CN109536017A - A kind of building materials oiliness protection of penetration agent and preparation method thereof - Google Patents
A kind of building materials oiliness protection of penetration agent and preparation method thereof Download PDFInfo
- Publication number
- CN109536017A CN109536017A CN201710710477.2A CN201710710477A CN109536017A CN 109536017 A CN109536017 A CN 109536017A CN 201710710477 A CN201710710477 A CN 201710710477A CN 109536017 A CN109536017 A CN 109536017A
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- China
- Prior art keywords
- parts
- building materials
- silicone oil
- penetration agent
- protection
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of building materials oiliness protection of penetration agent, component including following parts by weight: 75-85 parts of solvent naphtha, 0.5-1.5 parts of silicone oil, vinyl-three (the fluorine-based ethyoxyl of 2- first) 8-12 parts of silane, 2-5 parts of perfluorooctane sulfonate, 0.8-1.2 parts of organic solvent, 0.03-0.07 parts of catalyst.The present invention discloses a kind of preparation method of wall brick oiliness protection of penetration agent again simultaneously, comprising the following steps: the said components measured in the desired amount；Into solvent naphtha, silane is added and stirs 35min；Perfluorooctane sulfonate and silicone oil is added and stirs 20min；Organic solvent and catalyst is added and stirs 10min；It is finally stirred for machine and reverses and stir 15min, then clockwise stirring 15min.The present invention can well with heterogeneity and density, the protective layer that reaction forms the penetration depth with 8 millimeters to 12 millimeters is carried out by the building materials of main matrix of silicate, protection effect and the time that the products such as concrete, common brick, jointing agent, ceramic tile can effectively be enhanced reach long-term weatherability effect.
Description
Technical field
The present invention relates to the technical field of protective agent more particularly to a kind of building materials oiliness protection of penetration agent and its preparation sides
Method.
Background technique
Common brick, ceramic tile, concrete, jointing agent are construction materials common on the market, their common ground is with silicate
For primary raw material, above-mentioned material in use for some time, if maintenance is improper, the effect in terms of waterproof performance, weather resistance
It can have a greatly reduced quality, and building materials protective agent on the market is primarily directed to marble at present, the protective agent of the stone materials such as granite, for
Do not have substantially on the market using silicate as the protective agent of primary raw material.
In view of this, the present inventor's research and devise a kind of building materials oiliness protection of penetration agent and preparation method thereof, this case
Thus it generates.
Summary of the invention
The purpose of the present invention is to provide a kind of building materials oiliness protection of penetration agent and preparation method thereof, production through the invention
Product, so that effectively enhancing the protection effect of silicate building materials forming permeable formation by the building material surface of primary raw material of silicate
With the time, reach long-term weatherability and waterproof action.
To achieve the goals above, the technical scheme adopted by the invention to solve the technical problem is that:
A kind of building materials oiliness protection of penetration agent, the component including following parts by weight: 75-85 parts of solvent naphtha, silicone oil 0.5-1.5
Part, vinyl-three (the fluorine-based ethyoxyl of 2- first) 8-12 parts of silane, 0.8-1.2 parts of organic solvent, is urged at 2-5 parts of perfluorooctane sulfonate
0.03-0.07 parts of agent.
Preferably, the wall brick oiliness protection of penetration agent, the component including following parts by weight: 82.95 parts of solvent naphtha, silicon
1 part of oil, 10.5 parts of silane, 4.5 parts of sulfonic acid, 1 part of organic solvent, 0.05 part of catalyst.
Preferably, the solvent naphtha is one or more of D40 solvent naphtha, ethyl acetate, ethyl alcohol.
Preferably, the silicone oil is one of vinyl silicone oil, containing hydrogen silicone oil, positive methyl-silicone oil, hydroxy silicon oil or several
Kind.
Preferably, the catalyst is tetrabutyl titanate ester.
Preferably, the organic solvent is one or more of methanol, ethyl alcohol.
A kind of preparation method of wall brick oiliness protection of penetration agent, comprising the following steps: measure solvent naphtha, silicon in the desired amount
Oil, vinyl-three (the fluorine-based ethyoxyl of 2- first) silane, perfluorooctane sulfonate, organic solvent, catalyst；Into solvent naphtha, it is added
(the fluorine-based ethyoxyl of the 2- first) silane of vinyl-three simultaneously stirs 35min；Perfluorooctane sulfonate and silicone oil is added and stirs 20min；Add
Enter organic solvent and catalyst and stirs 10min；It is finally stirred for machine and reverses and stir 15min, then clockwise stirring 15min.
