CN109504943A - A kind of glassware craft of gilding - Google Patents
A kind of glassware craft of gilding Download PDFInfo
- Publication number
- CN109504943A CN109504943A CN201811388384.3A CN201811388384A CN109504943A CN 109504943 A CN109504943 A CN 109504943A CN 201811388384 A CN201811388384 A CN 201811388384A CN 109504943 A CN109504943 A CN 109504943A
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- CN
- China
- Prior art keywords
- glassware
- oven
- room temperature
- product
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B05D7/16—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of glassware craft of gilding, the technique production procedure following steps: glassware is cleaned, and air-dries dedusting；Oiliness substrate is sprayed toward glassware；Under vacuum conditions, aluminizer is powered in glassware；One layer of color aqueous paint is sprayed in the aluminium film surface of glassware, this layer of water paint is dried with oven, is down to room temperature after drying again.The present invention is cleaned using ultrasonic cleaning and High Pressure Pure Water, can effectively reduce glassware surface impurity residual；Use stage cooling, it is ensured that oiliness substrate is dry more quickly abundant, guarantees itself and glassware surface adsorbed close；Using hydrate colour paint, it is possible to reduce the pollution of organic solvent, while enhancing the absorption between paint and aluminium film, using stage cooling, residual moisture and solvent volatilization can be conducive to, while avoiding deforming because of fast cooling, cause to fall off.
Description
Technical field
The present invention relates to glassware coating techniques, and in particular to a kind of glassware Gold-plating technique.
Background technique
Plating is a kind of electron ion deposition process, is so that aluminium is attached to domestic glass surface essence by electric current using electrode
On thin pattern, its purpose is that increasing the beauty of domestic glass, practicability.
It is to plate the coat of metal in domestic glass, changes domestic glass surface nature or size.Assign domestic glass surface
The gloss beauty of pattern, prevents from wearing away article antirust；Improve electrical conductivity, lubricity, intensity, heat resistance, weatherability；Heat treatment
Anti-carburizi ng, nitridation；Size or the repairing of the glass of abrasion.
Coating of the existing oil paint containing organic solvent is free of benzene,toluene,xylene, formaldehyde, the toxic huge sum of money of free TDI
Belong to, toxic and irritating smell oil paint makees solvent with organic solvent, and there are fire risks when construction；It reduces to atmosphere dirt
Dye.General oil paint can not directly coat construction in wet structure and wet environment；Material surface is required high.3, oiliness
Qi Wufa is washed with water, and the consumption of cleaning solvent is larger.
Existing vacuum plating is utilized under vacuum condition, is deposited by the modes such as distilling or sputter in glass surface various
The film plating process of metal and nonmetal film.Available very thin overlay coating in this way, speed is fast, attachment
Power is good, and small pollution of the environment.
Previous vacuum plating product coating is improper due to being surface-treated, and surface coating material is easy embrittlement or not firm enough
Gu tend to fall off, process have the following deficiencies: glassware surface cleaning generally only with common clear water soaking flushing, by
It is alkalinity in usual water quality, has been easy fine solid residue and has been adsorbed on surface；Oiliness substrate blot it is dry during, uneven drying
It is even, cause oiliness substrate adsorptivity inadequate, is finally easy to cause the intermediate aluminium layer adsorption capacity being electroplated inadequate, fall off；Priming paint
Using oiliness material, high, area biggish for some humidity is required for dry, if dry inadequate, oiliness material is not easy
Absorption；Since the painted rear too fast cooling of temperature-fall period causes each section drying regime different, deformation occurs causes to fall off.
Summary of the invention
In view of the above-mentioned problems, the present invention is intended to provide a kind of surface clean is clean, coating strong adsorption force, sprays uniform glass
Glass vessel Gold-plating technique.
To realize the technical purpose, the scheme of the invention is: a kind of glassware craft of gilding, the technique production procedure
Following steps:
Glassware is placed in the ultrasonic cleaning agent for fill cleaning agent and cleans several minutes by the first step, then more with high pressure
Stock pure water rinsing 1-2 times；
Second step, with hot wind by clean glassware surface Quick-air-drying, to glassware electrostatic precipitation；
Glassware is naturally cooling to room temperature by third step, need to gold-plated position toward the specified of glassware by atomizer
Spray oiliness substrate；
4th step is directly placed into the product to put one's child in a boarding nursery in oven under room temperature, closes oven, is to slowly warm up to 170-200 DEG C
It is constant, maintain this temperature about 70-80 minutes, oven is closed；Given time one arrives, i.e. opening oven takes out product, is then allowed to stand
Product is allowed to be cooled to room temperature；
Aluminium film is electroplated in glassware under vacuum conditions in 5th step；
6th step sprays one layer of color aqueous paint in the aluminium film surface of glassware；；
Step 7: the product to put one's child in a boarding nursery is directly placed into oven under room temperature, oven is closed, is to slowly warm up to 170-190 DEG C
It is constant, maintain this temperature about 50-80 minutes, oven is closed；Cooled down using 40-50 minutes gradient types, i.e., opening oven, which takes out, produces
Product；Then about 20 minutes are stood under the dustless environment of drying allows product to be cooled to room temperature.
