CN109486102A - A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic and preparation method thereof - Google Patents
A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic and preparation method thereof Download PDFInfo
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- CN109486102A CN109486102A CN201811524179.5A CN201811524179A CN109486102A CN 109486102 A CN109486102 A CN 109486102A CN 201811524179 A CN201811524179 A CN 201811524179A CN 109486102 A CN109486102 A CN 109486102A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/16—Condensation polymers of aldehydes or ketones with phenols only of ketones with phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of Wear-resistant, high-temperature resistant environmentally-friendly plastics and preparation method thereof, belong to environmentally-friendly plastic technical field.It is composed of the following parts by weight: 20-40 parts of PEEK, 5-10 parts of MPPO, 18-25 parts of sodium carboxymethylcellulose, 2-5 parts of nano zine oxide, 8-14 parts of PTFE, 3-8 parts of filler, 1-4 parts of colorant, 3-6 parts of complex type antioxidant.Production method is first to be uniformly mixed PEEK, MPPO, sodium carboxymethylcellulose, nano zine oxide and PTFE in reaction kettle, and mixed liquor is made in stirring 2-3h after mixing at normal temperature, then mixed liquor made from step a is heated to 60-80 DEG C, and sequentially add filler, colorant and complex type antioxidant, it is put into molding machine after mixing, molding time is 10-20 minutes, it is cooled down to obtain environmentally-friendly plastic after molding, the environmentally-friendly plastic has wearability and high temperature resistance, provides prospect for the application of environmentally-friendly plastic.
Description
Technical field
The present invention relates to a kind of Wear-resistant, high-temperature resistant environmentally-friendly plastics and preparation method thereof, belong to environmentally-friendly plastic technical field.
Background technique
In daily life, plastics have also brought while bringing convenience to people's daily life and have been difficult to drop
Solution or the problem that can not be degraded, for this purpose, it not only has common plastics with the development of science and technology environmentally-friendly plastic comes into being
All advantages, also have the function of to degrade, therefore the use of environmentally-friendly plastic can be popularized largely, but current
When in use, there is also the not strong disadvantages of wear-resisting property and high temperature resistance, therefore also need to current ring for environmentally-friendly plastic
Guarantor's plastics, which are made, to be correspondingly improved.
Summary of the invention
Technical problem to be solved by the present invention lies in: a kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic and preparation method thereof is provided,
It solves current environmentally-friendly plastic when in use, and there is also the not strong problems of wear-resisting property and high temperature resistance.
The technical problems to be solved by the invention take following technical scheme to realize:
A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic, it is composed of the following parts by weight: 20~40 parts of PEEK, MPPO 5~
10 parts, 18~25 parts of sodium carboxymethylcellulose, 2~5 parts of nano zine oxide, 8~14 parts of PTFE, 3~8 parts of filler, coloring
1~4 part of agent, 3~6 parts of complex type antioxidant.
As preferred embodiment, the filler be diatomite, calcium carbonate, mica powder it is one or more.
As preferred embodiment, the colorant is one of titanium dioxide, nano-titanium dioxide, zinc ring or a variety of.
As preferred embodiment, the complex type antioxidant is 2,8- di-tert-butyl-4-methy phenol.
According to a kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic proposed the production method is as follows:
A, PEEK, MPPO, sodium carboxymethylcellulose, nano zine oxide and PTFE are uniformly mixed in reaction kettle, and in room temperature
Mixed liquor is made in lower stirring 2-3h after mixing；
B, mixed liquor made from step a is heated to 60-80 DEG C, and sequentially adds filler, colorant and complex type antioxidant,
It is put into molding machine after mixing, molding time is 10-20 minutes, is cooled down to obtain environmentally-friendly plastic after molding.
The beneficial effects of the present invention are:
(1), poisonous and harmful substances are free of in each component, will not be detrimental to health, it is green and pollution-free；
(2), it is used cooperatively using nano zine oxide and PTFE, enhances matrix abrasive resistance, reduce the plastic flow of PTFE
Property, improve the wearability of plastics；
(3), it is cooperated using PTFE, MPPO and PEEK three, matrix temperature capacity is enhanced, to improve plastics
Heat resistance, i.e. high temperature resistance.
Specific embodiment
In order to be easy to understand to technical means, creative features, achievable purpose and effectiveness of the invention, below with reference to tool
Body embodiment, the present invention is further explained.
A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic, it is composed of the following parts by weight: 20~40 parts of PEEK, MPPO
5~10 parts, 18~25 parts of sodium carboxymethylcellulose, 2~5 parts of nano zine oxide, 8~14 parts of PTFE, 3~8 parts of filler,
1~4 part of toner, 3~6 parts of complex type antioxidant.
Filler be diatomite, calcium carbonate, mica powder it is one or more.
Colorant is one of titanium dioxide, nano-titanium dioxide, zinc ring or a variety of.
