) * 2022-01-27 2022-03-22 广德辉龙环保科技有限公司 Coating for protecting surfaces of rhombic bag cages
CN114907743A (en) * 2022-03-28 2022-08-16 张家港市天源制漆涂装有限公司 Water-based dip-coating paint
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