CN109488261B - A kind of virtual construction method of ocean gas hydrate three phase dynamic - Google Patents
A kind of virtual construction method of ocean gas hydrate three phase dynamic Download PDFInfo
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- NMJORVOYSJLJGU-UHFFFAOYSA-N methane clathrate Chemical compound C.C.C.C.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O NMJORVOYSJLJGU-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000007789 gas Substances 0.000 claims abstract description 85
- 150000004677 hydrates Chemical class 0.000 claims abstract description 73
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
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- 230000004424 eye movement Effects 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 9
- 239000013535 sea water Substances 0.000 claims description 7
- 238000005516 engineering process Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- XCWPUUGSGHNIDZ-UHFFFAOYSA-N Oxypertine Chemical compound C1=2C=C(OC)C(OC)=CC=2NC(C)=C1CCN(CC1)CCN1C1=CC=CC=C1 XCWPUUGSGHNIDZ-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 12
- 238000004088 simulation Methods 0.000 abstract description 9
- 230000007246 mechanism Effects 0.000 abstract description 6
- 230000000007 visual effect Effects 0.000 abstract description 5
- 230000003993 interaction Effects 0.000 abstract description 4
- 238000011160 research Methods 0.000 abstract description 3
- 238000000605 extraction Methods 0.000 abstract description 2
- 230000008859 change Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 241001269238 Data Species 0.000 description 2
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
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- E—FIXED CONSTRUCTIONS
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- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B41/00—Equipment or details not covered by groups E21B15/00 - E21B40/00
- E21B41/0099—Equipment or details not covered by groups E21B15/00 - E21B40/00 specially adapted for drilling for or production of natural hydrate or clathrate gas reservoirs; Drilling through or monitoring of formations containing gas hydrates or clathrates
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Abstract
The present invention provides a kind of virtual construction methods of ocean gas hydrate three phase dynamic, this method utilizes eyeball tracking interaction positioning view position, point of observation position is obtained by three-dimensional space geometrical analysis, and according to depth pressure conversion and ocean temperature field model, obtain the pressure value and temperature value of given viewpoint, according to by geothermal gradient, water temperature gradient, the gas hydrates three-phase state discrimination model of the buildings such as deep-sea natural gas hydrate phase balance emulation curve, judge the gas hydrates physical state at the point of observation position, then the Dynamic Display in three-dimensional scenic, realize that with eyeball tracking be the gas hydrates three-phase state dynamic analog effect driven.The invention realizes the virtualization building and expression of ocean gas hydrate three-phase inversion, to intuitive, the visual expression stable mechanism of ocean gas hydrate, the gas hydrates three-phase virtual scene in different sea areas can be constructed based on the present invention, and is widely used for the fields such as the research of ocean gas hydrate laboratory testing analysis, situ extraction simulation, teaching and science popularization.
Description
Technical field
The invention belongs to the dynamic virtual scenario building technical fields of ocean gas hydrate stable mechanism, and in particular to
A kind of virtual construction method of ocean gas hydrate three phase dynamic, realizes dynamic construction marine natural by virtualization technology
Gas hydrate three-phase scene.
Background technique
Natural gas hydrate resources have the characteristics that distribution is wide, energy resource density is high, are a kind of potential energy, are also simultaneously
A kind of meta-stable energy, as ocean gas hydrate deep-sea different pressures, at a temperature of can behave as three kinds of shapes of solid, liquid, gas
State, phase conversion directly restrict the depth capacity and seam thickness to form gas hydrates, while being also gas water
Close the main reason for object exploitation difficulty is big.By virtual reality technology, gas hydrates environmental effect and three phase dynamic are simulated
Conversion process, form of the vivid reflection gas hydrates of energy under the environment such as different temperatures, pressure, facilitates auxiliary and sets
Count hydrate recovery scheme.
