CN109526717A - A kind of plant growing box and its plant replacing options for water process - Google Patents

A kind of plant growing box and its plant replacing options for water process Download PDF

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Publication number
CN109526717A
CN109526717A CN201811434823.XA CN201811434823A CN109526717A CN 109526717 A CN109526717 A CN 109526717A CN 201811434823 A CN201811434823 A CN 201811434823A CN 109526717 A CN109526717 A CN 109526717A
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cabinet
plant
parts
water process
row
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CN109526717B (en
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童年
童福良
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G31/00Soilless cultivation, e.g. hydroponics
    • A01G31/02Special apparatus therefor
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/02Receptacles, e.g. flower-pots or boxes; Glasses for cultivating flowers
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • C01B32/198Graphene oxide
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/02Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
    • C03B37/025Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor from reheated softened tubes, rods, fibres or filaments, e.g. drawing fibres from preforms
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00Fibre or filament compositions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/004Additives being defined by their length
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

Abstract

The invention belongs to environmental technology fields, more particularly to a kind of plant growing box for water process, the plantation group is made of multiple cabinets arranged in arrays, the cabinet includes rectangle frame, the rectangle frame upper surface, which is each side fixed between two adjacent cabinets of each row of annulus, is equipped with a retaining ring, the retaining ring be located on the annulus of two neighboring cabinet, the rectangle frame front end face is equipped with semi-ring, the rectangle frame front end face of each row is equipped with a cross bar, the cross bar both ends are separately fixed at river two sides, the semi-ring is hung on cross bar, the rectangle frame lower end surface is fixedly installed with the coaming plate for surrounding rectangular frame, the coaming plate lower end surface is equipped with bottom plate, several through-holes are offered on the coaming plate and bottom plate.The purpose is to: solve the problems, such as existing water plant replacement trouble.

Description

A kind of plant growing box and its plant replacing options for water process
Technical field
The invention belongs to environmental technology fields, and in particular to a kind of to replace for the plant growing box of water process and its plant Method.
Background technique
Water environment is one of fundamental of composing environment, is the important place that human society is depended on for existence and development, It is the field by Human impact and destruction most serious.The pollution and destruction of water environment have become the main environmental problem in the world today One of.
Water quality monitoring, which refers to, carries out unified timing or not to chemical substance, suspended matter, bed mud and the aquatic ecosystem in water The detection work of timing, water quality monitoring play a significant role in terms of safeguarding water environment health.
Phytoremediation technology refers to the indigenous microorganism collective effect by green plants and its rhizosphere, realizes to environment dirt The drop of dye is removed, and is a kind of current newer Treatment process in situ, and dominant mechanism is exactly to pass through plant and its micro- life of rhizosphere original inhabitants The metabolic activity of object absorbs the pollutant in environment, is accumulated or Degradation and Transformation.
But currently with phytoremediation water environment, even if find some plants have reached absorb saturation state or It is dead, it when needing replacing plant, needs to be lauched and pull out one by one, it is very inconvenient that replacement is got up.
Summary of the invention
The purpose of the present invention is: a kind of plant growing box for water process and its plant replacing options are intended to provide, are used To solve the problems, such as existing water plant replacement trouble.
To realize the above-mentioned technical purpose, The technical solution adopted by the invention is as follows:
A kind of plant growing box for water process, including being laterally placed in plantation group in river, the plantation group by Multiple cabinets arranged in arrays are constituted, and the cabinet includes rectangle frame, and each side fixation is set for the rectangle frame upper surface A retaining ring is equipped between two cabinets for having each row of annulus adjacent, the retaining ring be located in two neighboring cabinet On annulus, the rectangle frame front end face is equipped with semi-ring, and the rectangle frame front end face of each row is equipped with a cross bar, the cross Bar both ends are separately fixed at river two sides, and the semi-ring is hung on cross bar, and the rectangle frame lower end surface, which is fixedly installed with, to be used for The coaming plate of rectangular frame is surrounded, the coaming plate lower end surface is equipped with bottom plate, offers several through-holes on the coaming plate and bottom plate.
