CN109483910A - A kind of composite material vessel dry method winding, molding method - Google Patents

A kind of composite material vessel dry method winding, molding method Download PDF

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Publication number
CN109483910A
CN109483910A CN201811601733.5A CN201811601733A CN109483910A CN 109483910 A CN109483910 A CN 109483910A CN 201811601733 A CN201811601733 A CN 201811601733A CN 109483910 A CN109483910 A CN 109483910A
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CN
China
Prior art keywords
winding
composite material
material vessel
dry method
molding method
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811601733.5A
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Chinese (zh)
Inventor
黄道明
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Shanghai Yidi New Materials Technology Co Ltd
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Shanghai Yidi New Materials Technology Co Ltd
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Priority to CN201811601733.5A priority Critical patent/CN109483910A/en
Publication of CN109483910A publication Critical patent/CN109483910A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

The present invention relates to a kind of composite material vessel dry method winding, molding methods, comprising: heating prepegged strands or prepreg tape are wound to preparatory surface treated mold or liner/inserts surface, form the composite layer of container;There is the organic film of contractility, normal pressure or cure under pressure in the selection winding of composite material layer surface;After the completion of solidification that workpiece is cooling, removal mold and organic film obtain composite material vessel.The features such as short molding cycle of the present invention, high production efficiency, obtained composite material vessel is good with mechanical stability, and bearing capacity stablizes high, product weight and dimensional accuracy height, internal uniform, fine and close, and quality is reproducible, is suitable for military, civil field.

