CN106239929A - A kind of making forming method of composite material pipe - Google Patents

A kind of making forming method of composite material pipe Download PDF

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Publication number
CN106239929A
CN106239929A CN201610766758.5A CN201610766758A CN106239929A CN 106239929 A CN106239929 A CN 106239929A CN 201610766758 A CN201610766758 A CN 201610766758A CN 106239929 A CN106239929 A CN 106239929A
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CN
China
Prior art keywords
forming method
making forming
air bag
iron ore
carbon fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610766758.5A
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Chinese (zh)
Inventor
田献京
姚建美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG SHUANGYI TECHNOLOGY Co Ltd
Original Assignee
SHANDONG SHUANGYI TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANDONG SHUANGYI TECHNOLOGY Co Ltd filed Critical SHANDONG SHUANGYI TECHNOLOGY Co Ltd
Priority to CN201610766758.5A priority Critical patent/CN106239929A/en
Publication of CN106239929A publication Critical patent/CN106239929A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • B29L2023/22Tubes or pipes, i.e. rigid

Abstract

The invention discloses the making forming method of a kind of composite material pipe, be specifically related to composite production technical field.The method disclosed in the present comprises the steps: that (1) is entirely pneumatic by air bag, standby;(2) iron ore is filled, as core by internal for the air bag of step (1);(3) mandrel surface in step (2) pastes politef mould, smears hole sealing agent, then smearing release agent after stickup;(4) mandrel surface obtained in step (3) is wound around carbon fiber prepreg, is then around release cloth, heat shrink films;(5) baking oven elevated cure;(6) demoulding.Method provided by the present invention is without shorter mould in the service lifes such as silicone rubber, but uses blowing bag, iron ore, poly tetrafluoroethylene, heat shrink films etc., can effectively reduce cost, improves work efficiency;And gained tubing strength and stiffness are the highest.