In the past for the research and understanding of the conversion of its three-phase phase mainly based on the two-dimensional approach such as verbal description, picture,
The exploitation of gas hydrates imitative experimental appliance of some mechanism developments can also illustrate three-phase inversion, but nothing to a certain extent
Its dynamic process of method comprehensive representation, and since experiment condition, place etc. limit, exploitation simulation, experiment point can not be widely used for
The fields such as analysis, teaching and science popularization.
Currently, both at home and abroad still without gas hydrates three-phase inversion virtual reality scenario, gas hydrates three-phase turns
Changing is a dynamic process, carries out the demands such as exploitation simulation, experimental analysis using gas hydrates three-phase knowledge point to meet,
Urgently propose a kind of new departure for establishing ocean gas hydrate three-phase virtual scene and Dynamic Display.
Summary of the invention
The present invention proposes a kind of virtual construction method of ocean gas hydrate three phase dynamic, and overcoming can not visualize in the past
The problem of expressing complicated three phase change of ocean gas hydrate passes through visual angle positioning interaction mode dynamic control gas water
Three phase change what comes into a driver's of object is closed, immersion experience is hydrated natural gas to assist observation three phase change details of gas hydrates
Object is decomposed to be of great significance with synthesis process simulation, recovery process simulation and education and science popularization etc..
The present invention adopts the following technical solutions realizes: a kind of virtual side of building of ocean gas hydrate three phase dynamic
Method, comprising the following steps:
(1) according to related datas such as the temperature, geology, geography in gas hydrates preservation area, three-dimensional deep-marine-environment is constructed
Scene, including submarine geologic body, benthon, seawater etc.;
(2) construct gas hydrates threedimensional model, include solid-state, three kinds of liquid, gaseous state models, by setting shape,
The parameters such as size, color, transparency, material are to distinguish the gas hydrates model under different conditions;
(3) in deep sea hydrate preservation area 3-D geometric model scene, relative dimensional rectangular coordinate system is established, is based on eye
Ball tracing and positioning technology is obtained in observation sight and hydrate preservation area threedimensional model by eye movement position and its direction of observation
The intersection point of certain viewing surface, the intersection point calculate the position of point of observation by three-dimensional space geometrical analysis for point of observation;
(4) position is put according to the observation, carries out depth-pressure conversion, obtains point of observation depth corresponding pressure value;
(5) space of points position and models for temperature field according to the observation calculate the temperature value at point of observation position;
(6) based on the influence factor of natural gas hydrate phase balance emulation, it is equal that relevant parameter generation gas hydrates are set
Weigh curve, and simulates gas hydrates marine environment with this, the influence factor include gas composition, hole water constituent,
Pore radius, sediment grain size;
(7) natural gas hydrate phase balance emulation curve, water temperature gradient, geothermal gradient, sea-floor relief, gas hydrates are combined
Bottom circle etc. constructs gas hydrates three-phase discrimination model, according to the model determine current depth and temperature condition (or pressure with
Temperature) under, the physical state of given viewpoint gas hydrates;
(8) at the eyeball fixes point (i.e. point of observation) in three-dimensional scenic, sentenced according to gas hydrates solid-liquid gaseity
Break as a result, simultaneously the space coordinate of real time modifying gas hydrates model and its " whether visible " parameter, dynamic rendering are observed
At point and its gas hydrates threedimensional model and what comes into a driver's on periphery, realization are the gas hydrates three driven with eyeball tracking
Phase state dynamic analog effect.
