CN109534800A - A kind of magnetization high-bond height grinding consistent ceramic ground section and its manufacturing method - Google Patents
A kind of magnetization high-bond height grinding consistent ceramic ground section and its manufacturing method Download PDFInfo
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Abstract
The invention discloses a kind of magnetization high-bond height grinding consistent ceramic ground section and its manufacturing methods, the component of the ceramic grinding section is made of three kinds of function components, wherein the first function component A be using Nano-sized Alumina Powder, silicon carbide powder, molybdenum disulfide powder, yttria powder, Zirconium dioxide powder, titania powder, SiO 2 powder as raw material low-temperature sintering at ceramic matrix；Second of function component B is to lubricate surface layer using ferroso-ferric oxide, molybdenum disulfide, silver, copper, titanium as the cured magnetization of raw material high-temperature fusion；The third function component C is PVA plastic material；The component relationship of three kinds of compositions are as follows: grid-shaped mutually mix completely with component A securely of component C is combined into kernel, and component B is the modification film layer for being solidificated in core surface by supersonic flame spraying technique spray coating under protection of argon gas.Ceramic grinding segment table layer of the invention lubricates, grinding efficiency is high, binding force is good, abrasion is small, energy consumption is small, grinds more evenly.
Description
Technical field
The present invention relates to cement technical field more particularly to a kind of grinding consistent ceramic grindings of magnetization high-bond height
Section and its manufacturing method.
Background technique
In the prior art, with the rise of cement price, the industry of this field is worth rapid increase, and as technology is sent out
Exhibition, traditional steel abrading-ball are gradually replaced by ceramic grinding ball, but the equipment at present using ceramic ball grinding technique is all inevitable
Ground has two: 1, and since Ceramic Balls self weight is low, extruding force is insufficient under same stirring rate, and ball milling is imitated because caused by
Rate is low, i.e. separate unit ball mill inefficient low output；2, since ceramic grinding ball in the prior art mostly uses coarse sintering technology,
Structure is neither fine and close, again unbalanced, while brittleness is also big, easy fragmentation, thus loss is ground compared to raw steel matter in mechanical milling process
Ball is faster.
In the related patents applied at home, patent " a kind of efficient ball mill with magnetically grinding ball " (application number:
201410816874.4, publication date: 2016-7-20), a kind of technology for having used and having carried out the double-deck grinding with magnet steel ball is disclosed,
But due to using steel ball, hardness is low and quality weight, thus abrasive material loss and electric energy loss is higher and grinding effect is poor,
Magnetize the effect that abrading-ball does not have high self-bonding power and surface lubrication yet simultaneously.
In conclusion needing a kind of surface layer to lubricate on the market, grinding efficiency height, binding force is good, abrasion is small, energy consumption is small, grinds
The ceramic grinding section and its manufacturing method of mill more evenly.
Summary of the invention
To solve drawbacks described above existing in the prior art, the present invention is intended to provide a kind of surface layer lubricates, grinding efficiency is high,
Binding force is good, abrasion is small, energy consumption is small, the magnetization high-bond height of grinding more evenly grinds consistent ceramic ground section and its manufacturer
Method.
To achieve the goals above, the invention adopts the following technical scheme: a kind of grinding of magnetization high-bond height is uniformly made pottery
The component of porcelain ground section, the ceramic grinding section is made of three kinds of function components, and wherein the first function component A is with nano oxidized
65 parts -70 parts of aluminium powder, 6 parts -8 parts of silicon carbide powder, 2 parts -2.5 parts of molybdenum disulfide powder, 3 part -5 of yttria powder
Part, 5 parts -8 parts of Zirconium dioxide powder, 8 parts -10 parts of titania powder, 3 parts -5 parts of SiO 2 powder for raw material low temperature burn
The ceramic matrix formed；Second of function component B is 8 parts -10 parts of ferroferric oxide powder, 3 parts -5 parts of molybdenum disulfide powder, silver
3 parts -3.5 parts of powder, 1 part -1.2 parts of copper powder, 1 part -1.2 parts of titanium valve be raw material high-temperature fusion cured magnetization lubrication surface layer；The
Three kinds of function component C are PVA plastic materials；The component relationship of three kinds of compositions are as follows: component C is grid-shaped complete with component A securely
Complete mutually mix is combined into kernel, and component B is to be solidificated in core surface by supersonic flame spraying technique spray coating under protection of argon gas
Modification film layer.
