CN109572373A - A kind of Chinese herbaceous peony gear compound refractive power ink glass panel and its manufacturing method - Google Patents
A kind of Chinese herbaceous peony gear compound refractive power ink glass panel and its manufacturing method Download PDFInfo
- Publication number
- CN109572373A CN109572373A CN201811428923.1A CN201811428923A CN109572373A CN 109572373 A CN109572373 A CN 109572373A CN 201811428923 A CN201811428923 A CN 201811428923A CN 109572373 A CN109572373 A CN 109572373A
- Authority
- CN
- China
- Prior art keywords
- oxide
- ink
- parts
- ito film
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J1/00—Windows; Windscreens; Accessories therefor
- B60J1/02—Windows; Windscreens; Accessories therefor arranged at the vehicle front, e.g. structure of the glazing, mounting of the glazing
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B27/00—Tempering or quenching glass products
- C03B27/04—Tempering or quenching glass products using gas
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
- C03C17/2453—Coating containing SnO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/90—Other aspects of coatings
- C03C2217/94—Transparent conductive oxide layers [TCO] being part of a multilayer coating
- C03C2217/948—Layers comprising indium tin oxide [ITO]
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/151—Deposition methods from the vapour phase by vacuum evaporation
Abstract
The invention discloses a kind of Chinese herbaceous peony gear compound refractive power ink glass panel and its manufacturing method, vitreum composition is made of silica and potassium oxide；The vitreum convex surface is fixed with the high refractive layer that one layer of ocratation, cerium oxide, germanium tetrachloride are constituted, and concave surface is fixed with the low refractive layer that one layer of ocratation, zirconium oxide, titanium oxide, boron oxide are constituted；Internal curing has ink screen, the ink screen basic structure includes indium oxide: tin oxide is by different quality than cured high permeability ito film and harmonious ito film composition, transparent oil-based liquid between two membranes to be suspended with built-in electrically charged white particle and oppositely charged transparent grain microcapsules, the ink screen has two sets of static electric systems, first is that the transparent front and back electrostatic substrate being made of two sides ito film, second is that the left and right electrostatic substrate being made of two sides metal strip.Compound refractive power ink glass panel refracted portion external light of the invention, interior view translucency be good, adjustable transparency, wide adaptation range.
Description
Technical field
The present invention relates to glassware field more particularly to a kind of Chinese herbaceous peony gear compound refractive power ink glass panel and its systems
Make method.
Background technique
Ink screen, is made of two panels substrate, is coated with a kind of electric ink being made of countless small transparent grains above,
In conventional ink screen, these e-ink particles are sealed in interior liquid by many black and white particles with positive and negative electricity
It is formed in microcapsules, the charged particle of different colours can be moved because applying the difference of electric field towards different directions, in display screen
Surface shows black or white effect.But conventional ink screen only has black-and-white two color, opaque, hence it is evident that cannot be used for automobile-used preceding shelves
Glass.
With the development of the times, the degree of specialization of glass is higher and higher, wherein almost all of user vehicle is for hidden
Private considers, requires the tempered glass using light refracting (can see that outer but outside can not see inside by interior), in the prior art
Light refracting glass is outer surface coated glass, regardless of use which kind of mode plated film, plated be metal oxide or
Pure metal, this is to absorb certain band limits light using the optical absorption spectra of metal or metal oxide and realize function,
But it have been found that the effect of this shielding is just had a greatly reduced quality when interior brightness is higher than outside vehicle；On the other hand, metal oxide
General chemistry property list is now alkalinity, meets perishable aging when acid rain, equally, pure metallic silver (dioptric glass in the prior art
General all materials such as evaporation metal silver) also easily by the sulphur pollution blackening in air, therefore the reflecting glass of routine techniques is easy to become
Deformation color, service life are short.
Therefore, it is badly in need of that a kind of refracted portion external light, interior view translucency be good, adjustable transparency, adaptation range on the market
Wide Chinese herbaceous peony gear compound refractive power ink glass panel and its manufacturing method.
Summary of the invention
In view of the above defects of the prior art, the present invention is intended to provide a kind of refracted portion external light, interior view
Translucency is good, adjustable transparency, the Chinese herbaceous peony of wide adaptation range gear compound refractive power ink glass panel and its manufacturing method.