Further, the bottom plate right side is hinged in coaming plate right side, and the bottom plate left side is equipped with hook, the coaming plate Left side lower part is equipped with escape groove.The design of such structure, connect bottom plate left part with coaming plate by linking up with, bottom plate right part with enclose Plate is hinged, is fixed on bottom plate on coaming plate, when with changing plant, it is only necessary to hook be removed from coaming plate, work of the bottom plate in gravity With lower overturning, it can make to be planted in the intracorporal water plant of case and fall, after falling, hang up hook again, then fill in cabinet New water plant, it is easy to use;The design of escape groove makes bottom plate left end when pushing up, and is unlikely to be hindered by coaming plate Gear.
Further, the retaining ring includes the body of falling C-shaped ring and connecting rod, the right side free end hinge of the connecting rod and the body of falling C-shaped ring It connects, connecting rod left end lateral surface is equipped with external screw thread, is arranged with thread bush on the connecting rod.Such structure design, passes through spiral shell Line set matches with the external screw thread on connecting rod, in fixed connecting rod, by rotating thread bush, thread bush a part is made to be located at screw thread It puts on, a part is located at the mode on the free end on the left of the body of falling C-shaped ring, connecting rod is fastened on the body of falling C-shaped ring, structure letter It is single, it is easy to use.
Further, the corner location of the coaming plate is longitudinally equipped with support plate.Such structure design, is supported by support plate Coaming plate enhances the structural strength of coaming plate.
Invention by adopting the above technical scheme, when in use, plantation is for administering Ecology in cabinet, and passes through and determine The mode of phase replacement water plant guarantees the fresh and alive of plant, and the present invention is changed by the structure and arrangement of cabinet, is made The replacement of water plant is more convenient.
Further, cabinet raw material includes PP, PE, modified graphene oxide and the staple fiber containing fertilizer.
Further, cabinet includes following mass parts raw material:
250-400 parts of PP, PE waste plastic, 30-50 parts of maleic anhydrides, 20-30 parts of chitosans, 5 parts of antioxidants, 5 parts Stabilizer, 5-7 part dispersing agent, 8-10 parts of coupling agents, 50-60 parts of modified graphene oxides, 20-30 parts of staple fibers, 15-20 containing fertilizer Part crosslinking agent, 15-20 parts of defoaming agents.
The raw material of cabinet includes waste and old PP, PE plastics, modified graphene oxide and the staple fiber containing fertilizer, modified graphite oxide Alkene has stronger toughness and intensity, and has certain hydrophilic ability, waste and old PP, PE material is utilized again not only environmentally friendly Can also save resource, cabinet long period of soaking in water, will be slowly released containing nitrogenous fertilizer, the phosphate fertilizer in fertile staple fiber, with The nutrition that plant lacks in water harnessing is solved, the trouble thrown and spread nutritious fertilizer, and cabinet lighter weight are avoided, there is no Plant is submerged in water in growth process.
Further, the preparation step containing fertile staple fiber is as follows:
By phosphorus pentoxide carry out preliminary drying, then weigh sodium dihydrogen phosphate, boric acid, sodium carbonate, potassium carbonate, calcium carbonate, Magnesium carbonate crushing, silica, are uniformly mixed with phosphorus pentoxide, mixing are put into pre-burning 2- in 250-350 DEG C of Muffle furnace 3h is added diatomite, chitosan, is put into molten sintering in 500-600 DEG C of Muffle furnace, obtains phosphate glass, by phosphate Glass is cooled to 100-200 DEG C, and nitrogenous fertilizer, phosphate fertilizer, polyurethane, rosin is added, and is uniformly mixed, is put into 300-350 DEG C of Muffle furnace weight Molten 5-8min, glass metal is poured into and obtains glass bar in mold, is put into 100-180 DEG C of Muffle furnace the 30- that anneals after cooling Glass bar is stretched after 40min, the obtained phosphate glass fibre containing nitrogenous fertilizer, phosphate fertilizer, is cut into 3-4mm containing the short fibre of fertilizer Dimension.