A kind of manufacturing method of magnetization high-bond height grinding consistent ceramic ground section, comprising the following steps:
1) prepare before production
1. raw material prepare: preparation 65 parts -70 parts of Nano-sized Alumina Powder, 6 parts -8 parts of silicon carbide powder, two by weight
Vulcanize 2 parts -2.5 parts of molybdenum powder, 3 parts -5 parts of yttria powder, 5 parts -8 parts of Zirconium dioxide powder, titania powder 8
Part -10 parts, 3 parts -5 parts of SiO 2 powder, 8 parts -10 parts of ferroferric oxide powder, 3 parts -5 parts of molybdenum disulfide powder, silver powder 3
Parts -3.5 parts, 1 part -1.2 parts of copper powder, 1 part -1.2 parts of titanium valve, the solute of 5%-6%PVA containing mass fraction 68 parts of PVA aqueous solution -
75 parts；
2. auxiliary material prepares: preparing Enough Dl water；
2) preparation of superficial layer modified coating raw material
1. by the stage 1) the step ferroferric oxide powder, molybdenum disulfide powder, silver powder, copper powder, the titanium valve that 1. prepare be uniform
It mixes and mechanical lapping is to 10 μm -20 μm of hybrid particles partial size, obtain raw material to be sprayed；
3) sintering of alumina-based ceramic ball kernel
1. by the stage 1) the step alumina powder, silicon carbide powder, molybdenum disulfide powder, the yttria powder that 1. prepare
End, Zirconium dioxide powder, titania powder, SiO 2 powder are mixed and stirred for uniformly, obtaining mixed material；
2. by 1. mixed material that step obtains and stage 1) the PVA aqueous solution that 1. prepares of step is mixed and stirred for uniformly,
Obtain ceramic original slurry material；
3. cylindrical ceramic sintering mold is got out, in the ceramic original slurry material filling mold for then 2. obtaining step, pressure
Tightly, pressing force according to target Ceramic Balls final volume Vcm3It is calculated as 6VN/cm3-8VN/cm3；
4. the 3. mold for being filled with mixed material that step is obtained is placed in the argon gas that pressure in furnace is 12MPa-15Mpa
It in protective atmosphere, is sintered at a temperature of 1100 DEG C -1150 DEG C, sintering time 2h-3h；
5. coming out of the stove again when being furnace-cooled to 280 DEG C -300 DEG C after the completion of sintering and being air-cooled to room temperature, then deviate from mold, made pottery
Porcelain ground section crude green body, the ceramic grinding section crude green body are required ceramic grinding section kernel；
4) molding of alumina-based ceramic ball
1. using the stage 2) raw material to be sprayed that obtains is raw material, with the stage 3) the ceramic grinding section kernel that 5. obtains of step is
Target, using supersonic velocity flame plating equipment, in the argon gas protection environment that pressure is 1bar-1.1bar pressure, with 1880 DEG C-
1950 DEG C are outlet temperature, are spray away from spray treatment is carried out with 300mm-330mm, keep ceramic grinding section kernel with 10 °/s-
The angular speed of 12 °/s carries out spherical rotary to raw material spraying along knitting wool ball weaving track and finishes, and obtains surface modified ceramic ball；
2. carrying out vibration to 1. surface modified ceramic ball that step obtains using diamond abrasive vibrator deburring equipment
Burr and polishing treatment obtain ceramic grinding section to be processed；
3. 2. obtaining the ceramic grinding section to be processed proposed to step by electromagnetic induction applies the magnetic field that intensity is 2T-3T, adopt
It is magnetized with the buckyballs mode of magnetizing, magnetize time 10min-12min, magnetizes high-bond needed for obtaining after the completion of magnetizing
Height grinding consistent ceramic ground section.