Description

A kind of making forming method of composite material pipe
Technical field
The present invention relates to composite production technical field, be specifically related to the making molding side of a kind of composite material pipe Method.
Background technology
In recent years, carbon fiber pipe market development is rapid, is widely used in fields such as automobile, Aero-Space, buildings.China Composite material tube market development is the rapidest, product output continuous expansion, and national industrial policies encourage composite material tube industry Developing to high-tech product direction, domestic enterprise's newly-increased investment project investment gradually increases.Investor is to composite material tube market Concern increasingly closer, this makes composite material tube market increasingly be paid close attention to by each side.Therefore, such as minimum one-tenth It is high that basis, simplest method produce intensity, and the tubing of good rigidity becomes an extremely important problem.
Composite material tube manufacture method mostly is in the market:
1, winding method: this method molding needs wrapping machine, core, solidifying heating furnice, ingot stripper and masterful technique work People, the method is applied to large-sized workshop, and the investment of needs is relatively big, relatively costly.
2, silicone rubber method: its manufacture method is with silicone rubber as core, is wound around fiber cloth (fiber prepreg at silastic surface Material), utilize the principle that silicone rubber expands with heat and contract with cold, during heating, silicone rubber expands, and reaches the size of tubing requirement, lowers the temperature cold after solidification But, silicone rubber shrinkage, become original size, it is simple to the demoulding.Silicone rubber is only 2-3 time service life, so method is relatively costly.
3, air bag method: its manufacture method is using air bag as core, and fiber reinforced plastic mold is external mold, and wherein air bag is only For inner support effect.Owing to filling with air inside air bag, therefore core is softer, tubing inside dimension inaccuracy, product Can be relatively low.
Summary of the invention
The shortcoming of prior art in view of the above, it is an object of the invention to provide the making of a kind of composite material pipe Forming method, in order to improve the problem such as tubing high cost, low-intensity present in prior art.
To achieve these goals or other purposes, the present invention is achieved by the following technical solutions:
The making forming method of a kind of composite material pipe, comprises the steps:
(1) air bag is entirely pneumatic, standby;
(2) air bag after step (1) being inflated is internal fills iron ore, as core;
(3) mandrel surface in step (2) pastes politef mould, smears hole sealing agent, then smear after stickup Releasing agent;
(4) mandrel surface obtained in step (3) is wound around carbon fiber prepreg, is then around release cloth, heat shrink films;
(5) baking oven elevated cure: put in baking oven by the product that step (4) obtains, be warming up to 95-100 DEG C, is incubated 30- 35min, then proceedes to be warming up to 125-130 DEG C, is incubated 30-35min;
(6) demoulding: after insulation terminates in step (5), after baking oven naturally cools to room temperature, product is taken out, by thermal contraction Film, release cloth remove, and are poured out by iron ore, air bag and poly tetrafluoroethylene are removed, obtain composite material pipe.
Further, the diameter after described inflatable bag inflating is identical with pipe diameter.
Further, described air bag can heatproof more than 150 DEG C.
Further, a diameter of 0.2-0.3mm of described iron ore.Further, a diameter of 0.2mm of described iron ore.
Further, the hole sealing agent used in step (3) is that Zyvax Sealer AC (has than international trade purchased from an angstrom method Limit company).
Further, it is 1-4 time that described hole sealing agent smears number of times, and each interval time is 20min.When mould uses for the first time Time, the number of times of smearing of hole sealing agent is 4 times, and each interval time is 20min;When mould is not to use for the first time, hole sealing agent is smeared Number of times only needs once.
Further, the releasing agent used in step (3) is that FLEX-Z-5.0 releasing agent (has than international trade purchased from an angstrom method Limit company), one in Frekote-55NC releasing agent (purchased from Henkel-Le Tai).
Further, the number of times of smearing of described releasing agent is 2-6 time, and each interval time is 20min.When mould makes for the first time Number of times of smearing be 6 times, each interval time is 20min, only need to smear twice when reusing, and time interval is 20min.
Further, the carbon fiber prepreg used in step (4) is available from Jiangsu Tian Niao new and high technology company limited, carbon The 3k plain weave carbon fiber prepreg that fiber content is 59%, glue content is 41%, and carbon fiber content be 60%, glue content be The 150g unidirectional carbon prepreg of 40%.
Wherein, in the present invention, carbon fiber prepreg is the composite semi-finished products that resin is manufactured with carbon fiber, is generally divided into Two kinds of forms of dry and wet make, and carbon fiber prepreg used in the present invention is that wet method makes.
Further, step (4) core mould surface wrap two-layer carbon fiber prepreg, wherein top layer uses 3k plain weave carbon Fiber prepreg material, is 0 ° of winding;Internal layer use 150g unidirectional carbon prepreg, by 0 °/90 °/45 °/-45 °/-45 °/ 45 °/90 °/0 ° mode carries out symmetric layups.
Further, in the present invention release cloth can heatproof more than 150 DEG C, the acting as of release cloth facilitates composite product The demoulding, i.e. realizes goods and separates with mould.
Further, heat shrink films of the present invention is the transparent film material of PVC thermal contraction, can heatproof 150 DEG C with On, provide external pressure for production, it is achieved ensure the effect of product thickness.
Further, in step (5), the speed of twice intensification is 3 DEG C/min.
Further, during step of the present invention (6) demoulding, poly tetrafluoroethylene is not required to remove from air bag, convenient circulation Use.
More than Zong He, the making forming method of the composite material pipe of the present invention, use iron ore to be filled in air bag, energy The effective rigidity ensureing core, because the mobility of iron ore is easy to the demoulding during demoulding.Utilize poly tetrafluoroethylene, it is ensured that The aesthetic property of tube surfaces and stripping result.Use heat shrink films, it is ensured that product surface uniform-compression, structural behaviour is strong.
