CN109536237A - A kind of synergist and preparation method thereof - Google Patents
A kind of synergist and preparation method thereof Download PDFInfo
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- CN109536237A CN109536237A CN201910014528.7A CN201910014528A CN109536237A CN 109536237 A CN109536237 A CN 109536237A CN 201910014528 A CN201910014528 A CN 201910014528A CN 109536237 A CN109536237 A CN 109536237A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
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- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to chemical petroleum technical fields, in particular a kind of synergist, by following material, proportion is formed based on part: 3 parts~5 parts of alkali of compounding, 15 parts~25 parts of ammonium chloride, 20 parts~30 parts of polyethenoxy ether sulphonate, 5 parts~15 parts of petroleum sulfonate, 2 parts~4 parts of glycerol, 0.01 part~0.03 part of Spirit, 100 parts~200 parts of distilled water, 20 parts~30 parts of villaumite；Being added in the inside of synergist has petroleum sulfonate, it is to reduce oil water interfacial tension that it, which is acted on, preferably improve displacement efficiency, improving water drive swept volume, the residual oil for being detained stratum " washing by force " is come out on the basis of reduction oil and water mobility ratio, to improve oil recovery factor, the present invention is sealed using black plastic bucket, the better tightness of the invention that can be, synergist is avoided to be damaged by direct sunlight, and staff periodically surveys sample, so that the preservation of synergist is safer, it offers convenience to staff, it is further reduced the cost of enterprise's production.
Description
Technical field
The invention belongs to oilfield chemical auxiliary processing technique fields, and in particular to a kind of synergist and preparation method thereof.
Background technique
Gas synergist, i.e. natural gas synergist refer to natural gas applications when industrial enterprise, for the fire for improving natural gas
Flame temperature is to a kind of special chemical composition of addition, and natural gas accelerant is broadly divided into solid-state, liquid, Fen tri- kinds of shapes of Droplets at present
State, natural gas synergist are for natural gas combustion-supporting synergy, and adding principle is passed through using natural gas as main foundation gas source
What intelligent gas agent mixing apparatus and combustion adjuvant were prepared by fully mixing, ignition temperature can be improved in the natural gas after synergy, but substantially
Or natural gas, environmental-protecting performance are the same.
When petroleum operations, because degree of danger is higher, synergist when in use, may if staff is not under lock and key
The synergist inactivation that can be, and petroleum operations, generally in field work, staff's supervision is ineffective, may be such that synergist
The problems such as loss, improves the cost of petroleum operations.
Summary of the invention
For solve petroleum operations mentioned above in the background art when, because degree of danger is higher, synergist when in use, if
Staff is not under lock and key, the synergist inactivation that may be, and petroleum operations is generally in field work, staff
It supervises ineffective, may be such that the problems such as synergist is lost, the problem of improving the cost of petroleum operations.
The invention provides the following technical scheme: a kind of synergist, by following material, proportion is formed based on part: 3 parts of alkali of compounding
~5 parts, 15 parts~25 parts of ammonium chloride, 20 parts~30 parts of polyethenoxy ether sulphonate, 5 parts~15 parts of petroleum sulfonate, 2 parts of glycerol
~4 parts, 0.01 part~0.03 part of Spirit, 100 parts~200 parts of distilled water, 20 parts~30 parts of villaumite.
As a kind of synergist optimal technical scheme of the invention, the Spirit degree of the Spirit is 70 degree or 75 degree
White wine.
As a kind of synergist optimal technical scheme of the invention, the petroleum sulfonate is that petroleum and its fraction are former
Material.
As a kind of synergist optimal technical scheme of the invention, described by following material, proportion is formed based on part: compounding
It 4 parts of alkali, 20 parts of ammonium chloride, 25 parts of polyethenoxy ether sulphonate, 10 parts of petroleum sulfonate, 3 parts of glycerol, 0.02 part of Spirit, steams
150 parts of distilled water, 25 parts of villaumite.