To achieve the goals above, the invention adopts the following technical scheme: a kind of Chinese herbaceous peony keeps off compound refractive power ink glass
The manufacturing method of panel, comprising the following steps:
1) prepare before production
1. vitreum raw material prepare: preparation 85 parts -90 parts of silica, 10 parts -15 parts of potassium oxide by weight；
2. inner surface material prepares: preparation 8 parts -9 parts of ocratation, 0.5 part -0.6 part of cerium oxide, four chlorinations by weight
0.7 part -0.9 part of germanium；
3. outer surface material prepares: preparation 8 parts -9 parts of ocratation, 0.2 part -0.3 part of zirconium oxide, titanium oxide by weight
0.2 part -0.3 part, 0.6 part -0.8 part of boron oxide；
4. ink screen material prepares: preparing the metal strip being adapted with vehicle two sides A column, prepare enough built-in electrically charged white
The microcapsules of particle and oppositely charged transparent grain prepare enough transparent oil-based liquids, prepare enough indium oxides, enough oxidations
Tin；
5. technological preparation: preparation asbestos board, enough pure oxygens, silicon nitride ceramics container, furnace chamber top are integrated with recirculated water cooling
But the protective atmosphere heating furnace, enough hydrofluoric acid of system；
2) glass body firing, tempering and molding
1. by with 1) in after the step silica, the potassium oxide that 1. prepare be uniformly mixed and melt, poured in vacuum environment
Casting obtains vitreum fluid into the mold being adapted with automobile front windshield radian；
2. 1. vitreum fluid that step obtains is gas-cooled under the nitrogen of 3bar-4bar, i.e. acquisition tempering rear vitreous body；
3) composite glass structure of ink electrical screen built in
1. prepare two pieces of stages 2) obtain tempering rear vitreous body, be set to the first glass plate and the second glass plate；
2. using indium oxide: the mixture of the ratio mixture of tin oxide 20:1 in mass ratio is recessed in the first glass plate as raw material
High permeability ito film is deposited in side surface；Using indium oxide: the mixture of the ratio mixture of tin oxide 9:1 in mass ratio is raw material,
Harmonious ito film is deposited in the convex side surface of two glass plates；Two ito films are provided with metal lead wire close to panel bottom side region；It will
Two pieces of glass plates, which immerse, contains the stage 1) 4. step prepares in the transparent oil-based liquid of microcapsules, two pieces of glass plates is placed in parallel,
Two sides ito film close to and control room septal space 0.3mm-0.5mm after, place the stage 1 in gap side) metal that 4. prepares of step
Item, two metal strip bottoms are provided with metal lead wire, and then two pieces of glass plate surrounding gaps are closed while being incited somebody to action using insulating cement
Metal strip is separated with ito film, exposes four lead of bottom, the composite glass structure of built-in ink electrical screen needed for obtaining；
4) surface is deposited
1. in the confined space of protective atmosphere heating furnace, the ocratation, cerium oxide, the tetrachloro that are 2. prepared with step in 1)
Change germanium be raw material, in the stage 3) obtain composite glass structure convex surface on vapor deposition height tear photosphere open, obtain prefabricated composite glass structure；
2. being overturn the composite glass structure for having high refractive layer is solidified, the ocratation that is 3. prepared with step in 1), oxidation
Zirconium, titanium oxide, boron oxide are raw material, be deposited on 1. prefabricated composite glass structure concave surface that step obtains it is low tear photosphere open, obtain
Crude composite glass structure；
3. 2. crude composite glass structure that step is obtained is placed in hydrofluoric acid vapor environment, until crude compound glass knot
Mirror status is presented in two surfaces of convex-concave of structure, that is, Chinese herbaceous peony needed for obtaining keeps off compound refractive power ink glass panel.