Further, in the step (3): setting gas hydrates preservation section model as a cylindrical body, sea level is simple
A horizontal plane, the as upper top surface of cylindrical body are turned to, the relative dimensional rectangular coordinate system established is different from virtual reality field
Three-dimensional system of coordinate in scape, using the center of circle of top surface on cylindrical body as coordinate origin, X-axis positive direction is east, and Y-axis positive direction is north, Z
Axis is positive upwards perpendicular to XOY plane, and Z axis represents depth, is known in scene by the relative dimensional rectangular coordinate system of foundation
Depth value is negative value;
If XOZ plane is viewing surface, E (xe,ye,ze) point represent eye movement position, E ' (x ', 0, z ') point represent point of observation,
Eye movement direction is represented, point E ' isWith the intersection point of XOZ plane, then point E ' is in XOZ plane, so its y ' coordinate value is 0;If circle
Cylinder projects in YOZ plane, Eyoz, point E 'yozRespectively point E, subpoint of the point E ' in YOZ plane,ForIn YOZ
Divide vector in plane,Perpendicular to Y-axis, α isWith the angle of Y-axis;
Three-dimensional space geometrical analysis is carried out according to eye movement position and its direction of observation, the position of point of observation is obtained, that is, asks a little
Z ' the value of E ', it is assumed thatThenThen:
It can similarly obtain:
Further, in the step (7), in the physical state for judging gas hydrates, on viewing surface, building
Gas hydrates three-phase state discrimination model, if phase equilibrium line function is B (t, z), water temperature gradient function is T (t, z), ground
Warm gradient function is G (t, z), and sea-floor relief surface function is S (z), and gas hydrates bottom circle is D (z), then constructs natural gas
Hydrate three-phase state discrimination model are as follows:
Wherein, t=f (x, 0, z), f (x, 0, z) are ocean temperature field model, and 0 represents solid, and 1 represents gas, and 2 represent liquid
Body.
Compared with prior art, the advantages and positive effects of the present invention are:
The method that the present invention program is proposed, which realizes, moves ocean gas hydrate three-phase (solid-liquid-gas) variation
State virtually constructs, and it is opposite to calculate visual angle by three-dimensional space geometrical analysis using eyeball tracking interaction positioning view position
Hydrate preservation area threedimensional model position and corresponding abyssal depth are determined with models for temperature field in conjunction with depth pressure conversion and are observed
The pressure and temperature pointed out, according to by natural gas hydrate phase balance emulation curve, water temperature, geothermal gradient, sea-floor relief, natural
The gas hydrates three-phase discrimination model of the buildings such as gas hydrate bottom circle determines the physical state of the position gas hydrates,
Then the virtual views of the Dynamic Display position realize that with eyeball tracking be the gas hydrates three-phase state dynamic analog driven
Quasi- effect;
By virtualization to ocean gas hydrate three-phase inversion building and expression, thus intuitively, visual expression
The stable mechanism of ocean gas hydrate can construct the gas hydrates three-phase virtual field in different sea areas based on the present invention
Scape, and can be widely used for ocean gas hydrate laboratory simulation analysis and research, situ extraction simulation shows, teaching and
The fields such as science popularization.
Detailed description of the invention
Fig. 1 is the schematic illustration of the virtual construction method of gas hydrates three phase dynamic described in the embodiment of the present invention;
Fig. 2 is three-dimensional space of embodiment of the present invention geometrical analysis schematic diagram;
Wherein, the cylindrical body of left hand view (1) indicates ocean virtual scene, if XOZ plane is viewing surface, E point represents eye movement
Position, E ' point represent point of observation,Eye movement direction is represented, since point E ' isWith the intersection point of XOZ plane, then point E ' is flat in XOZ
On face, so its y ' coordinate value is 0;Right part of flg (2) is projection of the cylindrical body in YOZ plane in left hand view (1), Eyoz, point
E’yozRespectively point E, subpoint of the point E ' in YOZ plane,ForDivide vector in YOZ plane,Perpendicular to Y
Axis, α areWith the angle of Y-axis;
Fig. 3 is natural gas hydrate phase balance emulation curve and its stable region schematic diagram described in the embodiment of the present invention.
Specific embodiment
In order to which the above objects, features and advantages of the present invention is more clearly understood, with reference to the accompanying drawing and implement
The present invention will be further described for example.It should be noted that in the absence of conflict, in embodiments herein and embodiment
Feature can be combined with each other.