The chemical stability of phosphate glass is poorer than silicate glass, can be made into slow-releasing phosphate glass with this property Glass, slow-releasing phosphate glass have excellent sustained release performance, can by adjusting component come control its in water dissolution speed Rate accurately releases the substance in glass within long period of time, concentration needed for keeping aqueous solution for a long time, will Nitrogenous fertilizer, phosphate fertilizer are added into the preparation process of phosphate glass, and wire drawing is prepared into the staple fiber containing fertilizer, in water slow release During between fertilizer release for providing the nitrogenous fertilizer of plant, phosphate fertilizer for a long time.
Further, the preparation step of the modified graphene oxide includes:
Potassium peroxydisulfate, phosphorus pentoxide mixture are dissolved in after the concentrated sulfuric acid, graphite is added, taken out and clean, the addition concentrated sulfuric acid, The mixed solution of concentrated hydrochloric acid solution and polyacrylamide is added in hydrogenperoxide steam generator, stirring, subsequent centrifugal filtration under oil bath, Back flow reaction is carried out, ultrasonic disperse obtains modified graphene oxide after cleaning.
The active force of graphene oxide layer and interlayer weakens because interlamellar spacing increases, and modified graphene oxide has single Atomic structure and surface have hydrophilic oxygen-containing group to occur, and have stronger polarity, the hydrogen bond easy to form between hydrone, make its There is preferable dispersibility in water, dispersion can be mixed together with other solvents in the solution.
Further, it need to be maintained under the conditions of 0 DEG C of ice-water bath when the hydrogenperoxide steam generator is added.Avoid hydrogen peroxide with it is dense Sulfuric acid causes system temperature excessively high when mixing.
A kind of plant replacing options of the above-mentioned plant growing box for water process, comprising the following steps:
1) it, is operated in river with respect to the cabinet of two sides while adjacent two row, by the cultivation box of adjacent two row point It does not pull round about, most marginal cabinet is pulled out river;
2), river two sides operate simultaneously, and the cabinet for being drawn out river is removed from plantation group, and planted in cabinet Plant removes cabinet, then plants into new plant;
3), kind there is the cabinet of new plant be hung on the cabinet end of another row, and cross bar is hung on by semi-ring On, i.e., the cabinet removed from odd number row is hung on by retaining ring the end of the plantation group of even number row, horizontal from even number The cabinet removed on column is hung on the end of the plantation group of odd number row by retaining ring, while is hung on semi-ring on cross bar;
4) step 1)~step 3), is repeated, until the plant in the plantation group of entire row is all replaced;
5) it, is moved to next sequence plantation group, repeats step 1)~step 4), until having replaced all plants needed replacing Object.
Detailed description of the invention
The present invention can be further illustrated by the nonlimiting examples that attached drawing provides;
Fig. 1 is that the present invention is a kind of for the plant growing box of water process and its structural representation of plant replacing options embodiment Figure;
Fig. 2 is cultivation box in a kind of plant growing box and its plant replacing options embodiment for water process of the present invention Structural schematic diagram;
Fig. 3 is the knot of retaining ring in a kind of plant growing box and its plant replacing options embodiment for water process of the present invention Structure schematic diagram;
Main element symbol description is as follows:
Cabinet 1, rectangle frame 2, annulus 21, semi-ring 22, retaining ring 3, the body of falling C-shaped ring 31, connecting rod 32, thread bush 33, cross bar 4, Coaming plate 51, bottom plate 52, hook 53.
Specific embodiment
In order to make those skilled in the art that the present invention may be better understood, with reference to the accompanying drawings and examples to this hair Bright technical solution further illustrates.
Embodiment one:
As shown in FIG. 1 to 3, a kind of plant growing box for water process of the invention, including laterally it is placed in river In plantation group, plantation group is made of multiple cabinets 1 arranged in arrays, and cabinet 1 includes rectangle frame 2, and 2 upper surface of rectangle frame is left Right two sides, which are respectively fixed between two adjacent cabinets 1 of each row of annulus 21, is equipped with a retaining ring 3, and retaining ring 3, which is buckled, to be set On the annulus 21 of two neighboring cabinet 1,2 front end face of rectangle frame is equipped with semi-ring 22, and 2 front end face of rectangle frame of each row is equipped with A piece cross bar 4,4 both ends of cross bar are separately fixed at river two sides, and semi-ring 22 is hung on cross bar 4, the fixed peace in 2 lower end surface of rectangle frame Equipped with the coaming plate 51 for surrounding rectangular frame, 51 lower end surface of coaming plate is equipped with bottom plate 52, offers on coaming plate 51 and bottom plate 52 Several through-holes.
