CN109534722A - A kind of high-performance reclaimed bituminous pavement cold-repairing material and preparation method thereof - Google Patents

A kind of high-performance reclaimed bituminous pavement cold-repairing material and preparation method thereof Download PDF

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Publication number
CN109534722A
CN109534722A CN201811174543.XA CN201811174543A CN109534722A CN 109534722 A CN109534722 A CN 109534722A CN 201811174543 A CN201811174543 A CN 201811174543A CN 109534722 A CN109534722 A CN 109534722A
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China
Prior art keywords
bituminous pavement
repairing material
modified
reclaimed bituminous
cold
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CN201811174543.XA
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Chinese (zh)
Inventor
何靖斌
钟向宏
欧晔
李国民
梁红梅
苏亦平
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China Petroleum and Chemical Corp
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China Petroleum and Chemical Corp
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Priority to CN201811174543.XA priority Critical patent/CN109534722A/en
Publication of CN109534722A publication Critical patent/CN109534722A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/26Bituminous materials, e.g. tar, pitch
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/16Waste materials; Refuse from building or ceramic industry
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a kind of high-performance reclaimed bituminous pavement cold-repairing materials, consist of the following mass percentage components: high aromatic oil 2-5%;Plasticizer 0.05-0.1%;Modified-high polymer agent 0.1-0.4%;Latex modified agent 0.1-0.2%;Kerosene 0.7-1.5%;Waste asphalt pavement milling material 93-97%.The present invention solves the problems, such as the environmental pollution of asphalt roads milling waste material and recycles using the surface layer milling material of waste asphalt road as raw materials for production, more more environmentally-friendly than existing product technology and economize on resources;Using high aromatic oil, plasticizer, modified-high polymer agent carries out regeneration to the aged asphalt in waste and old gather materials and hydrodynamics are handled, and restores and enhances the high temperature and cryogenic property of aged asphalt.The invention also discloses the preparation methods of above-mentioned high-performance reclaimed bituminous pavement cold-repairing material.

Description

A kind of high-performance reclaimed bituminous pavement cold-repairing material and preparation method thereof
Technical field
The present invention relates to refinery products fields, and in particular to high-performance reclaimed bituminous pavement cold-repairing material and its preparation side Method.
Background technique
Since bituminous pavement has evenness of road surface, ride comfort, wear-proof sliding-proof, small, the suitable for mechanization construction of noise etc. all More advantages are used widely on the roads at different levels in China at present.But bituminous pavement is in use, due to for a long time by Solarization drenches with rain, the climatic effects such as freeze thawing, often will appear various parts along with driving vehicle constantly rolls, on road surface and opens It splits, pit slot, breakage, the diseases such as crack.The appearance of pavement disease not only reduces the service performance of bituminous pavement, affects road Normal pass, also increase the probability of traffic accident generation, therefore the various diseases occurred on bituminous pavement had to It is repaired and is conserved in time.
Traditional asphalt pavement repairing mostly uses hot-mix asphalt mixture to be repaired, but the use of hot-mix asphalt mixture It is much limited, is not suitable for the small scrappy engineering of project amount such as, is not suitable for the rain and snow weather of low temperature, it is big to apply man-hour requirement The experienced operator of amount and special-purpose machinery, using flexible is poor, cannot store for a long time, construction cost height etc..In order to solve these There is pitch cold-repairing material technology again in recent years in problem, but these pitch cold-repairing material technologies respectively have some disadvantages again.
For example, patent CN 201510198290.X proposes a kind of asphalt roads surface layer cold-repairing material, but its material for using Expect only gravel aggregate, common petroleum pitch and corresponding some cold repairing additives, thus its high-temperature behavior, cryogenic property, Anti-water damage property, anti-cracking performance etc. is all without significant advantage.
Patent CN 201310280739.8 proposes a kind of road surface cold-repairing material and preparation method thereof, the material used Only common building stones, No. 70 asphalts and corresponding some cold repairing additives, high-temperature behavior, cryogenic property, water resistant It damages performance and anti-cracking performance is also general.And two patent applications are all to be used as to gather materials using new building stones, one side cost It is higher, on the other hand belong to waste of resource.
