CN109504175A - A kind of Environmental-protection water-based ink resistant to high temperature and preparation method thereof - Google Patents
A kind of Environmental-protection water-based ink resistant to high temperature and preparation method thereof Download PDFInfo
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- CN109504175A CN109504175A CN201811483969.3A CN201811483969A CN109504175A CN 109504175 A CN109504175 A CN 109504175A CN 201811483969 A CN201811483969 A CN 201811483969A CN 109504175 A CN109504175 A CN 109504175A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to water-based ink technical fields, specially a kind of Environmental-protection water-based ink resistant to high temperature, raw material comprising following parts by weight of component: 30-45 parts of water-based acrylic resin lotion, 10-20 parts of pigment, 5-15 parts of tourmaline powder, 3-7 parts of hypophosphorous acid melamine salt, poly- carbon dioxide-epoxy propane 1-5 parts, 3-8 parts of dispersing agent, 2-6 parts of powdered carbon, 5-10 parts of triacetin, 10-15 parts of silicate fiber, 1-4 parts of phthalic acid ester, it further include a kind of preparation method of Environmental-protection water-based ink resistant to high temperature, present invention Environmental-protection water-based ink resistant to high temperature and preparation method thereof, so that water-based ink is provided with high temperature resistant, corrosion resistant effect, and do not have noxious material, it is convenient for decomposing, the feature of environmental protection is good, and being added has tourmaline powder and carbon dust, it can be to air In harmful substance carry out adsorption-decomposition function, improve the quality of air, reduce the pollution of air, increase the functionality and practicability of water-based ink, the feature of environmental protection is strong, convenient for promote, meet the use demand of modernization.
Description
Technical field
The present invention relates to water-based ink technical field, specifically a kind of Environmental-protection water-based ink resistant to high temperature and its preparation side
Method.
Background technique
Ink is by chromoplast (such as pigment, dyestuff), link stuff, fills out and (fill) the uniform of the material compositions such as material, additional material
Mixture；It can be carried out printing, and dry in printed body；It is to have color, the pulpous state adherent with certain fluidity.Cause
This, color (form and aspect), body bone (rheological properties such as dilute thick, fluidity) and drying property are three most important performances of ink.
There are many their type, and physical property is also different, and some is very thick, very viscous；And some is quite dilute.Some is connected with vegetable oil work
Ramming material；Some resins and solvent or water etc. make link stuff.These be all according to the object i.e. stock of printing, printing process,
The type of printing plate and drying means etc. determine.
Water-based ink has environmental protection, free from environmental pollution, the advantages that being harmful to human health, Chinese patent (Authorization Notice No.
108384322 A of CN) it discloses a kind of ink for furniture thin paper aqueous intaglio printing and is solved compared with oil-based ink
The generation of toxic gas improves the working environment of ink manufacturers and press operator, solves security risk, solves house
Have the existing discharge of paper intaglio printing industry and pollution problem.But the water-based ink does not have the effect of corrosion-and high-temp-resistant,
Do not have the effect of purification, can not meet the use demand of modernization yet.
Summary of the invention
The purpose of the present invention is to provide a kind of Environmental-protection water-based inks resistant to high temperature and preparation method thereof, to solve above-mentioned back
The problem of being proposed in scape technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of Environmental-protection water-based ink resistant to high temperature, the raw material comprising following parts by weight of component: water-based acrylic resin lotion
30-45 parts, 10-20 parts of pigment, 5-15 parts of tourmaline powder, 3-7 parts of hypophosphorous acid melamine salt, poly- carbon dioxide-epoxy propane
1-5 parts, 3-8 parts of dispersing agent, 2-6 parts of powdered carbon, 5-10 parts of triacetin, 10-15 parts of silicate fiber, phthalic acid ester 1-
4 parts.
As a further solution of the present invention: the raw material comprising following parts by weight of component: water-based acrylic resin lotion 35-
40 parts, 13-16 parts of pigment, 7-12 parts of tourmaline powder, 4-6 parts of hypophosphorous acid melamine salt, poly- carbon dioxide-epoxy propane 2-4
Part, 5-7 parts of dispersing agent, 3-5 parts of powdered carbon, 7-9 parts of triacetin, 11-13 parts of silicate fiber, 1-3 parts of phthalic acid ester.
As a further solution of the present invention: the raw material comprising following parts by weight of component: water-based acrylic resin lotion 38
Part, 14 parts of pigment, 10 parts of tourmaline powder, 5 parts of hypophosphorous acid melamine salt, 3 parts of poly- carbon dioxide-epoxy propane, dispersing agent 6
Part, 4 parts of powdered carbon, 8 parts of triacetin, 12 parts of silicate fiber, 2 parts of phthalic acid ester.