The present invention also provides a kind of preparation methods, comprise the following steps that
S1: weighing above-mentioned material, and 4 parts of compounding alkali, 20 parts and 3 parts of glycerol of ammonium chloride are dissolved in 150 parts of distilled water, forms mixing
Solution A, and mixed solution A is placed into reaction kettle, 0.5 hour~1 hour is stood, then mixed solution A is heated
Stirring 15 minutes~25 minutes, heating temperature is maintained at 60 DEG C~70 DEG C；
S2: being placed into reaction kettle 25 parts of polyethenoxy ether sulphonate, forms mixed solution B, then carries out to mixed solution B
Heating stirring 25 minutes~35 minutes, heating temperature was maintained at 80 DEG C~90 DEG C；
S3: then 10 parts and 25 parts of villaumite of petroleum sulfonate are placed into reaction kettle, mixed solution C is formed, then to mixing
Solution C carries out heating stirring 15 minutes~25 minutes, and heating temperature is maintained at 60 DEG C~70 DEG C, after completing work, so that mixing
Solution C is cooled to 20 DEG C~30 DEG C；
S4: being finally placed into reaction kettle 0.02 part of Spirit, forms mixed solution D, then heats to mixed solution D
Stirring 15 minutes~25 minutes, heating temperature is maintained at 20 DEG C~30 DEG C；
S5: control reactor temperature is maintained at 10 DEG C~20 DEG C and is de-gassed operation 4 minutes~6 minutes, discharge to mixed liquor
Air in mixed liquor；
S6: it is immediately fed into high temperature sterilization device after the mixed liquor D discharge reaction kettle after degassing, is sterilized at 115 DEG C~120 DEG C
10 minutes~15 minutes, and covered in the plastic barrel for being fitted into cleaning sterile under aseptic filling conditions, it seals, obtains synergist；
S7: the synergist after filling and capping is cooled down stage by stage, and cooling procedure makes product final temperature be cooled to 38 DEG C~40 DEG C
, then the synergist after filling and capping is placed under conditions of 15 DEG C~20 DEG C and is stored；
S8: periodically the synergist in sampling check plastic barrel, sampling check period are 15 days~25 days.
As a kind of preparation method optimal technical scheme of the invention, the internal temperature of the high temperature sterilization device is 150 DEG C
~200 DEG C.
As a kind of preparation method optimal technical scheme of the invention, the color of the plastic barrel is black.
Compared with prior art, the beneficial effects of the present invention are: the present invention is added by this recipe ratio in the inside of synergist
There is compounding alkali, its advantage is that price is cheaply more many than caustic soda and soda ash, and cost performance is also much higher, in the inside of synergist
Addition has petroleum sulfonate, and effect is to reduce oil water interfacial tension, preferably raising displacement efficiency, involves body improving water drive
The residual oil for being detained stratum " washing by force " is come out on the basis of product, reduction oil and water mobility ratio, to improve oil recovery factor, this hair
Bright to be sealed using black plastic bucket, the better tightness of the invention that can be avoids synergist from being damaged by direct sunlight, and
And staff periodically surveys sample, so that the preservation of synergist is safer, offers convenience to staff, further
Reduce the cost of enterprise's production.
Detailed description of the invention
Attached drawing is used to provide further understanding of the present invention, and constitutes part of specification, with reality of the invention
It applies example to be used to explain the present invention together, not be construed as limiting the invention.In the accompanying drawings:
Fig. 1 is flow diagram of the invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Embodiment 1
A kind of synergist, by following material, proportion is formed based on part: 3 parts of alkali of compounding, and 15 parts of ammonium chloride, polyethenoxy ether sulphonate
20 parts, 5 parts of petroleum sulfonate, 2 parts of glycerol, 0.01 part of Spirit, 100 parts of distilled water, 20 parts of villaumite.