Method provided by the present invention without shorter mould in the service lifes such as silicone rubber, but use blowing bag, iron ore, Poly tetrafluoroethylene, heat shrink films etc., can effectively reduce cost, improves work efficiency;And gained tubing strength and stiffness are equal Higher.
Accompanying drawing explanation
Fig. 1 is the structural representation of the pipe mold in the present invention obtained by step (4);
Fig. 2 is the schematic cross-section of Fig. 1.
Element numbers
1 iron ore
2 air bags
3 poly tetrafluoroethylenes
4 carbon fiber layers
5 heat shrink films.
Detailed description of the invention
Below by way of particular specific embodiment, embodiments of the present invention being described, those skilled in the art can be by this explanation Content disclosed by book understands other advantages and effect of the present invention easily.The present invention can also be by the most different concrete Embodiment is carried out or applies, and the every details in this specification can also be based on different viewpoints and application, at the not back of the body Various modification or change is carried out under the spirit of the present invention.
Refer to Fig. 1 to Fig. 2.It should be clear that structure depicted in this specification institute accompanying drawings, ratio, size etc., the most only in order to Coordinating the content disclosed in description, understand for those skilled in the art and read, being not limited to the present invention can be real The qualifications executed, therefore do not have technical essential meaning, the modification of any structure, the change of proportionate relationship or the tune of size Whole, under not affecting effect that the present invention can be generated by and the purpose that can reach, all should still fall in disclosed skill In the range of art content obtains and can contain.Meanwhile, in this specification cited as " on ", D score, "left", "right", " middle " and The term of " one " etc., is merely convenient to understanding of narration, and is not used to limit the enforceable scope of the present invention, its relativeness It is altered or modified, is changing under technology contents without essence, when being also considered as the enforceable category of the present invention.
Embodiment 1
The making forming method of a kind of composite material pipe, comprises the steps:
(1) air bag is entirely pneumatic, after inflation a diameter of 30mm of air bag, standby;
(2) iron ore is filled, as core by internal for the air bag of step (1);A diameter of 0.2mm of iron ore;
(3) mandrel surface in step (2) pastes politef mould, smears hole sealing agent, then smear after stickup Releasing agent;
(4) mandrel surface obtained in step (3) is wound around carbon fiber prepreg, is then around release cloth, heat shrink films;
(5) baking oven elevated cure: put in baking oven by the product that step (4) obtains, is warming up to 95 DEG C, is incubated 0.5h, so After be continuously heating to 130 DEG C, be incubated 0.5h, wherein heating rate is 3 DEG C/min;
(6) demoulding: after insulation terminates in step (5), after baking oven naturally cools to room temperature, product is taken out, by thermal contraction Film, release cloth remove, and are poured out by iron ore, air bag and poly tetrafluoroethylene are removed, obtain external diameter 32mm, internal diameter 30mm compound Material pipe.
Embodiment 2
The making forming method of a kind of composite material pipe, comprises the steps:
(1) air bag is entirely pneumatic, after inflation a diameter of 40mm of air bag, standby;
(2) iron ore is filled, as core by internal for the air bag of step (1);A diameter of 0.25mm of iron ore;
(3) mandrel surface in step (2) pastes poly tetrafluoroethylene, smears hole sealing agent, then smear after stickup Releasing agent;
(4) mandrel surface obtained in step (3) is wound around carbon fiber prepreg, is then around release cloth, heat shrink films;
(5) baking oven elevated cure: put in baking oven by the product that step (4) obtains, is warming up to 95 DEG C, is incubated 0.5h, so After be continuously heating to 130 DEG C, be incubated 0.5h, wherein heating rate is 3 DEG C/min;
(6) demoulding: after insulation terminates in step (5), after baking oven naturally cools to room temperature, product is taken out, by thermal contraction Film, release cloth remove, and are poured out by iron ore, air bag and poly tetrafluoroethylene are removed, obtain external diameter 42mm, internal diameter 40mm compound Material pipe.
Comparative example 1
Buying market uses routine to make composite material pipe prepared by forming method winding method, and its step is as follows:
(1) according to tubing specification, Internal core mould is made;
(2) according to specification requirement, fibre lay-up mode is designed;
(3) fibrous layer is rolled onto Internal core mould;
(4) baking hardening;
(5) depoling mould;
(6) grind pipe shaft and make its final product carbon fiber pipe internal diameter 30mm, thickness 1mm.
With reference to GB/T5349-2005 " Test method for longitudinal tensile properties of fiberreinforced thermosetting plastic pipe ", GB/T1446- 2005 " fibre reinforced plastics performance test methods " carry out correlated performance test to aforementioned tubes respectively;Application WDW-100 type is micro- Machine controls electronic universal tester and this above-mentioned composite material pipe is carried out mechanical test, and result shows as follows:
By above-mentioned the performance test results, it can be seen that the composite material pipe prepared by the method for the invention is with existing The tubing having technology to prepare is compared, and the performance such as hot strength, tensile modulus of elasticity, maximum load, breaking load all has and substantially carries High.
The principle of above-described embodiment merely exemplary explanation present invention and effect thereof, not for limiting the present invention.Any ripe Above-described embodiment all can be modified under the spirit and the scope of the present invention or change by the personage knowing this technology.Cause This, have usually intellectual such as complete with institute under technological thought without departing from disclosed spirit in art All equivalences become are modified or change, and must be contained by the claim of the present invention.

