CN107326304A - A kind of TMCP types surrender 500MPa grades of bridge steel plates and production method - Google Patents

A kind of TMCP types surrender 500MPa grades of bridge steel plates and production method Download PDF

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Publication number
CN107326304A
CN107326304A CN201710480911.2A CN201710480911A CN107326304A CN 107326304 A CN107326304 A CN 107326304A CN 201710480911 A CN201710480911 A CN 201710480911A CN 107326304 A CN107326304 A CN 107326304A
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surrender
temperature
rolling
steel plates
steel plate
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Inventor
邓建军
赵文忠
李�杰
龙杰
韦明
张志军
高雅
王晓书
耿宽宽
张海军
张鹏云
徐腾飞
谷盟森
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Wuyang Iron and Steel Co Ltd
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Wuyang Iron and Steel Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/28Normalising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The present invention discloses a kind of TMCP types and surrenders 500MPa grades of bridge steel plates and production method, and steel plate chemical composition composition and weight/mass percentage composition are:C:0.06 0.08%, Si:0.2 0.4%, Mn:1.45 1.55%, P≤0.01%, S≤0.002%, Nb:0.045 0.055%, V:0.035 0.045%, Ni:0.18 0.25%, Cr:0.20 0.25%, Mo:0.15 0.2%, Cu:0.15 0.2%, Alt:0.02~0.04%, surplus is Fe and inevitable impurity;Production method includes heating, rolling, cooling, tempering process.Steel plate yield strength >=500MPa of the present invention, tensile strength all >=630MPa, yield tensile ratio≤0.85,40 DEG C ballistic work >=120J, steel plate maximum gauge can reach 80mm.

Description

A kind of TMCP types surrender 500MPa grades of bridge steel plates and production method
Technical field
The invention belongs to metallurgical technology field, and in particular to a kind of TMCP types surrender 500MPa grades of bridge steel plates and producer Method.
Background technology
At present, it is domestic to lead to bridge, Pingtan bridge in the Shanghai built and the Wufeng Mount bridge project of construction be started, represent The highest level of domestic bridge manufacture, its design side is middle iron bridge innings group.In recent years, the dragon that bridge is manufactured at home In head enterprise under the common promotion of iron Shanhai Pass bridge factory and University On The Mountain Of Swallows, the condition of delivery of bridge steel is energetically to the TMCP easily welded Type transition, this also represent the developing direction of Bridges in Our Country steel.
The GB714-2015 of newest promulgation is by thermo-mechanical rolling(TMCP or TMCP+ tempering)The bridge composition of steel of delivery is independent List, carbon content, carbon equivalent, weld crack Sensitivity Index are limited to lower value, intensity, quality scale arrive for Q345qC Q500qF.All strength grade bridge Impact Toughness of Steel averages are promoted to more than 120J simultaneously, and yield tensile ratio is not higher than into 0.85 As recommendation, good profile is also by as the importance for weighing product quality.Required according to the Bridge Design of latest domestic, 370MPa, 420MPa and 500MPa are surrendered by as the primary intensity rank used.370MPa will turn into main flow, and key position will Using 420MPa grades, part large bridge will use 500MPa grades.
The content of the invention
500MPa grades of bridge steel plates are surrendered the technical problem to be solved in the present invention is to provide a kind of TMCP types;The present invention is also carried A kind of TMCP types have been supplied to surrender the production method of 500MPa grades of bridge steel plates.
In order to solve the above technical problems, the present invention is adopted the technical scheme that:A kind of TMCP types surrender 500MPa grades of bridges Steel plate, the steel plate chemical composition composition and weight/mass percentage composition are:C:0.06-0.08%, Si:0.20-0.40%, Mn:1.45- 1.55%, P≤0.010%, S≤0.002%, Nb:0.045-0.055%, V:0.035-0.045%, Ni:0.18-0.25%, Cr: 0.20-0.25%, Mo:0.15-0.20%, Cu:0.15-0.20%, Alt:0.020~0.040%, surplus is Fe and inevitable Impurity.
Carbon equivalent of the present invention is 0.40~0.46%, and steel plate is organized as ferrite+granular bainite+lath bayesian The complex tissue of body.
