CN109535458A - A kind of anionic film and preparation method thereof - Google Patents
A kind of anionic film and preparation method thereof Download PDFInfo
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- CN109535458A CN109535458A CN201710673192.6A CN201710673192A CN109535458A CN 109535458 A CN109535458 A CN 109535458A CN 201710673192 A CN201710673192 A CN 201710673192A CN 109535458 A CN109535458 A CN 109535458A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/54—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms
- B01D46/543—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms using membranes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
- C08J2475/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The present invention relates to a kind of anionic films and preparation method thereof, the anionic film is mainly used on the air intake source of air conditioning for automobiles, domestic air conditioning and some ventilation equipment and in household effects, driver's cabin, room and some closed places is set to obtain the fresh air containing anion in a steady stream, it makes one to keep the good state of mind when driving and usually living or work, there is the good state of mind just and can be reduced the generation of driving accident, it improves the quality of living, improves study and work efficiency.
Description
Technical field
The present invention relates to composite membranes to produce and process field, is specifically related to a kind of anionic film and preparation method thereof.
Background technique
It is well known that the quality of air quality is related to the health and the state of mind of people.
First
(1) direct effect of the anion to health
1, make cell activity: by promoting potassium, sodium ion exchange inside and outside film to cell membrane, keeping cell activity；
2, it purifies blood: its metabolism being promoted by the activation of cell, waste and poisonous and harmful substance are discharged in time
In vitro；
3, it recovers from fatigue: eliminating the pathogenic factor for causing fatigue, quickly regain one's strength；
4, stablize automatic nervous system: influencing automatic nervous system and obtain the stress function, adjust neuro vegetative function；
5, enhance disease resistance: set the mind at rest, increase the content of the third shape globulin in blood, improvement leucocyte quantity and
Quality, the function of enhancing leukocytes phagocytic bacterium；
6, inhibit growth of tumour cell: influence blood in charged particle component and and distribution, to make the work of cell body
Property enhancing；
7, it absorbs and shields electromagenetic wave radiation；
8, improve allergic constitution: adjustment automatic nervous system balance enhances the resistance to allergen；
(2) physiological effect of the anion to body system
Through modern medicine study, negative aeroion has different degrees of physiological effect to each system of human body.Simultaneously to having
Relationship unites relevant disease with adjuvant treatment and rehabilitative action.
1, central nervous system: improving cerebral cortex function, improves mental activity efficiency, improves sleep；
2, automatic nervous system: can influence the stress function of automatic nervous system, adjust vegetative dystonia；
3, respiratory system: promoting expectoration, and unimpeded respiratory tract improves ventilation and the ventilatory of lung；
4, cardiovascular system: having decompression, reducing heart rate, improves the function of myocardial nutrition situation；
5, blood hemopoietic system: can slow down erythrosedimentation rate, extend the clotting time, make around red blood cell, white blood cell
Quantity increases；
6, immune system: can enliven reticuloendothelial system function, and gamma globulin content increases in blood, to improve flesh
The immunity of body；
7, other: as promoted gastric secretion, raising appetite, the effects of boosting metabolism, inhibit bacterium；
It can be seen that anion is connected closely with the health of each system, that is, human body of human body, it is rich in so making great efforts creation one
The environment of anion, it will apparent facilitation is generated to human health.
And currently, under air conditioning for automobiles, domestic air conditioning and some opposing seal environment, due to not good air filtration
Technology, make one it is empty in such a case easily feel sleepy, lassitude be even easy hair produce health status such as flu, have a fever, from head to foot that
Soft inability etc. much with air quality quality or has been contaminated suitable relationship among these.
For this purpose, the present invention provides a kind of anionic films and preparation method thereof.The anionic film is mainly used in automobile
On the air intake source of air-conditioning, domestic air conditioning and some ventilation equipment and in household effects, make driver's cabin, room and some close
The place closed can obtain the fresh air containing anion in a steady stream, make one to keep good when driving and usually living or work
The good state of mind, having the good state of mind just can be reduced the generation of driving accident, improve the quality of living, improve study with
Working efficiency.
Summary of the invention
The present invention relates to a kind of anionic films and preparation method thereof.