52 right side of bottom plate is hinged in 51 right side of coaming plate, and 52 left side of bottom plate is equipped with hook 53, under 51 left side of coaming plate Portion is equipped with escape groove.The design of such structure, connect 52 left part of bottom plate with coaming plate 51 by hook 53,52 right part of bottom plate with enclose Plate 51 is hinged, is fixed on bottom plate 52 on coaming plate 51, when with changing plant, it is only necessary to hook 53 be removed from coaming plate 51, bottom plate 52 overturn under gravity, and the water plant being planted in cabinet 1 can be made to fall, and after falling, hang up hook 53 again, New water plant is filled in cabinet 1 again, it is easy to use;The design of escape groove is pushing up 52 left end of bottom plate When, it is unlikely to be stopped by coaming plate 51.
Retaining ring 3 includes the body of falling C-shaped ring 31 and connecting rod 32, and connecting rod 32 and the right side free end of the body of falling C-shaped ring 3 are hinged, connecting rod 32 left end lateral surfaces are equipped with external screw thread, are arranged with thread bush 33 on connecting rod 32.Such structure design, by thread bush 33 and even External screw thread on bar 32 matches, and in fixed connecting rod 32, by rotating thread bush 33, a part of thread bush 33 is made to be located at screw thread On set 33, a part is located at the mode on the free end in 31 left side of the body of falling C-shaped ring, and connecting rod 32 is fastened on the body of falling C-shaped ring 31, Structure is simple, easy to use.
The corner location of coaming plate 51 is longitudinally equipped with support plate.Such structure design, supports coaming plate 51 by support plate, increases The structural strength of strong coaming plate 51.
Embodiment two: the preparation of slow release fertilizer cabinet 1 one
S1 contains fertile staple fiber:
Phosphorus pentoxide easy to absorb moisture, need to by 200 mass parts phosphorus pentoxides in 100 DEG C of baking oven preliminary drying 10min, claim Take 400 mass parts sodium dihydrogen phosphates, 50 mass parts boric acid, 100 mass parts sodium carbonate, 100 mass parts potassium carbonate, 150 mass parts Calcium carbonate, the crushing of 100 mass parts magnesium carbonate, 50 mass parts silica, are uniformly mixed with phosphorus pentoxide, mixing are put into Pre-burning 2h in 250 DEG C of Muffle furnace, be added 50 mass parts diatomites, 50 mass parts chitosans, be put into 500 DEG C of Muffle furnace into Molten sintering obtains phosphate glass, and phosphate glass is cooled to 100 DEG C, 80 mass parts nitrogenous fertilizer, 80 mass parts phosphorus are added Fertilizer, 20 mass parts polyurethane, 10 mass parts rosin make to mix in glass and nitrogenous fertilizer, phosphate fertilizer as adhesive, wherein phosphorus Fertilizer selects calcium magnesium phosphate, and nitrogenous fertilizer selects ammonium chloride to be put into 300 DEG C of Muffle furnace remelting 5min after mixing, glass metal is poured into Glass bar is obtained in mold, is put into 100 DEG C of Muffle furnace the 30min that anneals after cooling, then glass bar is stretched, is obtained The phosphate glass fibre containing nitrogenous fertilizer, phosphate fertilizer be cut into 3mm and contain fertile staple fiber;
S2 modified graphene oxide:
10 mass parts potassium peroxydisulfates, 5 mass parts phosphorus pentoxide mixtures are dissolved in the concentrated sulfuric acid, in 70 DEG C of water bath conditions Under be put into 300 mass parts graphite, magnetic agitation 5h, taking-up is cooled to room temperature, deionized water washing, spontaneously dry, will be dried Graphite in the middle addition concentrated sulfuric acid, under the conditions of 0 DEG C of ice-water bath be added 65wt% hydrogenperoxide steam generator, be added after being stirred to react 1h 2-3 DEG C of deionized water stirs centrifugal filtration after 1h at normal temperature, adds in the case where 60 DEG C of baking ovens toast 30min, then 80 DEG C of oil baths The mixed solution for entering concentrated hydrochloric acid aqueous solution and polyacrylamide carries out back flow reaction, carries out ultrasonic disperse 3h after the reaction was completed, cold But it to room temperature, filters, wash, be dried to obtain modified graphene oxide;
The preparation of S3 cabinet 1:
It will be immersed in ethanol solution after PP, PE waste plastic chopping of 400 mass parts recycling, impregnate for 24 hours, use deionization Water cleans up, and is heated to 100 DEG C after air-drying, and reaches that 50 mass parts maleic anhydrides, 30 mass parts shells are added after molten condition is poly- Sugar, 5 mass parts antioxidants, 5 mass parts stabilizers, 7 mass parts dispersing agents, 10 mass parts coupling agents, stir evenly, will be waste and old Plastic ageing is accelerated after plastic heating to molten condition, the mechanical property of polymer is decreased obviously, so antioxygen is added Agent and stabilizer reduce the degradation of material, add 55 mass parts modified graphenes, 300 DEG C of Muffles are put into after ultrasonic disperse 3h Furnace takes out after 30min, after being cooled to 150 DEG C, 25 mass parts is contained fertile staple fiber, 20 mass parts crosslinking agents, 20 mass parts and are defoamed Agent mixing, which is added, is placed on 3h in high-speed mixer, mixing speed 300r/min, carries out wire drawing after mixing evenly, silk width is Obtained silk is compiled into cabinet 1 with a thickness of 1mm by 5mm.
Embodiment three:
S1 contains fertile staple fiber:
Phosphorus pentoxide easy to absorb moisture, need to by 150 mass parts phosphorus pentoxides in 100 DEG C of baking oven preliminary drying 8min, claim Take 450 mass parts sodium dihydrogen phosphates, 70 mass parts boric acid, 80 mass parts sodium carbonate, 80 mass parts potassium carbonate, 130 mass parts carbon Sour calcium, the crushing of 130 mass parts magnesium carbonate, 30 mass parts silica, are uniformly mixed with phosphorus pentoxide, mixing are put into 250 DEG C Muffle furnace in pre-burning 2h, 40 mass parts diatomites, 40 mass parts chitosans are added, are put into 550 DEG C of Muffle furnace into molten Melt sintering, obtain phosphate glass, phosphate glass is cooled to 150 DEG C, be added 80 mass parts nitrogenous fertilizer, 80 mass parts phosphate fertilizer, 17 mass parts polyurethane, 10 mass parts rosin make to mix in glass and nitrogenous fertilizer, phosphate fertilizer as adhesive, wherein phosphate fertilizer Calcium magnesium phosphate is selected, nitrogenous fertilizer selects ammonium chloride to be put into 300 DEG C of Muffle furnace remelting 6min after mixing, glass metal is poured into mould Glass bar is obtained in tool, is put into 120 DEG C of Muffle furnace the 32min that anneals after cooling, then glass bar is stretched, is obtained Phosphate glass fibre containing nitrogenous fertilizer, phosphate fertilizer is cut into 4mm and contains fertile staple fiber;
S2 modified graphene oxide:
7 mass parts potassium peroxydisulfates, 5 mass parts phosphorus pentoxide mixtures are dissolved in the concentrated sulfuric acid, in 70 DEG C of water bath conditions Under be put into 250 mass parts graphite, magnetic agitation 5h, taking-up is cooled to room temperature, deionized water washing, spontaneously dry, will be dried Graphite in the middle addition concentrated sulfuric acid, under the conditions of 0 DEG C of ice-water bath be added 65wt% hydrogenperoxide steam generator, be added after being stirred to react 1h 2-3 DEG C of deionized water stirs centrifugal filtration after 1h at normal temperature, adds in the case where 60 DEG C of baking ovens toast 30min, then 80 DEG C of oil baths The mixed solution for entering concentrated hydrochloric acid aqueous solution and polyacrylamide carries out back flow reaction, carries out ultrasonic disperse 3h after the reaction was completed, cold But it to room temperature, filters, wash, be dried to obtain modified graphene oxide;
The preparation of S3 cabinet 1:
It will be immersed in ethanol solution after PP, PE waste plastic chopping of 300 mass parts recycling, impregnate for 24 hours, use deionization Water cleans up, and is heated to 100 DEG C after air-drying, and reaches that 40 mass parts maleic anhydrides, 25 mass parts shells are added after molten condition is poly- Sugar, 5 mass parts antioxidants, 5 mass parts stabilizers, 5 mass parts dispersing agents, 10 mass parts coupling agents, stir evenly, will be waste and old Plastic ageing is accelerated after plastic heating to molten condition, the mechanical property of polymer is decreased obviously, so antioxygen is added Agent and stabilizer reduce the degradation of material, add 60 mass parts modified graphenes, 300 DEG C of Muffles are put into after ultrasonic disperse 3h Furnace takes out after 30min, after being cooled to 150 DEG C, 30 mass parts is contained fertile staple fiber, 17 mass parts crosslinking agents, 17 mass parts and are defoamed Agent mixing, which is added, is placed on 3h in high-speed mixer, mixing speed 400r/min, carries out wire drawing after mixing evenly, silk width is Obtained silk is compiled into cabinet 1 with a thickness of 2mm by 10mm.