Compared with prior art, the invention has the following advantages that (1) most crucial technical concept of the invention is how
It will organically be incorporated with antidetonation, lubrication, component and the hard of pooling feature and the extremely stable ceramic matrix of chemical property,
Present invention utilizes ceramic raw material be mixed in a certain proportion it is rear mutually promote molten characteristic, matched a kind of high rigidity, can low temperature
The ceramic matrix formula of sintering, the sintering temperature of low temperature are the bases that the present invention realizes；It then is all superfine powder using raw material
Advantage by it with PVA solution puddling at dirty solution, obtain permeability and wellability, while in sintering by liquefied
PVA increase surface can and internal bond, while having driven intrinsic air (source of Ceramic Balls inner air vent) between powder away, made this
Invention is finer and close；But since the ceramics for squeezing sintering certainly exist coarse, rough surface, the present invention utilizes this
The defects of routine techniques enhances the binding force of the modified film layer in surface layer, at the same by the ratio mixture of 3:1:1 ferroso-ferric oxide with
Silver, copper, titanium in molybdenum disulfide can generate (Ag under high temperature anaerobic environment72Cu28)97Ti3, this be a kind of pair of aluminium oxide especially
It is the fabulous alloy of the aluminium oxide wellability of rough surface, the wellability at 950 DEG C -1000 DEG C is best, this temperature
Degree is exactly mixed-powder during by turning liquid admittedly, significantly enhances the binding force of coating of the present invention and ceramic kernel,
Antibacterial ability (silver) is obtained simultaneously, and certain lubricity is provided；The silver of PVA in kernel, the not formed alloy in surface layer simultaneously
Grain, molybdenum disulfide can provide fabulous surface lubrication effect for the present invention.(2) present invention is exactly magnetic ball there are also a core technology
The ferroso-ferric oxide composition on surface, this composition obviously can provide certain magnetism after magnetizing for mill ball of the invention, by
In using ferroso-ferric oxide rather than kicker magnet neodymium iron boron, thus magnetic intensity of the invention will not be too high, is slightly less than to grind
This guarantees abrading-balls for (performance is by each component weight proportion and magnetize intensity and time realization) of abrading-ball self gravity
Between will not adhere, simultaneously because the interference in magnetic field, itself is in the case where mechanical force direction circulation is constant in routine techniques
Keeping the motion profile of the abrading-ball of certain regular motion also to become, changeable and uncontrollable (abrading-ball is constantly rotating, and magnetic pole constantly becomes
Change, the abrading-ball part abrading-ball that repels each other in part is attracting, destroys the direction that blender brings acting rules power), here it is promote this hair
Bright the reason of capable of grinding more evenly, two abrading-balls of simultaneous grinding contact also must be that magnetism is attracting, be additionally provided one
Fixed extruding force is equally ground thinner using the present invention.(3) present invention is made of three kinds of function components, wherein the first function
Energy component A is with Nano-sized Alumina Powder, silicon carbide powder, molybdenum disulfide powder, yttria powder, titanium dioxide zirconium powder
End, titania powder, SiO 2 powder be raw material low-temperature sintering at ceramic matrix；Second function component B be with
Ferroso-ferric oxide, molybdenum disulfide, silver, copper, titanium are that the cured magnetization of raw material high-temperature fusion lubricates surface layer；The third function component
C is PVA plastic material；Three kinds of composition firm connections, respectively there is effect.(4) the finished product density 3.6g/cm that the present invention obtains3-
3.9g/cm3, the only half of steel material, it is thus possible to effectively economize on electricity, energy conservation, reduce carbon emission；Ceramic hardness is high, wear-resisting
Property is good, and service life is long.Lubricate the present invention finally with surface layer, grinding efficiency is high, binding force is good, abrasion is small, energy consumption
The small, characteristic of grinding more evenly.
