CN109518846A - Perovskite glass curtain wall with flexible connection structure - Google Patents
Perovskite glass curtain wall with flexible connection structure Download PDFInfo
- Publication number
- CN109518846A CN109518846A CN201811078045.5A CN201811078045A CN109518846A CN 109518846 A CN109518846 A CN 109518846A CN 201811078045 A CN201811078045 A CN 201811078045A CN 109518846 A CN109518846 A CN 109518846A
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- CN
- China
- Prior art keywords
- curtain wall
- aluminium alloy
- layer
- pressing plate
- perovskite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B2/00—Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
- E04B2/88—Curtain walls
- E04B2/96—Curtain walls comprising panels attached to the structure through mullions or transoms
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B2/00—Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
- E04B2/88—Curtain walls
- E04B2/96—Curtain walls comprising panels attached to the structure through mullions or transoms
- E04B2/967—Details of the cross-section of the mullions or transoms
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/30—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Hybrid Cells (AREA)
Abstract
The invention provides a perovskite glass curtain wall with a flexible connection structure, and aims to solve the problems that a hidden frame glass curtain wall aluminum alloy pressing plate and a glass auxiliary frame are in hard contact, and two metal surfaces are easy to corrode, so that the service life of a curtain wall section bar is influenced, and the service life of the curtain wall is influenced; the curtain wall body and the curtain wall framework are fixed together through the aluminum alloy pressing plate and the aluminum alloy glass attached frame, and an aluminum alloy pressing plate adhesive tape and an aluminum alloy glass attached frame are arranged between the aluminum alloy pressing plate and the curtain wall framework. The invention has the advantages that the aluminum alloy pressing plate of the hidden frame glass curtain wall is connected with the adhesive tape, the hard contact between the aluminum alloy pressing plate and the glass auxiliary frame is avoided, the energy is saved, the environment is protected, 2, the notch 3 is designed on the aluminum alloy pressing plate, the aluminum alloy pressing plate is installed discontinuously, and the material is saved.
Description
Technical field:
The present invention relates to curtain wall mounting technique field, specifically one kind, which can be avoided two metal surface parts and be easy to produce corrosion, is asked
The perovskite glass curtain wall with flexible connecting structure of topic.
Background technique:
Hard contact is generated between concealed frame glass curtain wall aluminium alloy pressing plate and glass auxiliary frame, is easily corroded between two metal coverings,
To influence the service life of curtain wall profiles, the service life of curtain wall is influenced.
Summary of the invention
The present invention provide it is a kind of can be avoided two metal surface parts be easy to produce etching problem with flexible connecting structure
Perovskite glass curtain wall.
The object of the present invention is achieved like this: the curtain wall ontology and Curtain wall frame pass through aluminium alloy pressing plate and aluminium alloy
Glass auxiliary frame is fixed together, and aluminium alloy pressing plate adhesive tape is provided between aluminium alloy pressing plate and Curtain wall frame and aluminium alloy glass is attached
Frame, aluminium alloy pressing plate adhesive tape are inserted into aluminium alloy pressing plate, are provided with sealant between aluminium alloy glass auxiliary frame and curtain wall ontology, and two
Weather proofing sealant and foam glue strip, the outer surface of the weather proofing sealant layer and hollow tempering glass are provided between block curtain wall ontology
The outer surface of glass is provided with perovskite generating battery.
The perovskite generating battery includes core and clad, core including conductive metal sheet, and the core is iron
Piece, the external clad of core are one of copper, zinc, lead, tin, aluminium, be provided with outside the external clad of the core and
External coating layer material identical metal oxide layer is sequentially depositing calcium titanium ore bed, containing with a thickness of 20nm on metal oxide layer
Have lithium trifluoromethanesulfonimide and pyridine compounds and their composition and purity be 80% or more copper metal anode layer.
The conductive metal sheet, metal oxide layer, calcium titanium ore bed, with a thickness of 20nm contain lithium trifluoromethanesulfonimide
The copper metal anode layer that composition and purity with pyridine compounds and their are 80% or more constitutes perovskite generating battery.
Aluminium alloy pressing plate fixing bolt is provided on the aluminium alloy pressing plate corresponding position, aluminium alloy pressing plate fixing bolt
Nut is arranged in the slide groove of aluminium alloy munnion, the diameter phase of the notch and aluminium alloy pressing plate fixing bolt of the slide groove
Together.
The Curtain wall frame is made of aluminium alloy munnion and the horizontal frame of aluminium alloy, and skeleton is ' mouth ' font.
Aluminium alloy right-angle connector is additionally provided on the horizontal frame of aluminium alloy, the aluminium alloy right-angle connector is arranged in aluminium
The side of alloy horizontal frame end and aluminium alloy munnion.
It is an advantage of the invention that 1. concealed frame glass curtain wall aluminium alloy pressing plates add the connection type of adhesive tape, aluminium alloy pressing plate is avoided
The hard contact between glass auxiliary frame, energy conservation and environmental protection.