As a further solution of the present invention: the main component of the water-based acrylic resin lotion is to contain styrene
The styrene-acrylic resin cream of 15%-55%.
A kind of preparation method of Environmental-protection water-based ink resistant to high temperature, steps are as follows:
(1) pigment, tourmaline powder and carbon dust are added in water-based acrylic resin lotion, are heated at 90-120 DEG C,
And 30-50min is stirred with the revolving speed of 150-250r/min, obtain the first mixed liquor；
(2) by hypophosphorous acid melamine salt, poly- carbon dioxide-epoxy propane, triacetin, silicate fiber, adjacent benzene
It is uniform that dicarboxylic acid esters successively weigh ultrasonic disperse, obtains mixture；
(3) mixture in the first mixed liquor and step (2) in step (1) is mixed, and be added dispersing agent and
A certain amount of deionized water, is warming up to 150-180 DEG C, stirs 50-70min under the revolving speed of 200-350r/min, and it is mixed to obtain second
Close liquid；
(4) the second mixed liquor of step (3) is added in ball mill and is repeatedly ground, filtered after qualified, packed, i.e.,
Obtain finished product water-based ink.
As a further solution of the present invention: the ball mill is vertical type pearl-grinding machine or Horizontal sand mill.
As further scheme of the invention: being equipped with circulating cooling channel in the ball mill, the circulating cooling is logical
Road is equipped with cooling water inlet and cooling water outlet, the external refrigeration machine of cooling water inlet.
Compared with prior art, the beneficial effects of the present invention are: present invention Environmental-protection water-based ink resistant to high temperature and its preparation
Method, hypophosphorous acid melamine salt, poly- carbon dioxide-epoxy propane, triacetin, silicate fiber, phthalic acid ester
It cooperates, so that water-based ink is provided with high temperature resistant, corrosion resistant effect, and does not have noxious material, is convenient for point
Solution, the feature of environmental protection is good, and addition has tourmaline powder and carbon dust, can carry out adsorption-decomposition function to the harmful substance in air, improve
The quality of air reduces the pollution of air, increases the functionality and practicability of water-based ink, and the feature of environmental protection is strong, full convenient for promoting
The use demand modernized enough.
Specific embodiment
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the present invention can phase
Mutually combination.
Below in conjunction with embodiment, the present invention will be described in detail.
Embodiment one
A kind of Environmental-protection water-based ink resistant to high temperature, the raw material comprising following parts by weight of component: water-based acrylic resin lotion
30 parts, 10 parts of pigment, 5 parts of tourmaline powder, 3 parts of hypophosphorous acid melamine salt, 1 part of poly- carbon dioxide-epoxy propane, dispersing agent 3
Part, 2 parts of powdered carbon, 5 parts of triacetin, 10 parts of silicate fiber, 1 part of phthalic acid ester.
The main component of the water-based acrylic resin lotion is the styrene-acrylic resin cream containing styrene 15%.
A kind of preparation method of Environmental-protection water-based ink resistant to high temperature, steps are as follows:
(1) pigment, tourmaline powder and carbon dust are added in water-based acrylic resin lotion, are heated at 90 DEG C, and with
The revolving speed of 150r/min stirs 30min, obtains the first mixed liquor；
(2) by hypophosphorous acid melamine salt, poly- carbon dioxide-epoxy propane, triacetin, silicate fiber, adjacent benzene
It is uniform that dicarboxylic acid esters successively weigh ultrasonic disperse, obtains mixture；
(3) mixture in the first mixed liquor and step (2) in step (1) is mixed, and be added dispersing agent and
A certain amount of deionized water is warming up to 150 DEG C, stirs 50min under the revolving speed of 200r/min, obtains the second mixed liquor；
(4) the second mixed liquor of step (3) is added in ball mill and is repeatedly ground, filtered after qualified, packed, i.e.,
Obtain finished product water-based ink.
The ball mill is vertical type pearl-grinding machine or Horizontal sand mill.
Circulating cooling channel is equipped in the ball mill, the circulating cooling channel is equipped with cooling water inlet and goes out with cooling water
Mouthful, the external refrigeration machine of cooling water inlet.
Embodiment two
A kind of Environmental-protection water-based ink resistant to high temperature, the raw material comprising following parts by weight of component: water-based acrylic resin lotion
45 parts, 20 parts of pigment, 15 parts of tourmaline powder, 3 parts of hypophosphorous acid melamine salt, 5 parts of poly- carbon dioxide-epoxy propane, dispersing agent 8
Part, 6 parts of powdered carbon, 10 parts of triacetin, 15 parts of silicate fiber, 4 parts of phthalic acid ester.