Specific embodiment
Embodiment 1:
A kind of magnetization high-bond height grinding consistent ceramic ground section, the component of the ceramic grinding section is by three kinds of function components
Composition, wherein the first function component A be with Nano-sized Alumina Powder 65g, silicon carbide powder 8g, molybdenum disulfide powder 2.5g,
Yttria powder 5g, Zirconium dioxide powder 8g, titania powder 10g, SiO 2 powder 5g are raw material low temperature burning
The ceramic matrix formed；Second of function component B is ferroferric oxide powder 10g, molybdenum disulfide powder 5g, silver powder 3.5g, copper
Powder 1.2g, titanium valve 1.2g are that the cured magnetization of raw material high-temperature fusion lubricates surface layer；The third function component C is PVA polymer material
Material；The component relationship of three kinds of compositions are as follows: grid-shaped mutually mix completely with component A securely of component C is combined into kernel, and component B is
The modification film layer of core surface is solidificated in by supersonic flame spraying technique spray coating under protection of argon gas；
The manufacturing method of above-mentioned ceramic grinding section, comprising the following steps:
1) prepare before production
1. raw material prepare: preparation Nano-sized Alumina Powder 65g, silicon carbide powder 8g, molybdenum disulfide powder by weight
2.5g, yttria powder 5g, Zirconium dioxide powder 8g, titania powder 10g, SiO 2 powder 5g, four oxidations three
Iron powder 10g, molybdenum disulfide powder 5g, silver powder 3.5g, copper powder 1.2g, titanium valve 1.2g, the solute of 6%PVA containing mass fraction PVA
Aqueous solution 75g；
2. auxiliary material prepares: preparing Enough Dl water；
2) preparation of superficial layer modified coating raw material
1. by the stage 1) the step ferroferric oxide powder, molybdenum disulfide powder, silver powder, copper powder, the titanium valve that 1. prepare be uniform
It mixes and mechanical lapping is to 10 μm -20 μm of hybrid particles partial size, obtain raw material to be sprayed；
3) sintering of alumina-based ceramic ball kernel
1. by the stage 1) the step alumina powder, silicon carbide powder, molybdenum disulfide powder, the yttria powder that 1. prepare
End, Zirconium dioxide powder, titania powder, SiO 2 powder are mixed and stirred for uniformly, obtaining mixed material；
2. by 1. mixed material that step obtains and stage 1) the PVA aqueous solution that 1. prepares of step is mixed and stirred for uniformly,
Obtain ceramic original slurry material；
3. cylindrical ceramic sintering mold is got out, in the ceramic original slurry material filling mold for then 2. obtaining step, pressure
Tightly, pressing force according to target Ceramic Balls final volume Vcm3It is calculated as 8VN/cm3；
4. the 3. mold for being filled with mixed material that step is obtained is placed in the argon gas that pressure in furnace is 15Mpa and protects gas
It in atmosphere, is sintered at a temperature of 1150 DEG C, sintering time 2h-3h；
5. coming out of the stove again when being furnace-cooled to 280 DEG C after the completion of sintering and being air-cooled to room temperature, then deviate from mold, obtains ceramic grinding
Section crude green body, the ceramic grinding section crude green body are required ceramic grinding section kernel；
4) molding of alumina-based ceramic ball
1. using the stage 2) raw material to be sprayed that obtains is raw material, with the stage 3) the ceramic grinding section kernel that 5. obtains of step is
Target is outlet with 1950 DEG C in the argon gas protection environment that pressure is 1.1bar pressure using supersonic velocity flame plating equipment
Temperature is spray away from spray treatment is carried out with 300mm-330mm, keeps ceramic grinding section kernel with the angular speed of 10 °/s along knitting wool
Ball weaving track carries out spherical rotary to raw material spraying and finishes, and obtains surface modified ceramic ball；
2. carrying out vibration to 1. surface modified ceramic ball that step obtains using diamond abrasive vibrator deburring equipment
Burr and polishing treatment obtain ceramic grinding section to be processed；
3. the ceramic grinding section to be processed that proposes 2. is obtained to step by electromagnetic induction applies the magnetic field that intensity is 3T, using bar
Gram ball mode of magnetizing magnetizes, and magnetize time 12min, and magnetization high-bond height grinding needed for obtaining after the completion of magnetizing is uniformly
Ceramic grinding section.