Complex type antioxidant is 2,8- di-tert-butyl-4-methy phenol.
According to above-mentioned formula proposed the production method is as follows:
A, PEEK, MPPO, sodium carboxymethylcellulose, nano zine oxide and PTFE are uniformly mixed in reaction kettle, and in room temperature
Mixed liquor is made in lower stirring 2-3h after mixing；
B, mixed liquor made from step a is heated to 60-80 DEG C, and sequentially adds filler, colorant and complex type antioxidant,
It is put into molding machine after mixing, molding time is 10-20 minutes, is cooled down to obtain environmentally-friendly plastic after molding.
Embodiment one
A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic, it is composed of the following parts by weight: 20 parts of PEEK, 5 parts of MPPO, carboxylic first
18 parts of base sodium cellulosate, 2 parts of nano zine oxide, 8 parts of PTFE, 3 parts of filler, 1 part of colorant, 3 parts of complex type antioxidant.
Filler is diatomite, and colorant is nano-titanium dioxide, complex type antioxidant 2,8- di-t-butyl -4- methyl
Phenol.
According to above-mentioned formula proposed the production method is as follows:
PEEK, MPPO, sodium carboxymethylcellulose, nano zine oxide and PTFE are uniformly mixed in reaction kettle, and at normal temperature
Mixed liquor is made in stirring 2h after mixing；
B, mixed liquor made from step a is heated to 60 DEG C, and sequentially adds filler, colorant and complex type antioxidant, mixed
It is put into molding machine after conjunction, molding time is 10 minutes, is cooled down to obtain environmentally-friendly plastic after molding.
Embodiment two
A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic, it is composed of the following parts by weight: 22 parts of PEEK, 7 parts of MPPO, carboxylic first
20 parts of base sodium cellulosate, 3 parts of nano zine oxide, 10 parts of PTFE, 5 parts of filler, 2 parts of colorant, 4 parts of complex type antioxidant.
Filler is mica powder, and colorant is nano-titanium dioxide, complex type antioxidant 2,8- di-t-butyl -4- methyl
Phenol.
According to above-mentioned formula proposed the production method is as follows:
A, PEEK, MPPO, sodium carboxymethylcellulose, nano zine oxide and PTFE are uniformly mixed in reaction kettle, and in room temperature
Mixed liquor is made in lower stirring 2.5h after mixing；
B, mixed liquor made from step a is heated to 65 DEG C, and sequentially adds filler, colorant and complex type antioxidant, mixed
It is put into molding machine after conjunction, molding time is 15 minutes, is cooled down to obtain environmentally-friendly plastic after molding.
Embodiment three
A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic, it is composed of the following parts by weight: 25 parts of PEEK, 8 parts of MPPO, carboxylic first
19 parts of base sodium cellulosate, 4 parts of nano zine oxide, 11 parts of PTFE, 4 parts of filler, 3 parts of colorant, 5 parts of complex type antioxidant.
Filler is calcium carbonate, and colorant is nano-titanium dioxide, complex type antioxidant 2,8- di-t-butyl -4- methyl
Phenol.
According to above-mentioned formula proposed the production method is as follows:
A, PEEK, MPPO, sodium carboxymethylcellulose, nano zine oxide and PTFE are uniformly mixed in reaction kettle, and in room temperature
Mixed liquor is made in lower stirring 2.2h after mixing；
B, mixed liquor made from step a is heated to 70 DEG C, and sequentially adds filler, colorant and complex type antioxidant, mixed
It is put into molding machine after conjunction, molding time is 18 minutes, is cooled down to obtain environmentally-friendly plastic after molding.
Example IV
A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic, it is composed of the following parts by weight: 30 parts of PEEK, 7.5 parts of MPPO, carboxylic
22 parts of sodium carboxymethylcellulose pyce, 5 parts of nano zine oxide, 12 parts of PTFE, 6 parts of filler, 3.5 parts of colorant, complex type antioxidant
3.5 part.
Filler is the mixture of mica powder and calcium carbonate, and colorant is zinc ring, complex type antioxidant 2, the tertiary fourth of 8- bis-
Base -4- methylphenol.
According to above-mentioned formula proposed the production method is as follows:
A, PEEK, MPPO, sodium carboxymethylcellulose, nano zine oxide and PTFE are uniformly mixed in reaction kettle, and in room temperature
Mixed liquor is made in lower stirring 2.8h after mixing；
B, mixed liquor made from step a is heated to 68 DEG C, and sequentially adds filler, colorant and complex type antioxidant, mixed
It is put into molding machine after conjunction, molding time is 16 minutes, is cooled down to obtain environmentally-friendly plastic after molding.
Embodiment five
A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic, it is composed of the following parts by weight: 40 parts of PEEK, 10 parts of MPPO, carboxylic
25 parts of sodium carboxymethylcellulose pyce, 5 parts of nano zine oxide, 14 parts of PTFE, 8 parts of filler, 4 parts of colorant, complex type antioxidant 6
Part.