Compound refractive power ink glass panel is kept off using the Chinese herbaceous peony of above method manufacture, vitreum composition includes by weight
85 parts -90 parts of silica, 10 parts -15 parts of the potassium oxide of part meter；The vitreum convex surface is fixed with one layer of ocratation, oxidation
Cerium, germanium tetrachloride constitute high refractive layer, concave surface be fixed with one layer of ocratation, zirconium oxide, titanium oxide, boron oxide constitute it is low
Dioptric layer；Internal curing has ink screen, which includes indium oxide: the tin oxide ratio of 20:1 in mass ratio is solid
The high permeability ito film and indium oxide changed: the cured harmonious ito film of the tin oxide ratio of 9:1 in mass ratio forms, between two membranes
For the transparent oil-based liquid for being suspended with built-in electrically charged white particle and oppositely charged transparent grain microcapsules, which has
Two sets of static electric systems, first is that the transparent front and back electrostatic substrate being made of two sides ito film, second is that the left and right being made of two sides metal strip
Electrostatic substrate.
Compared with the prior art, the present invention as the above scheme is adopted, has the advantage that (1) is different from conventional ink
A set of static electric system by metal plate and ITO plate for counter electrode is arranged using black-and-white two color particle as the two poles of the earth developing factor in water screen,
The present invention is due to technical purpose difference, using white and transparent grain as the two poles of the earth developing factor, and the two sets of electrostatic in front and rear, left and right is arranged
It is freely adjustable thus to realize client only in the aobvious just principle of power consumption in a flash mutually changed using ink screen for system
Transparency regulation system: completely without incident light (such as will in the car during sleep, get off after to prevent others from peeping
When regarding car, summer as it is light-blocking heat-insulated when), white particle can be guided to be routed to just by the static electric system that front and back ito film is constituted
Face or the back side (being biased to difference according to particle charge polarity difference, but actual effect is the same), panel is presented impermeable at this time
Bright white can reflect almost all incident ray, heat-insulated every light；When needing incident light (as during driving), a left side can be passed through
The static electric system guidance white particle that right metal strip is constituted is routed to left or right side, opaque according to sphere sectional area principle
Part just at (in fact having with small part existing for latticed form on Chinese herbaceous peony shelves glass-film in the prior art with point
Black splotch existing for battle array shape form, does not influence to use completely), glass becomes light transmission.(2) using no iron material, greatly
The irony content in glass raw material of the invention is reduced, according to correlative study, the light transmittance of the smaller glass of iron content is better,
Vitreum of the invention is substantially superior to the light refracting glass of the prior art, while the present invention is medium and small up to 98% light transmittance
The cerium oxide of amount also can hermetic section infrared ray and ultraviolet light, have and a little assist heat-insulated effect.(3) present invention does not use absorption
The material of light but interior outer close function is realized by refractive power, principle is the glass that uses of the present invention by outer and interior folding
Light rate shows apparent downward gradient, according to correlative study, when light is transmitted to low refractive index material from high refractive index material
When middle, the light at portions incident angle will be reflected back, can be eternal fixedly by part by a two layers high turn low reflection
(30%-40%) vehicle UV light reflects back and (plays anti-glazing light effect when daytime), without being influenced by day and night, and light
Line is inversely propagated, and extinction effect can be showed, and can make to show brighter effect outside vehicle slightly by force by the light of interior sending
Fruit (plays light enhancing effect) when night, while also unaffected at phasic property.(4) the most thick main body of vitreum, that is, thickness of the invention
The physical toughened processing used, not only environmentally friendly but also quick, good manufacturability.(5) three layers are silicon-based glass, not by nature atmosphere
Existing overwhelming majority substance influences, durable and be unlikely to deform discoloration.
Specific embodiment
Embodiment 1:
A kind of compound refractive power ink glass panel of Chinese herbaceous peony gear, vitreum composition includes silica by weight
85Kg, potassium oxide 15Kg；The vitreum convex surface is fixed with the high refractive layer that one layer of ocratation, cerium oxide, germanium tetrachloride are constituted,
Concave surface is fixed with the low refractive layer that one layer of ocratation, zirconium oxide, titanium oxide, boron oxide are constituted；Internal curing has ink screen, should
Ink screen basic structure includes indium oxide: the cured high permeability ito film of the tin oxide ratio of 20:1 in mass ratio and indium oxide: oxygen
Change the cured harmonious ito film composition of the tin ratio of 9:1 in mass ratio, is to be suspended with built-in electrically charged white particle between two membranes
And the transparent oil-based liquid of oppositely charged transparent grain microcapsules, the ink screen have two sets of static electric systems, first is that by two sides ITO
The transparent front and back electrostatic substrate of film composition, second is that the left and right electrostatic substrate being made of two sides metal strip.