Summary of the invention
The first purpose of the invention is to provide a kind of high-performance reclaimed bituminous pavement cold-repairing materials.The cold-repairing material is with waste and old drip The surface layer milling material of green road carries out being used as skeleton structure raw material after loose screening process is forced in recycling heating, then multiple by addition It closes regenerative component and regeneration and hydrodynamics processing is carried out to the aged asphalt in waste and old gather materials, finally add a certain proportion of kerosene It is evenly mixed with latex modified agent and prepares finished product.The present invention not only solves the environmental pollution of asphalt roads milling waste material and returns Utilizing question is received, and there is superior service performance.
A second object of the present invention is to provide the preparation methods of above-mentioned high-performance reclaimed bituminous pavement cold-repairing material.
Above-mentioned first purpose of the invention can be realized by technical solution below:
High-performance reclaimed bituminous pavement cold-repairing material, consists of the following mass percentage components:
Preferably, the high-performance reclaimed bituminous pavement cold-repairing material, consists of the following mass percentage components:
It is further preferred that the high-performance reclaimed bituminous pavement cold-repairing material, consists of the following mass percentage components:
Preferably, the high aromatic oil is that the oil plant rich in aromatic hydrocarbons depressurizes side line furfural extract oil, and aromatic hydrocarbons contains Amount > 40%, initial boiling point > 200 DEG C.
Preferably, the plasticizer is dioctyl phthalate, active principle content > 99.5%.
Preferably, the modified-high polymer agent is linear structure SBS (s-B-S block copolymerization Object).
Preferably, the latex modified agent is SBR (butylbenzene) latex, is low temperature polymerization, the glue of low combination styrene-content Cream, solid content 10%-30%.
Preferably, the kerosene is solvent kerosene, impurity content < 0.1%.
Preferably, the waste asphalt pavement milling material is to reject partial size after loose screening process is forced in heating The particle of < 0.3mm, and the asphalt roads of skeleton structure is formed using the mix-design of half open gradation of AM-13 particulate formula Surface layer milling material.
Above-mentioned second purpose of the invention can be realized by technical solution below:
The preparation method of above-mentioned high-performance reclaimed bituminous pavement cold-repairing material, comprising the following steps:
1) high aromatic oil, plasticizer, modified-high polymer agent, latex modified agent, kerosene, waste asphalt pavement are weighed in proportion Milling material;
2) high aromatic oil of the amount of weighing half is taken to be uniformly mixed with plasticizer, the mixture for obtaining high aromatic oil and plasticizer is standby With;
3) it takes remaining high aromatic oil to be heated to 100-120 DEG C, is then put into togerther high speed shear with modified-high polymer agent and sets Standby middle circulation shear 10-20min, obtains the mixing object of high aromatic oil and modified-high polymer agent;
4) waste asphalt pavement milling material is heated to pouring into mixing plant after 100-150 DEG C of temperature, while step is added It is rapid 2) in high aromatic oil and plasticizer mixture, and 100-150 DEG C at a temperature of stir 10-15min;Then it adds The mixing object of high aromatic oil and modified-high polymer agent in step 3), 120 DEG C~160 DEG C at a temperature of continue stir 15- 30min obtains mixture;
5) kerosene and latex modified agent are added in the mixture of step 4), 80-100 DEG C at a temperature of, continue to stir 5-10min obtains high-performance reclaimed bituminous pavement cold-repairing material finished product.
Preferably, high-speed shearing equipment described in step 3) refers to modified pitch specialized high-speed cutter or colloid mill, shearing Grinding revolving speed is greater than 2000 turns per minute.
Preferably, mixing plant described in step 4) refers to that the asphalt with heating and temperature controlling function mixes and stirs furnace or mixes And pot.
Compared with prior art, the invention has the following advantages:
(1) present invention using the surface layer milling material of waste asphalt road carry out recycling heating force after loose screening process as The skeleton structure raw material of cold-repairing material solves the problems, such as the environmental pollution of asphalt roads milling waste material and recycles, than existing Product technology is more environmentally-friendly and economizes on resources.