Steel plate steel plate maximum gauge of the present invention can reach 70mm.
Steel plate yield strength >=500MPa of the present invention, tensile strength >=630MPa, yield tensile ratio≤0.85, -40 DEG C of punchings Hit work(>=120J.
Present invention also offers the production method that a kind of TMCP types surrender 500MPa grades of bridge steel plates, methods described includes adding Heat, rolling, cooling, tempering process;The rolling process uses recrystallization zone+Unhydrated cement two benches controlled rolling process.
Heating process of the present invention, 1240-1250 DEG C of the maximum heating temperature of steel billet, 1200-1220 DEG C of soaking temperature, Total heat time >=330min, soaking zone time inside furnace >=60min.
Rolling process of the present invention, using recrystallization zone+Unhydrated cement two benches controlled rolling process, the first stage rolls Temperature processed is 1000~1100 DEG C, and single pass rolling reduction is 10~20%, and it is 30~50% to add up reduction ratio.
Rolling process of the present invention, second stage rolling temperature is 850~880 DEG C, and it is 30~50% to add up reduction ratio.
Refrigerating work procedure of the present invention, uses ACC water coolings after rolling, it is 800-820 DEG C to enter coolant-temperature gage, and red temperature 500~ 550℃。
Tempering process of the present invention, 500-550 DEG C of heating-up temperature, soaking time coefficient 1.5min/mm.
The mentality of designing of the present invention and method is as follows:Carbon, manganese solution strengthening;Add appropriate Nb, V, Ni, Cr, Mo, Cu thin Change crystal grain, its carbonitride plays dispersion-strengthened action;By subsequently accurately controlled rolling and controlled cooling and sample hardening and tempering process, make steel plate With good mechanical property.Wherein, the effect of each component and content in the present invention is:
C:Carbon makes a significant impact on the surrender of steel, tensile strength, welding performance, and carbon can significantly improve steel plate by gap solid solution Intensity, but carbon content is too high, and the welding performance and toughness of steel can be influenceed again.
Si:As reducing agent and deoxidier in steelmaking process, while Si can also play solution strengthening effect, but exceed When 0.5%, the toughness of steel can be caused to decline, reduce the welding performance of steel.
Mn:Manganese is with low cost, can increase the toughness, intensity and hardness of steel, improves the quenching degree of steel, improves the hot-working of steel Performance;Manganese amount is too high, center segregation easily occurs for big thickness steel plate.
P、S:In general, p and ses are all harmful elements in steel, increase the fragility of steel;Phosphorus becomes welding performance It is bad, reduce plasticity;Sulphur reduces the ductility and toughness of steel, and crackle is caused in rolling;Therefore reduction p and ses should be tried one's best in steel In content.
Al:Aluminium is to add a small amount of aluminium in the deoxidier commonly used in steel, steel, can crystal grain thinning, improve impact flexibility;Aluminium is also It is too high then to influence hot-working character, welding performance and the machinability of steel with inoxidizability and corrosion resistance.
Nb:In order to promote the crystal grain refinement of steel rolling microscopic structure, intensity and toughness can be improved simultaneously, and niobium can be in controlled rolling By suppressing austenite recrystallization, effective refinement microstructure in journey, and pass through precipitation strength matrix;In welding process, niobium The segregation of atom and precipitation can hinder the roughening of austenite crystal during heating, and ensure to obtain relatively fine hot shadow after welding Ring district's groups to knit, improving welding property.
V:Main function is the alternate precipitation in γ-α transition processes and the precipitation strength in ferrite.
Ni:Main function is to ensure steel plate low-temperature flexibility.
Cr:Quenching degree and solution strengthening can be improved, it is possible to increase intensity and hardness of the steel under condition of heat treatment;But also make Steel plate toughness decreases, and increases temper brittleness, therefore can be required according to obdurability, it is determined that rational Cr contents, according to The obdurability of steel requires that different additions are different.
Mo:Main function improves temper resistance, significantly improves the elevated temperature strength of steel.