Above-mentioned Chinese herbaceous peony keeps off the manufacturing method of compound refractive power ink glass panel, comprising the following steps:
1) prepare before production
1. vitreum raw material prepare: preparation silica 85Kg, potassium oxide 15Kg by weight；
2. inner surface material prepares: preparation ocratation 8Kg, cerium oxide 0.5Kg, germanium tetrachloride 0.7Kg by weight；
3. outer surface material prepares: preparation ocratation 8Kg, zirconium oxide 0.2Kg, titanium oxide 0.2Kg, oxidation by weight
Boron 0.6Kg；
4. ink screen material prepares: preparing the metal strip being adapted with vehicle two sides A column, prepare enough built-in electrically charged white
The microcapsules of particle and oppositely charged transparent grain prepare enough transparent oil-based liquids, prepare enough indium oxides, enough oxidations
Tin；
5. technological preparation: preparation asbestos board, enough pure oxygens, silicon nitride ceramics container, furnace chamber top are integrated with recirculated water cooling
But the protective atmosphere heating furnace, enough hydrofluoric acid of system；
2) glass body firing, tempering and molding
1. by with 1) in after the step silica, the potassium oxide that 1. prepare be uniformly mixed and melt, poured in vacuum environment
Casting obtains vitreum fluid into the mold being adapted with automobile front windshield radian；
2. 1. vitreum fluid that step obtains is gas-cooled under the nitrogen of 3bar-4bar, i.e. acquisition tempering rear vitreous body；
3) composite glass structure of ink electrical screen built in
1. prepare two pieces of stages 2) obtain tempering rear vitreous body, be set to the first glass plate and the second glass plate；
2. using indium oxide: the mixture of the ratio mixture of tin oxide 20:1 in mass ratio is recessed in the first glass plate as raw material
High permeability ito film is deposited in side surface；Using indium oxide: the mixture of the ratio mixture of tin oxide 9:1 in mass ratio is raw material,
Harmonious ito film is deposited in the convex side surface of two glass plates；Two ito films are provided with metal lead wire close to panel bottom side region；It will
Two pieces of glass plates, which immerse, contains the stage 1) 4. step prepares in the transparent oil-based liquid of microcapsules, two pieces of glass plates is placed in parallel,
Two sides ito film close to and control room septal space 0.3mm after, place the stage 1 in gap side) metal strip that 4. prepares of step, two
Root metal strip bottom is provided with metal lead wire, is then closed metal strip in two pieces of glass plate surrounding gaps simultaneously using insulating cement
It is separated with ito film, exposes four lead of bottom, the composite glass structure of built-in ink electrical screen needed for obtaining；
4) surface is deposited
1. in the confined space of protective atmosphere heating furnace, the ocratation, cerium oxide, the tetrachloro that are 2. prepared with step in 1)
Change germanium be raw material, in the stage 3) obtain composite glass structure convex surface on vapor deposition height tear photosphere open, obtain prefabricated composite glass structure；
2. being overturn the composite glass structure for having high refractive layer is solidified, the ocratation that is 3. prepared with step in 1), oxidation
Zirconium, titanium oxide, boron oxide are raw material, be deposited on 1. prefabricated composite glass structure concave surface that step obtains it is low tear photosphere open, obtain
Crude composite glass structure；
3. 2. crude composite glass structure that step is obtained is placed in hydrofluoric acid vapor environment, until crude compound glass knot
Mirror status is presented in two surfaces of convex-concave of structure, that is, Chinese herbaceous peony needed for obtaining keeps off compound refractive power ink glass panel.
Being kept off according to the Chinese herbaceous peony of the present embodiment production with compound refractive power ink glass panel can freely adjust transparency, by it is interior extremely
Outer light transmittance 96%, vehicle UV light reflectivity 33%.