Described anionic film and preparation method thereof includes that following material and preparing department are rapid
One, takes nine degree of functionality Polyurethane resins, anion liquid, nano powder, photoinitiator, auxiliary agent several pieces, puts after mixing
Enter reaction kettle to react 2~4 hours, obtains anionic film coating；
Above-mentioned gained waterproof coating is uniformly coated on the table of the substrates such as pvc or pet or petg or pc with coating machine by two,
Face；
Three, are air-dried through oven hot air (80-120 degree)；
Four, are through strong/Weak ultraviolet irradiation solidification.
The nine degrees of functionality polyurethane acrylic resin oligomer INV-UV985
Products
UV985 is the nine officials polyurethane acrylic resin oligomer, and main functional group contains allyl double bonds, radiation-curable solid
Change or chemical crosslinking, product have color shallowly transparent, high rigidity damage resistant, bloom is without xanthochromia.It has wide range of applications, it both can be independent
It is used for UV photocureable coating as matrix resin, the products such as ink and adhesive can to gather with other acrylic systems, epoxy
Urethane, the materials such as nitro are blended, and for improving the surface hardness and gloss of material, adhesive strength and the color inhibition transparency have significantly
Effect.
Product main performance
High rigidity, high glaze, wear resistance are good；Highly cross-linked, rapid curing, cementability is good.
Water-tolerant, chemicals-resistant is excellent, colorless and transparent color inhibition, good weatherability
Excellent levelability and intermiscibility
Beneficial effects of the present invention
The air that anionic film of the present invention is mainly used in air conditioning for automobiles, domestic air conditioning and some ventilation equipment enters
On mouth source and household effects, driver's cabin, room and some closed places is enable to be obtained in a steady stream containing the pure and fresh of anion
Air makes one to keep the good state of mind when driving and usually living or work, there is good state of mind ability
The generation for reducing driving accident, improves the quality of living, and improves study and work efficiency.
Specific embodiment
Preferred embodiment 1
1. taking 40~60 parts of nine degree of functionality Polyurethane resin, 6~8 parts of anion liquid, 8~12 parts of nano powder, photoinitiator 3
~5, reaction kettle is put into after 2~4 parts of auxiliary agent, mixing to react 2~5 hours, obtain waterproof coating；
2. above-mentioned gained waterproof coating to be uniformly coated on to the table of the substrates such as pvc or pet or petg or pc with coating machine
Face；
3. being air-dried through oven hot air (80-120 degree)；
4. through strong/Weak ultraviolet irradiation solidification.
Preferred embodiment 2
1. taking 60~80 parts of nine degree of functionality Polyurethane resin, 8~12 parts of anion liquid, 12~14 parts of nano powder, light-initiated
Reaction kettle is put into after agent 6~8,3~5 parts of auxiliary agent, mixing to react 2~5 hours, obtains waterproof coating；
2. above-mentioned gained waterproof coating to be uniformly coated on to the table of the substrates such as pvc or pet or petg or pc with coating machine
Face；
3. being air-dried through oven hot air (80-120 degree)；
4. through strong/Weak ultraviolet irradiation solidification.
Preferred embodiment 3
1. taking 40 parts of nine degree of functionality Polyurethane resin, 8 parts of anion liquid, 9 parts of nano powder, photoinitiator 3,2 parts of auxiliary agent, mixing
It is put into reaction kettle after conjunction to react 3 hours, obtains waterproof coating；
2. above-mentioned gained waterproof coating to be uniformly coated on to the table of the substrates such as pvc or pet or petg or pc with coating machine
Face；
3. being air-dried through (90 degree) of oven hot air；
4. through strong/Weak ultraviolet irradiation solidification.
Preferred embodiment 4
1. take 60 parts of nine degree of functionality Polyurethane resin, 9 parts of anion liquid, 10 parts of nano powder, photoinitiator 4,3 parts of auxiliary agent,
It is put into reaction kettle after mixing to react 4 hours, obtains waterproof coating；
2. above-mentioned gained waterproof coating to be uniformly coated on to the table of the substrates such as pvc or pet or petg or pc with coating machine
Face；
3. being air-dried through (110 degree) of oven hot air；
4. through strong/Weak ultraviolet irradiation solidification.