Embodiment 2:
It is whole consistent with embodiment 1, it is in place of difference:
A kind of magnetization high-bond height grinding consistent ceramic ground section, the component of the ceramic grinding section is by three kinds of function components
Composition, wherein the first function component A is with Nano-sized Alumina Powder 70g, silicon carbide powder 6g, molybdenum disulfide powder 2g, three
Y 2 O powder 3g, Zirconium dioxide powder 5g, titania powder 8g, SiO 2 powder 3g be raw material low-temperature sintering at
Ceramic matrix；Second of function component B is ferroferric oxide powder 8g, molybdenum disulfide powder 3g, silver powder 3g, copper powder 1g, titanium
Powder 1g is that the cured magnetization of raw material high-temperature fusion lubricates surface layer；The third function component C is PVA plastic material；Three kinds of compositions
Component relationship are as follows: grid-shaped mutually mix completely with component A securely of component C is combined into kernel, and component B is under protection of argon gas
The modification film layer of core surface is solidificated in by supersonic flame spraying technique spray coating；
The manufacturing method of above-mentioned ceramic grinding section, comprising the following steps:
1) prepare before production
1. raw material prepare: preparation Nano-sized Alumina Powder 70g, silicon carbide powder 6g, molybdenum disulfide powder by weight
2g, yttria powder 3g, Zirconium dioxide powder 5g, titania powder 8g, SiO 2 powder 3g, ferroso-ferric oxide powder
Last 8g, molybdenum disulfide powder 3g, silver powder 3g, copper powder 1g, titanium valve 1g, the solute of 5%PVA containing mass fraction PVA aqueous solution 68g；
3) sintering of alumina-based ceramic ball kernel
3. cylindrical ceramic sintering mold is got out, in the ceramic original slurry material filling mold for then 2. obtaining step, pressure
Tightly, pressing force according to target Ceramic Balls final volume Vcm3It is calculated as 6VN/cm3；
4. the 3. mold for being filled with mixed material that step is obtained is placed in the argon gas that pressure in furnace is 12MPa and protects gas
It in atmosphere, is sintered at a temperature of 1100 DEG C, sintering time 2h；
5. coming out of the stove again when being furnace-cooled to 300 DEG C after the completion of sintering and being air-cooled to room temperature, then deviate from mold, obtains ceramic grinding
Section crude green body, the ceramic grinding section crude green body are required ceramic grinding section kernel；
4) molding of alumina-based ceramic ball
1. using the stage 2) raw material to be sprayed that obtains is raw material, with the stage 3) the ceramic grinding section kernel that 5. obtains of step is
Target is outlet temperature with 1880 DEG C in the argon gas protection environment that pressure is 1bar pressure using supersonic velocity flame plating equipment
It spends, is spray away from spray treatment is carried out with 330mm, keep ceramic grinding section kernel with the angular speed of 12 °/s along knitting wool ball weaving rail
Mark carries out spherical rotary to raw material spraying and finishes, and obtains surface modified ceramic ball；
3. the ceramic grinding section to be processed that proposes 2. is obtained to step by electromagnetic induction applies the magnetic field that intensity is 2T, using bar
Gram ball mode of magnetizing magnetizes, and magnetize time 10min, and magnetization high-bond height grinding needed for obtaining after the completion of magnetizing is uniformly
Ceramic grinding section.
The foregoing description of the disclosed embodiments, only for can be realized professional and technical personnel in the field or use this
Invention.Various modifications to these embodiments will be readily apparent to those skilled in the art, institute herein
The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore,
The present invention will not be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent widest scope of point.