Since present invention employs above-mentioned technical solutions, so that having the advantages that
The present invention can well and using silicate as the building materials of primary raw material, for example, common brick, ceramic tile, concrete, jointing agent etc.,
React and can be firmly attached to it is above-mentioned using silicate as on the building materials of primary raw material, the case where not changing building materials color
Under, form the protective layer with 8 millimeters to 12 millimeters of oiliness penetration depth, can effective Water-proof and oil-proof and antifouling, and energy
The effectively protection effect and guard time of the products such as enhancing concrete, common brick, jointing agent, ceramic tile, reaches long-term weatherability effect.
Specific embodiment
Embodiment 1
A kind of building materials oiliness protection of penetration agent, the component including following parts by weight: 75 parts of D40 solvent naphtha, vinyl silicone oil 0.5
Part, vinyl-three (the fluorine-based ethyoxyl of 2- first) 8 parts of silane, 2 parts of perfluorooctane sulfonate, 0.8 part of ethyl alcohol, tetrabutyl titanate ester
0.03 part.
Embodiment 2
A kind of building materials oiliness protection of penetration agent, the component including following parts by weight: 82.95 parts of D40 solvent naphtha, vinyl silicone oil
1 part, vinyl-three (the fluorine-based ethyoxyl of 2- first) 10.5 parts of silane, 4.5 parts of perfluorooctane sulfonate, 1 part of methanol, tetrabutyl titanate
0.05 part of ester.
Embodiment 3
A kind of building materials oiliness protection of penetration agent, the component including following parts by weight: 85 parts of ethyl acetate, 1.5 parts of containing hydrogen silicone oil,
Vinyl-three (the fluorine-based ethyoxyl of 2- first) 12 parts of silane, 5 parts of perfluorooctane sulfonate, 1.2 parts of ethyl alcohol, tetrabutyl titanate ester 0.07
Part.
Embodiment 4
A kind of building materials oiliness protection of penetration agent, the component including following parts by weight: 78 parts of ethyl alcohol, 0.8 part of positive methyl-silicone oil, second
Alkenyl-three (the fluorine-based ethyoxyl of 2- first) 9 parts of silane, 2-5 parts of perfluorooctane sulfonate, 0.8-1.2 parts of methanol, tetrabutyl titanate ester
0.04 part.
Embodiment 5
A kind of building materials oiliness protection of penetration agent, the component including following parts by weight: 85 parts of D40 solvent naphtha, hydroxy silicon oil 1.2
Part, vinyl-three (the fluorine-based ethyoxyl of 2- first) 8-12 parts of silane, 4 parts of perfluorooctane sulfonate, 1.2 parts of methanol, tetrabutyl titanate ester
0.07 part.
Embodiment 6
A kind of preparation method of wall brick oiliness protection of penetration agent, comprising the following steps: according to the respective formula of embodiment 1-5, press
Aequum measures solvent naphtha, silicone oil, vinyl-three (the fluorine-based ethyoxyl of 2- first) silane, perfluorooctane sulfonate, organic solvent, four
Butyltitanate；Into solvent naphtha, (the fluorine-based ethyoxyl of the 2- first) silane of vinyl-three is added and stirs 35min；It is pungent that perfluor is added
Alkyl sulfonic acid and silicone oil simultaneously stir 20min；Organic solvent and tetrabutyl titanate ester is added and stirs 10min；It is inverse to be finally stirred for machine
Turn and stir 15min, then clockwise stirring 15min.The above operation is to carry out under normal temperature and pressure conditions.
Building materials oiliness protection of penetration agent made from embodiment 1-5 is respectively coated on concrete, with JC/T973-2005
" architectural decoration lithotome protective agent " standard detection embodiment 1-5 protective agent performance, discovery embodiment 1-5 protective agent all have
There are good waterproofness, stain resistance, resistance to acid and alkali, ultraviolet-resistant aging and stability, see Table 1 for details.Simultaneously to the present invention
Protective agent has done infiltration comparative test, and comparative example is the antifouling oil-proofing agent SINO-365 of commercially available SICONG concrete, the results are shown in Table
2。
The stone protectant the performance test results table of the invention of table 1
By upper 1 testing result of table it is found that the resulting protective agent of embodiment 1-5 complies fully with building materials rower JC/T 973-2005 " builds
Build decoration lithotome protective agent " in defined performance indexes requirement, and waterproofness and stain resistance belong to
High-class product.
The permeability test result of the depth of penetration of the present invention of table 2 anti-stone protectant and comparative example
As shown in Table 2, the anti-stone protectant permeable formation 8-12mm of depth of penetration of the invention, hence it is evident that produced better than commercially available same type
Product, wherein with the permeance property effect of embodiment 2 be best.