Preferred embodiment 5
1. take 80 parts of nine degree of functionality Polyurethane resin, 15 parts of anion liquid, 18 parts of nano powder, photoinitiator 6,3 parts of auxiliary agent,
It is put into reaction kettle after mixing to react 3 hours, obtains waterproof coating；
2. above-mentioned gained waterproof coating to be uniformly coated on to the table of the substrates such as pvc or pet or petg or pc with coating machine
Face；
3. being air-dried through (110 degree) of oven hot air；
4. through strong/Weak ultraviolet irradiation solidification.
Preferred embodiment 6
1. taking 70 parts of nine degree of functionality Polyurethane resin, 30 parts of anion liquid, 20 parts of nano powder, photoinitiator 10, auxiliary agent 5
Reaction kettle is put into after part, mixing to react 4 hours, obtains waterproof coating；
2. above-mentioned gained waterproof coating to be uniformly coated on to the table of the substrates such as pvc or pet or petg or pc with coating machine
Face；
3. being air-dried through (120 degree) of oven hot air；
4. through strong/Weak ultraviolet irradiation solidification.
Preferred embodiment 7
1. taking 100 parts of nine degree of functionality Polyurethane resin, 30 parts of anion liquid, 25 parts of nano powder, photoinitiator 10, auxiliary agent 6
Reaction kettle is put into after part, mixing to react 4 hours, obtains waterproof coating；
2. above-mentioned gained waterproof coating to be uniformly coated on to the table of the substrates such as pvc or pet or petg or pc with coating machine
Face；
3. being air-dried through (100 degree) of oven hot air；
4. through strong/Weak ultraviolet irradiation solidification.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The present invention is not by upper
The limitation of embodiment is stated, the above embodiments and description only illustrate the principle of the present invention, is not departing from the present invention
Under the premise of spirit and scope, various changes and improvements may be made to the invention, these changes and improvements both fall within claimed
In the scope of the invention.The scope of the present invention is defined by the appended claims and its equivalents.
Claims (8)
1. invention is related to a kind of anionic film and preparation method thereof, it is characterised in that: one, take nine degree of functionality Polyurethane resins, is negative
Ionic liquid, nano powder, photoinitiator, auxiliary agent several pieces are put into reaction kettle and react 2~4 hours after mixing, obtain anionic film and apply
Material；Two, above-mentioned gained waterproof coating is uniformly coated on to the surface of the substrates such as pvc or pet or petg or pc with coating machine；
Three, it is air-dried through oven hot air (80-120 degree)；Four, through strong/Weak ultraviolet irradiation solidification.
2. anionic film according to claim 1 and preparation method thereof, it is characterised in that: further, preferred embodiment
1: one, take 40~60 parts of nine degree of functionality Polyurethane resin, 6~8 parts of anion liquid, 8~12 parts of nano powder, photoinitiator 3~5,
Reaction kettle is put into after 2~4 parts of auxiliary agent, mixing to react 2~5 hours, obtains waterproof coating；Two, with coating machine by above-mentioned gained
Waterproof coating is uniformly coated on the surface of the substrates such as pvc or pet or petg or pc；Three, through oven hot air (80-120 degree) wind
It is dry；Four, through strong/Weak ultraviolet irradiation solidification.
3. anionic film according to claim 1 and preparation method thereof, it is characterised in that: further, preferred embodiment
2: one, take 60~80 parts of nine degree of functionality Polyurethane resin, 8~12 parts of anion liquid, 12~14 parts of nano powder, photoinitiator 6~
8, reaction kettle is put into after 3~5 parts of auxiliary agent, mixing to react 2~5 hours, obtain waterproof coating；Two, with coating machine by above-mentioned institute
Obtain the surface that waterproof coating is uniformly coated on the substrates such as pvc or pet or petg or pc；Three, through oven hot air (80-120 degree)
It air-dries；Four, through strong/Weak ultraviolet irradiation solidification.
4. anionic film according to claim 1 and preparation method thereof, it is characterised in that: further, preferred embodiment
3: one, after taking 40 parts of nine degree of functionality Polyurethane resin, 8 parts of anion liquid, 9 parts of nano powder, photoinitiator 3,2 parts of auxiliary agent, mixing
It is put into reaction kettle to react 3 hours, obtains waterproof coating；Two, above-mentioned gained waterproof coating is uniformly coated on coating machine
The surface of the substrates such as pvc or pet or petg or pc；Three, it is air-dried through (90 degree) of oven hot air；Four, it is irradiated through strong/Weak ultraviolet solid
Change.