Preferably, the color aqueous paint is 50%~70% aqueous epoxy emulsion, 4%~12% water-based metal
Complex dyestuff, 0.1%~0.3% levelling agent, 5%~16% thermosetting resin, 4%~12% amino resins, 5%~16% alcohol
Acid resin, 2%~4% cosolvent, 4%~9% dyestuff.
Preferably, the cleaning water temperature is normal-temperature water, pH value 5.5-7.0,20~40KHz of ultrasonic frequency selection.
Preferably, the aluminium film is with a thickness of 10nm-250nm.
Preferably, being provided with dustless and dry sealing knot on the outside of glassware described in the third step to the 7th step
Structure.
Beneficial effects of the present invention, the present invention are cleaned using ultrasonic cleaning and High Pressure Pure Water, can effectively reduce glass
Vessel surface impurity residual；Using baking, it is ensured that oiliness substrate is dry more quickly abundant, guarantees itself and glassware table
Face adsorbed close；Using hydrate colour paint, it is possible to reduce the pollution of organic solvent, while enhancing the absorption between paint and aluminium film,
Using stage cooling, residual moisture and solvent volatilization can be conducive to, while avoiding deforming because of fast cooling, caused
It falls off.
Specific embodiment
Specific embodiment is described in further details the present invention below.
The cleaning water temperature is normal-temperature water, pH value 6.5, ultrasonic frequency selection 30KHz.The cleaning water temperature is normal
Warm water, pH value 5.5-7.0, ultrasonic frequency select 20~40KHz.Ultrasonic cleaning temperature, in general, ultrasonic wave is 30
Cavitation effect at DEG C -40 DEG C is best.Then temperature is higher for cleaning agent, acts on more significant.When usual practical application ultrasonic wave, use
The operating temperature of room temperature.Water quality acidity on the weak side can be conducive to surface smut simultaneously and vessel surface is detached from, and can be improved
Vessel surface finish.
The color aqueous paint is 63% aqueous epoxy emulsion, 6% water-based metal complex dyestuff, 0.15% levelling
Agent, 11% thermosetting resin, 8% amino resins, 8% alkyd resin, 4% cosolvent, 8% dyestuff.Wherein levelling agent can be with
Promote coating to form a smooth, smooth, uniform film during the drying and film forming process, improves the uniformity of spraying.It is wherein hot
Thermosetting resin heating is pressurizeed under lower action of ultraviolet light, is chemically reacted, crosslinking curing becomes insoluble material, Ke Yibao
Demonstrate,prove the stability of film forming.
Specific embodiment 1, the technique production procedure following steps:
Glassware is placed in the ultrasonic cleaning agent for fill cleaning agent and cleans several minutes by the first step, then more with high pressure
Stock pure water rinsing 1 time；
Second step, with hot wind by clean glassware surface Quick-air-drying, to glassware electrostatic precipitation；
Glassware is naturally cooling to room temperature by third step, need to gold-plated position toward the specified of glassware by atomizer
Spray oiliness substrate；
4th step is directly placed into the product to put one's child in a boarding nursery in oven under room temperature, closes oven, and it is constant to be to slowly warm up to 180 degree,
Maintain this temperature 70 minutes, oven is closed.Given time one arrives, i.e. opening oven takes out product, is then allowed to stand and allows within 20 minutes production
Product are cooled to room temperature；
Aluminium film is electroplated in glassware under vacuum conditions in 5th step；
6th step sprays one layer of color aqueous paint in the aluminium film surface of glassware；；
Step 7: the product to put one's child in a boarding nursery is directly placed into oven under room temperature, oven is closed, 180 DEG C of perseverances are to slowly warm up to
It is fixed, maintain this temperature 50 minutes, oven is closed, cools down using gradient type, gradually cools down within 40 minutes, so that vessel are slowly from 180
It is down within 100 DEG C, opens oven after being lower than 100 degrees Celsius and take out product；Then it is stood under the dustless environment of drying and allows production
Product are cooled to room temperature.