Embodiment 2:
It is whole consistent with embodiment 1, it is in place of difference:
A kind of compound refractive power ink glass panel of Chinese herbaceous peony gear, vitreum composition includes silica by weight
90Kg, potassium oxide 10Kg；The vitreum convex surface is fixed with the high refractive layer that one layer of ocratation, cerium oxide, germanium tetrachloride are constituted,
Concave surface is fixed with the low refractive layer that one layer of ocratation, zirconium oxide, titanium oxide, boron oxide are constituted；Internal curing has ink screen, should
Ink screen basic structure includes indium oxide: the cured high permeability ito film of the tin oxide ratio of 20:1 in mass ratio and indium oxide: oxygen
Change the cured harmonious ito film composition of the tin ratio of 9:1 in mass ratio, is to be suspended with built-in electrically charged white particle between two membranes
And the transparent oil-based liquid of oppositely charged transparent grain microcapsules, the ink screen have two sets of static electric systems, first is that by two sides ITO
The transparent front and back electrostatic substrate of film composition, second is that the left and right electrostatic substrate being made of two sides metal strip.
Above-mentioned Chinese herbaceous peony keeps off the manufacturing method of compound refractive power ink glass panel, comprising the following steps:
1) prepare before production
1. vitreum raw material prepare: preparation silica 90Kg, potassium oxide 10Kg by weight；
2. inner surface material prepares: preparation ocratation 9Kg, cerium oxide 0.6Kg, germanium tetrachloride 0.9Kg by weight；
3. outer surface material prepares: preparation ocratation 9Kg, zirconium oxide 0.3Kg, titanium oxide 0.3Kg, oxidation by weight
Boron 0.8Kg；
3) composite glass structure of ink electrical screen built in
2. using indium oxide: the mixture of the ratio mixture of tin oxide 20:1 in mass ratio is recessed in the first glass plate as raw material
High permeability ito film is deposited in side surface；Using indium oxide: the mixture of the ratio mixture of tin oxide 9:1 in mass ratio is raw material,
Harmonious ito film is deposited in the convex side surface of two glass plates；Two ito films are provided with metal lead wire close to panel bottom side region；It will
Two pieces of glass plates, which immerse, contains the stage 1) 4. step prepares in the transparent oil-based liquid of microcapsules, two pieces of glass plates is placed in parallel,
Two sides ito film close to and control room septal space 0.5mm after, place the stage 1 in gap side) metal strip that 4. prepares of step, two
Root metal strip bottom is provided with metal lead wire, is then closed metal strip in two pieces of glass plate surrounding gaps simultaneously using insulating cement
It is separated with ito film, exposes four lead of bottom, the composite glass structure of built-in ink electrical screen needed for obtaining；
Being kept off according to the Chinese herbaceous peony of the present embodiment production with compound refractive power ink glass panel can freely adjust transparency, by it is interior extremely
Outer light transmittance 98%, vehicle UV light reflectivity 39%.
The foregoing description of the disclosed embodiments, only for can be realized professional and technical personnel in the field or use this
Invention.Various modifications to these embodiments will be readily apparent to those skilled in the art, institute herein
The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore,
The present invention will not be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent widest scope of point.