A kind of preparation method, comprises the following steps that
S1: weighing above-mentioned material, and 3 parts of compounding alkali, 15 parts and 2 parts of glycerol of ammonium chloride are dissolved in 100 parts of distilled water, forms mixing
Solution A, and mixed solution A is placed into reaction kettle, 0.5 hour is stood, heating stirring 15 then is carried out to mixed solution A and is divided
Clock, heating temperature are maintained at 60 DEG C；
S2: being placed into reaction kettle 20 parts of polyethenoxy ether sulphonate, forms mixed solution B, then carries out to mixed solution B
Heating stirring 25 minutes, heating temperature was maintained at 80 DEG C；
S3: being then placed into reaction kettle 5 parts and 20 parts of villaumite of petroleum sulfonate, form mixed solution C, then molten to mixing
Liquid C is carried out heating stirring 15 minutes, and heating temperature is maintained at 60 DEG C, after completing work, so that mixed solution C is cooled to 20 DEG C；
S4: being finally placed into reaction kettle 0.01 part of Spirit, forms mixed solution D, then heats to mixed solution D
Stirring 15 minutes, heating temperature is maintained at 20 DEG C；
S5: control reactor temperature is maintained at 10 DEG C and is de-gassed operation 4 minutes to mixed liquor, and the sky in mixed liquor is discharged
Gas；
S6: being immediately fed into high temperature sterilization device after the mixed liquor D discharge reaction kettle after degassing, sterilize 10 minutes at 115 DEG C,
And covered in the plastic barrel under aseptic filling conditions being fitted into cleaning sterile, it seals, obtains synergist；
S7: the synergist after filling and capping is cooled down stage by stage, and cooling procedure makes product final temperature be cooled to 38 DEG C, so
The synergist after filling and capping is placed under conditions of 15 DEG C afterwards and is stored；
S8: periodically the synergist in sampling check plastic barrel, sampling check period are 15 days.
According in above scheme, in step S6, the internal temperature of the high temperature sterilization device is 150 DEG C.
According in above scheme, in step S6, the color of the plastic barrel is black.
Embodiment 2
A kind of synergist, by following material, proportion is formed based on part: 4 parts of alkali of compounding, and 20 parts of ammonium chloride, polyethenoxy ether sulphonate
25 parts, 10 parts of petroleum sulfonate, 3 parts of glycerol, 0.02 part of Spirit, 150 parts of distilled water, 25 parts of villaumite.
A kind of preparation method, comprises the following steps that
S1: weighing above-mentioned material, and 4 parts of compounding alkali, 20 parts and 3 parts of glycerol of ammonium chloride are dissolved in 150 parts of distilled water, forms mixing
Solution A, and mixed solution A is placed into reaction kettle, 0.8 hour is stood, heating stirring 20 then is carried out to mixed solution A and is divided
Clock, heating temperature are maintained at 65 DEG C；
S2: being placed into reaction kettle 25 parts of polyethenoxy ether sulphonate, forms mixed solution B, then carries out to mixed solution B
Heating stirring 30 minutes, heating temperature was maintained at 85 DEG C；
S3: then 10 parts and 25 parts of villaumite of petroleum sulfonate are placed into reaction kettle, mixed solution C is formed, then to mixing
Solution C carries out heating stirring 20 minutes, and heating temperature is maintained at 65 DEG C, after completing work, so that mixed solution C is cooled to 25
℃；
S4: being finally placed into reaction kettle 0.02 part of Spirit, forms mixed solution D, then heats to mixed solution D
Stirring 20 minutes, heating temperature is maintained at 25 DEG C；
S5: control reactor temperature is maintained at 10 DEG C~20 DEG C and is de-gassed operation 5 minutes to mixed liquor, is discharged in mixed liquor
Air；
S6: being immediately fed into high temperature sterilization device after the mixed liquor D discharge reaction kettle after degassing, sterilize 13 minutes at 118 DEG C,
And covered in the plastic barrel under aseptic filling conditions being fitted into cleaning sterile, it seals, obtains synergist；
S7: the synergist after filling and capping is cooled down stage by stage, and cooling procedure makes product final temperature be cooled to 39 DEG C, so
The synergist after filling and capping is placed under conditions of 18 DEG C afterwards and is stored；
S8: periodically the synergist in sampling check plastic barrel, sampling check period are 20 days.
According in above scheme, in step S6, the internal temperature of the high temperature sterilization device is 175 DEG C.
According in above scheme, in step S6, the color of the plastic barrel is black.
Embodiment 3
A kind of synergist, by following material, proportion is formed based on part: 5 parts of alkali of compounding, and 25 parts of ammonium chloride, polyethenoxy ether sulphonate
30 parts, 15 parts of petroleum sulfonate, 4 parts of glycerol, 0.03 part of Spirit, 200 parts of distilled water, 30 parts of villaumite.
