CN109569953A - Membrane material and lithium electrode plate substrate coating waste water method - Google Patents

Membrane material and lithium electrode plate substrate coating waste water method Download PDF

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Publication number
CN109569953A
CN109569953A CN201811534516.9A CN201811534516A CN109569953A CN 109569953 A CN109569953 A CN 109569953A CN 201811534516 A CN201811534516 A CN 201811534516A CN 109569953 A CN109569953 A CN 109569953A
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CN
China
Prior art keywords
constant temperature
electrode plate
lithium electrode
membrane material
plate substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811534516.9A
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Chinese (zh)
Inventor
聂旭峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangxi Mingguan Lithium Film Technology Co Ltd
Original Assignee
Jiangxi Mingguan Lithium Film Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangxi Mingguan Lithium Film Technology Co Ltd filed Critical Jiangxi Mingguan Lithium Film Technology Co Ltd
Priority to CN201811534516.9A priority Critical patent/CN109569953A/en
Priority to PCT/CN2018/125274 priority patent/WO2020118793A1/en
Publication of CN109569953A publication Critical patent/CN109569953A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C1/00Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
    • B05C1/04Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
    • B05C1/08Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
    • B05C1/10Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line the liquid or other fluent material being supplied from inside the roller
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B15/00Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
    • B05B15/50Arrangements for cleaning; Arrangements for preventing deposits, drying-out or blockage; Arrangements for detecting improper discharge caused by the presence of foreign matter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C1/00Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
    • B05C1/003Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating incorporating means for heating or cooling the liquid or other fluent material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C13/00Means for manipulating or holding work, e.g. for separate articles
    • B05C13/02Means for manipulating or holding work, e.g. for separate articles for particular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/28Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers

Landscapes

  • Application Of Or Painting With Fluid Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

A kind of membrane material of disclosure of the invention and lithium electrode plate substrate coating waste water method, including using membrane material and lithium electrode plate substrate as the painting cloth base material of processing object, using slit coating method, the painting cloth base material of coater unit is coated, it is to use constant temperature mirror roller for apparatus for coating, is matched corresponding temperature control equipment in being equipped in coater unit by applying cloth base material and masking liquid;The temperature range for controlling coater unit simultaneously is 20-80 DEG C.Using slit coating method, the painting cloth base material of coater unit is coated, the quality of membrane material and the coating of lithium electrode plate substrate is improved, there is preferable economic benefit.