Embodiment 2, (step 7 does not use gradient type to cool down, and directly takes out cooling) described technique production procedure walk as follows
It is rapid:
(1) glassware ultrasonic cleaning is clean, dry, electrostatic precipitation；
Glassware is placed in the ultrasonic cleaning agent for fill cleaning agent and cleans several minutes by the first step, then more with high pressure
Stock pure water rinsing 1 time；
Second step, with hot wind by clean glassware surface Quick-air-drying, to glassware electrostatic precipitation；
Glassware is naturally cooling to room temperature by third step, need to gold-plated position toward the specified of glassware by atomizer
Spray oiliness substrate；
4th step is directly placed into the product to put one's child in a boarding nursery in oven under room temperature, closes oven, be to slowly warm up to 180 DEG C it is constant,
Maintain this temperature 70 minutes, oven is closed.Given time one arrives, i.e. opening oven takes out product, is then allowed to stand and allows within 20 minutes production
Product are cooled to room temperature；
Aluminium film is electroplated in glassware under vacuum conditions in 5th step；
6th step sprays one layer of color aqueous paint in the aluminium film surface of glassware；；
Step 7: the product to put one's child in a boarding nursery is directly placed into oven under room temperature, oven is closed, 180 DEG C of perseverances are to slowly warm up to
It is fixed, maintain this temperature 70 minutes, oven is closed.Cooled down using gradient type, temperature is down to 150 DEG C and is kept for 15 minutes, is down to 110 DEG C
It is kept for 15 minutes, opens oven after being lower than 80 DEG C and take out product；Then standing under the dustless environment of drying allows product to be cooled to
Room temperature.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art within the technical scope of the present disclosure, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (5)
1. a kind of glassware craft of gilding, which is characterized in that the technique production procedure following steps:
Glassware is placed in the ultrasonic cleaning agent for fill cleaning agent and cleans several minutes by the first step, then pure with high pressure multiply
Water rinses 1-2 times；
Second step, with hot wind by clean glassware surface Quick-air-drying, to glassware electrostatic precipitation；
Glassware is naturally cooling to room temperature by third step, need to gold-plated position spraying toward the specified of glassware by atomizer
Oiliness substrate；
4th step is directly placed into the product to put one's child in a boarding nursery in oven under room temperature, closes oven, be to slowly warm up to 170-200 DEG C it is constant,
Maintain this temperature about 70-80 minutes, oven is closed；Given time one arrives, i.e. opening oven takes out product, is then allowed to stand about 20 points
Clock is cooled to room temperature by product；
Aluminium film is electroplated in glassware under vacuum conditions in 5th step；
6th step sprays one layer of color aqueous paint in the aluminium film surface of glassware；；
Step 7: the product to put one's child in a boarding nursery is directly placed into oven under room temperature, oven is closed, 170-190 DEG C of perseverance is to slowly warm up to
It is fixed, maintain this temperature about 50-80 minutes, oven is closed；Cooled down using 40-50 minutes gradient types, i.e. opening oven takes out product；
Then standing under the dustless environment of drying allows product to be cooled to room temperature.
2. process for performing vacuum plating on glass according to claim 1, it is characterised in that: the color aqueous paint for 50%~
70% aqueous epoxy emulsion, 4%~12% water-based metal complex dyestuff, 0.1%~0.3% levelling agent, 5%~16% heat
Gu resin, 4%~12% amino resins, 5%~16% alkyd resin, 2%~4% cosolvent, 4%~9% dyestuff.
3. glassware Gold-plating technique according to claim 1 or 2, it is characterised in that: the cleaning water temperature is normal-temperature water,
PH value is 5.5-7.0, and ultrasonic frequency selects 20~40KHz.
4. glassware Gold-plating technique according to claim 1 or 2, it is characterised in that: the aluminium film is with a thickness of 10nm-
250nm。
5. process for performing vacuum plating on glass according to claim 1 or 2, it is characterised in that: the third step is into the 7th step
Dustless and dry sealing structure is provided on the outside of the glassware.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811388384.3A CN109504943A (en) | 2018-11-20 | 2018-11-20 | A kind of glassware craft of gilding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811388384.3A CN109504943A (en) | 2018-11-20 | 2018-11-20 | A kind of glassware craft of gilding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109504943A true CN109504943A (en) | 2019-03-22 |
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ID=65749403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811388384.3A Pending CN109504943A (en) | 2018-11-20 | 2018-11-20 | A kind of glassware craft of gilding |
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| Country | Link |
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| CN (1) | CN109504943A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112326403A (en) * | 2020-11-10 | 2021-02-05 | 山东电力研究院 | Method for curing and film-forming coating |
| CN117328020A (en) * | 2023-10-08 | 2024-01-02 | 北京博宇半导体工艺器皿技术有限公司 | Method for manufacturing PBN product |
-
2018
- 2018-11-20 CN CN201811388384.3A patent/CN109504943A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112326403A (en) * | 2020-11-10 | 2021-02-05 | 山东电力研究院 | Method for curing and film-forming coating |
| CN117328020A (en) * | 2023-10-08 | 2024-01-02 | 北京博宇半导体工艺器皿技术有限公司 | Method for manufacturing PBN product |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190322 |
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| WD01 | Invention patent application deemed withdrawn after publication |