2. designing notch on aluminium alloy pressing plate.
3. discontinuous installs aluminium alloy pressing plate, material is saved.
The present invention also has the characteristics that structure is simple, easy to operate.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention；
Fig. 2 is the left view of Fig. 1.
Specific embodiment
Embodiment 1
Referring to Fig. 1 ~ 2, the curtain wall ontology 1 is fixed on Curtain wall frame 4 by aluminium alloy pressing plate 2 and aluminium alloy glass auxiliary frame 3
Together, aluminium alloy pressing plate adhesive tape 5 and aluminium alloy glass auxiliary frame, aluminium alloy pressing plate are provided between aluminium alloy pressing plate and Curtain wall frame
Adhesive tape is inserted into aluminium alloy pressing plate, is provided with sealant 6 between aluminium alloy glass auxiliary frame and curtain wall ontology, two pieces of curtain wall ontologies it
Between be provided with weather proofing sealant 7 and foam glue strip 8；The outer surface of the weather proofing sealant layer and the outer surface of hollow tempered glass
It is provided with perovskite generating battery.
The perovskite generating battery includes core and clad, core including conductive metal sheet, and the core is iron
Piece, the external clad of core are one of copper, zinc, lead, tin, aluminium, be provided with outside the external clad of the core and
External coating layer material identical metal oxide layer is sequentially depositing calcium titanium ore bed, containing with a thickness of 20nm on metal oxide layer
Have lithium trifluoromethanesulfonimide and pyridine compounds and their composition and purity be 80% or more copper metal anode layer.
The conductive metal sheet, metal oxide layer, calcium titanium ore bed, with a thickness of 20nm contain lithium trifluoromethanesulfonimide
The copper metal anode layer that composition and purity with pyridine compounds and their are 80% or more constitutes perovskite generating battery.
Aluminium alloy pressing plate fixing bolt 9, aluminium alloy pressing plate fixing bolt are provided on the aluminium alloy pressing plate corresponding position
Nut be arranged in the slide groove 10 of aluminium alloy munnion, the diameter of the notch of the slide groove and aluminium alloy pressing plate fixing bolt
It is identical.
The Curtain wall frame is made of aluminium alloy munnion and the horizontal frame of aluminium alloy, and skeleton is ' mouth ' font.
Aluminium alloy right-angle connector is additionally provided on the horizontal frame of aluminium alloy, the setting of aluminium alloy right-angle connector 11 exists
The side of aluminium alloy horizontal frame 12 end and aluminium alloy munnion 13.
The structure of the perovskite generating battery is to be followed successively by transparent conductive anode, honeycomb hole transport from top to bottom
Layer, calcium titanium ore bed, electronic interface layer, hole boundary layer, organic solar batteries layer, electron transfer layer and metallic cathode；It is above-mentioned
Perovskite battery the preparation method is as follows:
1) on the transparent conductive anode by acetone and washes of absolute alcohol using the extrusion coated technique of slit successively print with
Thermal annealing post-processing preparation honeycomb hole transmission layer, calcium titanium ore bed, electronic interface layer, hole boundary layer, organic solar electricity
Pond layer, electron transfer layer；
2) honeycomb hole transmission layer is to prepare poly- 3, the 4- ethylene dioxy of honeycomb as template by Properties of Polystyrene Nano Particles
Thiophene/poly styrene sulfonate (PEDOT:PSS) layer；
3) calcium titanium ore bed precursor solution is with PbI2 the and MAI mixed solution of 1:1 ratio；Use doping 5% polyurethane (PU)
Polyethoxy aziridine (PEIE) enhances the flexibility of laminated cell and guarantees charge transmission；
4) hole boundary layer is poly- [bis- (4- phenyl) (the 2,4,6- trimethylphenyl) for adulterating 5% high resiliency polystyrene (SBS)
Amine] i.e. PTAA
5) PTB7-Th that the concentration that organic solar batteries layer precursor solution mixed proportion is 1:1.5 is 13mg/ml with
FOIC；6) electron transfer layer is fullerene derivate PC61BM；
7) cathode of metal silver ion is had using vacuum coating technology preparation.
Claims (7)
1. having the perovskite glass curtain wall of flexible connecting structure, it includes: curtain wall ontology and Curtain wall frame, it is characterized in that: institute
It states curtain wall ontology and is fixed together with Curtain wall frame by aluminium alloy pressing plate and aluminium alloy glass auxiliary frame, aluminium alloy pressing plate and curtain wall
Aluminium alloy pressing plate adhesive tape and aluminium alloy glass auxiliary frame are provided between skeleton, aluminium alloy pressing plate adhesive tape is inserted into aluminium alloy pressing plate,
It is provided with sealant between aluminium alloy glass auxiliary frame and curtain wall ontology, is provided with weather proofing sealant and bubble between two pieces of curtain wall ontologies
Foam adhesive tape；The outer surface of the weather proofing sealant layer and the outer surface of hollow tempered glass are provided with perovskite generating battery.