Description

Membrane material and lithium electrode plate substrate coating waste water method
Technical field:
The present invention relates to a kind of coating waste water method of material, especially a kind of membrane material and lithium electrode plate substrate coating waste water side Method.
Background technique:
At present in light industry papermaking, membrane material processing, the fields such as lithium electrode piece manufacture, when to the processing of membrane material and lithium electrode sheet material Coating process, usually use item and stitch extrusion coated processing.Currently, it is multiple that item seam, which squeezes out (Slot-Die Coating) coating, The important and universal technique of one of condensation material molding, can be made high-accuracy multiple using item seam extrusion (Slot-Die Coating) Condensation material has excellent stability.The metals membrane material such as Paper Coating, thin-film material coating, copper foil, aluminium foil is coated at present Etc. being all made of room temperature coating method.Substrate surface completes the process of coating process, on the one hand to meet the physical machine of substrate itself Tool characteristic keeps stablizing, the mix adhesion strength and cohesive force of another aspect masking liquid itself by surface bonding connection function.And Item seam, which squeezes out common deficiency in (Slot-Die Coating) coating process, to be had: because substrate surface tension unevenness causes surfacing Degree not enough, directly results in and applies liquid level unevenness;Because rolled copper foil itself rolls due to repeatedly extending the immersion of oil gas in process, Cause masking liquid adhesive force insufficient in surface temperature unevenness, causes stripping layering etc. abnormal;Because masking liquid melt index is insufficient, after heat absorption Low temperature crystallization, blocking item seam coating head cause glue surface wire drawing abnormal.
So-called slit coating, be it is a kind of under a certain pressure, masking liquid is extruded along die gap and is transferred to shifting It a kind of the features such as coating technique on dynamic substrate, it is fast, painting film uniformity is good, coat window is wide with its coating speed, represents Wet coating future thrust.The application field of SDC is shifted from conventional film and papermaking etc. to new energy field, especially Solar battery and electrodes of lithium-ion batteries coating.The application of slit coating
Common coating method has item seam to squeeze out i.e. slit coating (Slot-Die Coating), blade coating (Comma Coating), the types such as dimple coating (Gravure Coating), wherein what is be most widely used is slit-aperture type coating method, There are IC, FPC, photoelectricity, the multi industries such as people's livelihood in its application product field.First by a web-like substrate, such as PP, BOPP, PET, PI, Masking liquid is overlying on substrate by copper foil etc. by apparatus for coating, and drying process removes solvent in masking liquid, finally coils into Volume, the as use of finished product or semi-finished product.Process key institute under pressure, masking liquid from being squeezed out in gap between upper and lower mould, Adhesive film is formed between mirror roller moving substrate and is transferred to substrate surface, forms wet film;The formation of glue film is the pass of film forming Key, in whole process.
But it when for membrane material and lithium electrode plate substrate coating waste water, is directly determined using common coating method and device The quality of membrane material and lithium electrode sheet material after coating.The principal element of appearance has: die lip cleannes, masking liquid for glue stability, Surface tension and dry solidification condition of mirror roller substrate etc.;Plant constant temperature mirror roller and its applied to answering in slit-aperture type coating With, slot coated or cry slit coating at present in light industry papermaking, membrane material processing, the fields such as lithium electrode piece manufacture obtain extensively Using.
Summary of the invention:
The present invention seeks to provide a kind of membrane material and lithium electrode plate substrate coating waste water method.Including with membrane material and lithium electrode Plate substrate is that the painting cloth base material of processing object is coated the painting cloth base material of coater unit, is mentioned using slit coating method The high quality of membrane material and the coating of lithium electrode plate substrate, has preferable economic benefit.
The present invention discloses a kind of membrane material and lithium electrode plate substrate coating waste water method, including with membrane material and lithium electrode piece Substrate is that the painting cloth base material of processing object is coated the painting cloth base material of coater unit, is using slit coating method It uses constant temperature mirror roller for apparatus for coating, controls in being equipped in coater unit by applying cloth base material and the masking liquid corresponding temperature that matches Device;The temperature range for controlling coater unit simultaneously is 20-80 DEG C.
The thermostatic mode of the constant temperature mirror roller is designed using contactless constant temperature, and constant temperature mirror roller is using auxiliary constant temperature system System carries out temperature control.
The constant temperature mirror roller controls its thermal evenness controlling within the scope of ± 1 DEG C.
The constant temperature mirror roller controls the straightness of its machining accuracy, bounce, concentricity≤0.002mm;Roughness Ra < 0.01。
The auxiliary constant temperature system is controlled using refrigerant cold cycling control mode.
The constant temperature mirror roller is applied to item and stitches coating backing roller, is reached by constant temperature mirror roller and is stitched to substrate, masking liquid and item Mold carries out constant temperature purpose.
The substrate improves surface tension by package back heating roller, and attaches back flow roll flatness, and guarantee passes through preheating It is completed in conjunction with masking liquid under substrate constant temperature, heats masking liquid temperature using the radiations heat energy of constant temperature mirror roller.
A kind of membrane material of the present invention and lithium electrode plate substrate coating waste water method, are mainly applied to item for constant temperature mirror roller In seam coating, it is especially applied in membrane material and lithium electrode plate substrate coating waste water method, uses the above method, base The process of coating process is completed on material surface, and the physical mechanical characteristic that on the one hand meet substrate itself keeps stablizing, on the other hand Mix adhesion strength and the cohesive force of masking liquid itself by surface bonding and connection function.The system comprises constant temperature mirror roller applications Coating backing roller is stitched in item, so that constant temperature substrate is reached by constant temperature mirror roller, the purpose that constant temperature masking liquid and constant temperature slit die have, Substrate reaches improvement surface tension by package back heating roller, reaches and attaches back flow roll flatness, to guarantee to pass through pre- hot substrate It is completed in conjunction with masking liquid under constant temperature, constant temperature mirror roller can also promote masking liquid temperature by radiations heat energy, effectively avoid masking liquid Crystallization Plugging item stitches coating head.
