CN109535599A - A kind of PVC stone plastic floor and preparation method thereof - Google Patents
A kind of PVC stone plastic floor and preparation method thereof Download PDFInfo
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- CN109535599A CN109535599A CN201811443383.4A CN201811443383A CN109535599A CN 109535599 A CN109535599 A CN 109535599A CN 201811443383 A CN201811443383 A CN 201811443383A CN 109535599 A CN109535599 A CN 109535599A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/105—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials of organic plastics with or without reinforcements or filling materials
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/107—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/18—Separately-laid insulating layers; Other additional insulating measures; Floating floors
- E04F15/181—Insulating layers integrally formed with the flooring or the flooring elements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/18—Separately-laid insulating layers; Other additional insulating measures; Floating floors
- E04F15/20—Separately-laid insulating layers; Other additional insulating measures; Floating floors for sound insulation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Civil Engineering (AREA)
- Structural Engineering (AREA)
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Floor Finish (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of PVC stone plastic floors and preparation method thereof, it is related to the manufacturing field of stone plastic floor, raw material composition including following parts by weight: 200~300 parts of PVC resin powder, 400~800 parts of calcareous filler, 20~40 parts of glass fibre, 1~2 part of activator, 3~7 parts of thickener, 5~10 parts of dispersing agent, 10~15 parts of stabilizer, 5~15 parts of regulator of plasticising, 5~10 parts of defoaming agent, the present invention passes through the proportion between specific raw material components, not only significantly improve the mechanical performance of PVC stone plastic floor, also improve its weather resistance, enhance the ability resistant to chemical etching on PVC stone plastic floor surface, avoid the deformation of PVC stone plastic floor in process, the PVC stone plastic floor being prepared excellent waterproof performance and sound insulation Effect, more traditional stone plastic floor, which is compared, has the characteristics that high tenacity, high intensity, more low weight, and technique is with short production cycle, at low cost, the production suitable for PVC stone plastic floor.
Description
Technical field
The present invention relates to the manufacturing fields of stone plastic floor, and in particular to a kind of PVC stone plastic floor and preparation method thereof.
Background technique
Plastics are more and more extensive with the development of science and technology is used in daily life, arrives space shuttle greatly
The small tableware to people is all using plastic products, is even more extensive use in building material industry plastic product.PVC stone plastic floor
Application places such as indoor family, hospital, school, office building, factory, public place, supermarket, business, the various fields of stadiums
Institute.It is the floor of main material gradually by the favor of consumer using PVC plastic.PVC stone plastic floor is a kind of high-quality, high-tech
The new terrestrial ornament materials that skill researchs and develops out constitutes high density, high microsteping reticular structure using natural marble powder
Solid base, surface is process coated with the macromolecule PVC wearing layer of superpower wear-resistant through procedures up to a hundred, and PVC stone modeling ground
Plate, because intensity is not easily-deformable enough, seriously affects the quality of PVC stone plastic floor, PVC stone plastic floor is in mechanical property in process
On requirement be not only not being met, weatherability, waterproof performance etc. be influence its service life an important factor for.Application number
A kind of stone plastic floor and preparation method thereof is disclosed for the patent of invention of CN201710917609.9, which includes under
The supreme stone molding base layer set gradually, color film layer and wearing layer, the stone molding base layer, color film layer and wearing layer are using embossing
Roll pressing molding, the stone plastic floor avoid the use of glue, energy conservation and environmental protection, expansion rate and shrinking percentage using one-shot forming technique
All smaller, performance is more stable, and high temperature resistant, the service life is longer, but stone plastic floor mechanical property made from the invention is lower,
Weather resistance is relatively low, and stone plastic floor is easily-deformable in process, influences the quality of stone plastic floor.For this purpose, the present invention proposes
A kind of PVC stone plastic floor and preparation method thereof, to solve problems of the prior art and deficiency.
Summary of the invention
In view of the above problems, the invention proposes a kind of PVC stone plastic floors and preparation method thereof.
In order to achieve the above purpose, the following technical solution is employed by the present invention:
A kind of PVC stone plastic floor, the raw material composition including following parts by weight: 200~300 parts of PVC resin powder, calcareous filling
400~800 parts of agent, 20~40 parts of glass fibre, 1~2 part of activator, 3~7 parts of thickener, 5~10 parts of dispersing agent, stabilizer
10~15 parts, plasticising 5~15 parts of regulator, 5~10 parts of defoaming agent.