Cu:It is the element often added in low-carbon bainite steel, Cu is added in big thick and high-strength degree steel to be significantly improved Because of low-carbon, roll reduction is not enough, roll caused by the low factor of rear cooling rate the thick thick bayesian brought of austenite crystal in steel Body is so that after the tempering of intensity decreases phenomenon, especially steel plate, have stronger precipitation strength effect, in order to prevent copper in cyrystal boundary segregation Cause strand and steel plate to ftracture, typically add a certain amount of nickel.
TMCP types of the present invention surrender 500MPa grades of bridge steel plate product standards and refer to GB/T 714-2015.
It is using the beneficial effect produced by above-mentioned technical proposal:1st, the Design of Chemical Composition of steel plate of the present invention is using low C, it is ensured that the good weldability of steel plate;Designed using Nb, V microalloying, being aided with the alloying elements such as Mo ensures armor plate strength, toughness Matching and resistance to elevated temperatures.2nd, steel plate of the present invention has good cryogenic property, and iron is obtained using controlled rolling and controlled cooling+tempering process skill The complex tissue of ferritic+granular bainite+ferrite bainite.3rd, there is 500MPa grades of Q500qE steel plates of the present invention surrender low-carbon to work as Amount and the features such as crack-sensitivity sex index, low yield strength ratio, low temperature rush good-toughness, weldability is good, Ceq:0.40~0.46%; Steel plate yield strength >=500MPa of the present invention, tensile strength >=630MPa, yield tensile ratio≤0.85, -40 DEG C of ballistic works >= 120J, steel plate maximum gauge can reach 70mm.
Brief description of the drawings
Fig. 1 is the micro-organization chart of the steel plate of embodiment 1;
Fig. 2 is the micro-organization chart of the steel plate of embodiment 2;
Fig. 3 is the micro-organization chart of the steel plate of embodiment 3;
Fig. 4 is the micro-organization chart of the steel plate of embodiment 4;
Fig. 5 is the micro-organization chart of the steel plate of embodiment 5;
Fig. 6 is the micro-organization chart of the steel plate of embodiment 6.
Embodiment
With reference to specific embodiment, the present invention is further detailed explanation.
TMCP types are surrendered 500MPa grades of bridge steel plates and produced using following methods:
(1)Smelting procedure:Molten steel is first through electric furnace smelting, and feeding LF refining furnace refining feeds Al line 4-5m/t steel during refining;Molten steel Temperature reaches that 1530-1550 DEG C is transferred to before VD stove Fruit storages, Fruit storage and adds CaSi blocks >=1.0kg/t steel and change Become inclusion morphology, vacuum≤66.6Pa of Fruit storage, vacuum retention time >=20min;Tap molten steel chemistry into It is grouped into and weight/mass percentage composition is:C:0.06-0.08%, Si:0.20-0.40%, Mn:1.45-1.55%, P≤0.010%, S≤ 0.002%, Nb:0.045-0.055%, V:0.035-0.045%, Ni:0.18-0.25, Cr:0.20-0.25%, Mo:0.15- 0.20%, Cu:0.15-0.20%, Alt:0.020~0.040%, surplus is Fe and inevitable impurity.
(2)Continuous casting working procedure:Become a useful person using 300mm thickness continuous casting billets, steel billet is heated according to 1.1min/mm.
(3)Heating process:1240~1250 DEG C of the maximum heating temperature of steel billet, 1200-1220 DEG C of soaking temperature, total heating Time >=330min, soaking zone time inside furnace >=60min.
(4)Rolling process:Rolled using recrystallization zone+Unhydrated cement two benches controlled rolling process, obtain semi-finished product Steel plate;First stage rolling temperature is 1000~1100 DEG C, and this stage single pass rolling reduction is 10~20%, and accumulative reduction ratio is 30~50%;Second stage rolling temperature is 850~880 DEG C, and it is 30~50% to add up reduction ratio.
(5)Refrigerating work procedure:ACC water coolings are used after rolling, enter 800-820 DEG C of coolant-temperature gage, 500~550 DEG C of red temperature.
(6)Tempering process:500-550 DEG C of heating-up temperature, soaking time coefficient 1.5min/mm.
Embodiment 1
It is 20mm, its chemical composition composition and weight/mass percentage composition that the present embodiment TMCP types, which surrender 500MPa grades of bridge steel plate thickness, It is shown in Table 1.