Have from common deficiency in existing item seam extrusion (Slot-Die Coating) coating process is overcome: because of substrate table Face tension unevenness causes surface smoothness inadequate, directly results in and applies liquid level unevenness;Because rolled copper foil itself is due to the stone roller that repeatedly extends The immersion for pressing oil gas in process causes masking liquid adhesive force insufficient, causes stripping layering etc. abnormal in surface temperature unevenness;Cause Masking liquid melt index is insufficient, low temperature crystallization after heat absorption, and blocking item seam coating head causes glue surface wire drawing abnormal.So as to membrane material and The reduction of lithium electrode piece processing cost plays significant role, generates great economic benefit.
Specific embodiment:
The present invention is described in further detail With reference to embodiment.Substrate described in this specification is membrane material Or with lithium electrode sheet material.
A kind of membrane material of the present invention and lithium electrode plate substrate coating waste water method, including with membrane material and lithium electrode plate substrate The painting cloth base material of coater unit is coated using slit coating method for the painting cloth base material of processing object, it is characterized in that It uses constant temperature mirror roller for apparatus for coating, controls in being equipped in coater unit by applying cloth base material and the masking liquid corresponding temperature that matches Device;The temperature range for controlling coater unit simultaneously is 20-80 DEG C.
The thermostatic mode of the constant temperature mirror roller is designed using contactless constant temperature, and constant temperature mirror roller is using auxiliary constant temperature system System carries out temperature control.
The constant temperature mirror roller controls its thermal evenness controlling within the scope of ± 1 DEG C.
The constant temperature mirror roller controls the straightness of its machining accuracy, bounce, concentricity≤0.002mm;Roughness Ra < 0.01。
The auxiliary constant temperature system is controlled using refrigerant cold cycling control mode.
The constant temperature mirror roller is applied to item and stitches coating backing roller, is reached by constant temperature mirror roller and is stitched to substrate, masking liquid and item Mold carries out constant temperature purpose.
The substrate improves surface tension by package back heating roller, and attaches back flow roll flatness, and guarantee passes through preheating It is completed in conjunction with masking liquid under substrate constant temperature, heats masking liquid temperature using the radiations heat energy of constant temperature mirror roller.
Coater unit installation requirement carries out accurate temperature setting and control according to the characteristics of substrate and masking liquid.Temperature one As 20 DEG C of -80 DEG C of of control range
The mirror roller thermostatic mode is the design of contactless constant temperature, and constant temperature mirror roller carries out temperature control by auxiliary constant temperature system System.
The temperature of the constant temperature mirror roller need to have enough stability, and temperature uniformity should be within the scope of ± 1 DEG C, with true Protect the quality of processing technology and product.The temperature supplementary controlled system can be refrigerant cold cycling control mode, can also By be other refrigeration and thermal cycle in a manner of.Constant temperature mirror roller of the present invention need to have enough machining accuracies simultaneously.Its straightness, Bounce, concentricity≤0.002mm.Roughness Ra 0.01 is at 14 grades of finish.
Embodiment 1
The method that a kind of processing that the embodiment of the present invention provides prepares membrane material, is to prepare high-performance aluminum plastic film, specific It is the successively structural order from inside to outside including adhesive: cast polypropylene film layer (hot sealing layer);Acrylic resin glue Glutinous layer;Aluminium foil layer;Polyurethane adhesive layer;Polyamide laminate film.
In the present embodiment, answer material structure that slot coated mode is used to carry out, aluminium foil adheres to as cloth base material, surface is applied Acrylic resin adhesive and cast polypropylene film carry out dry laminating, generate aluminum plastic film semi-finished product, adopt during gluing It is coated with aluminium foil.
Present embodiment is to use constant temperature mirror roller for apparatus for coating, micro- in the high-performance adhesive layer thickness 30 of coater unit Meter Shang Shu high-performance aluminum plastic film uses dry-forming method, using slot coated mode, opens constant temperature mirror roller and is heated to controlling The temperature of coater unit is coated in operational process at 60 degrees Celsius, is designed using contactless constant temperature, and aluminium foil thermal coefficient is controlled 230W/m K, on the basis of substrate excellent heating conduction, aluminium foil surface temperature reaches 54 degrees Celsius, and adhesive passes through slit It squeezes out, radiations heat energy can make glue temperature rise to 48 DEG C degrees Celsius, and constant temperature mirror roller controls its temperature uniformity in ± 1 DEG C of model In enclosing.And then realize higher coating accuracy, glue surface is without wire drawing, crystal point bad order;Enhance adhesive and aluminium foil bonding force, reaches Enhancing peel strength effect, the constant temperature mirror roller that the present invention uses is applied compared with the non-heated constant temperature mirror roller of the prior art, Simplify with technique, work continuously and produce glue-line good appearance, after tested, the present invention uses the application output aluminium of constant temperature mirror roller Plastic film interlayer peeling force increases to 11.62N/15mm by 7.85N/15mm.
It should be understood that the above above-mentioned technical solution disclosed in this invention, non-to limit it;Although referring to aforementioned Invention is explained in detail for each embodiment, those skilled in the art should understand that: it still can be to preceding It states technical solution documented by each embodiment to modify, or some or all of the technical features is equally replaced It changes;And these are modified or replaceed, the model for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution It encloses, should all cover within the scope of the claims and the description of the invention.