Preferably, the raw material composition including following parts by weight: 220~280 parts of PVC resin powder, calcareous filler 500~
700 parts, 25~35 parts of glass fibre, 1.2~1.8 parts of activator, 4~6 parts of thickener, 6~8 parts of dispersing agent, stabilizer 11~
14 parts, plasticising 8~12 parts of regulator, 6~8 parts of defoaming agent.
Preferably, the raw material composition including following parts by weight: 250 parts of PVC resin powder, 600 parts of calcareous filler, glass fibers
30 parts of dimension, 1.5 parts of activator, 5 parts of thickener, 7 parts of dispersing agent, 12 parts of stabilizer, plasticising 10 parts of regulator, 7 parts of defoaming agent.
Preferably, the calcareous filler is active powdered whiting;The activator be phosphoric acid propane diamine, dimethylbenzene,
One of prodan;The thickener is methylcellulose, sodium acrylate, hydroxymethyl cellulose, crosslinked polyethylene pyrroles
One of alkanone.
Preferably, the dispersing agent is alkyl phenol polyoxyethylene ether or naphthalene sulfonic acid-formaldehyde condensation product sodium salt;The stabilizer
For organic tin stabilizer.
Preferably, the plasticising regulator is adipic acid;The defoaming agent is silicone compound.
The preparation method of above-mentioned PVC stone plastic floor includes following preparation step:
(1) PVC resin powder, calcareous filler, glass fibre, activator are mixed in investment stirred autoclave, in revolving speed
It is 1~2h of stirring at 100~180 DEG C for 1000~1200r/min, temperature, after stirring, then by thickener, dispersing agent, steady
Determine agent, plasticising regulator, defoaming agent are put into stirred autoclave together, adjustment revolving speed is 400~500r/min, temperature be 90~
70~85min is stirred at 120 DEG C, after to be mixed, is cooled to 50~60 DEG C, is kept the temperature 30~60min;
(2) extruder is added in the raw material after heat preservation, raw material is uniformly heating to 180~220 DEG C and is squeezed out, control squeezes out
The barrel temperature of machine controls mold temperature at 190~225 DEG C at 185~220 DEG C, it is ensured that and engine speed is 20~45r/min,
Feeding revolving speed is 20~45r/min;
(3) size for the raw material after extrusion being carried out calendering formation, drawing, being cut into needs, after being air-cooled to room temperature, then leads to
Cutting, overlay film, fluting are crossed, PVC stone plastic floor finished product is obtained.
Due to using above-mentioned technical solution, the beneficial effects of the present invention are:
(1) present invention not only significantly improves the machinery of PVC stone plastic floor by the proportion between specific raw material components
Performance also improves its weather resistance, enhances the ability resistant to chemical etching on PVC stone plastic floor surface, avoids PVC stone modeling ground
The case where plate deforms in process;
(2) the PVC stone plastic floor that the present invention is prepared has excellent waterproof performance and soundproof effect, more traditional stone
Modeling floor, which is compared, has the characteristics that high tenacity, high intensity, more low weight;
(3) preparation process of the invention easily grasps, and the requirement to production equipment is low, and energy consumption is few in production process, nothing
Any production by-product and pollutant generate, and to human and environment without any harm, technique is with short production cycle, at low cost, are applicable in
In the production of PVC stone plastic floor.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the invention is clearly and completely described.Based on the embodiment of the present invention, the common skill in this field
Art personnel every other embodiment obtained without creative efforts belongs to the model that the present invention protects
It encloses.
Embodiment 1:
A kind of PVC stone plastic floor, the raw material composition including following parts by weight: 200 parts of PVC resin powder, calcareous filler 700
Part, 30 parts of glass fibre, 1.2 parts of phosphoric acid propane diamine, 5 parts of methylcellulose, 10 parts of alkyl phenol polyoxyethylene ether, Organotin Stabilized
12 parts of agent, 12 parts of adipic acid, 7 parts of silicone compound.