The drying that the present invention changes traditional wall brick protective agent is slow, and reaction is slow, and persistence is poor, working procedure complexity and cost
High organoleptic properties, instead of commonly using polyurethane as the protective agent of main material.Client uses more convenient, total project cost
More save.Product is fallen to 1-2 times using rear refresh rate from 10 years 5 to 6 times.Certainly, oiliness protection of penetration agent of the present invention is not only
It limits the use of in concrete, all there is identical or phase by the building materials of primary raw material such as common brick, ceramic tile, jointing agent of silicate to different
As effect.
The above is only the preferred embodiment of the present invention, therefore cannot successively limit the scope of implementation of the present invention, i.e., according to
Equivalent changes and modifications made by the invention patent range and description, should still be within the scope of the present invention.
Claims (7)
1. a kind of building materials oiliness protection of penetration agent, it is characterised in that: the component including following parts by weight: 75-85 parts of solvent naphtha,
0.5-1.5 parts of silicone oil, vinyl-three (the fluorine-based ethyoxyl of 2- first) 8-12 parts of silane, 2-5 parts of perfluorooctane sulfonate, organic solvent
0.8-1.2 parts, 0.03-0.07 parts of catalyst.
2. a kind of building materials oiliness protection of penetration agent as described in claim 1, it is characterised in that: the wall brick oiliness protection of penetration
Agent, the component including following parts by weight: 82.95 parts of solvent naphtha, 1 part of silicone oil, 10.5 parts of silane, 4.5 parts of sulfonic acid, organic solvent
1 part, 0.05 part of catalyst.
3. a kind of building materials oiliness protection of penetration agent as described in claim 1, it is characterised in that: the solvent naphtha is D40 solvent
One or more of oil, ethyl acetate, ethyl alcohol.
4. a kind of building materials oiliness protection of penetration agent as described in claim 1, it is characterised in that: the silicone oil is vinyl silicon
One or more of oil, containing hydrogen silicone oil, positive methyl-silicone oil, hydroxy silicon oil.
5. a kind of building materials oiliness protection of penetration agent as described in claim 1, it is characterised in that: the catalyst is tetrabutyl titanium
Acid esters.
6. a kind of building materials oiliness protection of penetration agent as described in claim 1, it is characterised in that: the organic solvent be methanol,
One or more of ethyl alcohol.
7. a kind of preparation method of wall brick oiliness protection of penetration agent, it is characterised in that: the following steps are included: measuring in the desired amount molten
Agent oil, silicone oil, vinyl-three (the fluorine-based ethyoxyl of 2- first) silane, perfluorooctane sulfonate, organic solvent, catalyst；To solvent naphtha
In, (the fluorine-based ethyoxyl of the 2- first) silane of vinyl-three is added and stirs 35min；Perfluorooctane sulfonate and silicone oil is added and stirs
20min；Organic solvent and catalyst is added and stirs 10min；It is finally stirred for machine and reverses and stir 15min, then clockwise stirring
15min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710710477.2A CN109536017A (en) | 2017-08-18 | 2017-08-18 | A kind of building materials oiliness protection of penetration agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710710477.2A CN109536017A (en) | 2017-08-18 | 2017-08-18 | A kind of building materials oiliness protection of penetration agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109536017A true CN109536017A (en) | 2019-03-29 |
Family
ID=65827158
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710710477.2A Pending CN109536017A (en) | 2017-08-18 | 2017-08-18 | A kind of building materials oiliness protection of penetration agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109536017A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116063923A (en) * | 2022-01-28 | 2023-05-05 | 浙江丽境环保科技工程有限公司 | Engine coating liquid and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1506426A (en) * | 2002-12-12 | 2004-06-23 | 曾繁杰 | Prepn of stone material surface protecting agent |
| CN104312396A (en) * | 2014-10-10 | 2015-01-28 | 东莞市长安东阳光铝业研发有限公司 | Penetration type nano stone protecting agent and preparation method thereof |
-
2017
- 2017-08-18 CN CN201710710477.2A patent/CN109536017A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1506426A (en) * | 2002-12-12 | 2004-06-23 | 曾繁杰 | Prepn of stone material surface protecting agent |
| CN104312396A (en) * | 2014-10-10 | 2015-01-28 | 东莞市长安东阳光铝业研发有限公司 | Penetration type nano stone protecting agent and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 聂无逸等: "《产业结构调整指导目录》", 31 August 2011, 中国经济出版社 * |
| 马贺伟等: "《皮革与纺织品环保指标及检测》", 31 July 2017, 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116063923A (en) * | 2022-01-28 | 2023-05-05 | 浙江丽境环保科技工程有限公司 | Engine coating liquid and application |
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Application publication date: 20190329 |
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