2. the perovskite glass curtain wall according to claim 1 with flexible connecting structure, it is characterized in that: the perovskite
Generating battery includes core and clad, core including conductive metal sheet, and the core is iron plate, the external clad of core
For one of copper, zinc, lead, tin, aluminium, it is provided with outside the external clad of the core identical with external coating layer material
Metal oxide layer is sequentially depositing calcium titanium ore bed on metal oxide layer, contains lithium trifluoromethanesulfonimide with a thickness of 20nm
The copper metal anode layer that composition and purity with pyridine compounds and their are 80% or more.
3. the perovskite glass curtain wall according to claim 2 with flexible connecting structure, it is characterized in that: the conductive gold
Belong to piece, metal oxide layer, calcium titanium ore bed, the group containing lithium trifluoromethanesulfonimide and pyridine compounds and their with a thickness of 20nm
It closes object and purity and constitutes perovskite generating battery for 80% or more copper metal anode layer.
4. the perovskite glass curtain wall according to claim 1 with flexible connecting structure, it is characterized in that: the aluminium alloy
Aluminium alloy pressing plate fixing bolt is provided on pressing plate corresponding position, the nut setting of aluminium alloy pressing plate fixing bolt is perpendicular in aluminium alloy
In the slide groove of frame, the notch of the slide groove is identical as the diameter of aluminium alloy pressing plate fixing bolt.
5. the perovskite glass curtain wall according to claim 1 with flexible connecting structure, it is characterized in that: the curtain wall bone
Frame is made of aluminium alloy munnion and the horizontal frame of aluminium alloy, and skeleton is ' mouth ' font.
6. the perovskite glass curtain wall according to claim 3 with flexible connecting structure, it is characterized in that: the aluminium alloy
Aluminium alloy right-angle connector is additionally provided on horizontal frame, the aluminium alloy right-angle connector setting is closed in the horizontal frame end of aluminium alloy and aluminium
The side of golden munnion.
7. the perovskite glass curtain wall according to claim 1 with flexible connecting structure, it is characterized in that: the perovskite
The structure of generating battery is to be followed successively by transparent conductive anode, honeycomb hole transmission layer, calcium titanium ore bed, electronic interface from top to bottom
Layer, hole boundary layer, organic solar batteries layer, electron transfer layer and metallic cathode；The preparation method of above-mentioned perovskite battery
It is as follows:
1) on the transparent conductive anode by acetone and washes of absolute alcohol using the extrusion coated technique of slit successively print with
Thermal annealing post-processing preparation honeycomb hole transmission layer, calcium titanium ore bed, electronic interface layer, hole boundary layer, organic solar electricity
Pond layer, electron transfer layer；
2) honeycomb hole transmission layer is to prepare poly- 3, the 4- ethylene dioxy of honeycomb as template by Properties of Polystyrene Nano Particles
Thiophene/poly styrene sulfonate (PEDOT:PSS) layer；
3) calcium titanium ore bed precursor solution is with PbI2 the and MAI mixed solution of 1:1 ratio；Use doping 5% polyurethane (PU)
Polyethoxy aziridine (PEIE) enhances the flexibility of laminated cell and guarantees charge transmission；
4) hole boundary layer is poly- [bis- (4- phenyl) (the 2,4,6- trimethylphenyl) for adulterating 5% high resiliency polystyrene (SBS)
Amine] i.e. PTAA
5) PTB7-Th that the concentration that organic solar batteries layer precursor solution mixed proportion is 1:1.5 is 13mg/ml with
FOIC；6) electron transfer layer is fullerene derivate PC61BM；
7) cathode of metal silver ion is had using vacuum coating technology preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811078045.5A CN109518846A (en) | 2018-09-16 | 2018-09-16 | Perovskite glass curtain wall with flexible connection structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811078045.5A CN109518846A (en) | 2018-09-16 | 2018-09-16 | Perovskite glass curtain wall with flexible connection structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109518846A true CN109518846A (en) | 2019-03-26 |
Family
ID=65771447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811078045.5A Pending CN109518846A (en) | 2018-09-16 | 2018-09-16 | Perovskite glass curtain wall with flexible connection structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109518846A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210017804A1 (en) * | 2018-03-30 | 2021-01-21 | Lixil Corporation | Glass panel support structure |
-
2018
- 2018-09-16 CN CN201811078045.5A patent/CN109518846A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210017804A1 (en) * | 2018-03-30 | 2021-01-21 | Lixil Corporation | Glass panel support structure |
| US11834894B2 (en) * | 2018-03-30 | 2023-12-05 | Lixil Corporation | Glass panel support structure |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190326 |
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| WD01 | Invention patent application deemed withdrawn after publication |