CN109554623A - 550MPa grades of Weather-resistance bridge steel plates of yield strength and its production method - Google Patents

550MPa grades of Weather-resistance bridge steel plates of yield strength and its production method Download PDF

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Publication number
CN109554623A
CN109554623A CN201811494831.3A CN201811494831A CN109554623A CN 109554623 A CN109554623 A CN 109554623A CN 201811494831 A CN201811494831 A CN 201811494831A CN 109554623 A CN109554623 A CN 109554623A
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weather
yield strength
bridge steel
resistance bridge
temperature
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CN201811494831.3A
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Inventor
刘宝喜
张阔斌
尹绍江
郑文超
梁桂梅
安海玉
杜秀珍
郝鑫
刘忠满
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TANGSHAN ZHONGHOU BOARD MATERIALS CO Ltd
Tangshan Iron and Steel Group Co Ltd
HBIS Co Ltd Tangshan Branch
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TANGSHAN ZHONGHOU BOARD MATERIALS CO Ltd
Tangshan Iron and Steel Group Co Ltd
HBIS Co Ltd Tangshan Branch
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Priority to CN201811494831.3A priority Critical patent/CN109554623A/en
Publication of CN109554623A publication Critical patent/CN109554623A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses a kind of yield strength 550MPa grades of Weather-resistance bridge steel plates and its production methods, its chemical component and its mass percentage are as follows: C 0.03%~0.07%, Mn 1.35%~1.45%, S≤0.005%, P 0.012%~0.018%, Si 0.25%~0.35%, Als 0.020%~0.050%, Nb 0.025%~0.034%, Ti 0.010%~0.025%, Cr 0.50%~0.70%, Ni 0.35%~0.45%, Cu 0.30%~0.45%, Mo 0.10%~0.30%, surplus are Fe and inevitable impurity.This plate property is excellent, solderability is good, with excellent low-temperature impact toughness, and has stronger weatherability;Production method does not need simply to carry out quenched (quenching+high tempering) processing, lower production costs;It is the highest Weather-resistance bridge steel of yield strength grade in current bridge steel standard.This method product has good weatherability, weather-proof sex index I >=6.5;With excellent welding performance, welding crack sensibility indices P cm≤0.24;With excellent notch impact toughness, -40 DEG C, v-notch ballistic work >=200J;Tensile strength >=670MPa, yield strength >=550MPa, elongation percentage A >=16%.