The present embodiment TMCP types surrender 500MPa grade bridge steel plates production method including smelting, continuous casting, heating, rolling, Cooling, tempering process, concrete technology step are as described below:
(1)Smelting procedure:Molten steel is first through electric furnace smelting, and feeding LF refining furnace refining feeds Al line 5m/t steel during refining;Molten steel temperature Degree reaches that 1540 DEG C are transferred to addition CaSi block 1.2kg/t steel change field trash before VD stove Fruit storages, Fruit storage Form, the vacuum 66.6Pa of Fruit storage, vacuum retention time 20min;Ladle chemistry of tapping is constituted and quality Percentage composition is shown in Table 1.
(2)Continuous casting working procedure:Become a useful person using 300mm thickness continuous casting billets, steel billet is heated according to 1.1min/mm.
(3)Heating process:1250 DEG C of the maximum heating temperature of steel billet, 1220 DEG C of soaking temperature, total heat time 331min, Soaking zone time inside furnace 63min.
(4)Rolling process:Rolled using recrystallization zone+Unhydrated cement two benches controlled rolling process, obtain semi-finished product Steel plate;First stage rolling temperature is 1030 DEG C, and this stage single pass rolling reduction is 20%, and it is 50% to add up reduction ratio;Second-order Section rolling temperature is 850 DEG C, and it is 30% to add up reduction ratio.
(5)Refrigerating work procedure:ACC water coolings are used after rolling, enter 810 DEG C of coolant-temperature gage, 510 DEG C of red temperature.
(6)Tempering process:511 DEG C of heating-up temperature, soaking time coefficient 1.5min/mm.
The mechanical property of bridge steel plate obtained by the present embodiment:Yield strength 535MPa, tensile strength 652MPa, yield tensile ratio 0.82, the average 268J of -40 DEG C of ballistic works;Fig. 1 sees in micro-organization chart, as seen from Figure 1 its be organized as ferrite+granular bainite+ The complex tissue of ferrite bainite.
Embodiment 2
It is 30mm, its chemical composition composition and weight/mass percentage composition that the present embodiment TMCP types, which surrender 500MPa grades of bridge steel plate thickness, It is shown in Table 1.
The present embodiment TMCP types surrender 500MPa grade bridge steel plates production method including smelting, continuous casting, heating, rolling, Cooling, tempering process, concrete technology step are as described below:
(1)Smelting procedure:Molten steel is first through electric furnace smelting, and feeding LF refining furnace refining feeds Al line 4m/t steel during refining;Molten steel temperature Degree reaches that 1535 DEG C are transferred to addition CaSi block 1.0kg/t steel change field trash before VD stove Fruit storages, Fruit storage Form, the vacuum 66.6Pa of Fruit storage, vacuum retention time 22min;Ladle chemistry of tapping is constituted and quality Percentage composition is shown in Table 1.
(2)Continuous casting working procedure:Become a useful person using 300mm thickness continuous casting billets, steel billet is heated according to 1.1min/mm.
(3)Heating process:1242 DEG C of the maximum heating temperature of steel billet, 1205 DEG C of soaking temperature, total heat time 335min, Soaking zone time inside furnace 62min.
(4)Rolling process:Rolled using recrystallization zone+Unhydrated cement two benches controlled rolling process, obtain semi-finished product Steel plate;First stage rolling temperature is 1020 DEG C, and this stage single pass rolling reduction is 12%, and it is 33% to add up reduction ratio;Second-order Section rolling temperature is 860 DEG C, and it is 37% to add up reduction ratio.
(5)Refrigerating work procedure:ACC water coolings are used after rolling, enter 820 DEG C of coolant-temperature gage, 520 DEG C of red temperature.
(6)Tempering process:521 DEG C of heating-up temperature, soaking time coefficient 1.5min/mm.
The mechanical property of bridge steel plate obtained by the present embodiment:Yield strength 545MPa, tensile strength 662MPa, yield tensile ratio 0.82, the average 258J of -40 DEG C of ballistic works;Fig. 2 sees in micro-organization chart, as seen from Figure 2 its be organized as ferrite+granular bainite+ The complex tissue of ferrite bainite.