A kind of preparation method, comprises the following steps that
S1: weighing above-mentioned material, and 5 parts of compounding alkali, 25 parts and 4 parts of glycerol of ammonium chloride are dissolved in 200 parts of distilled water, forms mixing
Solution A, and mixed solution A is placed into reaction kettle, 1 hour is stood, heating stirring 25 then is carried out to mixed solution A and is divided
Clock, heating temperature are maintained at 70 DEG C；
S2: being placed into reaction kettle 30 parts of polyethenoxy ether sulphonate, forms mixed solution B, then carries out to mixed solution B
Heating stirring 35 minutes, heating temperature was maintained at 90 DEG C；
S3: then 15 parts and 30 parts of villaumite of petroleum sulfonate are placed into reaction kettle, mixed solution C is formed, then to mixing
Solution C carries out heating stirring 25 minutes, and heating temperature is maintained at 70 DEG C, after completing work, so that mixed solution C is cooled to 30
℃；
S4: being finally placed into reaction kettle 0.03 part of Spirit, forms mixed solution D, then heats to mixed solution D
Stirring 25 minutes, heating temperature is maintained at 30 DEG C；
S5: control reactor temperature is maintained at 20 DEG C and is de-gassed operation 6 minutes to mixed liquor, and the sky in mixed liquor is discharged
Gas；
S6: being immediately fed into high temperature sterilization device after the mixed liquor D discharge reaction kettle after degassing, sterilize 15 minutes at 120 DEG C,
And covered in the plastic barrel under aseptic filling conditions being fitted into cleaning sterile, it seals, obtains synergist；
S7: the synergist after filling and capping is cooled down stage by stage, and cooling procedure makes product final temperature be cooled to 40 DEG C, so
The synergist after filling and capping is placed under conditions of 20 DEG C afterwards and is stored；
S8: periodically the synergist in sampling check plastic barrel, sampling check period are 25 days.
According in above scheme, in step S6, the internal temperature of the high temperature sterilization device is 200 DEG C.
According in above scheme, in step S6, the color of the plastic barrel is black.
In summary: the present invention is by this recipe ratio, and in the inside of synergist added with compounding alkali, its advantage is valence
Lattice are cheaply more many than caustic soda and soda ash, and cost performance is also much higher, and being added in the inside of synergist has petroleum sulfonate, act on
It is to reduce oil water interfacial tension, preferably improves displacement efficiency, on the basis improved water drive swept volume, reduce oil and water mobility ratio
On the residual oil for being detained stratum " washing by force " is come out, to improve oil recovery factor, the present invention, can using the sealing of black plastic bucket
The better tightness of the invention for being, avoids synergist from being damaged by direct sunlight, and staff periodically surveys sample,
So that the preservation of synergist is safer, offer convenience to staff, is further reduced the cost of enterprise's production.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (7)
1. a kind of synergist, which is characterized in that by following material, proportion is formed based on part: 3 parts~5 parts of alkali of compounding, ammonium chloride 15
Part~25 parts, 20 parts~30 parts of polyethenoxy ether sulphonate, 5 parts~15 parts of petroleum sulfonate, 2 parts~4 parts of glycerol, Spirit
0.01 part~0.03 part, 100 parts~200 parts of distilled water, 20 parts~30 parts of villaumite.
2. a kind of synergist according to claim 1, it is characterised in that: the Spirit degree of the Spirit is 70 degree or 75
The white wine of degree.
3. a kind of synergist according to claim 1, it is characterised in that: the petroleum sulfonate is petroleum and its fraction is
Raw material.
4. a kind of synergist according to claim 1, which is characterized in that described by following material, proportion is formed based on part:
4 parts of alkali of compounding, 20 parts of ammonium chloride, 25 parts of polyethenoxy ether sulphonate, 10 parts of petroleum sulfonate, 3 parts of glycerol, Spirit 0.02
Part, 150 parts of distilled water, 25 parts of villaumite.