Description

550MPa grades of Weather-resistance bridge steel plates of yield strength and its production method
Technical field
The invention belongs to metallurgical technology field more particularly to a kind of yield strength 550MPa grades of Weather-resistance bridge steel plate and Its production method.
Background technique
Although the intensity rank of bridge steel is increased to 690MPa grades by the GB/T714-2015 standard newly revised, the country The highest bridge steel intensity rank used so far is the Shanghai Changjiang River bridge for starting construction for 2014, strong for surrender The Q500qE of 500MPa grades of degree.In terms of Weather-resistance bridge steel, the application development in China is slower, and Wuhan Iron and Steel Plant takes the lead within 1989 It patrols on Si Heqiao and has carried out the exposed use test of 345MPa grades of weathering steels of yield strength, but is undesirable.Recent Weather-resistance bridge steel Develop into one of industrial hot spot, Anshan iron and steel plant etc. is carrying out 345MPa grades of Weather-resistance bridge steel semi-nudity application practices of yield strength;South Steel Weather-resistance bridge has been applied to the Sichuan-Tibet railway built and has hidden the wooden grand bridge, and highest yield strength rank reaches Q420qDNH.
The bridge steel standard GB/T714-2015 newly revised for 2015 has re-started stroke the intensity rank of bridge steel Point, Q550qNH is the highest yield strength grade in Weather-resistance bridge steel in the standard, and defined production method is to adjust Matter (quenching+high tempering) production.Application No. is a kind of " high-strength tenacity structural steel for bridge of CN201711181307.6 Q550qFNH cut deal and its production method " in describe a kind of Q550qFNH and its production method, but its thickness specification is big In 70mm, and the condition of delivery is quenched and tempered state (quenching+high tempering);Although the steel grade also has certain weatherability, resistance to Scaling index only exists in >=6.0 basic horizontal.
Summary of the invention
550MPa grades of yield strength the technical problem to be solved in the present invention is to provide a kind of fine corrosion resistance are weather-proof Bridge steel plate;The present invention also provides a kind of production methods of yield strength 550MPa grades of Weather-resistance bridge steel plates.
In order to solve the above technical problems, chemical component adopted by the present invention and its mass percentage are as follows: C 0.03% ~0.07%, Mn 1.35%~1.45%, S≤0.005%, P 0.012%~0.018%, Si 0.25%~0.35%, Als 0.020%~0.050%, Nb 0.025%~0.034%, Ti 0.010%~0.025%, Cr 0.50%~ 0.70%, Ni 0.35%~0.45%, Cu 0.30%~0.45%, Mo 0.10%~0.30%, surplus are Fe and can not The impurity avoided.
Steel plate thickness of the present invention is 12~60mm, and the condition of delivery is TMCP+ tempering.
Weather-proof sex index I >=6.5 of steel plate of the present invention, welding crack sensibility indices P cm≤0.24.
The method of the present invention includes continuous casting, heating, roughing, finish rolling, cooling process and tempering heat treatment process;
The roughing operation, 1000~1050 DEG C of start rolling temperature, finishing temperature >=970 DEG C, total reduction >=50%;
The finishing rolling step, start rolling temperature≤950 DEG C, total reduction >=50%, 770~810 DEG C of finishing temperature;
The cooling process, final cooling temperature are 350~550 DEG C;
The tempering heat treatment process, keeps the temperature 55~65min by 550~600 DEG C of tempering temperature.
Heating process described in the method for the present invention, slab enter heating furnace in room temperature, and heating time is 0.9~1.1min/mm Slab thickness.
The beneficial effects of adopting the technical scheme are that the present invention is had excellent performance, solderability is good, it is excellent to have Good low-temperature impact toughness, and there is stronger weatherability;Production method does not need simply to carry out quenched (quenching+high temperature time Fire) processing, lower production costs;It is the highest Weather-resistance bridge steel of yield strength grade in current bridge steel standard.
The method of the present invention product has good weatherability, weather-proof sex index I >=6.5;With excellent welding performance, Welding crack sensibility indices P cm≤0.24;With excellent notch impact toughness, -40 DEG C, v-notch ballistic work >= 200J;Tensile strength >=670MPa, yield strength >=550MPa, elongation percentage A >=16%;The condition of delivery is TMCP+ tempering, with The condition of delivery of quenched (quenching+tempering), which is compared, has apparent cost advantage.
Specific embodiment
The present invention will be further described in detail with reference to the specific embodiments.
Embodiment 1-30: 550MPa grades of Weather-resistance bridge steel plates of this yield strength and its production method are described in detail below.
1, this method include molten iron pretreatment, it is converter smelting, LF refining, RH refining, continuous casting, heating, roughing, finish rolling, cold But process and tempering heat treatment process, each process technique are as described below:
(1) continuous casting working procedure: the molten steel after molten iron pretreatment, converter smelting, LF refining, RH refining obtains thickness through continuous casting Degree is 200~280mm slab;Continuous casting process is using electromagnetic agitation and weight Reduction Technology;The offline slow cooling of slab is to room temperature, slow cooling Time >=36 hour.
(2) heating process: the slab of room temperature enters heating furnace, and heating time is 0.9~1.1min/mm slab thickness.
(3) roughing operation: 1000~1050 DEG C of start rolling temperature, finishing temperature >=970 DEG C, total reduction >=50%.
(4) finishing rolling step: start rolling temperature≤950 DEG C, total reduction >=50%, 770~810 DEG C of finishing temperature.
(5) cooling process: use ultrafast cooling, cooling velocity highest can be 120 DEG C/s, final cooling temperature be 350~ 550℃。
(6) heat treatment procedure: radiant tube type tempering furnace is used, 550~600 DEG C of tempering temperature, keeps the temperature 55~65min.
The specific process parameter of the continuous casting of each embodiment, heating and roughing operation is shown in Table 1, finish rolling, cooling and heat treatment work The specific process parameter of sequence is shown in Table 2.
Table 1: the concrete technology of continuous casting to roughing operation
Table 2: the concrete technology of finish rolling to heat treatment procedure
2, the chemical component of Weather-resistance bridge steel plate obtained by each embodiment and mass percentage are shown in Table 3, and surplus is for Fe and not Evitable impurity.
Table 3: the chemical component and content (wt%) of steel plate obtained by each embodiment
3, the thickness of Weather-resistance bridge steel plate obtained by each embodiment, weather-proof sex index I, welding crack sensibility indices P cm, Mechanical property and impact flexibility are shown in Table 4.
Table 4: the performance indicator of steel plate obtained by each embodiment
In table 4, embodiment 1-18 is whole plate stretching;Embodiment 19-21,25-27 is thickness direction a quarter position The φ 10mm pole set stretches and impact;Embodiment 22-24,28-30 is the φ 10mm circle of thickness direction half position Stick stretches and impact.

Claims (5)