A kind of virtual construction method of ocean gas hydrate three phase dynamic, principle is as shown in Figure 1, specifically include following
Step:
(1) according to related datas such as the temperature, geology, geography in gas hydrates preservation area, three-dimensional deep-marine-environment is constructed
Scene, including submarine geologic body, benthon, seawater etc.;
(2) construct gas hydrates threedimensional model, include solid-state, three kinds of liquid, gaseous state models, by setting shape,
The parameters such as size, color, transparency, material are to distinguish the gas hydrates model under different conditions;
(3) in deep sea hydrate preservation area 3-D geometric model scene, relative dimensional rectangular coordinate system is established, eye is passed through
Dynamic position and its direction of observation, calculate the intersection point of certain viewing surface in observation sight and hydrate preservation area threedimensional model, the friendship
Point calculates the position of point of observation by three-dimensional space geometrical analysis for point of observation;
(4) depth value put according to the observation carries out depth-pressure conversion, obtains observation depth corresponding pressure value;
(5) space of points position and models for temperature field according to the observation calculate the temperature value at point of observation position;
(6) due to influence natural gas hydrate phase balance emulation factor include gas composition, hole water constituent, pore radius,
The variation of microwave, surfactant under sediment grain size and experiment condition etc., influence factor can change the state of balancing each other, because
This as needed, setting relevant parameter generates natural gas hydrate phase balance emulation curve, simulates gas hydrates ocean with this
Environment.
(7) natural gas hydrate phase balance emulation curve, water temperature gradient, geothermal gradient, sea-floor relief, gas hydrates are combined
Bottom circle etc. constructs gas hydrates three-phase discrimination model, according to the model determine current depth and temperature condition (or pressure with
Temperature) under, the physical state of given viewpoint gas hydrates;
(8) at the eyeball fixes point (i.e. point of observation) in three-dimensional scenic, sentenced according to gas hydrates solid-liquid gaseity
Break as a result, simultaneously the space coordinate of real time modifying gas hydrates model and its " whether visible " parameter, dynamic rendering are observed
At point and its gas hydrates threedimensional model and what comes into a driver's on periphery, realization are the gas hydrates three driven with eyeball tracking
Phase state dynamic analog effect;
(9) using three-dimensional ocean gas hydrates scene as a system, it is input to the VR one for supporting eyeball interaction
Immersion experience is carried out in machine.
Step described in this programme (3) in the specific implementation, in the following ways:
If gas hydrates preservation section model is a cylindrical body, as shown in Fig. 2 (1), sea level is reduced to a water
Plane, the as upper top surface of cylindrical body, the relative dimensional rectangular coordinate system established are different from the three-dimensional in virtual reality scenario
Coordinate system, using the center of circle of top surface on cylindrical body as coordinate origin, X-axis positive direction be east, Y-axis positive direction be north, Z axis perpendicular to
XOY plane is positive upwards, and Z axis represents depth, equal by the depth value known to the relative dimensional rectangular coordinate system of foundation in scene
For negative value;
If XOZ plane is viewing surface, E point represents eye movement position, and E ' point represents point of observation,Represent eye movement direction, point E '
It isWith the intersection point of XOZ plane, then point E ' is in XOZ plane, so its y ' coordinate value is 0;Fig. 2 (2) is cylinder in Fig. 2 (1)
Projection of the body in YOZ plane, Eyoz, point E 'yozRespectively point E, subpoint of the point E ' in YOZ plane,ForIn YOZ
Divide vector in plane,Perpendicular to Y-axis, α isWith the angle of Y-axis;
Three-dimensional space geometrical analysis is carried out according to eye movement position and its direction of observation, obtains the position of point of observation, such as Fig. 2
(1) shown in, that is, the z ' value of point E ' is sought, it is assumed thatThenAs shown in Fig. 2 (2), then:
It can similarly obtain:
In the step (7), in the physical state for judging gas hydrates, on viewing surface, gas water is constructed
Object three-phase state discrimination model is closed, if phase equilibrium line function is B (t, z), water temperature gradient function is T (t, z), geothermal gradient letter
Number is G (t, z), and seabed surface function is S (z), and gas hydrates bottom circle is D (z), then constructs gas hydrates three-phase shape
State discrimination model are as follows:
Wherein, t=f (x, 0, z), f (x, 0, z) are ocean temperature field model, and 0 represents solid, and 1 represents gas, and 2 represent liquid
Body.