Claims (8)

1. the making forming method of a composite material pipe, it is characterised in that comprise the steps:
(1) air bag is entirely pneumatic, standby;
(2) air bag after step (1) being inflated is internal fills iron ore, as core;
(3) mandrel surface in step (2) pastes poly tetrafluoroethylene, smears hole sealing agent, then smear the demoulding after stickup Agent;
(4) mandrel surface obtained in step (3) is wound around carbon fiber prepreg, is then around release cloth, heat shrink films;
(5) baking oven elevated cure: put in baking oven by the product that step (4) obtains, be warming up to 95-100 DEG C, is incubated 30- 35min, then proceedes to be warming up to 125-130 DEG C, is incubated 30-35min;
(6) demoulding: after insulation terminates in step (5), after baking oven naturally cools to room temperature, taken out by product, by heat shrink films, takes off Mould cloth removes, and is poured out by iron ore, air bag and poly tetrafluoroethylene is removed, obtains composite material pipe.
Making forming method the most according to claim 1, it is characterised in that the diameter after described inflatable bag inflating and tubing Diameter is identical.
Making forming method the most according to claim 1, it is characterised in that described air bag can heatproof more than 150 DEG C.
Making forming method the most according to claim 1, it is characterised in that a diameter of 0.2-0.3mm of described iron ore.
Making forming method the most according to claim 1, it is characterised in that step (3) described hole sealing agent is smeared number of times and is 1-4 time, each interval time is 20min.
Making forming method the most according to claim 1, it is characterised in that step (3) described releasing agent smear number of times For 2-6 time, each interval time is 20min.
Making forming method the most according to claim 1, it is characterised in that in step (4), carbon fiber prepreg includes carbon The 3k plain weave carbon fiber prepreg that fiber content is 59%, glue content is 41%, and carbon fiber content be 60%, glue content be The 150g unidirectional carbon prepreg of 40%.
Making forming method the most according to claim 1, it is characterised in that in step (5), the speed of twice intensification is 3 ℃/min。
CN201610766758.5A 2016-08-30 2016-08-30 A kind of making forming method of composite material pipe Pending CN106239929A (en)

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Cited By (10)

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Publication number Priority date Publication date Assignee Title
CN108340596A (en) * 2018-02-10 2018-07-31 湖南狼图腾碳纤维科技有限公司 The production method of integral type buoy
CN108340597A (en) * 2018-02-10 2018-07-31 湖南狼图腾碳纤维科技有限公司 A kind of production method of two-part buoy
CN108908832A (en) * 2018-04-27 2018-11-30 湖南狼图腾碳纤维科技有限公司 A kind of Integral electronic buoy and preparation method thereof
CN109466091A (en) * 2018-07-17 2019-03-15 广州市勇源冰雪运动用品有限公司 A kind of preparation method and ice stick of ice stick
CN110774610A (en) * 2019-11-07 2020-02-11 哈尔滨工业大学 Multi-channel composite material special pipe and forming method thereof
CN110948909A (en) * 2019-12-11 2020-04-03 江苏新扬新材料股份有限公司 Forming method of square equal-section large-size composite material box
CN112477188A (en) * 2020-10-27 2021-03-12 贵州昊华中意环保设备有限公司 Control method of glass fiber reinforced plastic sand inclusion pipe winding machine
CN113524717A (en) * 2020-04-20 2021-10-22 徐涛 Manufacturing process method of hollow light fiber reinforced composite material helical spring
CN113997594A (en) * 2021-10-20 2022-02-01 江苏集萃碳纤维及复合材料应用技术研究院有限公司 Forming method for whistle
CN114518441A (en) * 2022-01-27 2022-05-20 武汉理工大学 Two-dimensional test model and method for simulating tunnel excavation stratum loss

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108340596A (en) * 2018-02-10 2018-07-31 湖南狼图腾碳纤维科技有限公司 The production method of integral type buoy
CN108340597A (en) * 2018-02-10 2018-07-31 湖南狼图腾碳纤维科技有限公司 A kind of production method of two-part buoy
CN108908832A (en) * 2018-04-27 2018-11-30 湖南狼图腾碳纤维科技有限公司 A kind of Integral electronic buoy and preparation method thereof
CN108908832B (en) * 2018-04-27 2020-07-14 湖南狼图腾碳纤维科技有限公司 Integrated electronic buoy and preparation method thereof
CN109466091A (en) * 2018-07-17 2019-03-15 广州市勇源冰雪运动用品有限公司 A kind of preparation method and ice stick of ice stick
CN110774610A (en) * 2019-11-07 2020-02-11 哈尔滨工业大学 Multi-channel composite material special pipe and forming method thereof
CN110948909A (en) * 2019-12-11 2020-04-03 江苏新扬新材料股份有限公司 Forming method of square equal-section large-size composite material box
CN110948909B (en) * 2019-12-11 2021-03-16 江苏新扬新材料股份有限公司 Forming method of square equal-section large-size composite material box
CN113524717A (en) * 2020-04-20 2021-10-22 徐涛 Manufacturing process method of hollow light fiber reinforced composite material helical spring
CN112477188A (en) * 2020-10-27 2021-03-12 贵州昊华中意环保设备有限公司 Control method of glass fiber reinforced plastic sand inclusion pipe winding machine
CN113997594A (en) * 2021-10-20 2022-02-01 江苏集萃碳纤维及复合材料应用技术研究院有限公司 Forming method for whistle
CN114518441A (en) * 2022-01-27 2022-05-20 武汉理工大学 Two-dimensional test model and method for simulating tunnel excavation stratum loss

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Application publication date: 20161221