The main component of the water-based acrylic resin lotion is the styrene-acrylic resin cream containing styrene 55%.
A kind of preparation method of Environmental-protection water-based ink resistant to high temperature, steps are as follows:
(1) pigment, tourmaline powder and carbon dust are added in water-based acrylic resin lotion, are heated at 120 DEG C, and with
The revolving speed of 250r/min stirs 50min, obtains the first mixed liquor；
(2) by hypophosphorous acid melamine salt, poly- carbon dioxide-epoxy propane, triacetin, silicate fiber, adjacent benzene
It is uniform that dicarboxylic acid esters successively weigh ultrasonic disperse, obtains mixture；
(3) mixture in the first mixed liquor and step (2) in step (1) is mixed, and be added dispersing agent and
A certain amount of deionized water is warming up to 180 DEG C, stirs 70min under the revolving speed of 350r/min, obtains the second mixed liquor；
(4) the second mixed liquor of step (3) is added in ball mill and is repeatedly ground, filtered after qualified, packed, i.e.,
Obtain finished product water-based ink.
The ball mill is vertical type pearl-grinding machine or Horizontal sand mill.
Circulating cooling channel is equipped in the ball mill, the circulating cooling channel is equipped with cooling water inlet and goes out with cooling water
Mouthful, the external refrigeration machine of cooling water inlet.
Embodiment three
A kind of Environmental-protection water-based ink resistant to high temperature, the raw material comprising following parts by weight of component: water-based acrylic resin lotion
38 parts, 14 parts of pigment, 10 parts of tourmaline powder, 5 parts of hypophosphorous acid melamine salt, 3 parts of poly- carbon dioxide-epoxy propane, dispersing agent 6
Part, 4 parts of powdered carbon, 8 parts of triacetin, 12 parts of silicate fiber, 2 parts of phthalic acid ester.
The main component of the water-based acrylic resin lotion is the styrene-acrylic resin cream containing styrene 35%.
A kind of preparation method of Environmental-protection water-based ink resistant to high temperature, steps are as follows:
(1) pigment, tourmaline powder and carbon dust are added in water-based acrylic resin lotion, are heated at 105 DEG C, and with
The revolving speed of 200r/min stirs 40min, obtains the first mixed liquor；
(2) by hypophosphorous acid melamine salt, poly- carbon dioxide-epoxy propane, triacetin, silicate fiber, adjacent benzene
It is uniform that dicarboxylic acid esters successively weigh ultrasonic disperse, obtains mixture；
(3) mixture in the first mixed liquor and step (2) in step (1) is mixed, and be added dispersing agent and
A certain amount of deionized water is warming up to 165 DEG C, stirs 60min under the revolving speed of 275r/min, obtains the second mixed liquor；
(4) the second mixed liquor of step (3) is added in ball mill and is repeatedly ground, filtered after qualified, packed, i.e.,
Obtain finished product water-based ink.
The ball mill is vertical type pearl-grinding machine or Horizontal sand mill.
Circulating cooling channel is equipped in the ball mill, the circulating cooling channel is equipped with cooling water inlet and goes out with cooling water
Mouthful, the external refrigeration machine of cooling water inlet.
Comparative example
Use water-based ink common in the market.
Experimental example
Prepare 40 closed elevated temperature vessels, and pour pollution air inside container, divides the container into 1,2,3,4 group, it will
Embodiment 1-3 and the water-based ink of comparative example are placed in corresponding container, test 12 hours are carried out, to heat-resisting quantity and air
Improvement property is detected, and test result is as follows:
| High temperature resistant rate % | Air improvement rate % | |
| Embodiment one | 80 | 100 |
| Embodiment two | 100 | 90 |
| Embodiment three | 90 | 100 |
| Comparative example | 20 | 10 |
Present invention Environmental-protection water-based ink resistant to high temperature and preparation method thereof, hypophosphorous acid melamine salt, poly- carbon dioxide-ring
Ethylene Oxide, triacetin, silicate fiber, phthalic acid ester cooperate, so that water-based ink is provided with high temperature resistant, resistance to
The effect of corrosion, and do not have noxious material, it being convenient for decomposing, the feature of environmental protection is good, and addition has tourmaline powder and carbon dust,
Adsorption-decomposition function can be carried out to the harmful substance in air, improve the quality of air, reduce the pollution of air, increase aqueous oil
The functionality and practicability of ink, the feature of environmental protection is strong, convenient for promoting, meets the use demand of modernization.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (7)
1. a kind of Environmental-protection water-based ink resistant to high temperature, which is characterized in that the raw material comprising following parts by weight of component: water soluble acrylic acid
30-45 parts of resin emulsion, 10-20 parts of pigment, 5-15 parts of tourmaline powder, 3-7 parts of hypophosphorous acid melamine salt, poly- carbon dioxide-
1-5 parts of propylene oxide, 3-8 parts of dispersing agent, 2-6 parts of powdered carbon, 5-10 parts of triacetin, 10-15 parts of silicate fiber, adjacent benzene two
1-4 parts of formic acid esters.