This programme is according to the stable theory formula that balances each other: 1/T=3.79 × 10-3-2.83×10-4LgP, wherein T is temperature
Degree/K, P is pressure/MPa, to tell about natural gas hydrate phase balance emulation curve, natural gas hydrate phase balance emulation curve such as Fig. 3 institute
Show, gas hydrates phase boundray curve and the water temperature gradient curve of hypothesis, geothermal gradient region enclosed by a curve △ in Fig. 3
OBC is exactly the region that pressure and temp condition is suitable for gas hydrates formation.Again because of gas hydrates in the seawater
Density will be lower than density of sea water, the region △ ABC within the scope of seawater, so this region formed gas hydrates will on
It is floating, and dissolve since temperature raises.Therefore remove the region △ ABC in the region △ OBC, i.e. the region △ ABO is the day to be formed
The stabilized zone of right gas compound;Natural gas hydrate phase balance emulation is calculated by the conversion of the depth of water and pressure, geothermal gradient
Boundary, it is current to observe if Fig. 3 gradually judges under current pressure and temperature (or depth and temperature) using phase equilibrium line as standard
The physical state of gas hydrates at point, to obtain natural gas hydrate stability zone information.
In fact, since ocean temperature has day, the moon, year, the variation of many years quasi-periodic and irregular variation, mainly by latitude
Degree, ocean current, season, effect of depth, show through directly observing: ocean temperature diurnal variation very little, change depth of water range from 0~30 meter
Place, and changing reachable 350 meters or so places of the depth of water year has a thermostat layer at 350 meters of the depth of water or so places.Three big oceans-the Pacific Ocean, the Atlantic Ocean and the Indian Ocean surface year is flat
Equal water temperature is about 17.4 DEG C, wherein, up to 19.1 DEG C, the Indian Ocean is taken second place with Pacific Ocean highest, up to 17.0 DEG C, the Atlantic Ocean is minimum, is
16.9℃.Water temperature generally reduces (every 1000 meters of the decline of depth, temperature about declines 1 °~2 DEG C) with the increase of depth, in depth
Water temperature at 1000 meters is about that be deeper than at 4~5 DEG C, 2000 meters for 2~3 DEG C be 1~2 DEG C 3000 meters at, so in the present embodiment
Ocean temperature field data can derive from the observation data in practical sea area, the ocean temperature lattice point that can also be issued using atmosphere
Data construct ocean temperature field model using certain interpolation algorithm, for example, using multiple quadratic form interpolation method etc..
The Operational Mechanisms that this programme adjusts natural gas hydrate phase balance emulation curve as scene dynamics, being capable of actual response
The state of gas hydrates under the present circumstances, thus intuitively, the visual expression stable mechanism of ocean gas hydrate;
Be driving with eyeball tracking, by marine environment large scene and the small scene of gas hydrates triphase flow organically combine and from
It adapts to, the more details of gas hydrates is understood convenient for observer;This method is easy to spread, can be according to different sea area seawater
Depth and the hydrate preservation amount in the sea area establish the threedimensional model of different spaces size, to express the hydrate three-phase of this area
Actual conditions can be widely used for different sea area gas hydrates three-phase experimental analyses and teaching field, for natural gas moisture
Solution is of great significance with synthesis process simulation, recovery process simulation, education, science popularization.
The above described is only a preferred embodiment of the present invention, being not that the invention has other forms of limitations, appoint
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
It imitates embodiment and is applied to other fields, but without departing from the technical solutions of the present invention, according to the technical essence of the invention
Any simple modification, equivalent variations and remodeling to the above embodiments, still fall within the protection scope of technical solution of the present invention.