(2) present invention using high aromatic oil, plasticizer, modified-high polymer agent as composite regenerated component in waste and old gather materials Aged asphalt carry out regeneration and hydrodynamics processing, restore and enhance the high temperature and cryogenic property of aged asphalt so that this Invention product has better pavement performance and endurance quality.
(3) present invention compared with traditional diesel fuel dilution agent, is more likely to volatilize, so this hair using kerosene as diluent Bright product has faster intensity profile speed than existing Bituminous Pavement Cold feed supplement, shortens the maintenance time, improves Construction efficiency enables the road repaired to come into operation faster.
(4) the latex modified agent that the present invention is added, on the one hand can improve the low temperature flexibility and crack resistance of product, another Aspect makes product have better adhesion, enhances the anti-water damage property of product.
Specific embodiment
The invention will be further described for following example, so that those skilled in the art can better understand the present invention And it can be practiced, but illustrated embodiment is not as a limitation of the invention.
Embodiment one
For producing 1000 grams of product of the present invention, raw material used and its proportion are as follows:
Product preparation step:
(1) first by 17.15 grams of high aromatic oils and plasticizer be mixed evenly high aromatic oil and plasticizer mixture For use;
(2) remaining 17.15 grams of high aromatic oils are heated to 110 DEG C, high speed is then put into togerther with modified-high polymer agent It is carried out circulation shear 15 minutes in shearing equipment, obtains the mixing object of high aromatic oil and modified-high polymer agent;
(3) it is poured into mixing plant after waste asphalt pavement milling material being heated to 125 DEG C of temperature, while step is added (1) mixture of high aromatic oil and plasticizer in, and 125 DEG C at a temperature of stir 10 minutes;Then step (2) are added In high aromatic oil and modified-high polymer agent mixing object, 140 DEG C at a temperature of continue stirring 20 minutes, obtain mixture;
(4) kerosene and latex modified agent are added in the mixture of step (3), 90 DEG C at a temperature of, continue 8 points of stirring Clock obtains high-performance reclaimed bituminous pavement cold-repairing material finished product.
Embodiment two
For producing 1000 grams of product of the present invention, raw material used and its proportion are as follows:
Product preparation step:
(1) first 21 grams of high aromatic oils and plasticizer are mixed evenly for use;
(2) remaining 21 grams of high aromatic oils are heated to 115 DEG C, are then put into togerther high speed shear with modified-high polymer agent It is carried out circulation shear 15 minutes in equipment;
(3) it is poured into mixing plant after waste asphalt pavement milling material being heated to 120 DEG C of temperature, while step is added (1) mixture of high aromatic oil and plasticizer in, and 120 DEG C at a temperature of stir 10 minutes;Then step (2) are added In high aromatic oil and modified-high polymer agent mixing object, 145 DEG C at a temperature of continue stirring 25 minutes;
(4) kerosene and latex modified agent are added in the mixture of step (3), 85 DEG C at a temperature of, continue 6 points of stirring Clock obtains high-performance reclaimed bituminous pavement cold-repairing material finished product.
Embodiment three
For producing 1000 grams of product of the present invention, raw material used and its proportion are as follows:
Product preparation step:
(1) first 13 grams of high aromatic oils and plasticizer are mixed evenly for use;
(2) remaining 13 grams of high aromatic oils are heated to 110 DEG C, are then put into togerther high speed shear with modified-high polymer agent It is carried out circulation shear 15 minutes in equipment;
(3) it is poured into mixing plant after waste asphalt pavement milling material being heated to 130 DEG C of temperature, while step is added (1) mixture of high aromatic oil and plasticizer in, and 130 DEG C at a temperature of stir 15 minutes;Then step (2) are added In high aromatic oil and modified-high polymer agent mixing object, 140 DEG C at a temperature of continue stirring 20 minutes;
(4) kerosene and latex modified agent are added in the mixture of step (3), 90 DEG C at a temperature of, continue 9 points of stirring Clock obtains high-performance reclaimed bituminous pavement cold-repairing material finished product.