The preparation method of above-mentioned PVC stone plastic floor includes following preparation step:
(1) PVC resin powder, calcareous filler, glass fibre, phosphoric acid propane diamine are mixed in investment stirred autoclave,
Revolving speed is 1200r/min, temperature is that 2h is stirred at 180 DEG C, after stirring, then by methylcellulose, alkylphenol-polyethenoxy
Ether, organic tin stabilizer, adipic acid, silicone compound are put into stirred autoclave together, and adjustment revolving speed is 500r/min, temperature
Degree is to stir 85min at 120 DEG C, after to be mixed, is cooled to 60 DEG C, keeps the temperature 60min;
(2) extruder is added in the raw material after heat preservation, raw material is uniformly heating to 220 DEG C and is squeezed out, extruder is controlled
Barrel temperature controls mold temperature at 225 DEG C at 220 DEG C, it is ensured that engine speed 45r/min, feeding revolving speed are 45r/min;
(3) size for the raw material after extrusion being carried out calendering formation, drawing, being cut into needs, after being air-cooled to room temperature, then leads to
Cutting, overlay film, fluting are crossed, PVC stone plastic floor finished product is obtained.
Embodiment 2:
A kind of PVC stone plastic floor, the raw material composition including following parts by weight: 250 parts of PVC resin powder, calcareous filler 400
Part, 25 parts of glass fibre, 1 part of dimethylbenzene, 7 parts of sodium acrylate, 6 parts of naphthalene sulfonic acid-formaldehyde condensation product sodium salt, organic tin stabilizer 11
Part, 15 parts of adipic acid, 6 parts of silicone compound.
The preparation method of above-mentioned PVC stone plastic floor includes following preparation step:
(1) PVC resin powder, calcareous filler, glass fibre, dimethylbenzene are mixed in investment stirred autoclave, in revolving speed
Be to stir 2h at 140 DEG C for 1100r/min, temperature, after stirring, then by sodium acrylate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt,
Organic tin stabilizer, adipic acid, silicone compound are put into stirred autoclave together, and adjustment revolving speed is 450r/min, temperature
It is to stir 80min at 110 DEG C, after to be mixed, is cooled to 55 DEG C, keeps the temperature 45min;
(2) extruder is added in the raw material after heat preservation, raw material is uniformly heating to 200 DEG C and is squeezed out, extruder is controlled
Barrel temperature controls mold temperature at 210 DEG C at 205 DEG C, it is ensured that engine speed 30r/min, feeding revolving speed are 30r/min;
(3) size for the raw material after extrusion being carried out calendering formation, drawing, being cut into needs, after being air-cooled to room temperature, then leads to
Cutting, overlay film, fluting are crossed, PVC stone plastic floor finished product is obtained.
Embodiment 3:
A kind of PVC stone plastic floor, the raw material composition including following parts by weight: 300 parts of PVC resin powder, calcareous filler 500
Part, 20 parts of glass fibre, 1.8 parts of prodan, 6 parts of hydroxymethyl cellulose, 5 parts of alkyl phenol polyoxyethylene ether, Organotin Stabilized
15 parts of agent, 5 parts of adipic acid, 8 parts of silicone compound.
The preparation method of above-mentioned PVC stone plastic floor includes following preparation step:
(1) PVC resin powder, calcareous filler, glass fibre, prodan are mixed in investment stirred autoclave, is being turned
Speed is 1000r/min, temperature is that 1h is stirred at 100 DEG C, after stirring, then by hydroxymethyl cellulose, alkylphenol-polyethenoxy
Ether, organic tin stabilizer, adipic acid, silicone compound are put into stirred autoclave together, and adjustment revolving speed is 400r/min, temperature
Degree is to stir 70min at 90 DEG C, after to be mixed, is cooled to 50 DEG C, keeps the temperature 30min;
(2) extruder is added in the raw material after heat preservation, raw material is uniformly heating to 1800 DEG C and is squeezed out, extruder is controlled
Barrel temperature controls mold temperature at 190 DEG C at 1850 DEG C, it is ensured that engine speed 20r/min, feeding revolving speed are 20r/min;
(3) size for the raw material after extrusion being carried out calendering formation, drawing, being cut into needs, after being air-cooled to room temperature, then leads to
Cutting, overlay film, fluting are crossed, PVC stone plastic floor finished product is obtained.
Embodiment 4:
A kind of PVC stone plastic floor, the raw material composition including following parts by weight: 220 parts of PVC resin powder, calcareous filler 800
Part, 35 parts of glass fibre, 2 parts of dimethylbenzene, 4 parts of crosslinked polyvinylpyrrolidone, 8 parts of alkyl phenol polyoxyethylene ether, organotin are steady
Determine 10 parts of agent, 8 parts of adipic acid, 10 parts of silicone compound.