Embodiment 3
It is 40mm, its chemical composition composition and weight/mass percentage composition that the present embodiment TMCP types, which surrender 500MPa grades of bridge steel plate thickness, It is shown in Table 1.
The present embodiment TMCP types surrender 500MPa grade bridge steel plates production method including smelting, continuous casting, heating, rolling, Cooling, tempering process, concrete technology step are as described below:
(1)Smelting procedure:Molten steel is first through electric furnace smelting, and feeding LF refining furnace refining feeds Al line 4.5m/t steel during refining;Molten steel Temperature reaches that 1532 DEG C are transferred to before VD stove Fruit storages, Fruit storage to add CaSi block 1.1kg/t steel and change and are mingled with Thing form, the vacuum 66.6Pa of Fruit storage, vacuum retention time 25min;Ladle chemistry of tapping is constituted and matter Amount percentage composition is shown in Table 1.
(2)Continuous casting working procedure:Become a useful person using 300mm thickness continuous casting billets, steel billet is heated according to 1.1min/mm.
(3)Heating process:1250 DEG C of the maximum heating temperature of steel billet, 1220 DEG C of soaking temperature, total heat time 338min, Soaking zone time inside furnace 65min.
(4)Rolling process:Rolled using recrystallization zone+Unhydrated cement two benches controlled rolling process, obtain semi-finished product Steel plate;First stage rolling temperature is 1040 DEG C, and this stage single pass rolling reduction is 15%, and it is 40% to add up reduction ratio;Second-order Section rolling temperature is 870 DEG C, and it is 39% to add up reduction ratio.
(5)Refrigerating work procedure:ACC water coolings are used after rolling, enter 805 DEG C of coolant-temperature gage, 530 DEG C of red temperature.
(6)Tempering process:531 DEG C of heating-up temperature, soaking time coefficient 1.5min/mm.
The mechanical property of bridge steel plate obtained by the present embodiment:Yield strength 555MPa, tensile strength 672MPa, yield tensile ratio 0.83, yield tensile ratio 0.83, the average 248J of -40 DEG C of ballistic works;Fig. 3 sees in micro-organization chart, as seen from Figure 3 its be organized as ferrite+ The complex tissue of granular bainite+ferrite bainite.
Embodiment 4
It is 50mm, its chemical composition composition and weight/mass percentage composition that the present embodiment TMCP types, which surrender 500MPa grades of bridge steel plate thickness, It is shown in Table 1.
The present embodiment TMCP types surrender 500MPa grade bridge steel plates production method including smelting, continuous casting, heating, rolling, Cooling, tempering process, concrete technology step are as described below:
(1)Smelting procedure:Molten steel is first through electric furnace smelting, and feeding LF refining furnace refining feeds Al line 4m/t steel during refining;Molten steel temperature Degree reaches that 1545 DEG C are transferred to addition CaSi block 1.2m/t steel change field trash shape before VD stove Fruit storages, Fruit storage State, the vacuum 66.6Pa of Fruit storage, vacuum retention time 30min;Ladle chemistry of tapping is constituted and quality hundred Point content is shown in Table 1.
(2)Continuous casting working procedure:Become a useful person using 300mm thickness continuous casting billets, steel billet is heated according to 1.1min/mm.
(3)Heating process:1246 DEG C of the maximum heating temperature of steel billet, 1212 DEG C of soaking temperature, total heat time 345min, Soaking zone time inside furnace 67min.
(4)Rolling process:Rolled using recrystallization zone+Unhydrated cement two benches controlled rolling process, obtain semi-finished product Steel plate;First stage rolling temperature is 1050 DEG C, and this stage single pass rolling reduction is 17%, and it is 45% to add up reduction ratio;Second-order Section rolling temperature is 865 DEG C, and it is 40% to add up reduction ratio.
(5)Refrigerating work procedure:ACC water coolings are used after rolling, enter 811 DEG C of coolant-temperature gage, 525 DEG C of red temperature.
(6)Tempering process:535 DEG C of heating-up temperature, soaking time coefficient 1.5min/mm.