5. anionic film according to claim 1 and preparation method thereof, it is characterised in that: further, preferred embodiment
4: one, after taking 60 parts of nine degree of functionality Polyurethane resin, 9 parts of anion liquid, 10 parts of nano powder, photoinitiator 4,3 parts of auxiliary agent, mixing
It is put into reaction kettle to react 4 hours, obtains waterproof coating；Two, above-mentioned gained waterproof coating is uniformly coated on coating machine
The surface of the substrates such as pvc or pet or petg or pc；Three, it is air-dried through (110 degree) of oven hot air；Four, it is irradiated through strong/Weak ultraviolet
Solidification.
6. anionic film according to claim 1 and preparation method thereof, it is characterised in that: further, preferred embodiment
5: one, 80 parts of nine degree of functionality Polyurethane resin, 15 parts of anion liquid, 18 parts of nano powder, photoinitiator 6,3 parts of auxiliary agent, mixing are taken
After be put into reaction kettle react 3 hours, obtain waterproof coating；Two, with coating machine by above-mentioned gained waterproof coating even spread
On the surface of the substrates such as pvc or pet or petg or pc；Three, it is air-dried through (110 degree) of oven hot air；Four, it is shone through strong/Weak ultraviolet
Penetrate solidification.
7. anionic film according to claim 1 and preparation method thereof, it is characterised in that: further, preferred embodiment 6
One, after taking 70 parts of nine degree of functionality Polyurethane resin, 30 parts of anion liquid, 20 parts of nano powder, photoinitiator 10,5 parts of auxiliary agent, mixing
It is put into reaction kettle to react 4 hours, obtains waterproof coating；Two, above-mentioned gained waterproof coating is uniformly coated on coating machine
The surface of the substrates such as pvc or pet or petg or pc；Three, it is air-dried through (120 degree) of oven hot air；Four, it is irradiated through strong/Weak ultraviolet
Solidification.
8. anionic film according to claim 1 and preparation method thereof, it is characterised in that: further, preferred embodiment
7: one, it takes 100 parts of nine degree of functionality Polyurethane resin, 30 parts of anion liquid, 25 parts of nano powder, photoinitiator 10,6 parts of auxiliary agent, mix
It is put into reaction kettle after conjunction to react 4 hours, obtains waterproof coating；Two, above-mentioned gained waterproof coating is uniformly applied with coating machine
Cloth is on the surface of the substrates such as pvc or pet or petg or pc；Three, it is air-dried through (100 degree) of oven hot air；Four, through strong/Weak ultraviolet
Irradiation solidification.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710673192.6A CN109535458A (en) | 2017-07-28 | 2017-07-28 | A kind of anionic film and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710673192.6A CN109535458A (en) | 2017-07-28 | 2017-07-28 | A kind of anionic film and preparation method thereof |
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Family
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110698840A (en) * | 2019-08-22 | 2020-01-17 | 金群英 | TPU polyester health-care composite film and production method thereof |
| CN117209829A (en) * | 2023-11-09 | 2023-12-12 | 江苏贝格丽新材料科技有限公司 | Negative oxygen ion antibacterial PP decorative film and preparation method thereof |
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| CN106243931A (en) * | 2016-01-28 | 2016-12-21 | 珠海市佳伟力环保科技有限公司 | Anion UV coating and using method thereof and purposes |
| CN106280958A (en) * | 2016-08-31 | 2017-01-04 | 湖州龙珠高分子新材料有限公司 | A kind of UV floor paint with anion emission function |
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2017
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| US20060157676A1 (en) * | 2005-01-14 | 2006-07-20 | Zaxxon Usa, Inc. | Ionic or ion-generating floor covering and method for embedding ion particles within a floor covering |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110698840A (en) * | 2019-08-22 | 2020-01-17 | 金群英 | TPU polyester health-care composite film and production method thereof |
| CN117209829A (en) * | 2023-11-09 | 2023-12-12 | 江苏贝格丽新材料科技有限公司 | Negative oxygen ion antibacterial PP decorative film and preparation method thereof |
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