The preparation method of above-mentioned PVC stone plastic floor includes following preparation step:
(1) PVC resin powder, calcareous filler, glass fibre, dimethylbenzene are mixed in investment stirred autoclave, in revolving speed
It is to stir 1h at 120 DEG C for 1100r/min, temperature, after stirring, then by crosslinked polyvinylpyrrolidone, alkyl phenol polyoxy
Vinethene, organic tin stabilizer, adipic acid, silicone compound are put into stirred autoclave together, and adjustment revolving speed is 450r/
Min, temperature are to stir 75min at 100 DEG C, after to be mixed, are cooled to 55 DEG C, keep the temperature 40min;
(2) extruder is added in the raw material after heat preservation, raw material is uniformly heating to 190 DEG C and is squeezed out, extruder is controlled
Barrel temperature controls mold temperature at 200 DEG C at 195 DEG C, it is ensured that engine speed 30r/min, feeding revolving speed are 30r/min;
(3) size for the raw material after extrusion being carried out calendering formation, drawing, being cut into needs, after being air-cooled to room temperature, then leads to
Cutting, overlay film, fluting are crossed, PVC stone plastic floor finished product is obtained.
Embodiment 5:
A kind of PVC stone plastic floor, the raw material composition including following parts by weight: 280 parts of PVC resin powder, calcareous filler 600
Part, 40 parts of glass fibre, 1.5 parts of phosphoric acid propane diamine, 3 parts of methylcellulose, 7 parts of naphthalene sulfonic acid-formaldehyde condensation product sodium salt, organotin
14 parts of stabilizer, 10 parts of adipic acid, 5 parts of silicone compound.
The preparation method of above-mentioned PVC stone plastic floor includes following preparation step:
(1) PVC resin powder, calcareous filler, glass fibre, phosphoric acid propane diamine are mixed in investment stirred autoclave,
Revolving speed is 1200r/min, temperature is that 1h is stirred at 160 DEG C, after stirring, then by methylcellulose, naphthalenesulfonateformaldehyde formaldehyde be condensed
Object sodium salt, organic tin stabilizer, adipic acid, silicone compound are put into stirred autoclave together, and adjustment revolving speed is 500r/
Min, temperature are to stir 80min at 90~120 DEG C, after to be mixed, are cooled to 60 DEG C, keep the temperature 50min;
(2) extruder is added in the raw material after heat preservation, raw material is uniformly heating to 210 DEG C and is squeezed out, extruder is controlled
Barrel temperature controls mold temperature at 220 DEG C at 215 DEG C, it is ensured that engine speed 40r/min, feeding revolving speed are 40r/min;
(3) size for the raw material after extrusion being carried out calendering formation, drawing, being cut into needs, after being air-cooled to room temperature, then leads to
Cutting, overlay film, fluting are crossed, PVC stone plastic floor finished product is obtained.
Following table is the method for preparing PVC stone plastic floor and commercially available common stone plastic floor using Examples 1 to 5 in performance
On detection data analytical table, as shown in table 1.
Table 1
In summary, the preparation method of PVC stone plastic floor of the present invention, significantly improve stone plastic floor mechanical property and
Weather resistance effectively raises the performance of the anti-machining deformation of PVC stone plastic floor.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments
Invention is explained in detail, those skilled in the art should understand that: it still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features;And these modification or
Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.
Claims (7)
1. a kind of PVC stone plastic floor, which is characterized in that the raw material composition including following parts by weight: PVC resin powder 200~300
Part, 400~800 parts of calcareous filler, 20~40 parts of glass fibre, 1~2 part of activator, 3~7 parts of thickener, dispersing agent 5~
10 parts, 10~15 parts of stabilizer, plasticising 5~15 parts of regulator, 5~10 parts of defoaming agent.
2. PVC stone plastic floor according to claim 1, which is characterized in that the raw material composition including following parts by weight: PVC
220~280 parts of resin-oatmeal, 500~700 parts of calcareous filler, 25~35 parts of glass fibre, 1.2~1.8 parts of activator, thickening
4~6 parts of agent, 6~8 parts of dispersing agent, 11~14 parts of stabilizer, plasticising 8~12 parts of regulator, 6~8 parts of defoaming agent.
3. PVC stone plastic floor according to claim 2, which is characterized in that the raw material composition including following parts by weight: PVC
250 parts of resin-oatmeal, 30 parts of glass fibre, 1.5 parts of activator, 5 parts of thickener, 7 parts of dispersing agent, is stablized 600 parts of calcareous filler
12 parts of agent, plasticising 10 parts of regulator, 7 parts of defoaming agent.