The mechanical property of bridge steel plate obtained by the present embodiment:Yield strength 515MPa, tensile strength 642MPa, yield tensile ratio 0.80, the average 227J of -40 DEG C of ballistic works;Fig. 4 sees in micro-organization chart, as seen from Figure 4 its be organized as ferrite+granular bainite+ The complex tissue of ferrite bainite.
Embodiment 5
It is 60mm, its chemical composition composition and weight/mass percentage composition that the present embodiment TMCP types, which surrender 500MPa grades of bridge steel plate thickness, It is shown in Table 1.
The present embodiment TMCP types surrender 500MPa grade bridge steel plates production method including smelting, continuous casting, heating, rolling, Cooling, tempering process, concrete technology step are as described below:
(1)Smelting procedure:Molten steel is first through electric furnace smelting, and feeding LF refining furnace refining feeds Al line 4.5m/t steel during refining;Molten steel Temperature reaches that 1530 DEG C are transferred to before VD stove Fruit storages, Fruit storage to add CaSi block 1.1kg/t steel and change and are mingled with Thing form, the vacuum 66.6Pa of Fruit storage, vacuum retention time 20min;Ladle chemistry of tapping is constituted and matter Amount percentage composition is shown in Table 1.
(2)Continuous casting working procedure:Become a useful person using 300mm thickness continuous casting billets, steel billet is heated according to 1.1min/mm.
(3)Heating process:1240 DEG C of the maximum heating temperature of steel billet, 1200 DEG C of soaking temperature, total heat time 330min, Soaking zone time inside furnace 60min.
(4)Rolling process:Rolled using recrystallization zone+Unhydrated cement two benches controlled rolling process, obtain semi-finished product Steel plate;First stage rolling temperature is 1000 DEG C, and this stage single pass rolling reduction is 10%, and it is 30% to add up reduction ratio;Second-order Section rolling temperature is 850 DEG C, and it is 30% to add up reduction ratio.
(5)Refrigerating work procedure:ACC water coolings are used after rolling, enter 800 DEG C of coolant-temperature gage, 500 DEG C of red temperature.
(6)Tempering process:550 DEG C of heating-up temperature, soaking time coefficient 1.5min/mm.
The mechanical property of bridge steel plate obtained by the present embodiment:Yield strength 520MPa, tensile strength 649MPa, yield tensile ratio 0.80, the average 297J of -40 DEG C of ballistic works;Fig. 5 sees in micro-organization chart, as seen from Figure 5 its be organized as ferrite+granular bainite+ The complex tissue of ferrite bainite.
Embodiment 6
It is 80mm, its chemical composition composition and weight/mass percentage composition that the present embodiment TMCP types, which surrender 500MPa grades of bridge steel plate thickness, It is shown in Table 1.
The present embodiment TMCP types surrender 500MPa grade bridge steel plates production method including smelting, continuous casting, heating, rolling, Cooling, tempering process, concrete technology step are as described below:
(1)Smelting procedure:Molten steel is first through electric furnace smelting, and feeding LF refining furnace refining feeds Al line 5m/t steel during refining;Molten steel temperature Degree reaches that 1550 DEG C are transferred to addition CaSi block 1.2m/t steel change field trash shape before VD stove Fruit storages, Fruit storage State, the vacuum 66.6Pa of Fruit storage, vacuum retention time 25min;Ladle chemistry of tapping is constituted and quality hundred Point content is shown in Table 1.
(2)Continuous casting working procedure:Become a useful person using 300mm thickness continuous casting billets, steel billet is heated according to 1.1min/mm.
(3)Heating process:1250 DEG C of the maximum heating temperature of steel billet, 1220 DEG C of soaking temperature, total heat time 350min, Soaking zone time inside furnace 70min.
(4)Rolling process:Rolled using recrystallization zone+Unhydrated cement two benches controlled rolling process, obtain semi-finished product Steel plate;First stage rolling temperature is 1100 DEG C, and this stage single pass rolling reduction is 20%, and it is 50% to add up reduction ratio;Second-order Section rolling temperature is 880 DEG C, and it is 50% to add up reduction ratio.
(5)Refrigerating work procedure:ACC water coolings are used after rolling, enter 820 DEG C of coolant-temperature gage, 550 DEG C of red temperature.