Description

A kind of composite material vessel dry method winding, molding method
Technical field
The invention belongs to field of compound material, in particular to a kind of composite material vessel dry method winding, molding method.
Background technique
Dry method winding is the new process to grow up on the basis of fiber Wet Winding Process, cloth tape wrapping.And use tradition fine The composite material vessel of wet winding technology is tieed up, has and needs the actually linear unstable, molding of one-pass molding finite thickness, fiber Blank is easily-deformable in the process, the production cycle is long, final resin content is high and control accuracy difference, product bearing capacity are low and control essence Degree poor, product weight and dimensional accuracy is low, needs secondary mechanical processing, internal uneven, the low disadvantage of quality repeatability.
CN201510541340 discloses a kind of Carbon Fiber Composite Propeller Shaft pipe dry method winding, molding method, molding In the process using the method by being heated to mold.Energy consumption is high for this method, and it is lower limited to be only applicable to forming temperature Resin types are not suitable for high forming temperature resin system and form the composite material element of low thermally conductive liner/inserts or larger thickness, And there is temperature gradient in thickness in composite material blank layer and surface, blank easily deforms, winding tension size It is limited, influence the molding effect of composite layer.Meanwhile composite material blank layer surface wind one layer of pellosil or Solidified again after PET film, the dry method winding blank layer for not needing pressurization will cause waste, larger solid for needing to apply The dry method winding blank for changing pressure is not all satisfied solidifying requirements using one layer of pellosil or PET film, for needing other sizes Other different layers of organic films or different types of film can be used in the dry method winding blank of solidifying pressure.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of composite material vessel dry method winding, molding method, this method Compared with the dry method winding shaping process of mold heating, molding thickness and resin type are unrestricted, and the linear holding of fiber is more Adding stabilization, forming process and solidification process control are more flexible effective, and interiors of products uniformity is more preferable, and mechanical stability is higher, The available saving control of energy source and power cost, appropriate products field are wider.
The present invention provides a kind of composite material vessel dry method winding, molding methods, comprising:
(1) prepegged strands or prepreg tape are heated, preparatory surface treated mold or liner/inserts table are wound to Face forms the composite layer of internal pressure vessel;
(2) wind after the completion of, composite material layer surface selection winding have contractility organic film, normal pressure or add It is cured;After the completion of solidification that workpiece is cooling, removal mold and organic film obtain composite material vessel.
Prepegged strands or prepreg tape in the step (1) impregnate fiber or fabric by thermosetting property or thermoplastic resin , resin content precision is less than ± 5%, width accuracy and is less than ± 2mm.
Heating prepegged strands or prepreg tape occur suitable resin viscosity to its surface in the step (1), but not make pre- Gel occurs for the resin soaked in yarn or prepreg tape.
The heating method is that hot wind, radiation, fiber be thermally conductive or hot-rolling.
In the step (1) surface treatment include die surface cleaning, coating release agent or patch release cloth, metal or Liner/insert surface roughening of non-metallic material or activation, spray or paste transition zone processing one or more of.
Mold in the step (1) is metal or nonmetal mould;Liner/inserts be metal or nonmetallic liner/ Inserts.
Winding in the step (1) makes prepegged strands or prepreg tape be wound in surface treated mold by the linear of design Or liner/insert surface.
Preferably, the winding process parameter in the step (1) are as follows: winding temperature accuracy is less than ± 8 DEG C, prepegged strands/band Width accuracy is less than ± 2mm, and winding tension is not more than the 80% of fibrous fracture strength, and speed of wrap is not more than 200m/min.
Canoe in the step (1) and (2) includes spiral, plane or circumferential direction.
The pressure of solidification temperature and cure under pressure in the step (2) is according to the resin reaction characteristic in prepegged strands/band It determines.
Beneficial effect
(1) molding cycle of the present invention can foreshorten to 1/2 or less traditional fibre Wet Winding Process;
(2) composite material vessel of same bearing capacity, composite material layer weight of the invention can be wetter than traditional fibre Method winding mitigates 20% or more, and the weight accuracy of composite layer may be controlled within ± 5%;
(3) composite layer of condition of equivalent thickness, bearing capacity of the present invention can be than the pressure-bearing energy of traditional fibre Wet Winding Process Power improves 20% or more;
(4) the quality repeatable accuracy of product of the present invention can improve 30% or more than traditional fibre Wet Winding Process;
(5) compared with the dry method winding shaping process of mold heating, molding thickness of the present invention and resin type are unrestricted, Low heat transfer liner/inserts composite material pressure container, practicable hightension winding, forming process, solidification side can be formed Formula and solidification process control are more flexible effective, more stable, product bearing capacity and the pressure-bearing stability of the linear holding of fiber Higher, dimensional accuracy is higher, and compact structure and uniformity are more preferable, and quality is more stable, the available saving of energy source and power cost Control;
(6) compared with traditional fiber wet-winding craft, strap winding process, existing dry method winding technology, this hair It is bright the operation is more convenient flexibly, be suitable for the bar for having different performance requirement, pipe, tank, ring, spherical shape or aforementioned combinatorial contour structures, The polymer matrix composites layer that different resins and fiber type, winding temperature, winding tension, speed of wrap, solidifying pressure require It is Wrapping formed.
Detailed description of the invention
Fig. 1 is equipment schematic diagram of the invention;Wherein, 1 is prepegged strands/band for mold or inserts or liner, 2, and 3 be effective Heating zone, 4 be conductive filament head, and 5 be heating device.
Fig. 2 is process flow chart of the invention.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention Rather than it limits the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, those skilled in the art Member can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited Range.
Embodiment 1
The molding and solidification of certain thermal insulating liner internal pressure vessel
(1) heating carbon fibre initial rinse yarn is wrapped on the good thermal insulating liner of preforming to 50 DEG C, forms interior pressure-volume The composite layer of device.Wherein, prepegged strands winding temperature control is (50 ± 8) DEG C, prepegged strands bandwidth ± 0.5mm, winding tension 50~80N, 60~80m/min of speed of wrap.
(2) after the completion of winding, 2 layers of organic film, low pressure curing type are wound again on the surface of winding blank;It will after the completion of solidification Workpiece is cooled to room temperature, and removal mold and organic film obtain composite material vessel.
Through detecting, the present embodiment composite material vessel burst pressure is 79MPa, is made with traditional fibre wet-winding craft Identical liner, suitable outer dimension internal pressure vessel burst pressure be 47MPa.
Embodiment 2
The molding and solidification of certain external pressure vessel
(1) heating glass fiber prepegged strands are to 60 DEG C, on the mold after being wrapped in surface treated, form outer pressure-volume The composite layer of device.Wherein, prepegged strands winding temperature control is (60 ± 5) DEG C, prepegged strands bandwidth ± 0.5mm, winding tension 30~50N, 50~60m/min of speed of wrap.
(2) after the completion of winding, normal heating solidification;Workpiece is cooled to room temperature after the completion of solidification, removal mold is answered Condensation material external pressure vessel.
Through 0.1MPa-60MPa-0.1MPa circulation External Hydrostatic Pressure test, the present embodiment composite material external pressure vessel 2000 times Loop test is without destruction, unstable failure when the 7th circulation of composite material external pressure vessel that heating mould obtains under the same terms.
Embodiment 3
The molding and solidification of certain low temperature thin-walled pressure vessel
(1) heating glass fiber prepreg tape on the mold after being wrapped in surface treated, forms container to 50 DEG C Composite layer.Wherein, prepreg tape winding temperature control be (50 ± 3) DEG C, prepegged strands bandwidth ± 0.2mm, winding tension 20~ 25N, 30~40m/min of speed of wrap.
(2) after the completion of winding, normal heating solidification;Workpiece is cooled to room temperature after the completion of solidification, removal mold is answered Condensation material shell.
Through -200 DEG C of helium leak detections, the compactness and uniformity of the present embodiment low temperature thin-walled pressure vessel are good, the helium of wall thickness Gas leak rate≤1 × 10-10Pa·m3/ s, totally 1000 product qualification rates are greater than 95% to 10 batches of continuous production.Under the same terms The container uniformity of fabric wet winding is poor and unstable, and 40% or more is more than leak rate index, batch qualification rate maximum difference 32%.