Claims (2)
1. a kind of magnetization high-bond height grinds consistent ceramic ground section, it is characterised in that: the component of the ceramic grinding section is by three
Kind function component composition, wherein the first function component A is with 65 parts -70 parts of Nano-sized Alumina Powder, 6 part -8 of silicon carbide powder
Part, 2 parts -2.5 parts of molybdenum disulfide powder, 3 parts -5 parts of yttria powder, 5 parts -8 parts of Zirconium dioxide powder, titanium dioxide powder
End 8 parts -10 parts, 3 parts -5 parts of SiO 2 powder for raw material low-temperature sintering at ceramic matrix；Second of function component B be
8 parts -10 parts of ferroferric oxide powder, 3 parts -5 parts of molybdenum disulfide powder, 3 parts -3.5 parts of silver powder, 1 part -1.2 parts of copper powder, titanium valve 1
- 1.2 parts of part lubricate surface layer for the cured magnetization of raw material high-temperature fusion；The third function component C is PVA plastic material；Three kinds
The component relationship of composition are as follows: grid-shaped mutually mix completely with component A securely of component C is combined into kernel, and component B is to protect in argon gas
The lower modification film layer that core surface is solidificated in by supersonic flame spraying technique spray coating of shield.
2. a kind of manufacturing method of magnetization high-bond height grinding consistent ceramic ground section, it is characterised in that the following steps are included:
1) prepare before production
1. raw material prepare: preparation 65 parts -70 parts of Nano-sized Alumina Powder, 6 parts -8 parts of silicon carbide powder, curing by weight
2 parts -2.5 parts of molybdenum powder, 3 parts -5 parts of yttria powder, 5 parts -8 parts of Zirconium dioxide powder, 8 part -10 of titania powder
Part, 3 parts -5 parts of SiO 2 powder, 8 parts -10 parts of ferroferric oxide powder, 3 parts -5 parts of molybdenum disulfide powder, 3 part -3.5 of silver powder
Part, 68 parts -75 parts of PVA aqueous solution of 1 part -1.2 parts of copper powder, 1 part -1.2 parts of titanium valve, the solute of 5%-6%PVA containing mass fraction；
2. auxiliary material prepares: preparing Enough Dl water；
2) preparation of superficial layer modified coating raw material
1. by the stage 1) the step ferroferric oxide powder, molybdenum disulfide powder, silver powder, copper powder, the titanium valve that 1. prepare uniformly mix
And mechanical lapping obtains raw material to be sprayed to 10 μm -20 μm of hybrid particles partial size；
3) sintering of alumina-based ceramic ball kernel
1. by the stage 1) step 1. prepare alumina powder, silicon carbide powder, molybdenum disulfide powder, yttria powder,
Zirconium dioxide powder, titania powder, SiO 2 powder are mixed and stirred for uniformly, obtaining mixed material；
2. by 1. mixed material that step obtains and stage 1) the PVA aqueous solution that 1. prepares of step is mixed and stirred for uniformly, acquisition
Ceramic original slurry material；
3. getting out cylindrical ceramic sintering mold, in the ceramic original slurry material filling mold for then 2. obtaining step, compress, pressure
Clamp force according to target Ceramic Balls final volume Vcm3It is calculated as 6VN/cm3-8VN/cm3；
4. the 3. mold for being filled with mixed material that step is obtained is placed in the argon gas that pressure in furnace is 12MPa-15Mpa and protects
It in atmosphere, is sintered at a temperature of 1100 DEG C -1150 DEG C, sintering time 2h-3h；
5. coming out of the stove again when being furnace-cooled to 280 DEG C -300 DEG C after the completion of sintering and being air-cooled to room temperature, then deviate from mold, obtains ceramics and grind
Section crude green body is ground, which is required ceramic grinding section kernel；