4. PVC stone plastic floor according to claim 1, which is characterized in that the calcareous filler is active heavy carbonic acid
Calcium;The activator is one of phosphoric acid propane diamine, dimethylbenzene, prodan;The thickener is methylcellulose, propylene
One of sour sodium, hydroxymethyl cellulose, crosslinked polyvinylpyrrolidone.
5. PVC stone plastic floor according to claim 1, which is characterized in that the dispersing agent is alkyl phenol polyoxyethylene ether
Or naphthalene sulfonic acid-formaldehyde condensation product sodium salt;The stabilizer is organic tin stabilizer.
6. PVC stone plastic floor according to claim 1, which is characterized in that the plasticising regulator is adipic acid;It is described to disappear
Infusion is silicone compound.
7. the preparation method of any PVC stone plastic floor according to claim 1~6, which is characterized in that including following preparation
Step:
(1) PVC resin powder, calcareous filler, glass fibre, activator are mixed in investment stirred autoclave, is in revolving speed
1000~1200r/min, temperature are that 1~2h is stirred at 100~180 DEG C, after stirring, then by thickener, dispersing agent, stabilization
Agent, plasticising regulator, defoaming agent are put into stirred autoclave together, adjustment revolving speed is 400~500r/min, temperature be 90~
70~85min is stirred at 120 DEG C, after to be mixed, is cooled to 50~60 DEG C, is kept the temperature 30~60min;
(2) extruder is added in the raw material after heat preservation, raw material is uniformly heating to 180~220 DEG C and is squeezed out, extruder is controlled
Barrel temperature controls mold temperature at 190~225 DEG C at 185~220 DEG C, it is ensured that engine speed is 20~45r/min, feeding
Revolving speed is 20~45r/min;
(3) size for the raw material after extrusion being carried out calendering formation, drawing, being cut into needs, after being air-cooled to room temperature, then passes through sanction
It cuts, overlay film, fluting, obtains PVC stone plastic floor finished product.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111792876A (en) * | 2020-07-24 | 2020-10-20 | 山东旭龙新材料有限公司 | SPC stone plastic floor material and floor thereof |
CN112812466A (en) * | 2020-12-31 | 2021-05-18 | 欧迪嘉建材江苏有限公司 | Preparation method of oil-stain-resistant stone-plastic floor |
CN112848423A (en) * | 2020-12-31 | 2021-05-28 | 欧迪嘉建材江苏有限公司 | Production process of stone-plastic floor |
CN113603980A (en) * | 2021-08-03 | 2021-11-05 | 无锡市博大竹木业有限公司 | Preparation process of environment-friendly renewable SPC floor |
CN116239846A (en) * | 2022-12-30 | 2023-06-09 | 浙江晶通新材料集团有限公司 | PVC floor with high strength, low expansion and deformation resistance and production process thereof |
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CN106280132A (en) * | 2016-08-31 | 2017-01-04 | 山东霞光实业有限公司 | A kind of environmental protection stone plastic floor and preparation method thereof |
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JPS6337150A (en) * | 1986-07-31 | 1988-02-17 | Shin Etsu Polymer Co Ltd | Vinyl chloride resin composition for flooring material |
CN105133818A (en) * | 2015-09-25 | 2015-12-09 | 江苏贝尔装饰材料有限公司 | High-strength PVC sheet floor and manufacturing method thereof |
CN106280132A (en) * | 2016-08-31 | 2017-01-04 | 山东霞光实业有限公司 | A kind of environmental protection stone plastic floor and preparation method thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111792876A (en) * | 2020-07-24 | 2020-10-20 | 山东旭龙新材料有限公司 | SPC stone plastic floor material and floor thereof |
CN112812466A (en) * | 2020-12-31 | 2021-05-18 | 欧迪嘉建材江苏有限公司 | Preparation method of oil-stain-resistant stone-plastic floor |
CN112848423A (en) * | 2020-12-31 | 2021-05-28 | 欧迪嘉建材江苏有限公司 | Production process of stone-plastic floor |
CN113603980A (en) * | 2021-08-03 | 2021-11-05 | 无锡市博大竹木业有限公司 | Preparation process of environment-friendly renewable SPC floor |
CN113603980B (en) * | 2021-08-03 | 2022-08-05 | 无锡市博大竹木业有限公司 | Preparation process of environment-friendly renewable SPC floor |
CN116239846A (en) * | 2022-12-30 | 2023-06-09 | 浙江晶通新材料集团有限公司 | PVC floor with high strength, low expansion and deformation resistance and production process thereof |
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Application publication date: 20190329 |