Example IV:
S1 contains fertile staple fiber:
Phosphorus pentoxide easy to absorb moisture, need to by 100 mass parts phosphorus pentoxides in 100 DEG C of baking oven preliminary drying 5min, claim Take 300 mass parts sodium dihydrogen phosphates, 50 mass parts boric acid, 60 mass parts sodium carbonate, 60 mass parts potassium carbonate, 100 mass parts carbon Sour calcium, the crushing of 80 mass parts magnesium carbonate, 15 mass parts silica, are uniformly mixed with phosphorus pentoxide, mixing are put into 250 DEG C Muffle furnace in pre-burning 2h, be added 30 mass parts diatomites, 30 mass parts chitosans, be put into 600 DEG C of Muffle furnace into melting Sintering, obtains phosphate glass, and phosphate glass is cooled to 100 DEG C, 60 mass parts nitrogenous fertilizer, 60 mass parts phosphate fertilizer, 15 are added Mass parts polyurethane, 5 mass parts rosin make to mix in glass and nitrogenous fertilizer, phosphate fertilizer as adhesive, wherein phosphate fertilizer is selected Calcium magnesium phosphate, nitrogenous fertilizer select ammonium chloride to be put into 330 DEG C of Muffle furnace remelting 7min after mixing, glass metal is poured into mold Obtain glass bar, the 35min that anneals be put into 130 DEG C of Muffle furnace after cooling and stretches glass bar, obtain containing nitrogenous fertilizer, The phosphate glass fibre of phosphate fertilizer is cut into 4mm and contains fertile staple fiber;
S2 modified graphene oxide:
5 mass parts potassium peroxydisulfates, 5 mass parts phosphorus pentoxide mixtures are dissolved in the concentrated sulfuric acid, in 70 DEG C of water bath conditions Under be put into 200 mass parts graphite, magnetic agitation 5h, taking-up is cooled to room temperature, deionized water washing, spontaneously dry, will be dried Graphite in the middle addition concentrated sulfuric acid, under the conditions of 0 DEG C of ice-water bath be added 55wt% hydrogenperoxide steam generator, be added after being stirred to react 1h 2-3 DEG C of deionized water stirs centrifugal filtration after 1h at normal temperature, adds in the case where 60 DEG C of baking ovens toast 30min, then 80 DEG C of oil baths The mixed solution for entering concentrated hydrochloric acid aqueous solution and polyacrylamide carries out back flow reaction, carries out ultrasonic disperse 3h after the reaction was completed, cold But it to room temperature, filters, wash, be dried to obtain modified graphene oxide;
The preparation of S3 cabinet 1:
It will be immersed in ethanol solution after PP, PE waste plastic chopping of 250 mass parts recycling, impregnate for 24 hours, use deionization Water cleans up, and is heated to 100 DEG C after air-drying, and reaches that 30 mass parts maleic anhydrides, 20 mass parts shells are added after molten condition is poly- Sugar, 5 mass parts antioxidants, 5 mass parts stabilizers, 5 mass parts dispersing agents, 8 mass parts coupling agents, stir evenly, will be waste and old Plastic ageing is accelerated after plastic heating to molten condition, the mechanical property of polymer is decreased obviously, so antioxygen is added Agent and stabilizer reduce the degradation of material, add 50 mass parts modified graphenes, 300 DEG C of Muffles are put into after ultrasonic disperse 3h Furnace takes out after 30min, after being cooled to 150 DEG C, 20 mass parts is contained fertile staple fiber, 15 mass parts crosslinking agents, 15 mass parts and are defoamed Agent mixing, which is added, is placed on 3h in high-speed mixer, mixing speed 500r/min, carries out wire drawing after mixing evenly, silk width is Obtained silk is compiled into cabinet 1 with a thickness of 2mm by 15mm.