5. a kind of preparation method according to claim 1, which is characterized in that comprise the following steps that
S1: weighing above-mentioned material, and 4 parts of compounding alkali, 20 parts and 3 parts of glycerol of ammonium chloride are dissolved in 150 parts of distilled water, forms mixing
Solution A, and mixed solution A is placed into reaction kettle, 0.5 hour~1 hour is stood, then mixed solution A is heated
Stirring 15 minutes~25 minutes, heating temperature is maintained at 60 DEG C~70 DEG C；
S2: being placed into reaction kettle 25 parts of polyethenoxy ether sulphonate, forms mixed solution B, then carries out to mixed solution B
Heating stirring 25 minutes~35 minutes, heating temperature was maintained at 80 DEG C~90 DEG C；
S3: then 10 parts and 25 parts of villaumite of petroleum sulfonate are placed into reaction kettle, mixed solution C is formed, then to mixing
Solution C carries out heating stirring 15 minutes~25 minutes, and heating temperature is maintained at 60 DEG C~70 DEG C, after completing work, so that mixing
Solution C is cooled to 20 DEG C~30 DEG C；
S4: being finally placed into reaction kettle 0.02 part of Spirit, forms mixed solution D, then heats to mixed solution D
Stirring 15 minutes~25 minutes, heating temperature is maintained at 20 DEG C~30 DEG C；
S5: control reactor temperature is maintained at 10 DEG C~20 DEG C and is de-gassed operation 4 minutes~6 minutes, discharge to mixed liquor
Air in mixed liquor；
S6: it is immediately fed into high temperature sterilization device after the mixed liquor D discharge reaction kettle after degassing, is sterilized at 115 DEG C~120 DEG C
10 minutes~15 minutes, and covered in the plastic barrel for being fitted into cleaning sterile under aseptic filling conditions, it seals, obtains synergist；
S7: the synergist after filling and capping is cooled down stage by stage, and cooling procedure makes product final temperature be cooled to 38 DEG C~40 DEG C
, then the synergist after filling and capping is placed under conditions of 15 DEG C~20 DEG C and is stored；
S8: periodically the synergist in sampling check plastic barrel, sampling check period are 15 days~25 days.
6. a kind of preparation method according to claim 5, it is characterised in that: the internal temperature of the high temperature sterilization device is
150 DEG C~200 DEG C.
7. a kind of preparation method according to claim 5, it is characterised in that: the color of the plastic barrel is black.
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| CN201910014528.7A CN109536237A (en) | 2019-01-08 | 2019-01-08 | A kind of synergist and preparation method thereof |
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| CN201910014528.7A CN109536237A (en) | 2019-01-08 | 2019-01-08 | A kind of synergist and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1865392A (en) * | 2006-06-15 | 2006-11-22 | 中国石化股份胜利油田分公司地质科学研究院 | Highly effective mixed oil expellant applied to tertiary oil recovery and its preparation method |
| CN104388072A (en) * | 2014-11-21 | 2015-03-04 | 新疆贝肯石油科技开发有限责任公司 | Chemical synergist for SAGD (Steam Assisted Gravity Drainage) super-viscous oil recovery and preparation method thereof |
| CN104946229A (en) * | 2015-05-29 | 2015-09-30 | 中国石油天然气股份有限公司 | Composite synergist for fiber fracturing fluid, and preparation method and use method thereof |
| CN105315981A (en) * | 2014-07-03 | 2016-02-10 | 新疆贝肯石油科技开发有限责任公司 | Heavy oil thermal recovery chemical synergist and preparation method of same |
-
2019
- 2019-01-08 CN CN201910014528.7A patent/CN109536237A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1865392A (en) * | 2006-06-15 | 2006-11-22 | 中国石化股份胜利油田分公司地质科学研究院 | Highly effective mixed oil expellant applied to tertiary oil recovery and its preparation method |
| CN105315981A (en) * | 2014-07-03 | 2016-02-10 | 新疆贝肯石油科技开发有限责任公司 | Heavy oil thermal recovery chemical synergist and preparation method of same |
| CN104388072A (en) * | 2014-11-21 | 2015-03-04 | 新疆贝肯石油科技开发有限责任公司 | Chemical synergist for SAGD (Steam Assisted Gravity Drainage) super-viscous oil recovery and preparation method thereof |
| CN104946229A (en) * | 2015-05-29 | 2015-09-30 | 中国石油天然气股份有限公司 | Composite synergist for fiber fracturing fluid, and preparation method and use method thereof |
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