Example IV
For producing 1000 grams of product of the present invention, raw material used and its proportion are as follows:
Product preparation step:
(1) first 25 grams of high aromatic oils and plasticizer are mixed evenly for use;
(2) remaining 25 grams of high aromatic oils are heated to 100 DEG C, are then put into togerther high speed shear with modified-high polymer agent It is carried out circulation shear 10 minutes in equipment;
(3) it is poured into mixing plant after waste asphalt pavement milling material being heated to 110 DEG C of temperature, while step is added (1) mixture of high aromatic oil and plasticizer in, and 110 DEG C at a temperature of stir 10 minutes;Then step (2) are added In high aromatic oil and modified-high polymer agent mixing object, 120 DEG C at a temperature of continue stirring 15 minutes;
(4) kerosene and latex modified agent are added in the mixture of step (3), 90 DEG C at a temperature of, continue 6 points of stirring Clock obtains high-performance reclaimed bituminous pavement cold-repairing material finished product.
Embodiment five
For producing 1000 grams of product of the present invention, raw material used and its proportion are as follows:
Product preparation step:
(1) first 10 grams of high aromatic oils and plasticizer are mixed evenly for use;
(2) remaining 10 grams of high aromatic oils are heated to 120 DEG C, are then put into togerther high speed shear with modified-high polymer agent It is carried out circulation shear 20 minutes in equipment;
(3) it is poured into mixing plant after waste asphalt pavement milling material being heated to 140 DEG C of temperature, while step is added (1) mixture of high aromatic oil and plasticizer in, and 140 DEG C at a temperature of stir 15 minutes;Then step (2) are added In high aromatic oil and modified-high polymer agent mixing object, 150 DEG C at a temperature of continue stirring 30 minutes;
(4) kerosene and latex modified agent are added in the mixture of step (3), 95 DEG C at a temperature of, continue stirring 10 Minute, obtain high-performance reclaimed bituminous pavement cold-repairing material finished product.
To embodiment one to five products obtained therefrom of embodiment according to " highway engineering pitch and Asphalt Mixture Experiment regulation " JTG The test method of E20-2011 and the technical standard of " standard specification for construction and acceptance of highway asphalt pavement " JTG F40-2004 are to each reality The properties of sample for applying example is detected, and measurement result is as shown in table 1.
1 embodiment performance evaluation of table
Project test Embodiment one Embodiment two Embodiment three Example IV Embodiment five
Construction workability It is good It is good It is good It is good It is good
The intensity profile time 4 days 4 days 4 days 4 days 4 days
Marshall stability, kN 8.7 8.9 8.3 9.5 8.1
Soak Marshall residual stability, % 94.2 94.7 93.9 94.5 93.8
Adhesion grade 5 5 5 5 5
Table 1 the result shows that, product of the present invention construction workability is good, and intensity profile is fast, and stability is high, and water resistant damages ability By force, adhesion is excellent, and the properties of product are fully achieved and are better than traditional asphalt roads cold-repairing material product.
The above embodiment of the present invention is not limiting the scope of the present invention, and embodiments of the present invention are not limited to This, all this kind above content according to the present invention is not departing from this according to the ordinary technical knowledge and customary means of this field Modification, replacement or change under the premise of inventing above-mentioned basic fundamental thought, to other diversified forms that above structure of the present invention is made More, it should all fall within the scope and spirit of the invention.

Claims (10)

1. a kind of high-performance reclaimed bituminous pavement cold-repairing material, which is characterized in that consist of the following mass percentage components:
2. high-performance reclaimed bituminous pavement cold-repairing material according to claim 1, it is characterised in that: by following mass percent Group be grouped as:
3. high-performance reclaimed bituminous pavement cold-repairing material according to claim 1, it is characterised in that: by following mass percent Group be grouped as:
4. high-performance reclaimed bituminous pavement cold-repairing material according to claim 1 to 3, it is characterised in that: the Gao Fang Hydrocarbon ils is that the oil plant rich in aromatic hydrocarbons depressurizes side line furfural extract oil, arene content > 40%, initial boiling point > 200 DEG C.