1. a kind of yield strength 550MPa grades of Weather-resistance bridge steel plates, which is characterized in that its chemical component and its mass percentage Are as follows: C 0.03%~0.07%, Mn 1.35%~1.45%, S≤0.005%, P 0.012%~0.018%, Si 0.25%~0.35%, Als 0.020%~0.050%, Nb 0.025%~0.034%, Ti 0.010%~0.025%, Cr 0.50%~0.70%, Ni 0.35%~0.45%, Cu 0.30%~0.45%, Mo 0.10%~0.30%, surplus are Fe and inevitable impurity.
2. yield strength 550MPa grades of Weather-resistance bridge steel plates according to claim 1, it is characterised in that: the steel plate thickness For 12~60mm, the condition of delivery is TMCP+ tempering.
3. yield strength 550MPa grades of Weather-resistance bridge steel plates according to claim 1 or 2, it is characterised in that: the steel plate Weather-proof sex index I >=6.5, welding crack sensibility indices P cm≤0.24.
4. the production method of yield strength 550MPa grades of Weather-resistance bridge steel plate described in claim 1, it is characterised in that: it includes connecting Casting, heating, roughing, finish rolling, cooling process and tempering heat treatment process;
The roughing operation, 1000~1050 DEG C of start rolling temperature, finishing temperature >=970 DEG C, total reduction >=50%;
The finishing rolling step, start rolling temperature≤950 DEG C, total reduction >=50%, 770~810 DEG C of finishing temperature;
The cooling process, final cooling temperature are 350~550 DEG C;
The tempering heat treatment process, keeps the temperature 60min by 550~600 DEG C of tempering temperature.
5. the production method of yield strength 550MPa grades of Weather-resistance bridge steel plates according to claim 4, it is characterised in that: institute Heating process is stated, slab enters heating furnace in room temperature, and heating time is 0.9~1.1min/mm slab thickness.
CN201811494831.3A 2018-12-07 2018-12-07 550MPa grades of Weather-resistance bridge steel plates of yield strength and its production method Pending CN109554623A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110863139A (en) * 2019-10-31 2020-03-06 鞍钢股份有限公司 Ultralow-temperature-impact-resistant 420 MPa-grade weather-resistant bridge steel and production method thereof
CN111118401A (en) * 2020-02-28 2020-05-08 五矿营口中板有限责任公司 High-performance large-thickness easy-to-weld bridge structural steel and manufacturing method thereof
CN111455287A (en) * 2020-03-30 2020-07-28 南京钢铁股份有限公司 500 MPa-grade low-yield-ratio weather-resistant bridge steel and manufacturing method thereof
CN114262841A (en) * 2021-10-26 2022-04-01 包头钢铁(集团)有限责任公司 420 MPa-level weather-resistant structural steel with impact work of more than 150J at-80 ℃ and production method thereof
CN114606436A (en) * 2022-02-14 2022-06-10 包头钢铁(集团)有限责任公司 370 MPa-grade rare earth weather-resistant structural steel for polar region and production method thereof
CN114645201A (en) * 2022-03-14 2022-06-21 安阳钢铁股份有限公司 High-toughness Q500qNH bridge weather-resistant steel plate and manufacturing method thereof

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CN103320719A (en) * 2013-06-19 2013-09-25 宝山钢铁股份有限公司 Low-cost large-heat-input-weldable high-toughness steel plate and manufacturing method thereof
CN103938110A (en) * 2014-04-28 2014-07-23 江苏沙钢集团有限公司 FQ70-level ultrahigh-strength extra-thickness steel plate for ocean engineering and manufacturing method thereof
CN105008569A (en) * 2013-02-28 2015-10-28 杰富意钢铁株式会社 Thick steel plate and production method for thick steel plate
CN105385955A (en) * 2015-12-26 2016-03-09 首钢总公司 Welded structural steel with yield strength of 500 MPa and preparation method

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CN1367848A (en) * 1999-02-05 2002-09-04 伯利恒钢铁公司 Method of making weathering grade plate and product therefrom
CN101235469A (en) * 2008-02-28 2008-08-06 武汉钢铁(集团)公司 High-strength easy-formation atmospheric corrosion resisting steel
CN101665888A (en) * 2008-09-04 2010-03-10 株式会社神户制钢所 Thick steel board
CN101876032A (en) * 2009-12-26 2010-11-03 舞阳钢铁有限责任公司 Weather-resistance bridge high-strength steel plate and production method thereof
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CN101787489A (en) * 2010-03-11 2010-07-28 燕山大学 Easy-welding low-carbon bainitic steel and manufacturing method thereof
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CN105385955A (en) * 2015-12-26 2016-03-09 首钢总公司 Welded structural steel with yield strength of 500 MPa and preparation method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110863139A (en) * 2019-10-31 2020-03-06 鞍钢股份有限公司 Ultralow-temperature-impact-resistant 420 MPa-grade weather-resistant bridge steel and production method thereof
CN111118401A (en) * 2020-02-28 2020-05-08 五矿营口中板有限责任公司 High-performance large-thickness easy-to-weld bridge structural steel and manufacturing method thereof
CN111455287A (en) * 2020-03-30 2020-07-28 南京钢铁股份有限公司 500 MPa-grade low-yield-ratio weather-resistant bridge steel and manufacturing method thereof
CN114262841A (en) * 2021-10-26 2022-04-01 包头钢铁(集团)有限责任公司 420 MPa-level weather-resistant structural steel with impact work of more than 150J at-80 ℃ and production method thereof
CN114606436A (en) * 2022-02-14 2022-06-10 包头钢铁(集团)有限责任公司 370 MPa-grade rare earth weather-resistant structural steel for polar region and production method thereof
CN114645201A (en) * 2022-03-14 2022-06-21 安阳钢铁股份有限公司 High-toughness Q500qNH bridge weather-resistant steel plate and manufacturing method thereof

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Application publication date: 20190402