Filler is the mixture of diatomite and calcium carbonate, and colorant is the mixture of titanium dioxide and zinc ring, compound anti-
Oxygen agent is 2,8- di-tert-butyl-4-methy phenol.
According to above-mentioned formula proposed the production method is as follows:
A, PEEK, MPPO, sodium carboxymethylcellulose, nano zine oxide and PTFE are uniformly mixed in reaction kettle, and in room temperature
Mixed liquor is made in lower stirring 2.8h after mixing；
B, mixed liquor made from step a is heated to 80 DEG C, and sequentially adds filler, colorant and complex type antioxidant, mixed
It is put into molding machine after conjunction, molding time is 18 minutes, is cooled down to obtain environmentally-friendly plastic after molding.
One, embodiment two, embodiment three, example IV, embodiment five in conjunction with the embodiments, to made environmentally-friendly plastic into
Row heat-resistant experiment and wear-resisting experiment, experimental result are as follows:
As seen from the above table, it is 558.15K that environmentally-friendly plastic obtained in embodiment two, which has thermal coefficient, and tensile strength is 32 Mpa
High-fire resistance and high-wearing feature, i.e., embodiment is second is that the most preferred scheme of the present invention.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, without departing from the spirit and scope of the present invention, this hair
Bright to will also have various changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The present invention claims
Protection scope is defined by the appending claims and its equivalent thereof.
Claims (5)
1. a kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic, which is characterized in that it is composed of the following parts by weight: PEEK 20~
40 parts, 5~10 parts of MPPO, 18~25 parts of sodium carboxymethylcellulose, 2~5 parts of nano zine oxide, 8~14 parts of PTFE, filling
3~8 parts of agent, 1~4 part of colorant, 3~6 parts of complex type antioxidant.
2. a kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic according to claim 1, it is characterised in that: the filler be diatomite,
Calcium carbonate, mica powder it is one or more.
3. a kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic according to claim 1, it is characterised in that: the colorant be titanium dioxide,
One of nano-titanium dioxide, zinc ring are a variety of.
4. a kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic according to claim 1, it is characterised in that: the complex type antioxidant is 2,
8- di-tert-butyl-4-methy phenol.
5. a kind of production method that Wear-resistant, high-temperature resistant environmentally-friendly plastic is proposed according to claim 1, it is characterised in that:
A. PEEK, MPPO, sodium carboxymethylcellulose, nano zine oxide and PTFE are uniformly mixed in reaction kettle, and in room temperature
Mixed liquor is made in lower stirring 2-3h after mixing；
B. mixed liquor made from step a is heated to 60-80 DEG C, and sequentially adds filler, colorant and complex type antioxidant,
It is put into molding machine after mixing, molding time is 10-20 minutes, is cooled down to obtain environmentally-friendly plastic after molding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811524179.5A CN109486102A (en) | 2018-12-13 | 2018-12-13 | A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811524179.5A CN109486102A (en) | 2018-12-13 | 2018-12-13 | A kind of Wear-resistant, high-temperature resistant environmentally-friendly plastic and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109486102A true CN109486102A (en) | 2019-03-19 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103214788A (en) * | 2013-05-10 | 2013-07-24 | 合肥通用机械研究院 | Wear-resistant, high-strength and light polyether-ether-ketone composite material |
| CN103602040A (en) * | 2013-11-25 | 2014-02-26 | 大连路阳科技开发有限公司 | Self-lubricating wear-resistant polyether-ether-ketone slip sheet and formula and preparation method thereof |
| JP2017179244A (en) * | 2016-03-31 | 2017-10-05 | 住友ベークライト株式会社 | Foamed body and method for producing foamed body |
-
2018
- 2018-12-13 CN CN201811524179.5A patent/CN109486102A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103214788A (en) * | 2013-05-10 | 2013-07-24 | 合肥通用机械研究院 | Wear-resistant, high-strength and light polyether-ether-ketone composite material |
| CN103602040A (en) * | 2013-11-25 | 2014-02-26 | 大连路阳科技开发有限公司 | Self-lubricating wear-resistant polyether-ether-ketone slip sheet and formula and preparation method thereof |
| JP2017179244A (en) * | 2016-03-31 | 2017-10-05 | 住友ベークライト株式会社 | Foamed body and method for producing foamed body |
Non-Patent Citations (3)
| Title |
|---|
| 杨桂生等: "《中国战略性新兴产业.新材料.工程塑料》", 31 December 2017, 中国铁道出版社 * |
| 胡保全 等: "《先进复合材料》", 31 May 2013, 国防工业出版社 * |
| 胡影: "氧化锌/碳纤维/聚醚醚酮复合材料的制备及性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
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Application publication date: 20190319 |