4) molding of alumina-based ceramic ball
1. using the stage 2) raw material to be sprayed that obtains is raw material, using the stage 3) the ceramic grinding section kernel that 5. obtains of step is target
Material, using supersonic velocity flame plating equipment, in the argon gas protection environment that pressure is 1bar-1.1bar pressure, with 1880 DEG C-
1950 DEG C are outlet temperature, are spray away from spray treatment is carried out with 300mm-330mm, keep ceramic grinding section kernel with 10 °/s-
The angular speed of 12 °/s carries out spherical rotary to raw material spraying along knitting wool ball weaving track and finishes, and obtains surface modified ceramic ball；
2. carrying out vibrator deburring to 1. surface modified ceramic ball that step obtains using diamond abrasive vibrator deburring equipment
And polishing treatment, that is, obtain ceramic grinding section to be processed；
3. the ceramic grinding section to be processed that proposes 2. is obtained to step by electromagnetic induction applies the magnetic field that intensity is 2T-3T, using bar
Gram ball mode of magnetizing magnetizes, and magnetize time 10min-12min, magnetization high-bond Gao Yan needed for obtaining after the completion of magnetizing
Grind consistent ceramic ground section.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110788266A (en) * | 2019-11-05 | 2020-02-14 | 青岛嘉乐智能自动化科技有限公司 | High-abrasion-resistance long-service-life four-axis forging and pressing robot |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3625666A (en) * | 1968-06-19 | 1971-12-07 | Ind Distributors 1946 Ltd | Method of forming metal-coated diamond abrasive wheels |
| CN104774036A (en) * | 2014-01-10 | 2015-07-15 | 江西嘉顺瓷业有限公司 | Composite coating material and ceramic vessel |
| CN105772165A (en) * | 2014-12-22 | 2016-07-20 | 佛山市宝航机械装备行业知识产权服务有限公司 | Efficient ball mill with magnetic grinding balls |
| CN105859259A (en) * | 2016-04-02 | 2016-08-17 | 山东天汇研磨耐磨技术开发有限公司 | Ceramic grinding ball for cement ball mill, and preparation method thereof |
| WO2018080756A1 (en) * | 2016-10-25 | 2018-05-03 | 3M Innovative Properties Company | Functional abrasive particles, abrasive articles, and methods of making the same |
| CN108033782A (en) * | 2017-12-28 | 2018-05-15 | 济南泉润陶瓷科技有限公司 | A kind of preparation method of high-performance high alumina ceramic mill ball |
| CN108383529A (en) * | 2018-03-05 | 2018-08-10 | 吉林大学 | A kind of construction method of the friction surface with porous structure ceramic layer |
-
2018
- 2018-12-29 CN CN201811644638.3A patent/CN109534800A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3625666A (en) * | 1968-06-19 | 1971-12-07 | Ind Distributors 1946 Ltd | Method of forming metal-coated diamond abrasive wheels |
| CN104774036A (en) * | 2014-01-10 | 2015-07-15 | 江西嘉顺瓷业有限公司 | Composite coating material and ceramic vessel |
| CN105772165A (en) * | 2014-12-22 | 2016-07-20 | 佛山市宝航机械装备行业知识产权服务有限公司 | Efficient ball mill with magnetic grinding balls |
| CN105859259A (en) * | 2016-04-02 | 2016-08-17 | 山东天汇研磨耐磨技术开发有限公司 | Ceramic grinding ball for cement ball mill, and preparation method thereof |
| WO2018080756A1 (en) * | 2016-10-25 | 2018-05-03 | 3M Innovative Properties Company | Functional abrasive particles, abrasive articles, and methods of making the same |
| CN108033782A (en) * | 2017-12-28 | 2018-05-15 | 济南泉润陶瓷科技有限公司 | A kind of preparation method of high-performance high alumina ceramic mill ball |
| CN108383529A (en) * | 2018-03-05 | 2018-08-10 | 吉林大学 | A kind of construction method of the friction surface with porous structure ceramic layer |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110788266A (en) * | 2019-11-05 | 2020-02-14 | 青岛嘉乐智能自动化科技有限公司 | High-abrasion-resistance long-service-life four-axis forging and pressing robot |
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