Claims (9)

1. a kind of composite material vessel dry method winding, molding method, comprising:
(1) prepegged strands or prepreg tape are heated, preparatory surface treated mold or liner/inserts surface, shape are wound to At the composite layer of internal pressure vessel;
(2) after the completion of winding, there is the organic film of contractility in the selection winding of composite material layer surface, normal pressure or pressurization are solid Change;After the completion of solidification that workpiece is cooling, removal mold and organic film obtain composite material vessel.
2. a kind of composite material vessel dry method winding, molding method according to claim 1, it is characterised in that: the step (1) prepegged strands or prepreg tape in impregnate fiber by thermosetting property or thermoplastic resin or fabric obtains, and resin content precision is small It is less than ± 2mm in ± 5%, width accuracy.
3. a kind of composite material vessel dry method winding, molding method according to claim 1, it is characterised in that: the step (1) heating prepegged strands or prepreg tape occur suitable resin viscosity to its surface in, but not make in prepegged strands or prepreg tape Gel occurs for resin.
4. a kind of composite material vessel dry method winding, molding method according to claim 1, it is characterised in that: the heating Mode is that hot wind, radiation, fiber be thermally conductive or hot-rolling.
5. a kind of composite material vessel dry method winding, molding method according to claim 1, it is characterised in that: the step (1) surface treatment in includes the cleaning of die surface, coats release agent or paste the interior of release cloth, metal or non-metallic material Lining/insert surface roughening or activation, spray or paste transition zone processing one or more of.
6. a kind of composite material vessel dry method winding, molding method according to claim 1, it is characterised in that: the step (1) mold in is metal or nonmetal mould;Liner/inserts is metal or nonmetallic liner/inserts.
7. a kind of composite material vessel dry method winding, molding method according to claim 1, it is characterised in that: the step (1) winding in makes prepegged strands or prepreg tape be wound in surface treated mold or liner/insert surface by the linear of design.
8. a kind of composite material vessel dry method winding, molding method according to claim 1 or claim 7, it is characterised in that: described Winding process parameter in step (1) are as follows: winding temperature accuracy is less than ± 8 DEG C, and prepegged strands/bandwidth precision is less than ± 2mm, twines It is not more than the 80% of fibrous fracture strength around tension, speed of wrap is not more than 200m/min.
9. a kind of composite material vessel dry method winding, molding method according to claim 1, it is characterised in that: the step (1) and the canoe in (2) includes spiral, plane or circumferential direction.
CN201811601733.5A 2018-12-26 2018-12-26 A kind of composite material vessel dry method winding, molding method Pending CN109483910A (en)

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Application Number Priority Date Filing Date Title
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CN109483910A true CN109483910A (en) 2019-03-19

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111070736A (en) * 2019-12-13 2020-04-28 上海工程技术大学 Method for improving bending performance of carbon fiber wound metal mixing pipe
CN112297465A (en) * 2020-09-02 2021-02-02 江苏新扬新材料股份有限公司 Large composite material rocket engine shell winding method
CN113650318A (en) * 2021-08-05 2021-11-16 浙江抟原复合材料有限公司 Dry winding forming method for composite material gas cylinder
CN113954400A (en) * 2021-10-15 2022-01-21 上海朗旦复合材料科技有限公司 Method for manufacturing full composite material pressure container
CN115195161A (en) * 2022-07-26 2022-10-18 山东中恒景新碳纤维科技发展有限公司 Manufacturing method of composite material gas cylinder with woven structure and composite material gas cylinder

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CN102642316A (en) * 2012-04-24 2012-08-22 东华大学 Continuous preparation method of composite material tube
CN105058764A (en) * 2015-08-31 2015-11-18 江苏恒神股份有限公司 Dry-method winding formation method for carbon fiber composite transmission axle tube
CN105666842A (en) * 2016-01-27 2016-06-15 余姚中国塑料城塑料研究院有限公司 Processing method of high-temperature thermoplastic composite product

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Publication number Priority date Publication date Assignee Title
CN102642316A (en) * 2012-04-24 2012-08-22 东华大学 Continuous preparation method of composite material tube
CN105058764A (en) * 2015-08-31 2015-11-18 江苏恒神股份有限公司 Dry-method winding formation method for carbon fiber composite transmission axle tube
CN105666842A (en) * 2016-01-27 2016-06-15 余姚中国塑料城塑料研究院有限公司 Processing method of high-temperature thermoplastic composite product

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111070736A (en) * 2019-12-13 2020-04-28 上海工程技术大学 Method for improving bending performance of carbon fiber wound metal mixing pipe
CN111070736B (en) * 2019-12-13 2021-07-23 上海工程技术大学 Method for improving bending performance of carbon fiber wound metal mixing pipe
CN112297465A (en) * 2020-09-02 2021-02-02 江苏新扬新材料股份有限公司 Large composite material rocket engine shell winding method
CN113650318A (en) * 2021-08-05 2021-11-16 浙江抟原复合材料有限公司 Dry winding forming method for composite material gas cylinder
CN113954400A (en) * 2021-10-15 2022-01-21 上海朗旦复合材料科技有限公司 Method for manufacturing full composite material pressure container
CN115195161A (en) * 2022-07-26 2022-10-18 山东中恒景新碳纤维科技发展有限公司 Manufacturing method of composite material gas cylinder with woven structure and composite material gas cylinder
CN115195161B (en) * 2022-07-26 2024-05-24 山东中恒景新碳纤维科技发展有限公司 Manufacturing method of braided structure composite material gas cylinder and composite material gas cylinder

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Application publication date: 20190319