Claims (2)
1. the manufacturing method that a kind of Chinese herbaceous peony keeps off compound refractive power ink glass panel, it is characterised in that the following steps are included:
1) prepare before production
1. vitreum raw material prepare: preparation 85 parts -90 parts of silica, 10 parts -15 parts of potassium oxide by weight；
2. inner surface material prepares: preparation 8 parts -9 parts of ocratation, 0.5 part -0.6 part of cerium oxide, germanium tetrachloride by weight
0.7 part -0.9 part；
3. outer surface material prepares: preparation 8 parts -9 parts of ocratation, 0.2 part -0.3 part of zirconium oxide, titanium oxide 0.2 by weight
- 0.3 part, 0.6 part -0.8 part of boron oxide of part；
4. ink screen material prepares: preparing the metal strip being adapted with vehicle two sides A column, prepare enough built-in electrically charged white particles
And microcapsules, the enough transparent oil-based liquids of preparation, the enough indium oxides of preparation, enough tin oxide of oppositely charged transparent grain；
5. technological preparation: preparation asbestos board, enough pure oxygens, silicon nitride ceramics container, furnace chamber top are integrated with circulating water system
Protective atmosphere heating furnace, the enough hydrofluoric acid of system；
2) glass body firing, tempering and molding
1. by with 1) in after the step silica, the potassium oxide that 1. prepare be uniformly mixed and melt, cast in vacuum environment to
In the mold being adapted with automobile front windshield radian, vitreum fluid is obtained；
2. 1. vitreum fluid that step obtains is gas-cooled under the nitrogen of 3bar-4bar, i.e. acquisition tempering rear vitreous body；
3) composite glass structure of ink electrical screen built in
1. prepare two pieces of stages 2) obtain tempering rear vitreous body, be set to the first glass plate and the second glass plate；
2. using indium oxide: the mixture of the ratio mixture of tin oxide 20:1 in mass ratio is raw material, in the first glass plate concave side table
High permeability ito film is deposited in face；Using indium oxide: the mixture of the ratio mixture of tin oxide 9:1 in mass ratio is raw material, in the second glass
Harmonious ito film is deposited in the convex side surface of glass plate；Two ito films are provided with metal lead wire close to panel bottom side region；By two pieces
Glass plate, which immerses, contains the stage 1) 4. step prepares in the transparent oil-based liquid of microcapsules, two pieces of glass plates is placed in parallel, two sides
Ito film close to and control room septal space 0.3mm-0.5mm after, place the stage 1 in gap side) metal strip that 4. prepares of step,
Two metal strip bottoms are provided with metal lead wire, are then closed metal in two pieces of glass plate surrounding gaps simultaneously using insulating cement
Item is separated with ito film, exposes four lead of bottom, the composite glass structure of built-in ink electrical screen needed for obtaining；
4) surface is deposited
1. in the confined space of protective atmosphere heating furnace, the ocratation, cerium oxide, the germanium tetrachloride that are 2. prepared with step in 1)
For raw material, in the stage 3) vapor deposition height tears photosphere open on the composite glass structure convex surface that obtains, obtain prefabricated composite glass structure；
2. being overturn the composite glass structure for having high refractive layer is solidified, ocratation, zirconium oxide, the oxygen 3. prepared with step in 1)
Change titanium, boron oxide is raw material, be deposited on 1. prefabricated composite glass structure concave surface that step obtains it is low tear photosphere open, obtain crude multiple
Close glass structure；
3. 2. crude composite glass structure that step is obtained is placed in hydrofluoric acid vapor environment, until crude composite glass structure
Mirror status is presented in two surfaces of convex-concave, that is, Chinese herbaceous peony needed for obtaining keeps off compound refractive power ink glass panel.
2. a kind of Chinese herbaceous peony using the manufacture of claim 1 the method keeps off compound refractive power ink glass panel, it is characterised in that:
Its vitreum composition includes 10 parts -15 parts of 85 parts -90 parts of silica, potassium oxide by weight；The vitreum convex surface is solid
Surely have one layer of ocratation, cerium oxide, germanium tetrachloride constitute high refractive layer, concave surface be fixed with one layer of ocratation, zirconium oxide,
The low refractive layer that titanium oxide, boron oxide are constituted；Internal curing has ink screen, which includes indium oxide: oxidation
The cured high permeability ito film of the tin ratio of 20:1 in mass ratio and indium oxide: the tin oxide ratio of 9:1 in mass ratio is cured
Weighing apparatus property ito film forms, and is to be suspended with built-in electrically charged white particle and oppositely charged transparent grain microcapsules between two membranes