Claims (3)
1. a kind of virtual construction method of ocean gas hydrate three phase dynamic, which comprises the following steps:
(1) according to the temperature, geology and geography information in gas hydrates preservation area, three-dimensional deep-marine-environment scene is constructed, this
Scape includes submarine geologic body, benthon and seawater;
(2) gas hydrates threedimensional model is constructed, which includes solid-state, three kinds of liquid, gaseous state models;
(3) in the three-dimensional deep-marine-environment scene in hydrate preservation area, relative dimensional rectangular coordinate system is established, is based on eyeball tracking
Location technology obtains certain observation in observation sight and hydrate preservation area threedimensional model by eye movement position and its direction of observation
The intersection point in face, the intersection point obtain the position of point of observation by three-dimensional space geometrical analysis for point of observation;
(4) according to the position of point of observation obtained, depth-pressure conversion is carried out, obtains point of observation depth corresponding pressure value;
(5) space of points position and models for temperature field according to the observation, obtain the temperature value at point of observation position;
(6) based on the influence factor of natural gas hydrate phase balance emulation, relevant parameter is set and generates natural gas hydrate phase balance emulation song
Line, and gas hydrates marine environment is simulated with this, the influence factor includes gas composition, hole water constituent, hole
Radius, sediment grain size;
(7) natural gas hydrate phase balance emulation curve, water temperature gradient, geothermal gradient, sea-floor relief and gas hydrates bottom are combined
Boundary constructs gas hydrates three-phase discrimination model, and observes under the conditions of determining current pressure and temperature according to three-phase discrimination model
The physical state of gas hydrates at point;
(8) in given viewpoint, according to the physical state judging result of gas hydrates, real time modifying gas hydrates are three-dimensional
Model state, dynamic render the gas hydrates threedimensional model and what comes into a driver's on given viewpoint and its periphery, realize with eyeball tracking
For the gas hydrates three-phase state dynamic analog effect of driving.
2. the virtual construction method of ocean gas hydrate three phase dynamic according to claim 1, it is characterised in that: described
In step (3):
If gas hydrates preservation section model is a cylindrical body, sea level is the upper top surface of cylindrical body, and that is established is opposite
For three-dimensional cartesian coordinate system using the center of circle of top surface on cylindrical body as coordinate origin, X-axis positive direction is east, and Y-axis positive direction is north, Z axis
It perpendicular to XOY plane, is positive upwards, Z axis represents depth;
If XOZ plane is viewing surface, E (xe,ye,ze) point represent eye movement position, E ' (x ', 0, z ') point represent point of observation,It represents
Eye movement direction, point E ' areWith the intersection point of XOZ plane, then point E ' is in XOZ plane, if cylindrical body forms throwing in YOZ plane
Shadow, point Eyoz(ye,ze) and point E 'yoz(0, z ') respectively point E and subpoint of the point E ' in YOZ plane,ForIt is flat in YOZ
Divide vector on face,Perpendicular to Y-axis, α isWith the angle of Y-axis;
Three-dimensional space geometrical analysis is carried out according to eye movement position and its direction of observation, the position of point of observation is obtained, that is, asks point E's '
Z ' value, ifThenThen:
It can similarly obtain:
3. the virtual construction method of ocean gas hydrate three phase dynamic according to claim 2, it is characterised in that: described
In step (7), in the physical state for judging gas hydrates, on viewing surface, gas hydrates three-phase state is constructed
Discrimination model, if phase equilibrium line function is B (t, z), water temperature gradient function is T (t, z), and geothermal gradient function is G (t, z),
Seabed surface function is S (z), and gas hydrates bottom circle is D (z), then constructs gas hydrates three-phase state discrimination model
Are as follows:
Wherein, t=f (x, 0, z), f (x, 0, z) are ocean temperature field model, and 0 represents solid, and 1 represents gas, and 2 represent liquid.
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CN110188488B (en) * | 2019-06-03 | 2023-04-07 | 中国石油大学(华东) | Simulation method and system for seabed natural gas hydrate outcrop and surrounding environment |
CN111508564B (en) * | 2020-06-18 | 2023-10-03 | 应急管理部国家自然灾害防治研究院 | Quantification of quartz H 2 O-CO 2 System and method for hydrothermal fluid ore-forming process of NaCl system |
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