Claims (7)

  1. It 1. a kind of membrane material and lithium electrode plate substrate coating waste water method, including with membrane material and lithium electrode plate substrate is processing pair The painting cloth base material of elephant is coated the painting cloth base material of coater unit, using slit coating method it is characterized in that using constant temperature Mirror roller is apparatus for coating, is matched corresponding temperature control equipment in being equipped in coater unit by applying cloth base material and masking liquid;Together When control coater unit temperature range be 20-80 DEG C.
  2. 2. a kind of membrane material according to claim 1 and lithium electrode plate substrate coating waste water method, it is characterized in that the perseverance The thermostatic mode of warm mirror roller is designed using contactless constant temperature, and constant temperature mirror roller carries out temperature control using auxiliary constant temperature system System.
  3. 3. a kind of membrane material according to claim 1 or 2 and lithium electrode plate substrate coating waste water method, it is characterized in that described Constant temperature mirror roller controls its thermal evenness controlling within the scope of ± 1 DEG C.
  4. 4. a kind of membrane material according to claim 1 or 2 and lithium electrode plate substrate coating waste water method, it is characterized in that described Constant temperature mirror roller controls the straightness of its machining accuracy, bounce, concentricity≤0.002mm;Roughness Ra < 0.01.
  5. 5. a kind of membrane material according to claim 2 and lithium electrode plate substrate coating waste water method, it is characterized in that described auxiliary Helping constant temperature system is controlled using refrigerant cold cycling control mode.
  6. 6. a kind of membrane material according to claim 1 or 2 and lithium electrode plate substrate coating waste water method, it is characterized in that described Constant temperature mirror roller is applied to item and stitches coating backing roller, is reached by constant temperature mirror roller and carries out constant temperature to substrate, masking liquid and a slit die tool Purpose.
  7. 7. a kind of membrane material according to claim 1 or 2 and lithium electrode plate substrate coating waste water method, it is characterized in that described Substrate improves surface tension by package back heating roller, and attaches back flow roll flatness, and guarantee passes through pre- hot substrate constant temperature Lower completion heats masking liquid temperature in conjunction with masking liquid, using the radiations heat energy of constant temperature mirror roller.
CN201811534516.9A 2018-12-14 2018-12-14 Membrane material and lithium electrode plate substrate coating waste water method Pending CN109569953A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201811534516.9A CN109569953A (en) 2018-12-14 2018-12-14 Membrane material and lithium electrode plate substrate coating waste water method
PCT/CN2018/125274 WO2020118793A1 (en) 2018-12-14 2018-12-29 Method for coating and processing membrane material and lithium electrode sheet base material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811534516.9A CN109569953A (en) 2018-12-14 2018-12-14 Membrane material and lithium electrode plate substrate coating waste water method