2. a kind of Environmental-protection water-based ink resistant to high temperature according to claim 1, which is characterized in that include following parts by weight group
The raw material divided: 35-40 parts of water-based acrylic resin lotion, 13-16 parts of pigment, 7-12 parts of tourmaline powder, hypophosphorous acid melamine
4-6 parts of salt, carbon dioxide-epoxy propane 2-4 parts poly-, 5-7 parts of dispersing agent, 3-5 parts of powdered carbon, 7-9 parts of triacetin, silicic acid
11-13 parts of fiber, 1-3 parts of phthalic acid ester.
3. a kind of Environmental-protection water-based ink resistant to high temperature according to claim 2, which is characterized in that include following parts by weight group
The raw material divided: 38 parts of water-based acrylic resin lotion, 10 parts of tourmaline powder, 5 parts of hypophosphorous acid melamine salt, is gathered 14 parts of pigment
3 parts of carbon dioxide-epoxy propane, 6 parts of dispersing agent, 4 parts of powdered carbon, 8 parts of triacetin, 12 parts of silicate fiber, O-phthalic
2 parts of acid esters.
4. a kind of Environmental-protection water-based ink resistant to high temperature according to claim 3, which is characterized in that the water soluble acrylic acid tree
The main component of fat liquor is the styrene-acrylic resin cream containing styrene 15%-55%.
5. a kind of preparation method of Environmental-protection water-based ink resistant to high temperature as described in claim 1, which is characterized in that step is such as
Under:
(1) pigment, tourmaline powder and carbon dust are added in water-based acrylic resin lotion, are heated at 90-120 DEG C, and with
The revolving speed of 150-250r/min stirs 30-50min, obtains the first mixed liquor；
(2) by hypophosphorous acid melamine salt, poly- carbon dioxide-epoxy propane, triacetin, silicate fiber, O-phthalic
It is uniform that acid esters successively weighs ultrasonic disperse, obtains mixture；
(3) mixture in the first mixed liquor and step (2) in step (1) is mixed, and dispersing agent and certain is added
The deionized water of amount, is warming up to 150-180 DEG C, stirs 50-70min under the revolving speed of 200-350r/min, obtains the second mixed liquor；
(4) the second mixed liquor of step (3) is added in ball mill and is repeatedly ground, filtered after qualified, pack to get at
Product water-based ink.
6. a kind of preparation method of Environmental-protection water-based ink resistant to high temperature as claimed in claim 5, which is characterized in that the bead mill
Machine is vertical type pearl-grinding machine or Horizontal sand mill.
7. a kind of preparation method of Environmental-protection water-based ink resistant to high temperature as claimed in claim 6, which is characterized in that the bead mill
Be equipped with circulating cooling channel in machine, the circulating cooling channel is equipped with cooling water inlet and cooling water outlet, the cooling water into
The external refrigeration machine of mouth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811483969.3A CN109504175A (en) | 2018-12-06 | 2018-12-06 | A kind of Environmental-protection water-based ink resistant to high temperature and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811483969.3A CN109504175A (en) | 2018-12-06 | 2018-12-06 | A kind of Environmental-protection water-based ink resistant to high temperature and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109504175A true CN109504175A (en) | 2019-03-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811483969.3A Withdrawn CN109504175A (en) | 2018-12-06 | 2018-12-06 | A kind of Environmental-protection water-based ink resistant to high temperature and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN109504175A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114989105A (en) * | 2022-07-15 | 2022-09-02 | 什邡市太丰新型阻燃剂有限责任公司 | Pollution-free method for synthesizing superfine melamine hypophosphite and flame retardant method thereof |
-
2018
- 2018-12-06 CN CN201811483969.3A patent/CN109504175A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114989105A (en) * | 2022-07-15 | 2022-09-02 | 什邡市太丰新型阻燃剂有限责任公司 | Pollution-free method for synthesizing superfine melamine hypophosphite and flame retardant method thereof |
| CN114989105B (en) * | 2022-07-15 | 2024-01-12 | 什邡市太丰新型阻燃剂有限责任公司 | Pollution-free method for synthesizing superfine melamine hypophosphite and flame-retardant method thereof |
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Application publication date: 20190322 |
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