Transparent oil-based liquid, the ink screen have two sets of static electric systems, first is that the transparent front and back electrostatic substrate being made of two sides ito film, two
The left and right electrostatic substrate being made of two sides metal strip.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811428923.1A CN109572373A (en) | 2018-11-27 | 2018-11-27 | A kind of Chinese herbaceous peony gear compound refractive power ink glass panel and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811428923.1A CN109572373A (en) | 2018-11-27 | 2018-11-27 | A kind of Chinese herbaceous peony gear compound refractive power ink glass panel and its manufacturing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109572373A true CN109572373A (en) | 2019-04-05 |
Family
ID=65924977
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811428923.1A Pending CN109572373A (en) | 2018-11-27 | 2018-11-27 | A kind of Chinese herbaceous peony gear compound refractive power ink glass panel and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109572373A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101828785A (en) * | 2010-03-29 | 2010-09-15 | 中国人民解放军总后勤部军需装备研究所 | Color changeable camouflage textile based on electronic ink display technology and manufacture method thereof |
| CN103576402A (en) * | 2012-08-01 | 2014-02-12 | 余志刚 | Transparent electronic ink paper |
| CN103969906A (en) * | 2013-02-04 | 2014-08-06 | 联想(北京)有限公司 | Electronic ink screen, display switching method and electronic equipment |
| CN108101360A (en) * | 2017-12-28 | 2018-06-01 | 宁波俐辰新能源有限公司 | A kind of light refracting tempered glass and its manufacturing method |
-
2018
- 2018-11-27 CN CN201811428923.1A patent/CN109572373A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101828785A (en) * | 2010-03-29 | 2010-09-15 | 中国人民解放军总后勤部军需装备研究所 | Color changeable camouflage textile based on electronic ink display technology and manufacture method thereof |
| CN103576402A (en) * | 2012-08-01 | 2014-02-12 | 余志刚 | Transparent electronic ink paper |
| CN103969906A (en) * | 2013-02-04 | 2014-08-06 | 联想(北京)有限公司 | Electronic ink screen, display switching method and electronic equipment |
| CN108101360A (en) * | 2017-12-28 | 2018-06-01 | 宁波俐辰新能源有限公司 | A kind of light refracting tempered glass and its manufacturing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6805183B2 (en) | Multi-functional material system for surface display unit | |
| JP5849970B2 (en) | Article having a low-reflection film | |
| CN106467360A (en) | A kind of light guide plate and the optical display with backlight | |
| CN105319616A (en) | Anti-dazzle film substrate and article | |
| JP2008233547A (en) | Lens glass material for on-vehicle camera and lens for on-vehicle camera | |
| CN1400939A (en) | Antireflective UV blocking multilayer coatings wherin film has cerium oxide | |
| CN104220391B (en) | glass plate with high energy transmissivity | |
| CN108423986B (en) | Borosilicate glass, anti-halation input window glass and preparation method thereof | |
| WO2015163330A1 (en) | Anti-glare-layer substrate and article | |
| KARASU et al. | The latest developments in glass science and technology | |
| WO2014175367A1 (en) | Glass, chemically strengthened glass, external member and electronic device | |
| WO2014175366A1 (en) | Glass with coating film, chemically strengthened glass with coating film, external member and electronic device | |
| TW201425261A (en) | White glass | |
| JP2016041481A (en) | Transparent base material with antiglare antireflection film, and article | |
| CN110272204B (en) | Composite cover plate glass, total reflection display device, chromium-aluminum quartz glass and preparation method | |
| JP7175610B2 (en) | glass | |
| JP2013256446A (en) | Lens glass material for on-vehicle camera and lens for on-vehicle camera | |
| TW201925127A (en) | Optical glass, optical member, and optical device | |
| TW201422555A (en) | White glass | |
| CN109572373A (en) | A kind of Chinese herbaceous peony gear compound refractive power ink glass panel and its manufacturing method | |
| WO2018135504A1 (en) | Wavelength-selectively permeable laminated glass | |
| JP6488575B2 (en) | Near-infrared absorbing structure | |
| CN109397790A (en) | Chinese herbaceous peony the gear multi-functional composite glass structure of lifting and its manufacturing method | |
| JP2020121889A (en) | Wavelength selective transparent glass article | |
| CN208921891U (en) | A kind of medical treatment perspective optical mirror slip |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20201209 Address after: 511458 second industrial zone, Datong village, 100m south of the intersection of Weimin street and Yuxing street, Nansha District, Guangzhou City, Guangdong Province Applicant after: Zhang Yuanyuan Address before: 315000 3a, 3rd floor, 3rd floor, building 1, No. 317, Guanghua Road, hi tech Zone, Ningbo City, Zhejiang Province Applicant before: NINGBO FULL-LIGHTING TECHNOLOGY Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190405 |
|
| RJ01 | Rejection of invention patent application after publication |