(6)Tempering process:500 DEG C of heating-up temperature, soaking time coefficient 1.5min/mm.
The mechanical property of bridge steel plate obtained by the present embodiment:Yield strength 545MPa, tensile strength 659MPa, yield tensile ratio 0.83, the average 247J of -40 DEG C of ballistic works;Fig. 6 sees in micro-organization chart, as seen from Figure 6 its be organized as ferrite+granular bainite+ The complex tissue of ferrite bainite.
The embodiment 1-6 light plates chemical composition of table 1 is constituted and weight/mass percentage composition(%)
In table 1, the surplus of chemical composition is Fe and inevitable impurity.
From above-described embodiment, this method production 500MPa grades of high-ductility bridge steel plates of surrender have low carbon equivalent, The features such as low yield strength ratio, low temperature rush good-toughness, weldability is good.
Above example is only used to illustrative and not limiting technical scheme, although with reference to above-described embodiment to this hair It is bright to be described in detail, it will be understood by those within the art that:Still the present invention can be modified or be waited With replacement, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should cover the power in the present invention Among sharp claimed range.

Claims (10)

1. a kind of TMCP types surrender 500MPa grades of bridge steel plates, it is characterised in that the steel plate chemical composition composition and quality hundred Point content is:C:0.06-0.08%, Si:0.20-0.40%, Mn:1.45-1.55%, P≤0.010%, S≤0.002%, Nb: 0.045-0.055%, V:0.035-0.045%, Ni:0.18-0.25%, Cr:0.20-0.25%, Mo:0.15-0.20%, Cu: 0.15-0.20%, Alt:0.020~0.040%, surplus is Fe and inevitable impurity.
2. a kind of TMCP types according to claim 1 surrender 500MPa grades of bridge steel plates, it is characterised in that the carbon is worked as Measure as 0.40~0.46%, the complex tissue for being organized as ferrite+granular bainite+ferrite bainite of steel plate.
3. a kind of TMCP types according to claim 1 surrender 500MPa grades of bridge steel plates, it is characterised in that the steel plate Steel plate maximum gauge can reach 70mm.
4. a kind of TMCP types according to claim 1 surrender 500MPa grades of bridge steel plates, it is characterised in that the steel plate Yield strength >=500MPa, tensile strength >=630MPa, yield tensile ratio≤0.85, -40 DEG C of ballistic work >=120J.
5. the production method of 500MPa grades of bridge steel plates is surrendered based on a kind of TMCP types described in claim 1-4 any one, It is characterized in that, methods described includes heating, rolling, cooling, tempering process;The rolling process is using recrystallization zone+not Recrystallization zone two benches controlled rolling process.
6. a kind of TMCP types according to claim 5 surrender the production method of 500MPa grades of bridge steel plates, it is characterised in that The heating process, 1240-1250 DEG C of the maximum heating temperature of steel billet, 1200-1220 DEG C of soaking temperature, total heat time >= 330min, soaking zone time inside furnace >=60min.
7. a kind of TMCP types according to claim 5 surrender the production method of 500MPa grades of bridge steel plates, it is characterised in that The rolling process, using recrystallization zone+Unhydrated cement two benches controlled rolling process, first stage rolling temperature is 1000~ 1100 DEG C, single pass rolling reduction is 10~20%, and it is 30~50% to add up reduction ratio.
8. a kind of TMCP types according to claim 5-7 any one surrender the production method of 500MPa grades of bridge steel plates, Characterized in that, the rolling process, second stage rolling temperature is 850~880 DEG C, it is 30~50% to add up reduction ratio.
9. a kind of TMCP types according to claim 5-7 any one surrender the production method of 500MPa grades of bridge steel plates, Characterized in that, the refrigerating work procedure, uses ACC water coolings after rolling, it is 800-820 DEG C, red temperature 500~550 to enter coolant-temperature gage ℃。
10. a kind of TMCP types according to claim 5-7 any one surrender the production method of 500MPa grades of bridge steel plates, Characterized in that, the tempering process, 500-550 DEG C of heating-up temperature, soaking time coefficient 1.5min/mm.