A kind of plant replacing options of the above-mentioned plant growing box for water process, comprising the following steps:
1) it, is operated in river with respect to the cabinet 1 of two sides while adjacent two row, by the cultivation box 1 of adjacent two row It pulls round about respectively, most marginal cabinet 1 is pulled out river;
2), river two sides operate simultaneously, and the cabinet 1 for being drawn out river is removed from plantation group, and plants in cabinet 1 Plant remove cabinet 1, then plant into new plant;
3), kind there is the cabinet 1 of new plant be hung on 1 end of cabinet of another row, and is hung on by semi-ring 22 On cross bar 4, i.e., the cabinet 1 removed from odd number row by retaining ring 3 be hung on even number row plantation group end, from The cabinet 1 removed in even number row is hung on the end of the plantation group of odd number row by retaining ring 3, while is hung on semi-ring 22 On cross bar 4;
4) step 1)~step 3), is repeated, until the plant in the plantation group of entire row is all replaced;
5) it, is moved to next sequence plantation group, repeats step 1)~step 5), until having replaced all plants needed replacing Object.
In the present embodiment, when in use, plantation is for administering Ecology in cabinet 1, and it is aquatic to pass through periodic replacement The mode of plant guarantees the fresh and alive of plant, and the present invention is changed by the structure and arrangement of cabinet 1, makes water plant It replaces more convenient.
A kind of plant growing box and its plant replacing options for water process provided by the invention has been carried out in detail above It is thin to introduce.The explanation of specific embodiment is merely used to help understand method and its core concept of the invention.It should be pointed out that for For those skilled in the art, without departing from the principle of the present invention, if can also be carried out to the present invention Dry improvement and modification, these improvements and modifications also fall within the scope of protection of the claims of the present invention.

Claims (10)

1. a kind of plant growing box for water process, it is characterised in that: described including the plantation group being laterally placed in river Plantation group is made of multiple cabinets (1) arranged in arrays, and the cabinet (1) includes rectangle frame (2), on the rectangle frame (2) End face, which is each side fixed between two adjacent cabinets (1) of each row of annulus (21), is equipped with a retaining ring (3), the retaining ring (3) be located on the annulus (21) of two neighboring cabinet (1), and rectangle frame (2) front end face is equipped with semi-ring (22), the rectangle frame (2) front end face of each row is equipped with a cross bar (4), and cross bar (4) both ends are separately fixed at river Road two sides, the semi-ring (22) are hung on cross bar (4), and rectangle frame (2) lower end surface is fixedly installed with for surrounding rectangle The coaming plate (51) of frame, coaming plate (51) lower end surface are equipped with bottom plate (52), open up on the coaming plate (51) and bottom plate (52) There are several through-holes.
2. a kind of plant growing box for water process according to claim 1, it is characterised in that: the bottom plate (52) is right End face is hinged in coaming plate (51) right side, and bottom plate (52) left side, which is equipped with, links up with (53), under coaming plate (51) left side Portion is equipped with escape groove.
3. a kind of plant growing box for water process according to claim 2, it is characterised in that: retaining ring (3) packet The body of falling C-shaped ring (31) and connecting rod (32) are included, the connecting rod (32) and the right side free end of the body of falling C-shaped ring (3) are hinged, the connecting rod (32) left end lateral surface is equipped with external screw thread, is arranged with thread bush (33) on the connecting rod (32).