5. high-performance reclaimed bituminous pavement cold-repairing material according to claim 1 to 3, it is characterised in that: the plasticizer For dioctyl phthalate, active principle content > 99.5%.
6. high-performance reclaimed bituminous pavement cold-repairing material according to claim 1 to 3, it is characterised in that: the high polymer Modifying agent is linear structure SBS.
7. high-performance reclaimed bituminous pavement cold-repairing material according to claim 1 to 3, it is characterised in that: the latex changes Property agent be low temperature polymerization, the SBR latex of low combination styrene-content, solid content 10%-30%.
8. high-performance reclaimed bituminous pavement cold-repairing material according to claim 1 to 3, it is characterised in that: the kerosene For solvent kerosene, impurity content < 0.1%.
9. high-performance reclaimed bituminous pavement cold-repairing material according to claim 1 to 3, it is characterised in that: described is waste and old Bituminous pavement milling material is the surface layer milling material of asphalt roads, it is desirable that after having to pass through the loose screening process of heating pressure, is rejected The particle of partial size < 0.3mm, and skeleton structure is formed using the mix-design of half open gradation of AM-13 particulate formula.
10. a kind of production method of high-performance reclaimed bituminous pavement cold-repairing material, which comprises the following steps:
1) high aromatic oil, plasticizer, modified-high polymer agent, latex modified agent, kerosene, waste asphalt pavement milling are weighed in proportion Material;
2) high aromatic oil of the amount of weighing half is taken to be uniformly mixed with plasticizer, the mixture for obtaining high aromatic oil and plasticizer is spare;
3) it takes remaining high aromatic oil to be heated to 100-120 DEG C, is then put into togerther in high-speed shearing equipment with modified-high polymer agent Circulation shear 10-20min obtains the mixing object of high aromatic oil and modified-high polymer agent;
4) waste asphalt pavement milling material is heated to pouring into mixing plant after 100-150 DEG C of temperature, while step 2) is added In high aromatic oil and plasticizer mixture, and 100-150 DEG C at a temperature of stir 10-15min;Then step is added 3) the mixing object of high aromatic oil and modified-high polymer agent in, 120 DEG C~160 DEG C at a temperature of continue stir 15-30min, Obtain mixture;
5) kerosene and latex modified agent are added in the mixture of step 4), 80-100 DEG C at a temperature of, continue to stir 5- 10min obtains high-performance reclaimed bituminous pavement cold-repairing material finished product.
CN201811174543.XA 2018-10-09 2018-10-09 A kind of high-performance reclaimed bituminous pavement cold-repairing material and preparation method thereof Pending CN109534722A (en)

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CN110436822A (en) * 2019-09-09 2019-11-12 广州市市政工程维修处 A kind of road surface repair materials and preparation method thereof, a kind of method for repairing road surface
CN111500078A (en) * 2020-05-11 2020-08-07 四川快马重工机械有限公司 Oily cold patch asphalt and preparation process thereof
CN111732370A (en) * 2020-06-28 2020-10-02 江苏天诺环境工程技术开发有限公司 High-performance cold-patch material based on old asphalt pavement milling material and preparation method thereof
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CN110436822A (en) * 2019-09-09 2019-11-12 广州市市政工程维修处 A kind of road surface repair materials and preparation method thereof, a kind of method for repairing road surface
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CN111500078A (en) * 2020-05-11 2020-08-07 四川快马重工机械有限公司 Oily cold patch asphalt and preparation process thereof
CN111732370A (en) * 2020-06-28 2020-10-02 江苏天诺环境工程技术开发有限公司 High-performance cold-patch material based on old asphalt pavement milling material and preparation method thereof
CN114426412A (en) * 2020-10-29 2022-05-03 中国石油化工股份有限公司 Asphalt pavement sealing material and preparation method and application thereof
CN115418109A (en) * 2022-10-12 2022-12-02 广西兴尚市政工程有限公司 Regenerated asphalt pavement and preparation method thereof

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Application publication date: 20190329