CN201710480911.2A 2017-06-22 2017-06-22 A kind of TMCP types surrender 500MPa grades of bridge steel plates and production method Pending CN107326304A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109161670A (en) * 2018-08-31 2019-01-08 邯郸钢铁集团有限责任公司 A kind of heat treatment method of TMCP technique Q550D low temperature prompt tempering
CN109518069A (en) * 2018-11-30 2019-03-26 湖南华菱湘潭钢铁有限公司 A kind of production method of low yield strength ratio bridge structure sheet metal
CN109759445A (en) * 2019-01-25 2019-05-17 舞阳钢铁有限责任公司 Control the production method of TMCP shape steel plate performance difference end to end
CN110423938A (en) * 2019-07-24 2019-11-08 舞阳钢铁有限责任公司 TMCP type surrenders 500MPa level structure steel plate and its production method
CN115807192A (en) * 2022-12-12 2023-03-17 湖南华菱湘潭钢铁有限公司 Low-carbon 420 MPa-level TMCP structural steel and production method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127719A (en) * 2011-03-10 2011-07-20 东北大学 Thick steel plate for ocean platform structure with yield strength of 500MPa grade and manufacture method thereof
CN103757560A (en) * 2014-01-15 2014-04-30 扬州龙川钢管有限公司 Large-caliber high-strength seamless steel tube for machinery and TMCP (thermomechanical rolling process) production method thereof
CN104328356A (en) * 2014-09-29 2015-02-04 南京钢铁股份有限公司 Manufacturing method of thin-specification high-strength-structure steel plate with steckel mill
CN104946980A (en) * 2015-06-18 2015-09-30 舞阳钢铁有限责任公司 TMCP and tempering type 550 Mpa-level corrosion resistant bridge steel and production method thereof
CN105112806A (en) * 2015-09-25 2015-12-02 江苏省沙钢钢铁研究院有限公司 High-crack-arrest-toughness steel plate with yield strength of 460MPa and production method thereof
CN105950973A (en) * 2016-05-13 2016-09-21 江阴兴澄特种钢铁有限公司 Thick-specification X80 pipeline steel plate excellent in ultralow-temperature drop hammer performance and manufacturing method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127719A (en) * 2011-03-10 2011-07-20 东北大学 Thick steel plate for ocean platform structure with yield strength of 500MPa grade and manufacture method thereof
CN103757560A (en) * 2014-01-15 2014-04-30 扬州龙川钢管有限公司 Large-caliber high-strength seamless steel tube for machinery and TMCP (thermomechanical rolling process) production method thereof
CN104328356A (en) * 2014-09-29 2015-02-04 南京钢铁股份有限公司 Manufacturing method of thin-specification high-strength-structure steel plate with steckel mill
CN104946980A (en) * 2015-06-18 2015-09-30 舞阳钢铁有限责任公司 TMCP and tempering type 550 Mpa-level corrosion resistant bridge steel and production method thereof
CN105112806A (en) * 2015-09-25 2015-12-02 江苏省沙钢钢铁研究院有限公司 High-crack-arrest-toughness steel plate with yield strength of 460MPa and production method thereof
CN105950973A (en) * 2016-05-13 2016-09-21 江阴兴澄特种钢铁有限公司 Thick-specification X80 pipeline steel plate excellent in ultralow-temperature drop hammer performance and manufacturing method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109161670A (en) * 2018-08-31 2019-01-08 邯郸钢铁集团有限责任公司 A kind of heat treatment method of TMCP technique Q550D low temperature prompt tempering
CN109518069A (en) * 2018-11-30 2019-03-26 湖南华菱湘潭钢铁有限公司 A kind of production method of low yield strength ratio bridge structure sheet metal
CN109759445A (en) * 2019-01-25 2019-05-17 舞阳钢铁有限责任公司 Control the production method of TMCP shape steel plate performance difference end to end
CN110423938A (en) * 2019-07-24 2019-11-08 舞阳钢铁有限责任公司 TMCP type surrenders 500MPa level structure steel plate and its production method
CN115807192A (en) * 2022-12-12 2023-03-17 湖南华菱湘潭钢铁有限公司 Low-carbon 420 MPa-level TMCP structural steel and production method thereof

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