4. a kind of plant growing box for water process according to claim 3, it is characterised in that: the coaming plate (51) Corner location is longitudinally equipped with support plate.
5. a kind of plant growing box for water process according to claim 4, it is characterised in that: the cabinet (1) is Plastic box, cabinet (1) raw material include PP, PE, modified graphene oxide and the staple fiber containing fertilizer.
6. a kind of plant growing box for water process according to claim 5, it is characterised in that: cabinet (1) packet Include following mass parts raw material:
250-400 parts of PP, PE waste plastic, 30-50 parts of maleic anhydrides, 20-30 parts of chitosans, 5 parts of antioxidants, 5 parts of stabilizations Agent, 5-7 parts of dispersing agents, 8-10 parts of coupling agents, 50-60 parts of modified graphene oxides, the 20-30 parts of staple fibers containing fertilizer, 15-20 parts of friendships Join agent, 15-20 parts of defoaming agents.
7. a kind of plant growing box for water process according to claim 6, it is characterised in that: described containing fertile staple fiber Preparation step it is as follows:
Phosphorus pentoxide is being subjected to preliminary drying, is then weighing sodium dihydrogen phosphate, boric acid, sodium carbonate, potassium carbonate, calcium carbonate, carbonic acid Magnesium powder is broken, silica, is uniformly mixed with phosphorus pentoxide, mixing is put into pre-burning 2-3h in 250-350 DEG C of Muffle furnace, is added Enter diatomite, chitosan, is put into molten sintering in 500-600 DEG C of Muffle furnace, obtains phosphate glass, phosphate glass is cold But 100-200 DEG C is arrived, nitrogenous fertilizer, phosphate fertilizer, polyurethane, rosin is added, is uniformly mixed, is put into 300-350 DEG C of Muffle furnace remelting 5- Glass metal is poured into and obtains glass bar in mold by 8min, after the 30-40min that anneals is put into 100-180 DEG C of Muffle furnace after cooling Glass bar is stretched, the obtained phosphate glass fibre containing nitrogenous fertilizer, phosphate fertilizer, is cut into 3-4mm and contains fertile staple fiber.
8. a kind of plant growing box for water process according to claim 7, it is characterised in that: the modified oxidized stone The preparation step of black alkene includes:
Potassium peroxydisulfate, phosphorus pentoxide mixture are dissolved in after the concentrated sulfuric acid, graphite is added, taken out and clean, the concentrated sulfuric acid, peroxide is added Change hydrogen solution, stirring, the mixed solution of concentrated hydrochloric acid solution and polyacrylamide is added in subsequent centrifugal filtration under oil bath, carries out Back flow reaction, ultrasonic disperse obtain modified graphene oxide after cleaning.
9. a kind of plant growing box for water process according to claim 8, it is characterised in that: the hydrogen peroxide is molten Liquid need to be maintained under the conditions of 0 DEG C of ice-water bath when being added.
10. a kind of plant replacing options for the plant growing box of water process, including following step as claimed in claim 9 It is rapid:
1) it, is operated in river with respect to the cabinet (1) of two sides while adjacent two row, by the cultivation box (1) of adjacent two row It pulls round about respectively, most marginal cabinet (1) is pulled out river;
2), river two sides operate simultaneously, and the cabinet (1) for being drawn out river is removed from plantation group, and the plantation in cabinet (1) Plant remove cabinet (1), then plant into new plant;
3), kind there is the cabinet (1) of new plant be hung on cabinet (1) end of another row, and is hung by semi-ring (22) On cross bar (4), i.e., the cabinet (1) removed from odd number row is hung on by retaining ring (3) the plantation group of even number row End is hung on the cabinet (1) removed from even number row by retaining ring (3) end of the plantation group of odd number row, simultaneously It is hung on semi-ring (22) on cross bar (4);
4) step 1)~step 3), is repeated, until the plant in the plantation group of entire row is all replaced;
5) it, is moved to next sequence plantation group, repeats step 1)~step 4), until having replaced all plants needed replacing.
CN201811434823.XA 2018-11-28 2018-11-28 Plant planting box for water treatment and plant replacement method thereof Active CN109526717B (en)

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