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WO (1) WO2020118793A1 (en)

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JP2012003968A (en) * 2010-06-17 2012-01-05 Nissan Motor Co Ltd Coating device and method for producing electrode foil
CN106269386A (en) * 2015-05-15 2017-01-04 伍秋涛 A kind of apparatus for coating improving solvent-free adhesive levelability and method
CN106847411A (en) * 2015-12-07 2017-06-13 宁波惠之星新材料科技有限公司 A kind of coating system, a kind of nano-silver thread conductive film and preparation method thereof
CN107150006A (en) * 2016-03-03 2017-09-12 罗巴泰克股份公司 For the apparatus and method being applied to adhesive on substrate
CN107737705A (en) * 2017-10-10 2018-02-27 青岛国轩电池有限公司 A kind of method of coater oven temperature pre-adjustment
CN108480135A (en) * 2018-05-24 2018-09-04 陈鸿奇 A kind of apparatus for coating of coiled film base material coating
CN108772245A (en) * 2018-07-09 2018-11-09 广东华粘新材料研究有限公司 A kind of coating system that vertical bar type slit extrusion die is combined with multiple roll

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CN2279962Y (en) * 1996-12-31 1998-04-29 中国科学院感光化学研究所 Device for hot melt coating
JP2002237373A (en) * 2001-02-09 2002-08-23 Japan Servo Co Ltd Heat roller control device
US7501921B2 (en) * 2005-05-13 2009-03-10 Magnetnotes, Ltd. Temperature controlled magnetic roller
CN102500524B (en) * 2011-11-08 2014-12-10 东莞新能源科技有限公司 Process for coating lithium battery

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030194497A1 (en) * 2002-04-15 2003-10-16 Fuji Photo Film Co., Ltd. Coating method, coating apparatus, and method and apparatus for manufacturing pattern members using webs on which coating films have been formed by coating method and coating apparatus
JP2012003968A (en) * 2010-06-17 2012-01-05 Nissan Motor Co Ltd Coating device and method for producing electrode foil
CN106269386A (en) * 2015-05-15 2017-01-04 伍秋涛 A kind of apparatus for coating improving solvent-free adhesive levelability and method
CN106847411A (en) * 2015-12-07 2017-06-13 宁波惠之星新材料科技有限公司 A kind of coating system, a kind of nano-silver thread conductive film and preparation method thereof
CN107150006A (en) * 2016-03-03 2017-09-12 罗巴泰克股份公司 For the apparatus and method being applied to adhesive on substrate
CN107737705A (en) * 2017-10-10 2018-02-27 青岛国轩电池有限公司 A kind of method of coater oven temperature pre-adjustment
CN108480135A (en) * 2018-05-24 2018-09-04 陈鸿奇 A kind of apparatus for coating of coiled film base material coating
CN108772245A (en) * 2018-07-09 2018-11-09 广东华粘新材料研究有限公司 A kind of coating system that vertical bar type slit extrusion die is combined with multiple roll

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Application publication date: 20190405